CN104120439A - Environment-friendly type water-based metal cleaning agent and manufacturing method thereof - Google Patents
Environment-friendly type water-based metal cleaning agent and manufacturing method thereof Download PDFInfo
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- CN104120439A CN104120439A CN201410337986.1A CN201410337986A CN104120439A CN 104120439 A CN104120439 A CN 104120439A CN 201410337986 A CN201410337986 A CN 201410337986A CN 104120439 A CN104120439 A CN 104120439A
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Abstract
The invention discloses an environment-friendly type water-based metal cleaning agent and a manufacturing method of the agent. The cleaning agent comprises, by weight, three to 10 percent of silicate lipid compounds and triethanolamine, one percent to 8 percent of sodium carbonate, 1.5 percent to 5 percent of 1,4-butanediol copolymers, five percent to 20 percent of triethanolamine, three percent to 9 percent of nonylphenols polyoxyethylene ether RF-10, three percent to 8 percent of alkanolamine phosphate, two percent to 6 percent of azelaic acid, one percent to four percent of polyethylene glycol, 0.2 percent to four percent of ether defoaming agents SPG-70, 0.5 percent to two percent of mildew-proof sterilizing agents KF88, and the balance water. According to the environment-friendly type water-based metal cleaning agent and the manufacturing method of the agent, the agent is formed by compounding a plurality of solvents and water, and the environment-friendly type water-based metal cleaning agent is uniform and transparent and free of delamination and precipitation liquid, completely meets standard requirements for the anti-rust property and the anti-corrosion property of metal such as cast iron, steel, aluminum and copper, can completely meet use requirements, and is non-poisonous, harmless and green.
Description
Technical field
The present invention relates to a kind of clean-out system and preparation method thereof, relate in particular to a kind of environmentally-friendly water-based metal cleaner and preparation method thereof, for mechanical workout manufacturing metal parts inter process, clean with antirust.
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Background technology
In automobile product and the component manufacturing, use and maintenance process.Often use and clean the various dirts that are attached on product and component surface (as the scrap metal in the course of processing, cutting fluid, abrasive material and various grease, ionogen and the hand perspirations such as dust and acid, alkali, salt, frictional wear product and corrosion product etc.), and reach certain surface clearness, to guarantee carrying out smoothly of manufacturing procedure, eliminate the hidden danger of corrosion of metal and frictional wear, prevent the continuation development of corrosion and wearing and tearing, guarantee product inherence and surface quality, increase the service life.
Metal cleaner has broad variety, and water fluid metal cleaner is representing modern technique and development trend.Aqueous liquid cleansing tensio-active agent, washing assistant, rust-preventive agent, defoamer, mould inhibitor and water etc. in many form.Such clean-out system do not have smell or smell less, can not burn, use safety, operator are endangered little; Use preparation is convenient, cost is low; Cleaning performance is good, has good rust-preventing characteristic, non-corrosibility.Aqueous cleaning agent containing nitrite has fabulous rust-preventing characteristic, but nitrite has severe toxicity, has indirect carcinogenesis effect with common use of trolamine.And often not undesirable containing its rust-preventing characteristic of aqueous cleaning agent of nitrite, cost is high again, and user is reluctant to accept.Therefore, develop a kind of non-toxic, environmental friendly aqueous liquid cleansing, and rust-proof effect can compare favourably with nitrite effect, cost slightly increases or the moderate inevitable choice that just becomes.
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Summary of the invention
Technical problem to be solved by this invention is to provide a kind of environmentally-friendly water-based metal cleaner and preparation method thereof, and cleaning performance is good, has good rust-preventing characteristic, non-corrosibility, and not containing toxicant, belongs to nontoxic, harmless Green Product.
The present invention solves the problems of the technologies described above the technical scheme adopting to be to provide a kind of environmentally-friendly water-based metal cleaner, mainly comprises following component: water, silicic acid lipoid substance and trolamine, sodium carbonate, one or four butyleneglycol multipolymers, trolamine, base phenol polyethenoxy ether RF-10, alkylol amide phosphoric acid ester, nonane diacid, polyoxyethylene glycol, ether defoaming agent SPG-70 and antimildew disinfectant KF88.
