CN104098951B - A kind of five metals detergent for ink and preparation method thereof - Google Patents
A kind of five metals detergent for ink and preparation method thereof Download PDFInfo
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Abstract
The invention belongs to clean-out system technical field, being specifically related to a kind of five metals detergent for ink and preparation method thereof, does is it made up of the raw material of following weight part: MF-CL? 1 ~ 5 part, MF-EH? 0.5 ~ 3 part, Sodium dodecylbenzene sulfonate 2 ~ 10 parts, tripoly phosphate sodium STPP 1 ~ 5 part, anhydrous sodium metasilicate 1 ~ 5 part, water glass 0.5 ~ 3 part, pure water 70 ~ 95 parts; Five metals detergent for ink of the present invention can not only remove the indissoluble curing inks adhered on ink spraying equipment fast, ensure that good cleaning speed is with cleaning performance, and it is little to the corrodibility of ink spraying equipment, not containing inflammable and explosive composition, all must without the liquid precipitated after mixing with arbitrary proportion with pure water, belong to low toxicity, environment-friendly cleaning agent, little to harm; Preparation method of the present invention is simple to operate, and raw material is easy to get, be easy to preparation, and production cost is low, is conducive to popularity application.
Description
Technical field
The invention belongs to clean-out system technical field, particularly relate to a kind of five metals detergent for ink and preparation method thereof.
Background technology
Ink is usually used in various product external packaging and text printout, in recent years, along with constantly popularizing of China's printing industry color printing technology, in the process of ink printing, needing the ink type often changing different colours, is therefore the important leverage of the high-quality printed matter of printing place to the ink matting that ink spraying printing equipment remains.
Traditional gasoline, kerosene clean-out system is eliminated gradually because of the larger potential safety hazard of inflammable and explosive existence, people have developed water soluble ink scavenger on this basis, but existing water-soluble washing agent mainly adopts butyl glycol ether, the chemical solventss such as N-Methyl pyrrolidone, wherein butyl glycol ether high volatility, in use can produce strong impulse smell, N-Methyl pyrrolidone has stronger toxicity, Long Term Contact can have a strong impact on the healthy of workman, especially poor at operative's environment, be easy under the condition that ventilation effect is bad produce occupational illness, there is etching problem to ink spraying equipment in this kind of clean-out system in addition, the infringement of life-time service to equipment is larger.
Summary of the invention
The object of the invention is to provide a kind of cleaning performance good for the deficiencies in the prior art and low toxicity, environmental protection, the five metals detergent for ink little to harm.
Another object of the present invention is to provide a kind of preparation method of five metals detergent for ink.
To achieve these goals, the present invention by the following technical solutions.
A kind of five metals detergent for ink, it is made up of the raw material of following weight part:
MF-CL1 ~ 5 part
MF-EH0.5 ~ 3 part
Sodium dodecylbenzene sulfonate 2 ~ 10 parts
Tripoly phosphate sodium STPP 1 ~ 5 part
Anhydrous sodium metasilicate 1 ~ 5 part
Water glass 0.5 ~ 3 part
Pure water 70 ~ 95 parts,
Wherein, described MF-CL wins the waterborne anti-rust clean-out system that name that wound Degussa Specialty Chemical company limited produces is called REWOQUATMFCL, for amber color liquid, be 1.06g/cm3 25 DEG C of condition lower densities, pH value is 8-11, viscosity number is 8mPa.s, MF-CL has the remarkable clean ability of deoiling and excellent rust resistance and corrosion resistance ability, thoroughly can not only remove the indissoluble curing inks on ink spraying equipment, and in weakly alkaline, to cast iron, steel, copper, the metals such as aluminium and alloy thereof all have the effect of rust resistance and corrosion resistance, can not cause damage to equipment in cleaning process, the specific cation tensio-active agent contained, wettability is good, anti-static dust-proof, and give clean surface bright property.
Wherein, described MF-EH wins the antirust built surfactant of low temperature oil removing that name that wound Degussa Specialty Chemical company limited produces is called REWOQUATMFEH, for brown liquid, be 0.985g/cm3 25 DEG C of condition lower densities, pH is value 7-10, and viscosity number is 60mPa.s, and MF-EH not only has the remarkable clean ability of deoiling and excellent rust resistance and corrosion resistance ability, and easily degrade, environmental pollution is little.
