CN102660752A - Environment-friendly efficient bubble-free cleaning agent - Google Patents

Environment-friendly efficient bubble-free cleaning agent Download PDF

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Publication number
CN102660752A
CN102660752A CN201210143014XA CN201210143014A CN102660752A CN 102660752 A CN102660752 A CN 102660752A CN 201210143014X A CN201210143014X A CN 201210143014XA CN 201210143014 A CN201210143014 A CN 201210143014A CN 102660752 A CN102660752 A CN 102660752A
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Prior art keywords
environment
out system
agent
friendly high
cleaning agent
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CN201210143014XA
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Inventor
宋铁成
仲伟兰
宋传军
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SHANGHAI FUDAO CHEMICAL TECHNOLOGY DEVELOPMENT CO LTD
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SHANGHAI FUDAO CHEMICAL TECHNOLOGY DEVELOPMENT CO LTD
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Priority to CN201210143014XA priority Critical patent/CN102660752A/en
Publication of CN102660752A publication Critical patent/CN102660752A/en
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Abstract

The invention discloses an environment-friendly efficient bubble-free cleaning agent which is prepared from the following components in percentage by weight: 10-20% of a composite surfactant, 5-10% of an auxiliary detergent, 5-15% of an antirust agent, 6-13% of triethanolamine, 1-3% of a hard water resisting agent, 2-3% of a sterilizing agent, 0.1-0.3% of a de-foaming agent and the balance of water. The environment-friendly efficient bubble-free cleaning agent has high cleaning speed and is easy to rinse, can efficiently clean oil stains on the surface of a work piece and improves the machining quality; the environment-friendly efficient bubble-free cleaning agent has fewer bubbles and strong seepage force, and a bubble-free property provides guarantee to the use of a high-pressure spraying field; the environment-friendly efficient bubble-free cleaning agent has excellent anti-rusting and anti-corrosion properties, is suitable for a long-period machining process, effectively avoids corroding and rusting of the work pieces, saves the next section of an anti-rusting and anti-corrosion work procedure, saves the production cost, simplifies the machining process and improves the production efficiency; and the green environment-friendly performance and the low odor of the cleaning agent guarantee the physical health of staff.