Above-mentioned environmentally-friendly water-based metal cleaner, wherein, in described clean-out system, the mass percent of each component is as follows:
Silicic acid lipoid substance and trolamine: 3-10%;
Sodium carbonate: 1-8%;
One or four butyleneglycol multipolymer: 1.5-5%;
Trolamine: 5-20%;
Base phenol polyethenoxy ether RF-10:3-9%;
Alkylol amide phosphoric acid ester: 3-8%;
Nonane diacid: 2-6%;
Polyoxyethylene glycol: 1-4%;
Ether defoaming agent SPG-70:0.2-4%;
Antimildew disinfectant KF88:0.5-2%;
Surplus is water.
The present invention is for solving the problems of the technologies described above the preparation method that a kind of above-mentioned environmentally-friendly water-based metal cleaner is also provided, wherein, comprise the steps: a) first by silicic acid lipoid substance and trolamine ratio mix and blend heating in reactor of 4:3 in mass ratio, heating and temperature control is at 50 ℃, at this temperature, constant temperature is 2 hours, and synthesizing water-solubility silicon compound is as rust-preventive agent monomer; B) in container, add water, be heated to 50 ℃ and remain on this temperature, under agitation slowly add sodium carbonate, one or four butyleneglycol multipolymers, be sufficiently uniformly dissolved; C) in above-mentioned solution, slowly add trolamine, simultaneously stirring and dissolving is even; D) and then slowly add alkylphenol polyoxyethylene RF-10 and alkylol amide amine phosphoric acid ester, stirring and dissolving is even simultaneously; E) finally in above-mentioned solution, slowly add quantitative polyether antifoam agent SPG-70 and antimildew disinfectant KF88, stirring and dissolving is even simultaneously, is final water base metal cleaning agent.
The preparation method of above-mentioned environmentally-friendly water-based metal cleaner, wherein, the quality percentage composition of each component adding in described preparation method is: silicic acid lipoid substance and trolamine: 3-10%; Sodium carbonate: 1-8%; One or four butyleneglycol multipolymer: 1.5-5%; Trolamine: 5-20%; Base phenol polyethenoxy ether RF-10:3-9%; Alkylol amide phosphoric acid ester: 3-8%; Nonane diacid: 2-6%; Polyoxyethylene glycol: 1-4%; Ether defoaming agent SPG-70:0.2-4%; Antimildew disinfectant KF88:0.5-2%; Surplus is water.
The present invention contrasts prior art following beneficial effect: environmentally-friendly water-based metal cleaner provided by the invention and preparation method thereof, by tensio-active agent, washing assistant, rust-preventive agent, solubilizing agent, defoamer, mould inhibitor and water are composite, form, for homogeneous transparent, without layering, without precipitation liquid, to all conformance with standard requirements completely of the rust-preventing characteristic of the metals such as cast iron, steel, aluminium, copper, corrodibility, can meet service requirements completely, and product is nontoxic, harmless, it is Green Product.
Embodiment
Below in conjunction with embodiment, the invention will be further described.