Preferably, a kind of five metals detergent for ink, it is made up of the raw material of following weight part:
MF-CL2 ~ 4 part
MF-EH1.5 ~ 2.5 part
Sodium dodecylbenzene sulfonate 3 ~ 8 parts
Tripoly phosphate sodium STPP 2 ~ 4 parts
Anhydrous sodium metasilicate 1.5 ~ 4 parts
Water glass 1 ~ 2 part
Pure water 75 ~ 85 parts.
Another is preferred, a kind of five metals detergent for ink, and it is made up of the raw material of following weight part:
MF-CL1 ~ 3 part
MF-EH0.5 ~ 2 part
Sodium dodecylbenzene sulfonate 2 ~ 6 parts
Tripoly phosphate sodium STPP 1 ~ 3 part
Anhydrous sodium metasilicate 1 ~ 2 part
Water glass 0.5 ~ 1.5 part
Pure water 70 ~ 80 parts.
Wherein, described Sodium dodecylbenzene sulfonate is a kind of anion surfactant, and its foaming power is strong, degreasing power is high, easily with multiple additive compound, has significant clean effect to oily dirt.
Wherein, described anhydrous sodium metasilicate is used as clean-out system auxiliary agent, not only strong detergency, and has antiseptic and rustproof effect.
Wherein, described water glass is weakly alkaline, can spray printing equipment surface and form layer protecting film, play good corrosion-resisting function at ink.
After various raw material of the present invention mixes, obtained five metals detergent for ink is not containing poisonous and harmful and inflammable and explosive hazardous chemical, belong to a kind of low-toxicity clean-out system, little to harm, in use to water source, air and soil are all pollution-free, discharge waste liquid can be degraded by microorganisms, belong to a kind of environment-friendly cleaning agent, environmental pollution is little, the indissoluble curing inks adhered on ink spraying equipment can be removed fast, not only ensure that good cleaning speed and cleaning performance, and it is little to the corrodibility of ink spraying equipment, repeatedly use safety is effective, cost is low, there is higher economic and social benefit.
Another is preferred, a kind of five metals detergent for ink, and it is made up of the raw material of following weight part:
MF-CL3 ~ 5 part
MF-EH2 ~ 3 part
Sodium dodecylbenzene sulfonate 6 ~ 10 parts
Tripoly phosphate sodium STPP 3 ~ 5 parts
Anhydrous sodium metasilicate 2 ~ 5 parts
Water glass 1.5 ~ 3 parts
Pure water 80 ~ 95 parts.
Preferred, a kind of five metals detergent for ink, it is made up of the raw material of following weight part:
MF-CL2 part
MF-EH1.5 part
Sodium dodecylbenzene sulfonate 3 parts
Tripoly phosphate sodium STPP 2 parts
Anhydrous sodium metasilicate 1.5 parts
Water glass 1 part
Pure water 75 parts.
Another is preferred, a kind of five metals detergent for ink, and it is made up of the raw material of following weight part:
MF-CL4 part
MF-EH2.5 part
Sodium dodecylbenzene sulfonate 8 parts
Tripoly phosphate sodium STPP 4 parts
Anhydrous sodium metasilicate 4 parts
Water glass 2 parts
Pure water 85 parts.
Another is preferred, a kind of five metals detergent for ink, and it is made up of the raw material of following weight part:
MF-CL3 part
MF-EH2 part
Sodium dodecylbenzene sulfonate 6 parts
Tripoly phosphate sodium STPP 3 parts
Anhydrous sodium metasilicate 2 parts
Water glass 1.5 parts
Pure water 80 parts.
A preparation method for five metals detergent for ink, it comprises following preparation process:
(1) various raw material is taken by described proportioning raw materials;
(2) various raw material mixing and stirring step (1) taken, obtained five metals detergent for ink.
Compared with prior art, the present invention has the following advantages:
(1) five metals detergent for ink of the present invention is not containing poisonous and harmful and inflammable and explosive hazardous chemical, belongs to a kind of low-toxicity clean-out system, little to harm.
(2) five metals detergent for ink of the present invention is in use all pollution-free to water source, air and soil, and discharge waste liquid can be degraded by microorganisms, and belong to a kind of environment-friendly cleaning agent, environmental pollution is little.
