CN104532274A - Novel water-based paraffin removal cleaning agent for aluminum alloy - Google Patents

Novel water-based paraffin removal cleaning agent for aluminum alloy Download PDF

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Publication number
CN104532274A
CN104532274A CN201410821421.0A CN201410821421A CN104532274A CN 104532274 A CN104532274 A CN 104532274A CN 201410821421 A CN201410821421 A CN 201410821421A CN 104532274 A CN104532274 A CN 104532274A
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CN
China
Prior art keywords
parts
paraffin removal
sodium
water
aluminum alloy
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CN201410821421.0A
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Chinese (zh)
Inventor
杨伟帅
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Suzhou Lotte Chemical Technology Co Ltd
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Suzhou Lotte Chemical Technology Co Ltd
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Priority to CN201410821421.0A priority Critical patent/CN104532274A/en
Publication of CN104532274A publication Critical patent/CN104532274A/en
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G1/00Cleaning or pickling metallic material with solutions or molten salts
    • C23G1/24Cleaning or pickling metallic material with solutions or molten salts with neutral solutions

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)

Abstract

The invention discloses a novel water-based paraffin removal cleaning agent for an aluminum alloy. The cleaning agent is prepared from the following raw materials in parts by weight: 45-55 parts of potassium pyrophosphate, 1.5-3.5 parts of borax, 20-30 parts of sodium dodecyl sulfonate, 10-15 parts of dodecyl benzene sulfonate, 3-5 parts of sodium gluconate, 20-35 parts of fatty alcohol-polyoxyethylene ether, 2-5 parts of sodium benzoate, 3-5 parts of sodium silicate, 5-10 parts of benzotriazole and the balance of pure water. Through the manner, the novel water-based paraffin removal cleaning agent for the aluminum alloy is safe and free of toxic and side effects in use, can be directly prepared by water, and is convenient and simple to operate and high in grease and paraffin removal efficiency of the aluminum alloy. The cleaning efficiency can reach up to 99.9%. The cleaning agent is free of any corrosive effects on the aluminum alloy and the cleaning quality of the aluminum alloy is improved.