Embodiment 1
(1) first by silicic acid lipoid substance and trolamine ratio mix and blend heating in reactor of 4:3 in mass ratio, heating and temperature control is at 50 ℃, at this temperature, constant temperature is 2 hours, synthesizing water-solubility silicon compound is as rust-preventive agent monomer, and silicic acid lipoid substance and the trolamine quality in preparation total content is 5%;
(2) in container, add water, the mass ratio of water total content in preparation is 55%, is heated to 50 ℃ and remain on this temperature, under agitation slowly adds sodium carbonate, one or four butyleneglycol multipolymers, is sufficiently uniformly dissolved; The mass ratio of sodium carbonate in total content is that the mass ratio of 5%, one four butyleneglycol multipolymer in total content is 2%;
(3) in above-mentioned solution, slowly add trolamine, simultaneously stirring and dissolving is even, the mass ratio of trolamine in total content is 15%;
(4) and then slowly add alkylphenol polyoxyethylene RF-10, alkylol amide amine phosphoric acid ester, stirring and dissolving is even simultaneously; The mass ratio of alkylphenol polyoxyethylene RF-10 in total content is 7%, and the mass ratio of alkylol amide phosphoric acid ester in total content is 4%, and the mass ratio of nonane diacid in total content is 4%, and the mass ratio of polyoxyethylene glycol in total content is 2%;
(5) finally in above-mentioned solution, slowly add quantitative polyether antifoam agent SPG-70, antimildew disinfectant KF88, the mass ratio 0.5% of polyether antifoam agent SPG-70 in total content, the mass ratio 0.5% of antimildew disinfectant KF88 in total content, stirring and dissolving is even simultaneously, is final water base metal cleaning agent.
Embodiment 2
(1) first by silicic acid lipoid substance and trolamine ratio mix and blend heating in reactor of 4:3 in mass ratio, heating and temperature control is at 50 ℃, at this temperature, constant temperature is 2 hours, synthesizing water-solubility silicon compound is as rust-preventive agent monomer, and silicic acid lipoid substance and the trolamine quality in preparation total content is 4%;
(2) in container, add water, the mass ratio of water total content in preparation is 58%, is heated to 50 ℃ and remain on this temperature, under agitation slowly adds sodium carbonate, one or four butyleneglycol multipolymers, is sufficiently uniformly dissolved; The mass ratio of sodium carbonate in total content is that the mass ratio of 8%, one four butyleneglycol multipolymer in total content is 2%;
(3) in above-mentioned solution, slowly add trolamine, simultaneously stirring and dissolving is even, the mass ratio of trolamine in total content is 17%;
(4) and then slowly add alkylphenol polyoxyethylene RF-10, alkylol amide amine phosphoric acid ester, stirring and dissolving is even simultaneously; The mass ratio of alkylphenol polyoxyethylene RF-10 in total content is 3%, and the mass ratio of alkylol amide phosphoric acid ester in total content is 3%, and the mass ratio of nonane diacid in total content is 2%, and the mass ratio of polyoxyethylene glycol in total content is 1%;
(5) finally in above-mentioned solution, slowly add quantitative polyether antifoam agent SPG-70, antimildew disinfectant KF88, the mass ratio 0.5% of polyether antifoam agent SPG-70 in total content, the mass ratio 1.5% of antimildew disinfectant KF88 in total content, stirring and dissolving is even simultaneously, is final water base metal cleaning agent.
Embodiment 3
(1) first by silicic acid lipoid substance and trolamine ratio mix and blend heating in reactor of 4:3 in mass ratio, heating and temperature control is at 50 ℃, at this temperature, constant temperature is 2 hours, synthesizing water-solubility silicon compound is as rust-preventive agent monomer, and silicic acid lipoid substance and the trolamine quality in preparation total content is 8%;
(2) in container, add water, the mass ratio of water total content in preparation is 45%, is heated to 50 ℃ and remain on this temperature, under agitation slowly adds sodium carbonate, one or four butyleneglycol multipolymers, is sufficiently uniformly dissolved; The mass ratio of sodium carbonate in total content is that the mass ratio of 8%, one four butyleneglycol multipolymer in total content is 1%;
(3) in above-mentioned solution, slowly add trolamine, simultaneously stirring and dissolving is even, the mass ratio of trolamine in total content is 17%;
(4) and then slowly add alkylphenol polyoxyethylene RF-10, alkylol amide amine phosphoric acid ester, stirring and dissolving is even simultaneously; The mass ratio of alkylphenol polyoxyethylene RF-10 in total content is 5%, and the mass ratio of alkylol amide phosphoric acid ester in total content is 3%, and the mass ratio of nonane diacid in total content is 6%, and the mass ratio of polyoxyethylene glycol in total content is 4%;
(5) finally in above-mentioned solution, slowly add quantitative polyether antifoam agent SPG-70, antimildew disinfectant KF88, the mass ratio 1.5% of polyether antifoam agent SPG-70 in total content, the mass ratio 1.5% of antimildew disinfectant KF88 in total content, stirring and dissolving is even simultaneously, is final water base metal cleaning agent.