(3) five metals detergent for ink of the present invention can not only remove the indissoluble curing inks adhered on ink spraying equipment fast, ensure that good cleaning speed is with cleaning performance, and it is little to the corrodibility of ink spraying equipment, repeatedly use safety is effective, cost is low, has higher economic and social benefit.
(4) preparation method of the present invention is simple to operate, required equipment is few, and raw material is easy to get, be easy to preparation, all must without the liquid precipitated after mixing with arbitrary proportion with pure water, and production cost is low, is conducive to popularity application.
Embodiment
Below in conjunction with specific embodiment, the present invention is described in detail.
embodiment 1.
A kind of five metals detergent for ink, it is made up of the raw material of following weight part: MF-CL1 part, MF-EH0.5 part, Sodium dodecylbenzene sulfonate 2 parts, tripoly phosphate sodium STPP 1 part, anhydrous sodium metasilicate 1 part, water glass 0.5 part, pure water 95 parts.
The present embodiment preparation method, comprise following preparation process:
(1) MF-CL1 part, MF-EH0.5 part, Sodium dodecylbenzene sulfonate 2 parts, tripoly phosphate sodium STPP 1 part, anhydrous sodium metasilicate 1 part, water glass 0.5 part, pure water 95 parts is taken;
(2) various raw material mixing and stirring step (1) taken, obtained five metals detergent for ink.
embodiment 2.
A kind of five metals detergent for ink, it is made up of the raw material of following weight part: MF-CL3 part, MF-EH2 part, Sodium dodecylbenzene sulfonate 6 parts, tripoly phosphate sodium STPP 3 parts, anhydrous sodium metasilicate 2 parts, water glass 1.5 parts, pure water 80 parts.
The present embodiment preparation method, comprise following preparation process:
(1) MF-CL3 part, MF-EH2 part, Sodium dodecylbenzene sulfonate 6 parts, tripoly phosphate sodium STPP 3 parts, anhydrous sodium metasilicate 2 parts, water glass 1.5 parts, pure water 80 parts is taken;
(2) various raw material mixing and stirring step (1) taken, obtained five metals detergent for ink.
embodiment 3.
A kind of five metals detergent for ink, it is made up of the raw material of following weight part: MF-CL5 part, MF-EH3 part, Sodium dodecylbenzene sulfonate 10 parts, tripoly phosphate sodium STPP 5 parts, anhydrous sodium metasilicate 5 parts, water glass 3 parts, pure water 70 parts.
The present embodiment preparation method, comprise following preparation process:
(1) hexanaphthene 80 parts, diacetone alcohol 30 parts, diethylene glycol monobutyl ether 5 parts, dehydrated alcohol 20 parts is taken;
(2) various raw material mixing and stirring step (1) taken, obtained five metals detergent for ink.
embodiment 4.
A kind of five metals detergent for ink, it is made up of the raw material of following weight part: MF-CL2 part, MF-EH1.5 part, Sodium dodecylbenzene sulfonate 3 parts, tripoly phosphate sodium STPP 2 parts, anhydrous sodium metasilicate 1.5 parts, water glass 1 part, pure water 75 parts.
The present embodiment preparation method, comprise following preparation process:
(1) MF-CL2 part, MF-EH1.5 part, Sodium dodecylbenzene sulfonate 3 parts, tripoly phosphate sodium STPP 2 parts, anhydrous sodium metasilicate 1.5 parts, water glass 1 part, pure water 75 parts is taken;
(2) various raw material mixing and stirring step (1) taken, obtained five metals detergent for ink.
embodiment 5.
A kind of five metals detergent for ink, it is made up of the raw material of following weight part: MF-CL4 part, MF-EH2.5 part, Sodium dodecylbenzene sulfonate 8 parts, tripoly phosphate sodium STPP 4 parts, anhydrous sodium metasilicate 4 parts, water glass 2 parts, pure water 85 parts.
The present embodiment preparation method, comprise following preparation process:
(1) MF-CL4 part, MF-EH2.5 part, Sodium dodecylbenzene sulfonate 8 parts, tripoly phosphate sodium STPP 4 parts, anhydrous sodium metasilicate 4 parts, water glass 2 parts, pure water 85 parts is taken;
(2) various raw material mixing and stirring step (1) taken, obtained five metals detergent for ink.
