CN104098951A - Hardware printing ink cleaning agent and preparation method thereof - Google Patents
Hardware printing ink cleaning agent and preparation method thereof Download PDFInfo
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- CN104098951A CN104098951A CN201310114771.9A CN201310114771A CN104098951A CN 104098951 A CN104098951 A CN 104098951A CN 201310114771 A CN201310114771 A CN 201310114771A CN 104098951 A CN104098951 A CN 104098951A
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Abstract
The invention belongs to the technical field of cleaning agents and especially relates to a handware printing ink cleaning agent and a preparation method thereof. The handware printing ink cleaning agent comprises, by weight, 1-5 parts of MF-CL, 0.5-3 parts of MF-EH, 2-10 parts of sodium dodecyl benzene sulfonate, 1-5 parts of sodium tripolyphosphate, 1-5 parts of anhydrous sodium metasilicate, 0.5-3 parts of sodium silicate and 70-95 parts of purified water. The handware printing ink cleaning agent can fast remove indissolvable cured printing ink adhering to a printing ink spraying device, can guarantee a good cleaning rate and cleaning effects, has small corrosivity to the printing ink spraying device, and does not contain inflammable and explosive ingredients. The handware printing ink cleaning agent and purified water can be mixed into a liquid without precipitates according to any ratios. The handware printing ink cleaning agent belongs to a low-toxicity and eco-friendly cleaning agent and produces small damage on the human body. The preparation method has simple processes, utilizes easily available raw materials, has simple preparation processes and a low production cost and is conducive to general popularization application.
Description
Technical field
The invention belongs to clean-out system technical field, relate in particular to a kind of five metals detergent for ink and preparation method thereof.
Background technology
Ink is usually used in various product external packagings and text printout, in recent years, along with constantly popularizing of China's printing industry color printing technology, in the process of ink printing, needing often to change the ink type of different colours, is therefore the important leverage of the high-quality printed matter of printing place to residual ink matting on ink spraying printing equipment.
Traditional gasoline, kerosene clean-out system is because inflammable and explosive existence is eliminated gradually compared with large potential safety hazard, people have developed water soluble ink scavenger on this basis, but existing water-soluble washing agent mainly adopts butyl glycol ether, the chemical solventss such as N-Methyl pyrrolidone, butyl glycol ether high volatility wherein, in use can produce strong impulse smell, N-Methyl pyrrolidone has stronger toxicity, Long Term Contact can have a strong impact on the healthy of workman, especially poor in workman's operating environment, under the bad condition of ventilation effect, be easy to produce occupational illness, there is etching problem to ink spraying equipment in this class clean-out system in addition, life-time service is larger to the infringement of equipment.
Summary of the invention
The object of the invention is provides the good and low toxicity of a kind of cleaning performance, environmental protection, the five metals detergent for ink little to harm for the deficiencies in the prior art.
Another object of the present invention is to provide a kind of preparation method of five metals detergent for ink.
To achieve these goals, the present invention by the following technical solutions.
A five metals detergent for ink, it is comprised of the raw material of following weight part:
1～5 part of MF-CL
0.5～3 part of MF-EH
2～10 parts of Sodium dodecylbenzene sulfonatees
1～5 part of tripoly phosphate sodium STPP
1～5 part of anhydrous sodium metasilicate
0.5～3 part of water glass
70～95 parts of pure water,
Wherein, described MF-CL is called the waterborne anti-rust clean-out system of REWOQUAT MF CL for winning the name of the extraordinary Chemical Co., Ltd. of wound Degussa production, for amber color liquid, 25 ℃ of condition lower densities, be 1.06g/cm3, pH value is 8-11, viscosity number is 8mPa.s, MF-CL has the remarkable clean ability of deoiling and good rust resistance and corrosion resistance ability, can not only thoroughly remove the indissoluble curing inks on ink spraying equipment, and be weakly alkaline, to cast iron, steel, copper, the metals such as aluminium and alloy thereof all have the effect of rust resistance and corrosion resistance, in cleaning process, can not cause damage to equipment, the specific cation tensio-active agent containing, wettability is good, anti-static dust-proof, and give clean surface bright property.