Environmentally-friendly water-based metal cleaner provided by the invention is homogeneous transparent, without layering, nothing, precipitates liquid, be applicable to clean before cast iron, the cleaning of steel part mechanical workout inter process and rust-proof seal, also being applicable to the non-ferrous metal mechanical workout inter processes such as aluminium, copper cleans, can clean various metals material part, combined assembly simultaneously, have that inter process and short-term are antirust, corrosion-resisting function; Can with the process matching such as plating, sprinkling, mopping, can clean by normal temperature, heated wash better effects if, product is nontoxic, harmless, is Green Product.Environmentally-friendly water-based metal cleaner physicochemical property test-results provided by the invention, rust-preventing characteristic, corrodibility to metals such as cast iron, steel, aluminium, copper all can meet service requirements, meet the requirement of the general water base metal cleaning agent > of light industry standard QB/T 2117-1995 < < >, a vapour company standard Q/CA M-169-2006 < < technological process clean-out system and rust-preventive agent > > etc. completely; And carried out control experiment with nitrite type aqueous cleaning agent, experimental result is better than the latter completely.
Although the present invention discloses as above with preferred embodiment; so it is not in order to limit the present invention, any those skilled in the art, without departing from the spirit and scope of the present invention; when doing a little modification and perfect, so protection scope of the present invention is worked as with being as the criterion that claims were defined.
Claims (4)
1. an environmentally-friendly water-based metal cleaner, it is characterized in that, mainly comprise following component: water, silicic acid lipoid substance and trolamine, sodium carbonate, one or four butyleneglycol multipolymers, trolamine, base phenol polyethenoxy ether RF-10, alkylol amide phosphoric acid ester, nonane diacid, polyoxyethylene glycol, ether defoaming agent SPG-70 and antimildew disinfectant KF88.
2. environmentally-friendly water-based metal cleaner as claimed in claim 1, is characterized in that, in described clean-out system, the mass percent of each component is as follows:
Silicic acid lipoid substance and trolamine: 3-10%;
Sodium carbonate: 1-8%;
One or four butyleneglycol multipolymer: 1.5-5%;
Trolamine: 5-20%;
Base phenol polyethenoxy ether RF-10:3-9%;
Alkylol amide phosphoric acid ester: 3-8%;
Nonane diacid: 2-6%;
Polyoxyethylene glycol: 1-4%;
Ether defoaming agent SPG-70:0.2-4%;
Antimildew disinfectant KF88:0.5-2%;
Surplus is water.
3. a preparation method for environmentally-friendly water-based metal cleaner as claimed in claim 1, is characterized in that, comprises the steps:
A) first by silicic acid lipoid substance and trolamine ratio mix and blend heating in reactor of 4:3 in mass ratio, heating and temperature control is at 50 ℃, and at this temperature, constant temperature is 2 hours, and synthesizing water-solubility silicon compound is as rust-preventive agent monomer;
B) in container, add water, be heated to 50 ℃ and remain on this temperature, under agitation slowly add sodium carbonate, one or four butyleneglycol multipolymers, be sufficiently uniformly dissolved;
C) in above-mentioned solution, slowly add trolamine, simultaneously stirring and dissolving is even;
D) and then slowly add alkylphenol polyoxyethylene RF-10 and alkylol amide amine phosphoric acid ester, stirring and dissolving is even simultaneously;
E) finally in above-mentioned solution, slowly add quantitative polyether antifoam agent SPG-70 and antimildew disinfectant KF88, stirring and dissolving is even simultaneously, is final water base metal cleaning agent.