Description

The still clean-out system of environment-friendly high-efficiency
Technical field
The present invention relates to clean-out system, the still clean-out system of environment-friendly high-efficiency on particularly a kind of clean metal surface.
Background technology
Metal parts, the part of industries such as mechanical means, mechanical workout, automobile steamer production all need routine cleaning, repairing and replacing, and tradition is many comes cleaning components with gasoline, diesel oil as clean-out system, and resource is not only wasted in this cleaning, and contaminate environment.In recent years, the metal cleaner that is exclusively used in the clean metal surface has obtained using widely, can be widely used in oil removing, rust cleaning, the scrubbing operation of metal material surfaces such as aluminum products, brass work, stainless steel, iron, iron and steel, nickel, titanium alloy.This metalloid clean-out system low price, safe in utilization.
At present; Commercially available Industrial Metal rinse product ubiquity that cleaning performance is not enough, anti-rust and anti-corrosion is not enough and the course of processing in the problem of aspects such as foam is big, irritating smell appears; Cause problems such as workpiece corrosion in the course of processing, workpiece surface quality reduction and processing environment deterioration; Greatly reduce process for processing efficient and cost, workman's safety and healthy in serious threat.
Summary of the invention
The technical problem that the present invention will solve is: in order to overcome the problems referred to above, provide a kind of environment-friendly high-efficiency still clean-out system, cleaning performance is good, can wash the greasy dirt of workpiece surface expeditiously, has improved processing quality; The still property of clean-out system is used for the high-pressure spraying occasion assurance is provided; Good protection against corrosion antirust ability is suitable for the complete processing of LP, farm labourer's preface, has avoided the corrosion between the workpiece and gets rusty; This clean-out system environmental protection has guaranteed that the staff's is healthy.
The technical solution adopted for the present invention to solve the technical problems is: the still clean-out system of a kind of environment-friendly high-efficiency, form by following components by weight percent:
Figure BDA00001619390300021
Described complexed surfactant is AEO (AEO), fatty acid alkyl amide (6501, Ninol), TX10 (TX-10, OP-10) sodium oleate, one or more in StNa and the petroleum sodium sulfonate.
Described washing assistant is wherein one or more such as yellow soda ash, water glass, sodium sulfate.
Described rust-preventive agent is organic acid salt, wherein one or more of organic ester, acid amides etc.
Described anti-hard water agent is EDTA Disodium EDTA-two Na, wherein one or both such as ether carboxylic acid.
Described sterilant is wherein one or more such as hexahydrotriazine class, morpholine class, benzisothiazole ketone and derivatives class thereof.
Described skimmer is wherein one or more such as modified organic silicon class, polyethers and esters of acrylic acid.
The invention has the beneficial effects as follows: the clean-out system that the additive of low smell such as the tensio-active agent of the still clean-out system of environment-friendly high-efficiency through selecting effective environmental protection for use, purification agent, antirust rut preventives is mixed with; Cleaning speed is fast; Be prone to rinsing; Can high efficiencyly wash the greasy dirt of workpiece surface, improve processing quality; Foam is few, and seepage force is strong, and the use that still property is the high-pressure spraying occasion provides assurance; The antirust resistance to corrosion that clean-out system is good is suitable for the complete processing of LP, farm labourer's preface, has effectively avoided the corrosion of workpiece inter process and gets rusty; Save the antirust corrosion process of hypomere; For enterprise saves production cost, simplified processing process shortens the process-cycle and enhances productivity; The green environmental protection of clean-out system, low smell property have guaranteed that the staff's is healthy.
Embodiment
Specific embodiment is done further detailed explanation to the present invention now.These these embodiment are interpreted as only being used to the present invention is described and need not limit protection scope of the present invention.After having read content of the present invention, those skilled in the art can do various modifications to the present invention, the variation that these are equivalent and modify the protection domain fall into the present invention equally and limited.
Embodiment one
The still clean-out system of environment-friendly high-efficiency of the present invention selects for use green additive configuration to form, and components by weight percent is following: complexed surfactant AEO 10%, washing assistant yellow soda ash 10%; Rust-preventive agent acid amides 8%; Trolamine 10%, anti-hard water agent ether carboxylic acid 1%, sterilant morpholine 2%; Skimmer polyethers 0.1%, surplus are water.
Preparing method and step are following:
At first, go out the quality of needed water according to the total of required clean-out system.In filling the mediation still of this quality water; Under the normal temperature condition, AEO, yellow soda ash, acid amides are added in the entry in proportion successively, after stirring and dissolving is complete; Add trolamine, ether carboxylic acid, morpholine and polyethers again and in water, be stirred to transparently fully, promptly get.
Embodiment two
The still clean-out system of environment-friendly high-efficiency of the present invention selects for use green additive configuration to form, and components by weight percent is following: complexed surfactant fatty acid alkyl amide (6501, Ninol) 15%; Washing assistant water glass 8%, rust-preventive agent acid amides 15%, trolamine 10%; Anti-hard water agent EDTA-2Na1%; Sterilant hexahydrotriazine 2%, skimmer propenoate 0.1%, surplus is a water.
Preparing method and step are following:
At first, go out the quality of needed water according to the total of required clean-out system.In the mediation still of the water that fills this quality; Under the normal temperature condition, fatty acid alkyl amide, water glass, acid amides are added in the entry in proportion successively, after stirring and dissolving is complete; Add trolamine, EDTA-2Na, hexahydrotriazine and propenoate again and in water, be stirred to transparently fully, promptly get.
Embodiment three
The still clean-out system of environment-friendly high-efficiency of the present invention selects for use green additive configuration to form, and components by weight percent is following: complexed surfactant fatty acid alkyl amide (6501, Ninol) 20%; Washing assistant sodium sulfate 5%, rust-preventive agent sorbitol monooleate 12%, trolamine 6%; Anti-hard water agent EDTA-2Na3%; Sterilant hexahydrotriazine 2.5%, skimmer propenoate 0.2%, surplus is a water.
Preparing method and step are following:
At first, go out the quality of needed water according to the total of required clean-out system.In the mediation still of the water that fills this quality; Under the normal temperature condition; Add in the entry successively fatty acid alkyl amide, sodium sulfate, sorbitol monooleate in proportion; Stirring and dissolving fully after, add trolamine, EDTA-2Na, hexahydrotriazine and propenoate again and in water, be stirred to transparently fully, promptly get.
Embodiment four
The still clean-out system of environment-friendly high-efficiency of the present invention selects for use green additive configuration to form, and components by weight percent is following: complexed surfactant TX10 (TX-10, OP-10) 18%; Washing assistant sodium sulfate 6%, rust-preventive agent sorbitol monooleate 5%, trolamine 13%; Anti-hard water agent ether carboxylic acid 2%; Sterilant benzisothiazole ketone 3%, skimmer propenoate 0.3%, surplus is a water.
Preparing method and step are following:
At first, go out the quality of needed water according to the total of required clean-out system.In the mediation still of the water that fills this quality; Under the normal temperature condition; Add TX10, sodium sulfate, sorbitol monooleate in the entry successively; Stirring and dissolving fully after, add trolamine, ether carboxylic acid and RH-893 and propenoate again and in water, be stirred to transparently fully, promptly get.
Performance index of the present invention such as following table:
Testing experiment result in above table can know: this product degreasing and stupid dirty ability are strong, and 3% aqueous solution washing power has reached 95%.Cleaning speed is fast, is prone to rinsing; Rust protection property is good, and this product not phosphorous and strong acid-base and volatile toxic substance do not injure skin, do not fire not quick-fried, easy to store.Metal especially carbon steel and cast iron had good rust inhibition; Foam is few, and seepage force is strong, is applicable to that cleaning machine carries out spray washing, water-saving, saves time and power saving; Waste liquid can reach a national class standard (GB8978-88) through simple process, and production technique is simple, does not need special production equipment, and investment cost is few, and production cost is low.
More than show and only described principal character of the present invention and inventive point.Those skilled in the art should understand, and the present invention is not restricted to the described embodiments.Under the prerequisite that does not break away from point of the present invention and protection domain, the present invention also has various variations, and these variations and improvement all will fall in the scope of requirement protection of the present invention.The scope that the present invention requires to protect is limited appending claims and equivalent thereof.