Wherein, described MF-EH is called the antirust built surfactant of low temperature oil removing of REWOQUAT MF EH for winning the name of the extraordinary Chemical Co., Ltd. of wound Degussa production, for brown liquid, 25 ℃ of condition lower densities, be 0.985g/cm3, pH is value 7-10, and viscosity number is 60mPa.s, and MF-EH not only has the remarkable clean ability of deoiling and good rust resistance and corrosion resistance ability, and easily degraded, environmental pollution is little.
Preferably, a kind of five metals detergent for ink, it is comprised of the raw material of following weight part:
2～4 parts of MF-CL
1.5～2.5 parts of MF-EH
3～8 parts of Sodium dodecylbenzene sulfonatees
2～4 parts of tripoly phosphate sodium STPPs
1.5～4 parts of anhydrous sodium metasilicates
1～2 part of water glass
75～85 parts of pure water.
Another is preferred, a kind of five metals detergent for ink, and it is comprised of the raw material of following weight part:
1～3 part of MF-CL
0.5～2 part of MF-EH
2～6 parts of Sodium dodecylbenzene sulfonatees
1～3 part of tripoly phosphate sodium STPP
1～2 part of anhydrous sodium metasilicate
0.5～1.5 part of water glass
70～80 parts of pure water.
Wherein, described Sodium dodecylbenzene sulfonate is a kind of anion surfactant, and its foaming power is strong, degreasing power is high, easily, with multiple additive compound, oily dirt is had to significant clean effect.
Wherein, described anhydrous sodium metasilicate is as clean-out system auxiliary agent, strong detergency not only, and there is antiseptic and rustproof effect.
Wherein, described water glass is weakly alkaline, can spray printing equipment surface at ink and form layer protecting film, plays good corrosion-resisting function.
After various raw material of the present invention mixes, the five metals detergent for ink making is not containing poisonous and harmful and inflammable and explosive hazardous chemical, belong to a kind of low toxicity type clean-out system, little to harm, in use to water source, air and soil are all pollution-free, discharge waste liquid can be degraded by microorganisms, belong to a kind of environment-friendly cleaning agent, environmental pollution is little, can remove fast the indissoluble curing inks adhering on ink spraying equipment, good cleaning speed and cleaning performance have not only been guaranteed, and little to the corrodibility of ink spraying equipment, repeatedly use safe and effective, cost is low, there is higher economic and social benefit.
Another is preferred, a kind of five metals detergent for ink, and it is comprised of the raw material of following weight part:
3～5 parts of MF-CL
2～3 parts of MF-EH
6～10 parts of Sodium dodecylbenzene sulfonatees
3～5 parts of tripoly phosphate sodium STPPs
2～5 parts of anhydrous sodium metasilicates
1.5～3 parts of water glass
80～95 parts of pure water.
Preferred, a kind of five metals detergent for ink, it is comprised of the raw material of following weight part:
2 parts of MF-CL
1.5 parts of MF-EH
3 parts of Sodium dodecylbenzene sulfonatees
2 parts of tripoly phosphate sodium STPPs
1.5 parts of anhydrous sodium metasilicates
1 part of water glass
75 parts of pure water.
Another is preferred, a kind of five metals detergent for ink, and it is comprised of the raw material of following weight part:
4 parts of MF-CL
2.5 parts of MF-EH
8 parts of Sodium dodecylbenzene sulfonatees
4 parts of tripoly phosphate sodium STPPs
4 parts of anhydrous sodium metasilicates
2 parts of water glass
85 parts of pure water.
Another is preferred, a kind of five metals detergent for ink, and it is comprised of the raw material of following weight part:
3 parts of MF-CL
2 parts of MF-EH
6 parts of Sodium dodecylbenzene sulfonatees
3 parts of tripoly phosphate sodium STPPs
2 parts of anhydrous sodium metasilicates
1.5 parts of water glass
80 parts of pure water.
A preparation method for five metals detergent for ink, it comprises following preparation process:
(1) by described proportioning raw materials, take various raw materials;
(2) the various raw material mixing and stirring that step (1) taken, make five metals detergent for ink.
Compared with prior art, the present invention has the following advantages:
(1) five metals detergent for ink of the present invention, not containing poisonous and harmful and inflammable and explosive hazardous chemical, belongs to a kind of low toxicity type clean-out system, little to harm.
(2) five metals detergent for ink of the present invention is in use all pollution-free to water source, air and soil, and discharge waste liquid can be degraded by microorganisms, and belongs to a kind of environment-friendly cleaning agent, and environmental pollution is little.