Description

The novel water-based paraffin removal clean-out system of a kind of aluminium alloy
Technical field
The present invention relates to paraffin removal clean-out system, particularly relate to the novel water-based paraffin removal clean-out system of a kind of aluminium alloy.
Background technology
Aluminium alloy has excellent physicochemical property and surface treatment properties, applies very extensive.In order to improve its over-all properties, surface smoothness and decorative effect, surface treatment must be carried out to it, reaching result of use.Aluminum alloy surface process mainly contains three kinds of methods: mechanical polishing, chemical rightenning and electrochemical etching.Chemistry and electrochemical etching all will use strong acid and highly basic, producing a large amount of discarded, waste liquid, having a serious impact the health of operator when operating, and simultaneously also seriously pollute physical environment.So, generally mechanical polishing is adopted for aluminium alloy extrusions, but mechanical polishing can need to use aluminium alloy buffing wax, cause aluminum alloy surface can leave a large amount of residual wax, must clean it.
At present, following several method is mainly used in metal paraffin removal, degreasing, degreasing: organic solvent method, chemical method, electrochemical process and Aqueous cleaning machine method etc.Conventional organic solvent can not remove buffing wax completely, and chloride solvent not only toxicity is large, and have hydrolysis to occur, corrosion is had to workpiece, be not suitable for place's wax of aluminium alloy extrusions, and chemical method or electrochemical process can use highly basic or strong acid, also be not suitable for cleaning.
Summary of the invention
The technical problem that the present invention mainly solves is to provide the novel water-based paraffin removal clean-out system of a kind of aluminium alloy, during use, safety non-toxic is secondary, can configure by direct water, simply easy to operate, high to aluminium alloy degreasing paraffin removal efficiency, cleaning efficiency up to 99.9%, and is formed without any corrosive nature aluminium alloy, improves the cleaning quality of aluminium alloy.
For solving the problems of the technologies described above, the invention provides the novel water-based paraffin removal clean-out system of a kind of aluminium alloy, comprising following raw material component and being prepared from:
Potassium pyrophosphate: 45 ~ 55;
Borax: 1.5 ~ 3.5;
Sodium laurylsulfonate: 20 ~ 30;
Sodium dodecylbenzene sulfonate: 10 ~ 15;
Sunmorl N 60S: 3 ~ 5;
Fatty alcohol-polyoxyethylene ether: 20 ~ 35;
Sodium Benzoate: 2 ~ 5;
Water glass: 3 ~ 5;
Benzotriazole: 5 ~ 10;
All the other are pure water.
In the present invention's preferred embodiments, described each raw material component specifically comprises:
Potassium pyrophosphate: 48;
Borax: 2.5;
Sodium laurylsulfonate: 25;
Sodium dodecylbenzene sulfonate: 13;
Sunmorl N 60S: 4.5;
Fatty alcohol-polyoxyethylene ether: 25;
Sodium Benzoate: 4;
Water glass: 4.5;
Benzotriazole: 8;
All the other are pure water.
In the present invention's preferred embodiments, described each raw material component specifically comprises:
Potassium pyrophosphate: 50;
Borax: 3;
Sodium laurylsulfonate: 27.5;
Sodium dodecylbenzene sulfonate: 14.5;
Sunmorl N 60S: 5;
Fatty alcohol-polyoxyethylene ether: 28.5;
Sodium Benzoate: 3.5;
Water glass: 5;
Benzotriazole: 8.5;
All the other are pure water.
In the present invention's preferred embodiments, described Sodium Benzoate and benzotriazole are not AR level.
In the present invention's preferred embodiments, the pH value of described pure water is 6.5 ~ 7.2.
The invention has the beneficial effects as follows: the novel water-based paraffin removal clean-out system of a kind of aluminium alloy of the present invention, during use, safety non-toxic is secondary, can configure by direct water, simply easy to operate, high to aluminium alloy degreasing paraffin removal efficiency, cleaning efficiency up to 99.9%, and is formed without any corrosive nature aluminium alloy, improves the cleaning quality of aluminium alloy.
Embodiment
Be clearly and completely described to the technical scheme in the embodiment of the present invention below, obviously, described embodiment is only a part of embodiment of the present invention, instead of whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art, not making other embodiments all obtained under creative work prerequisite, belong to the scope of protection of the invention.
Embodiment 1
The novel water-based paraffin removal clean-out system of a kind of aluminium alloy, comprises following raw material component and is prepared from:
Potassium pyrophosphate: 45 ~ 55;
Borax: 1.5 ~ 3.5;
Sodium laurylsulfonate: 20 ~ 30;
Sodium dodecylbenzene sulfonate: 10 ~ 15;
Sunmorl N 60S: 3 ~ 5;
Fatty alcohol-polyoxyethylene ether: 20 ~ 35;
Sodium Benzoate: 2 ~ 5;
Water glass: 3 ~ 5;
Benzotriazole: 5 ~ 10;
All the other are pure water.
The preparation method of above-mentioned clean-out system, comprise the steps: by potassium pyrophosphate: 45 ~ 55, borax: 1.5 ~ 3.5, sodium laurylsulfonate: 20 ~ 30, Sodium dodecylbenzene sulfonate: 10 ~ 15, Sunmorl N 60S: 3 ~ 5, fatty alcohol-polyoxyethylene ether: 20 ~ 35, Sodium Benzoate: 2 ~ 5, water glass: 3 ~ 5, benzotriazole: the raw material of 5 ~ 10 is configured, then add pH value be 6.7 pure water carry out stirring and obtain clean-out system finished product.
Embodiment 2
The novel water-based paraffin removal clean-out system of a kind of aluminium alloy, described each raw material component specifically comprises:
Potassium pyrophosphate: 48;
Borax: 2.5;
Sodium laurylsulfonate: 25;
Sodium dodecylbenzene sulfonate: 13;
Sunmorl N 60S: 4.5;
Fatty alcohol-polyoxyethylene ether: 25;
Sodium Benzoate: 4;
Water glass: 4.5;
Benzotriazole: 8;
All the other are pure water.
The preparation method of above-mentioned clean-out system, comprise the steps: by potassium pyrophosphate: 48, borax: 2.5, sodium laurylsulfonate: 25, Sodium dodecylbenzene sulfonate: 13, Sunmorl N 60S: 4.5, fatty alcohol-polyoxyethylene ether: 25, Sodium Benzoate: 4, water glass: 4.8, benzotriazole: the raw material of 8 is configured, then add pH value be 7 pure water carry out stirring and obtain clean-out system finished product.
Embodiment 3
The novel water-based paraffin removal clean-out system of a kind of aluminium alloy, described each raw material component specifically comprises:
Potassium pyrophosphate: 50;
Borax: 3;
Sodium laurylsulfonate: 27.5;
Sodium dodecylbenzene sulfonate: 14.5;
Sunmorl N 60S: 5;
Fatty alcohol-polyoxyethylene ether: 28.5;
Sodium Benzoate: 3.5;
Water glass: 5;
Benzotriazole: 8.5;
All the other are pure water.
The preparation method of above-mentioned clean-out system, comprises the steps: by potassium pyrophosphate: 50; Borax: 3; Sodium laurylsulfonate: 27.5, Sodium dodecylbenzene sulfonate: 14.5, Sunmorl N 60S: 5, fatty alcohol-polyoxyethylene ether: 28.5, Sodium Benzoate: 3.5, water glass: 5, benzotriazole: 8.5, water glass: 5, benzotriazole: the raw material of 8.5 is configured, then add pH value be 7.2 pure water carry out stirring and obtain clean-out system finished product.
The invention has the beneficial effects as follows: the novel water-based paraffin removal clean-out system of a kind of aluminium alloy of the present invention, during use, safety non-toxic is secondary, can configure by direct water, simply easy to operate, high to aluminium alloy degreasing paraffin removal efficiency, cleaning efficiency up to 99.9%, and is formed without any corrosive nature aluminium alloy, improves the cleaning quality of aluminium alloy.
The foregoing is only embodiments of the invention; not thereby the scope of the claims of the present invention is limited; every utilize description of the present invention to do equivalent structure or equivalent flow process conversion; or be directly or indirectly used in other relevant technical field, be all in like manner included in scope of patent protection of the present invention.