Claims (7)

1. still clean-out system of environment-friendly high-efficiency is characterized in that being made up of following components by weight percent:
Figure FDA00001619390200011
2. the still clean-out system of environment-friendly high-efficiency according to claim 1; It is characterized in that: described complexed surfactant is an AEO; Fatty acid alkyl amide, TX10 sodium oleate, one or more in StNa and the petroleum sodium sulfonate.
3. the still clean-out system of environment-friendly high-efficiency according to claim 1 is characterized in that: described washing assistant is one or more in yellow soda ash, water glass, the sodium sulfate.
4. the still clean-out system of environment-friendly high-efficiency according to claim 1 is characterized in that: described rust-preventive agent is one or more in organic acid salt, organic ester, the acid amides.
5. the still clean-out system of environment-friendly high-efficiency according to claim 1 is characterized in that: described anti-hard water agent is one or both in EDTA Disodium, the ether carboxylic acid.
6. the still clean-out system of environment-friendly high-efficiency according to claim 1 is characterized in that: described sterilant is one or more in hexahydrotriazine class, morpholine class, benzisothiazole ketone and the derivatives class thereof.
7. the still clean-out system of environment-friendly high-efficiency according to claim 1 is characterized in that: described skimmer is one or more in modified organic silicon class, polyethers and the esters of acrylic acid.
CN201210143014XA 2012-05-09 2012-05-09 Environment-friendly efficient bubble-free cleaning agent Pending CN102660752A (en)