(3) five metals detergent for ink of the present invention not only can be removed the indissoluble curing inks adhering on ink spraying equipment fast, guaranteed that good cleaning speed is with cleaning performance, and little to the corrodibility of ink spraying equipment, repeatedly use safe and effective, cost is low, has higher economic and social benefit.
(4) preparation method of the present invention is simple to operate, required equipment is few, and raw material is easy to get, is easy to preparation, all must be without the liquid of precipitation after mixing with arbitrary proportion with pure water, and production cost is low, is conducive to generally apply.
Embodiment
Below in conjunction with specific embodiment, the present invention is described in detail.
embodiment 1.
A five metals detergent for ink, it is comprised of the raw material of following weight part: 1 part of MF-CL, 0.5 part of MF-EH, 2 parts of Sodium dodecylbenzene sulfonatees, 1 part of tripoly phosphate sodium STPP, 1 part of anhydrous sodium metasilicate, 0.5 part of water glass, 95 parts of pure water.
The present embodiment preparation method, comprise following preparation process:
(1) take 1 part of MF-CL, 0.5 part of MF-EH, 2 parts of Sodium dodecylbenzene sulfonatees, 1 part of tripoly phosphate sodium STPP, 1 part of anhydrous sodium metasilicate, 0.5 part of water glass, 95 parts of pure water;
(2) the various raw material mixing and stirring that step (1) taken, make five metals detergent for ink.
embodiment 2.
A five metals detergent for ink, it is comprised of the raw material of following weight part: 3 parts of MF-CL, 2 parts of MF-EH, 6 parts of Sodium dodecylbenzene sulfonatees, 3 parts of tripoly phosphate sodium STPPs, 2 parts of anhydrous sodium metasilicates, 1.5 parts of water glass, 80 parts of pure water.
The present embodiment preparation method, comprise following preparation process:
(1) take 3 parts of MF-CL, 2 parts of MF-EH, 6 parts of Sodium dodecylbenzene sulfonatees, 3 parts of tripoly phosphate sodium STPPs, 2 parts of anhydrous sodium metasilicates, 1.5 parts of water glass, 80 parts of pure water;
(2) the various raw material mixing and stirring that step (1) taken, make five metals detergent for ink.
embodiment 3.
A five metals detergent for ink, it is comprised of the raw material of following weight part: 5 parts of MF-CL, 3 parts of MF-EH, 10 parts of Sodium dodecylbenzene sulfonatees, 5 parts of tripoly phosphate sodium STPPs, 5 parts of anhydrous sodium metasilicates, 3 parts of water glass, 70 parts of pure water.
The present embodiment preparation method, comprise following preparation process:
(1) take 80 parts of hexanaphthenes, 30 parts of diacetone alcohols, 5 parts of diethylene glycol monobutyl ethers, 20 parts of dehydrated alcohols;
(2) the various raw material mixing and stirring that step (1) taken, make five metals detergent for ink.
embodiment 4.
A five metals detergent for ink, it is comprised of the raw material of following weight part: 2 parts of MF-CL, 1.5 parts of MF-EH, 3 parts of Sodium dodecylbenzene sulfonatees, 2 parts of tripoly phosphate sodium STPPs, 1.5 parts of anhydrous sodium metasilicates, 1 part of water glass, 75 parts of pure water.
The present embodiment preparation method, comprise following preparation process:
(1) take 2 parts of MF-CL, 1.5 parts of MF-EH, 3 parts of Sodium dodecylbenzene sulfonatees, 2 parts of tripoly phosphate sodium STPPs, 1.5 parts of anhydrous sodium metasilicates, 1 part of water glass, 75 parts of pure water;
(2) the various raw material mixing and stirring that step (1) taken, make five metals detergent for ink.
embodiment 5.
A five metals detergent for ink, it is comprised of the raw material of following weight part: 4 parts of MF-CL, 2.5 parts of MF-EH, 8 parts of Sodium dodecylbenzene sulfonatees, 4 parts of tripoly phosphate sodium STPPs, 4 parts of anhydrous sodium metasilicates, 2 parts of water glass, 85 parts of pure water.