4. the preparation method of environmentally-friendly water-based metal cleaner as claimed in claim 3, is characterized in that, the quality percentage composition of each component adding in described preparation method is: silicic acid lipoid substance and trolamine: 3-10%; Sodium carbonate: 1-8%; One or four butyleneglycol multipolymer: 1.5-5%; Trolamine: 5-20%; Base phenol polyethenoxy ether RF-10:3-9%; Alkylol amide phosphoric acid ester: 3-8%; Nonane diacid: 2-6%; Polyoxyethylene glycol: 1-4%; Ether defoaming agent SPG-70:0.2-4%; Antimildew disinfectant KF88:0.5-2%; Surplus is water.
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| CN201410337986.1A CN104120439A (en) | 2014-07-16 | 2014-07-16 | Environment-friendly type water-based metal cleaning agent and manufacturing method thereof |
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| CN201410337986.1A CN104120439A (en) | 2014-07-16 | 2014-07-16 | Environment-friendly type water-based metal cleaning agent and manufacturing method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105018238A (en) * | 2015-06-30 | 2015-11-04 | 安徽德诺化工有限公司 | Cleaning liquid for sapphire substrate wafer |
| CN107779892A (en) * | 2017-11-03 | 2018-03-09 | 徐州工程学院 | A kind of environmentally-friendly water-based metal cleaner and preparation method thereof |
| EP3392377A4 (en) * | 2015-12-18 | 2018-11-14 | Posco | Composition for washing pickled steel plate, method for washing pickled steel plate by using same, and steel plate obtained thereby |
| WO2020013978A1 (en) * | 2018-07-13 | 2020-01-16 | Bl Technologies, Inc. | An anti-fouling dispersant composition and method of use |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102660752A (en) * | 2012-05-09 | 2012-09-12 | 上海福岛化工科技发展有限公司 | Environment-friendly efficient bubble-free cleaning agent |
| CN102747378A (en) * | 2012-07-24 | 2012-10-24 | 中国第一汽车股份有限公司 | Environment-friendly water-based metal cleaner |
| CN103741156A (en) * | 2013-12-23 | 2014-04-23 | 天津市澳路浦润滑油有限公司 | Water base reaction type multifunctional metal cleaning agent and preparation method thereof |
-
2014
- 2014-07-16 CN CN201410337986.1A patent/CN104120439A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102660752A (en) * | 2012-05-09 | 2012-09-12 | 上海福岛化工科技发展有限公司 | Environment-friendly efficient bubble-free cleaning agent |
| CN102747378A (en) * | 2012-07-24 | 2012-10-24 | 中国第一汽车股份有限公司 | Environment-friendly water-based metal cleaner |
| CN103741156A (en) * | 2013-12-23 | 2014-04-23 | 天津市澳路浦润滑油有限公司 | Water base reaction type multifunctional metal cleaning agent and preparation method thereof |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105018238A (en) * | 2015-06-30 | 2015-11-04 | 安徽德诺化工有限公司 | Cleaning liquid for sapphire substrate wafer |
| EP3392377A4 (en) * | 2015-12-18 | 2018-11-14 | Posco | Composition for washing pickled steel plate, method for washing pickled steel plate by using same, and steel plate obtained thereby |
| US11028322B2 (en) | 2015-12-18 | 2021-06-08 | Posco | Composition for washing pickled steel plate, method for washing pickled steel plate by using same, and steel plate obtained thereby |
| US11332667B2 (en) | 2015-12-18 | 2022-05-17 | Posco | Composition for washing pickled steel plate, method for washing pickled steel plate by using same, and steel plate obtained thereby |
| CN107779892A (en) * | 2017-11-03 | 2018-03-09 | 徐州工程学院 | A kind of environmentally-friendly water-based metal cleaner and preparation method thereof |
| WO2020013978A1 (en) * | 2018-07-13 | 2020-01-16 | Bl Technologies, Inc. | An anti-fouling dispersant composition and method of use |
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Application publication date: 20141029 |