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Cited By (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103014741A (en) * 2012-11-15 2013-04-03 尹艺颖 Environment-friendly metal degreasing cleaning agent capable of realizing wastewater treatment and preparation method thereof
CN103046059A (en) * 2012-12-17 2013-04-17 厦门科珑精细化工有限公司 Environment-friendly concentrated multifunctional metal cleaning agent and preparation method thereof
CN103046066A (en) * 2013-01-08 2013-04-17 上海尤希路化学工业有限公司 High-performance and environment-friendly water-based cleaning agent
CN104120439A (en) * 2014-07-16 2014-10-29 上海嘉恒热处理有限公司 Environment-friendly type water-based metal cleaning agent and manufacturing method thereof
CN104264170A (en) * 2014-09-28 2015-01-07 无锡康柏斯机械科技有限公司 Cleaning agent for mechanical components and parts and production process of cleaning agent
CN104388216A (en) * 2014-11-14 2015-03-04 无锡信大气象传感网科技有限公司 Electronic element cleaning agent and preparation method thereof
CN104450231A (en) * 2014-11-14 2015-03-25 无锡信大气象传感网科技有限公司 Electronic part washing agent and preparation method thereof
CN105368604A (en) * 2015-12-11 2016-03-02 天津璞誉环保科技开发有限公司 Environment-friendly crude oil washing agent
CN105400606A (en) * 2015-12-16 2016-03-16 无锡吉进环保科技有限公司 Preparation method for cleaning agent for industrial crude oil pipelines
CN105524743A (en) * 2015-12-16 2016-04-27 无锡吉进环保科技有限公司 Industrial crude oil pipeline cleaning agent
CN105780030A (en) * 2016-05-12 2016-07-20 江西瑞思博化工有限公司 Precision metal cleaning agent and preparation method thereof
CN107099395A (en) * 2017-03-29 2017-08-29 广州市极合技术咨询有限公司 A kind of alkaline cleaner and preparation method thereof
CN107267998A (en) * 2017-06-15 2017-10-20 潍坊万方环保科技有限公司 A kind of metal detergent formula and preparation method thereof
CN107418763A (en) * 2017-06-16 2017-12-01 苏州永创达电子有限公司 A kind of iundustrial oil pollution cleanser
CN107587152A (en) * 2017-08-11 2018-01-16 徐州华通浮动油封科技有限公司 A kind of special potent degreasing agent of ironware
CN108754508A (en) * 2018-08-30 2018-11-06 湖北诚祥科技有限公司 Rust-proof type metal cleaner
CN109022171A (en) * 2018-07-26 2018-12-18 苏州瑞奇丽新材料有限公司 A kind of still cleaning agent of high temperature and preparation method thereof
CN109294751A (en) * 2018-10-22 2019-02-01 南京安伦化工科技有限公司 A kind of chemical industry equipment detergent
CN109321372A (en) * 2018-09-20 2019-02-12 南京巨鲨显示科技有限公司 A kind of still cleaning agent
CN109504972A (en) * 2018-12-06 2019-03-22 汎宇化学(昆山)有限公司 Water-soluble washing agent and preparation method thereof
CN111423941A (en) * 2020-05-06 2020-07-17 上海尤希路化学工业有限公司 Water-based cleaning agent for high-efficiency, low-foam and low-residue engine cylinder head and cylinder body terminal assembly process
CN116180097A (en) * 2022-12-20 2023-05-30 广州三孚新材料科技股份有限公司 Nickel alloy phosphorus-free corrosion inhibition cleaning agent and preparation method and use method thereof

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CN101684561A (en) * 2008-09-28 2010-03-31 魏发灿 Efficient metal scavenger
CN101705496A (en) * 2009-11-16 2010-05-12 南通飞拓生物科技有限公司 Environment-friendly metal cleaner
CN101928950A (en) * 2010-09-01 2010-12-29 常州市永丰油脂厂 Metal cleaner used for coating production line and preparation method thereof