The present embodiment preparation method, comprise following preparation process:
(1) take 4 parts of MF-CL, 2.5 parts of MF-EH, 8 parts of Sodium dodecylbenzene sulfonatees, 4 parts of tripoly phosphate sodium STPPs, 4 parts of anhydrous sodium metasilicates, 2 parts of water glass, 85 parts of pure water;
(2) the various raw material mixing and stirring that step (1) taken, make five metals detergent for ink.
The addition of each component of the five metals detergent for ink of embodiment 1-5 is as shown in table 1.
Table 1.
| Component/part | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 |
| MF-CL | 1 | 3 | 5 | 2 | 4 |
| MF-EH | 0.5 | 2 | 3 | 1.5 | 2.5 |
| Sodium dodecylbenzene sulfonate | 2 | 6 | 10 | 3 | 8 |
| Tripoly phosphate sodium STPP | 1 | 3 | 5 | 2 | 4 |
| Anhydrous sodium metasilicate | 1 | 2 | 5 | 1.5 | 4 |
| Water glass | 0.5 | 1.5 | 3 | 1 | 2 |
| Pure water | 95 | 80 | 70 | 75 | 85 |
According to ROHS Directive2011/65/EU examination criteria, the five metals detergent for ink of the preparation of embodiment 1-5 is detected, concrete detected result is as shown in table 2.
Table 2.
Note: (1) 1 mg/Kg=1ppm=0.0001%
(2) MDL=method upper limit of detection
(3) ND=does not detect (< MDL)
(4) "--"=to content no requirement (NR).
Five metals detergent for ink prepared by embodiment 1-5 is measured according to EN 14582:2007 method, adopts IC to analyze, and concrete detected result is as shown in table 3.
Table 3.
Interpretation of result: the detected result of five metals detergent for ink of the present invention meets ROHS Directive2011/65/EU examination criteria completely, and not containing poisonous and harmful and inflammable and explosive hazardous chemical, belong to a kind of low toxicity type clean-out system, little to harm, not fluorine-containing, chlorine, bromine, the halogenic ingredients such as iodine, in use to water source, air and soil are all pollution-free, discharge waste liquid can be degraded by microorganisms, belong to a kind of environment-friendly cleaning agent, environmental pollution is little, not only can remove fast the indissoluble curing inks adhering on ink spraying equipment, guaranteed that good cleaning speed is with cleaning performance, and little to the corrodibility of ink spraying equipment, repeatedly use safe and effective, cost is low, there is higher economic and social benefit.
Finally should be noted that; above embodiment is only for illustrating technical scheme of the present invention but not limiting the scope of the invention; although the present invention is explained in detail with reference to preferred embodiment; those of ordinary skill in the art is to be understood that; can modify or be equal to replacement technical scheme of the present invention, and not depart from essence and the scope of technical solution of the present invention.
Claims (8)
1. a five metals detergent for ink, is characterized in that, it is comprised of the raw material of following weight part:
1～5 part of MF-CL
0.5～3 part of MF-EH
2～10 parts of Sodium dodecylbenzene sulfonatees
1～5 part of tripoly phosphate sodium STPP
1～5 part of anhydrous sodium metasilicate
0.5～3 part of water glass
70～95 parts of pure water,
Wherein, described MF-CL is waterborne anti-rust clean-out system, by nonionic, positively charged ion, zwitterionics and inhibiter are composite, forms;
Wherein, described MF-EH is the antirust built surfactant of low temperature oil removing, by positively charged ion with nonionic built surfactant is composite forms.
2. five metals detergent for ink according to claim 1, is characterized in that, it is comprised of the raw material of following weight part:
2～4 parts of MF-CL
1.5～2.5 parts of MF-EH
3～8 parts of Sodium dodecylbenzene sulfonatees
2～4 parts of tripoly phosphate sodium STPPs
1.5～4 parts of anhydrous sodium metasilicates
1～2 part of water glass
75～85 parts of pure water.
3. five metals detergent for ink according to claim 1, is characterized in that, it is comprised of the raw material of following weight part:
1～3 part of MF-CL
0.5～2 part of MF-EH
2～6 parts of Sodium dodecylbenzene sulfonatees
1～3 part of tripoly phosphate sodium STPP
1～2 part of anhydrous sodium metasilicate
0.5～1.5 part of water glass
70～80 parts of pure water.