The addition of each component of the five metals detergent for ink of embodiment 1-5 is as shown in table 1.
Table 1.
Component/part | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 |
MF-CL | 1 | 3 | 5 | 2 | 4 |
MF-EH | 0.5 | 2 | 3 | 1.5 | 2.5 |
Sodium dodecylbenzene sulfonate | 2 | 6 | 10 | 3 | 8 |
Tripoly phosphate sodium STPP | 1 | 3 | 5 | 2 | 4 |
Anhydrous sodium metasilicate | 1 | 2 | 5 | 1.5 | 4 |
Water glass | 0.5 | 1.5 | 3 | 1 | 2 |
Pure water | 95 | 80 | 70 | 75 | 85 |
Detect according to the five metals detergent for ink of ROHSDirective2011/65/EU examination criteria to the preparation of embodiment 1-5, concrete detected result is as shown in table 2.
Table 2.
Note: (1) 1mg/Kg=1ppm=0.0001%
(2) MDL=method upper limit of detection
(3) ND=does not detect (< MDL)
(4) "--"=to content no requirement (NR).
Five metals detergent for ink prepared by embodiment 1-5 measures according to EN14582:2007 method, and adopt IC to analyze, concrete detected result is as shown in table 3.
Table 3.
Interpretation of result: the detected result of five metals detergent for ink of the present invention meets ROHSDirective2011/65/EU examination criteria completely, and not containing poisonous and harmful and inflammable and explosive hazardous chemical, belong to a kind of low-toxicity clean-out system, little to harm, not fluorine-containing, chlorine, bromine, the halogenic ingredients such as iodine, in use to water source, air and soil are all pollution-free, discharge waste liquid can be degraded by microorganisms, belong to a kind of environment-friendly cleaning agent, environmental pollution is little, the indissoluble curing inks adhered on ink spraying equipment can not only be removed fast, ensure that good cleaning speed is with cleaning performance, and it is little to the corrodibility of ink spraying equipment, repeatedly use safety is effective, cost is low, there is higher economic and social benefit.
Finally should be noted that; above embodiment is only for illustration of technical scheme of the present invention but not limiting the scope of the invention; although be explained in detail the present invention with reference to preferred embodiment; those of ordinary skill in the art is to be understood that; can modify to technical scheme of the present invention or equivalent replacement, and not depart from essence and the scope of technical solution of the present invention.
Claims (8)
1. a five metals detergent for ink, is characterized in that, it is made up of the raw material of following weight part:
MF-CL1 ~ 5 part
MF-EH0.5 ~ 3 part
Sodium dodecylbenzene sulfonate 2 ~ 10 parts
Tripoly phosphate sodium STPP 1 ~ 5 part
Anhydrous sodium metasilicate 1 ~ 5 part
Water glass 0.5 ~ 3 part
Pure water 70 ~ 95 parts,
Wherein, described MF-CL wins the waterborne anti-rust clean-out system that name that wound Degussa Specialty Chemical company limited produces is called REWOQUATMFCL, forms by nonionic, positively charged ion, zwitterionics and inhibiter are composite;
Wherein, described MF-EH wins the antirust built surfactant of low temperature oil removing that name that wound Degussa Specialty Chemical company limited produces is called REWOQUATMFEH, by positively charged ion with nonionic built surfactant is composite forms.
2. five metals detergent for ink according to claim 1, is characterized in that, it is made up of the raw material of following weight part:
MF-CL2 ~ 4 part
MF-EH1.5 ~ 2.5 part
Sodium dodecylbenzene sulfonate 3 ~ 8 parts
Tripoly phosphate sodium STPP 2 ~ 4 parts
Anhydrous sodium metasilicate 1.5 ~ 4 parts
Water glass 1 ~ 2 part
Pure water 75 ~ 85 parts.
3. five metals detergent for ink according to claim 1, is characterized in that, it is made up of the raw material of following weight part:
MF-CL1 ~ 3 part
MF-EH0.5 ~ 2 part
Sodium dodecylbenzene sulfonate 2 ~ 6 parts
Tripoly phosphate sodium STPP 1 ~ 3 part
Anhydrous sodium metasilicate 1 ~ 2 part
Water glass 0.5 ~ 1.5 part
Pure water 70 ~ 80 parts.