Claims (5)

1. the novel water-based paraffin removal clean-out system of aluminium alloy, is characterized in that, comprises following raw material component and is prepared from:
Potassium pyrophosphate: 45 ~ 55;
Borax: 1.5 ~ 3.5;
Sodium laurylsulfonate: 20 ~ 30;
Sodium dodecylbenzene sulfonate: 10 ~ 15;
Sunmorl N 60S: 3 ~ 5;
Fatty alcohol-polyoxyethylene ether: 20 ~ 35;
Sodium Benzoate: 2 ~ 5;
Water glass: 3 ~ 5;
Benzotriazole: 5 ~ 10;
All the other are pure water.
2. the novel water-based paraffin removal clean-out system of aluminium alloy according to claim 1, is characterized in that, described each raw material component specifically comprises:
Potassium pyrophosphate: 48;
Borax: 2.5;
Sodium laurylsulfonate: 25;
Sodium dodecylbenzene sulfonate: 13;
Sunmorl N 60S: 4.5;
Fatty alcohol-polyoxyethylene ether: 25;
Sodium Benzoate: 4;
Water glass: 4.5;
Benzotriazole: 8;
All the other are pure water.
3. the novel water-based paraffin removal clean-out system of aluminium alloy according to claim 1, is characterized in that, described each raw material component specifically comprises:
Potassium pyrophosphate: 50;
Borax: 3;
Sodium laurylsulfonate: 27.5;
Sodium dodecylbenzene sulfonate: 14.5;
Sunmorl N 60S: 5;
Fatty alcohol-polyoxyethylene ether: 28.5;
Sodium Benzoate: 3.5;
Water glass: 5;
Benzotriazole: 8.5;
All the other are pure water.
4. the novel water-based paraffin removal clean-out system of aluminium alloy according to claim 1, is characterized in that, described Sodium Benzoate and benzotriazole are not AR level.
5. the novel water-based paraffin removal clean-out system of aluminium alloy according to claim 1, is characterized in that, the pH value of described pure water is 6.5 ~ 7.2.
CN201410821421.0A 2014-12-26 2014-12-26 Novel water-based paraffin removal cleaning agent for aluminum alloy Pending CN104532274A (en)

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Application Number Priority Date Filing Date Title
CN201410821421.0A CN104532274A (en) 2014-12-26 2014-12-26 Novel water-based paraffin removal cleaning agent for aluminum alloy

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CN104532274A true CN104532274A (en) 2015-04-22

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104894581A (en) * 2015-05-26 2015-09-09 上海臣光工业介质有限公司 Novel aluminum alloy weakly-basic powdered cleaning agent and using method thereof
CN105063645A (en) * 2015-08-06 2015-11-18 苏州好洁清洁器具有限公司 Water base cleaning agent for aluminum alloy pipe
CN105063644A (en) * 2015-08-06 2015-11-18 苏州好洁清洁器具有限公司 Preparation method of water-based cleaning agent for aluminum alloy pipe
CN107059025A (en) * 2017-06-19 2017-08-18 苏州锐耐洁电子科技新材料有限公司 A kind of metal cleaner with antirust function
CN107217273A (en) * 2017-05-27 2017-09-29 湖南工业大学 One kind dewaxing oil removing cleaning agent and its preparation method and application
CN107910246A (en) * 2017-11-10 2018-04-13 北京鼎泰芯源科技发展有限公司 Lower wall method for inp wafer

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101285193A (en) * 2007-04-09 2008-10-15 比亚迪股份有限公司 Acidic solution for treating surface of magnesium alloy and processing method

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101285193A (en) * 2007-04-09 2008-10-15 比亚迪股份有限公司 Acidic solution for treating surface of magnesium alloy and processing method

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104894581A (en) * 2015-05-26 2015-09-09 上海臣光工业介质有限公司 Novel aluminum alloy weakly-basic powdered cleaning agent and using method thereof
CN105063645A (en) * 2015-08-06 2015-11-18 苏州好洁清洁器具有限公司 Water base cleaning agent for aluminum alloy pipe
CN105063644A (en) * 2015-08-06 2015-11-18 苏州好洁清洁器具有限公司 Preparation method of water-based cleaning agent for aluminum alloy pipe
CN107217273A (en) * 2017-05-27 2017-09-29 湖南工业大学 One kind dewaxing oil removing cleaning agent and its preparation method and application
CN107059025A (en) * 2017-06-19 2017-08-18 苏州锐耐洁电子科技新材料有限公司 A kind of metal cleaner with antirust function
CN107910246A (en) * 2017-11-10 2018-04-13 北京鼎泰芯源科技发展有限公司 Lower wall method for inp wafer

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Application publication date: 20150422

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