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CN101684561A (en) * 2008-09-28 2010-03-31 魏发灿 Efficient metal scavenger
CN101705496A (en) * 2009-11-16 2010-05-12 南通飞拓生物科技有限公司 Environment-friendly metal cleaner
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Cited By (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103014741A (en) * 2012-11-15 2013-04-03 尹艺颖 Environment-friendly metal degreasing cleaning agent capable of realizing wastewater treatment and preparation method thereof
CN103046059A (en) * 2012-12-17 2013-04-17 厦门科珑精细化工有限公司 Environment-friendly concentrated multifunctional metal cleaning agent and preparation method thereof
CN103046059B (en) * 2012-12-17 2015-05-06 厦门科珑精细化工有限公司 Environment-friendly concentrated multifunctional metal cleaning agent and preparation method thereof
CN103046066A (en) * 2013-01-08 2013-04-17 上海尤希路化学工业有限公司 High-performance and environment-friendly water-based cleaning agent
CN103046066B (en) * 2013-01-08 2014-08-27 上海尤希路化学工业有限公司 High-performance and environment-friendly water-based cleaning agent
CN104120439A (en) * 2014-07-16 2014-10-29 上海嘉恒热处理有限公司 Environment-friendly type water-based metal cleaning agent and manufacturing method thereof
CN104264170A (en) * 2014-09-28 2015-01-07 无锡康柏斯机械科技有限公司 Cleaning agent for mechanical components and parts and production process of cleaning agent
CN104388216A (en) * 2014-11-14 2015-03-04 无锡信大气象传感网科技有限公司 Electronic element cleaning agent and preparation method thereof
CN104450231A (en) * 2014-11-14 2015-03-25 无锡信大气象传感网科技有限公司 Electronic part washing agent and preparation method thereof
CN105368604A (en) * 2015-12-11 2016-03-02 天津璞誉环保科技开发有限公司 Environment-friendly crude oil washing agent
CN105400606A (en) * 2015-12-16 2016-03-16 无锡吉进环保科技有限公司 Preparation method for cleaning agent for industrial crude oil pipelines
CN105524743A (en) * 2015-12-16 2016-04-27 无锡吉进环保科技有限公司 Industrial crude oil pipeline cleaning agent
CN105780030A (en) * 2016-05-12 2016-07-20 江西瑞思博化工有限公司 Precision metal cleaning agent and preparation method thereof
CN107099395A (en) * 2017-03-29 2017-08-29 广州市极合技术咨询有限公司 A kind of alkaline cleaner and preparation method thereof
CN107267998A (en) * 2017-06-15 2017-10-20 潍坊万方环保科技有限公司 A kind of metal detergent formula and preparation method thereof
CN107418763A (en) * 2017-06-16 2017-12-01 苏州永创达电子有限公司 A kind of iundustrial oil pollution cleanser
CN107587152A (en) * 2017-08-11 2018-01-16 徐州华通浮动油封科技有限公司 A kind of special potent degreasing agent of ironware
CN109022171A (en) * 2018-07-26 2018-12-18 苏州瑞奇丽新材料有限公司 A kind of still cleaning agent of high temperature and preparation method thereof
CN108754508A (en) * 2018-08-30 2018-11-06 湖北诚祥科技有限公司 Rust-proof type metal cleaner
CN109321372A (en) * 2018-09-20 2019-02-12 南京巨鲨显示科技有限公司 A kind of still cleaning agent
CN109294751A (en) * 2018-10-22 2019-02-01 南京安伦化工科技有限公司 A kind of chemical industry equipment detergent
CN109504972A (en) * 2018-12-06 2019-03-22 汎宇化学(昆山)有限公司 Water-soluble washing agent and preparation method thereof
CN111423941A (en) * 2020-05-06 2020-07-17 上海尤希路化学工业有限公司 Water-based cleaning agent for high-efficiency, low-foam and low-residue engine cylinder head and cylinder body terminal assembly process
CN116180097A (en) * 2022-12-20 2023-05-30 广州三孚新材料科技股份有限公司 Nickel alloy phosphorus-free corrosion inhibition cleaning agent and preparation method and use method thereof

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Application publication date: 20120912