4. five metals detergent for ink according to claim 1, is characterized in that, it is made up of the raw material of following weight part:
MF-CL3 ~ 5 part
MF-EH2 ~ 3 part
Sodium dodecylbenzene sulfonate 6 ~ 10 parts
Tripoly phosphate sodium STPP 3 ~ 5 parts
Anhydrous sodium metasilicate 2 ~ 5 parts
Water glass 1.5 ~ 3 parts
Pure water 80 ~ 95 parts.
5. five metals detergent for ink according to claim 1, is characterized in that, it is made up of the raw material of following weight part:
MF-CL2 part
MF-EH1.5 part
Sodium dodecylbenzene sulfonate 3 parts
Tripoly phosphate sodium STPP 2 parts
Anhydrous sodium metasilicate 1.5 parts
Water glass 1 part
Pure water 75 parts.
6. five metals detergent for ink according to claim 1, is characterized in that, it is made up of the raw material of following weight part:
MF-CL4 part
MF-EH2.5 part
Sodium dodecylbenzene sulfonate 8 parts
Tripoly phosphate sodium STPP 4 parts
Anhydrous sodium metasilicate 4 parts
Water glass 2 parts
Pure water 85 parts.
7. five metals detergent for ink according to claim 1, is characterized in that, it is made up of the raw material of following weight part:
MF-CL3 part
MF-EH2 part
Sodium dodecylbenzene sulfonate 6 parts
Tripoly phosphate sodium STPP 3 parts
Anhydrous sodium metasilicate 2 parts
Water glass 1.5 parts
Pure water 80 parts.
8. the preparation method of the five metals detergent for ink described in claim 1 to 7 any one, is characterized in that, it comprises following preparation process:
(1) various raw material is taken by described proportioning raw materials;
(2) various raw material mixing and stirring step (1) taken, obtained five metals detergent for ink.
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CN105331181B (en) * | 2015-12-07 | 2018-02-13 | 北京印刷学院 | A kind of high performance print detergent for ink and preparation method thereof |
CN112251300B (en) * | 2020-10-26 | 2021-11-23 | 深圳全棉时代科技有限公司 | Cleaning composition and cleaning wet tissue and application thereof |
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CN1640958A (en) * | 2004-01-02 | 2005-07-20 | 鸿富锦精密工业(深圳)有限公司 | Ink detergent |
CN1923917A (en) * | 2005-08-30 | 2007-03-07 | 武汉市江汉区新民印刷厂 | Ink nano cleaning agent |
JP2012158171A (en) * | 2011-01-11 | 2012-08-23 | Ricoh Co Ltd | Cleaning solvent/filling liquid, cartridge containing the same, and methods of cleaning, filling and storing ink jet recording device using the same |
CN102952425A (en) * | 2012-11-19 | 2013-03-06 | 南京信息工程大学 | Water-based printing ink cleaning agent and preparation method thereof |
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Patent Citations (6)
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US4927556A (en) * | 1987-06-04 | 1990-05-22 | Minnesota Mining And Manufacturing Company | Aqueous based composition containing dibasic ester and thickening agent for removing coatings |
EP1188578A1 (en) * | 2000-09-18 | 2002-03-20 | Agfa-Gevaert | Method of lithographic printing with a reusable substrate |
CN1640958A (en) * | 2004-01-02 | 2005-07-20 | 鸿富锦精密工业(深圳)有限公司 | Ink detergent |
CN1923917A (en) * | 2005-08-30 | 2007-03-07 | 武汉市江汉区新民印刷厂 | Ink nano cleaning agent |
JP2012158171A (en) * | 2011-01-11 | 2012-08-23 | Ricoh Co Ltd | Cleaning solvent/filling liquid, cartridge containing the same, and methods of cleaning, filling and storing ink jet recording device using the same |
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Address after: 523000 Pu heart village, two row Town, Shek Pai Town, Guangdong, Dongguan Patentee after: Guangdong Jian Xin Polytron Technologies Inc Address before: 523333, Guangdong City, Dongguan province stone Pai Town, Po two road Jintian restaurant, 100 meters on the left, Dongguan Xin Xin Electronic Materials Co., Ltd. Patentee before: Dongguan Jianxin Electronic Material Co., Ltd. |