4. five metals detergent for ink according to claim 1, is characterized in that, it is comprised of the raw material of following weight part:
3～5 parts of MF-CL
2～3 parts of MF-EH
6～10 parts of Sodium dodecylbenzene sulfonatees
3～5 parts of tripoly phosphate sodium STPPs
2～5 parts of anhydrous sodium metasilicates
1.5～3 parts of water glass
80～95 parts of pure water.
5. five metals detergent for ink according to claim 1, is characterized in that, it is comprised of the raw material of following weight part:
2 parts of MF-CL
1.5 parts of MF-EH
3 parts of Sodium dodecylbenzene sulfonatees
2 parts of tripoly phosphate sodium STPPs
1.5 parts of anhydrous sodium metasilicates
1 part of water glass
75 parts of pure water.
6. five metals detergent for ink according to claim 1, is characterized in that, it is comprised of the raw material of following weight part:
4 parts of MF-CL
2.5 parts of MF-EH
8 parts of Sodium dodecylbenzene sulfonatees
4 parts of tripoly phosphate sodium STPPs
4 parts of anhydrous sodium metasilicates
2 parts of water glass
85 parts of pure water.
7. five metals detergent for ink according to claim 1, is characterized in that, it is comprised of the raw material of following weight part:
3 parts of MF-CL
2 parts of MF-EH
6 parts of Sodium dodecylbenzene sulfonatees
3 parts of tripoly phosphate sodium STPPs
2 parts of anhydrous sodium metasilicates
1.5 parts of water glass
80 parts of pure water.
8. the preparation method of the five metals detergent for ink described in claim 1 to 7 any one, is characterized in that, it comprises following preparation process:
(1) by described proportioning raw materials, take various raw materials;
(2) the various raw material mixing and stirring that step (1) taken, make five metals detergent for ink.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310114771.9A CN104098951B (en) | 2013-04-03 | 2013-04-03 | A kind of five metals detergent for ink and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310114771.9A CN104098951B (en) | 2013-04-03 | 2013-04-03 | A kind of five metals detergent for ink and preparation method thereof |
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| CN104098951A true CN104098951A (en) | 2014-10-15 |
| CN104098951B CN104098951B (en) | 2016-01-20 |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105331181A (en) * | 2015-12-07 | 2016-02-17 | 北京印刷学院 | High-performance printing ink detergent and preparing method thereof |
| CN112251300A (en) * | 2020-10-26 | 2021-01-22 | 深圳全棉时代科技有限公司 | Cleaning composition and cleaning wet tissue and application thereof |
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| JP2012158171A (en) * | 2011-01-11 | 2012-08-23 | Ricoh Co Ltd | Cleaning solvent/filling liquid, cartridge containing the same, and methods of cleaning, filling and storing ink jet recording device using the same |
| CN102952425A (en) * | 2012-11-19 | 2013-03-06 | 南京信息工程大学 | Water-based printing ink cleaning agent and preparation method thereof |
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2013
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Patent Citations (6)
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| US4927556A (en) * | 1987-06-04 | 1990-05-22 | Minnesota Mining And Manufacturing Company | Aqueous based composition containing dibasic ester and thickening agent for removing coatings |
| EP1188578A1 (en) * | 2000-09-18 | 2002-03-20 | Agfa-Gevaert | Method of lithographic printing with a reusable substrate |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN105331181A (en) * | 2015-12-07 | 2016-02-17 | 北京印刷学院 | High-performance printing ink detergent and preparing method thereof |
| CN112251300A (en) * | 2020-10-26 | 2021-01-22 | 深圳全棉时代科技有限公司 | Cleaning composition and cleaning wet tissue and application thereof |
| CN112251300B (en) * | 2020-10-26 | 2021-11-23 | 深圳全棉时代科技有限公司 | Cleaning composition and cleaning wet tissue and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104098951B (en) | 2016-01-20 |
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Address after: 523000 Pu heart village, two row Town, Shek Pai Town, Guangdong, Dongguan Patentee after: Guangdong Jian Xin Polytron Technologies Inc Address before: 523333, Guangdong City, Dongguan province stone Pai Town, Po two road Jintian restaurant, 100 meters on the left, Dongguan Xin Xin Electronic Materials Co., Ltd. Patentee before: Dongguan Jianxin Electronic Material Co., Ltd. |