CN108754508A - Rust-proof type metal cleaner - Google Patents
Rust-proof type metal cleaner Download PDFInfo
- Publication number
- CN108754508A CN108754508A CN201811000395.XA CN201811000395A CN108754508A CN 108754508 A CN108754508 A CN 108754508A CN 201811000395 A CN201811000395 A CN 201811000395A CN 108754508 A CN108754508 A CN 108754508A
- Authority
- CN
- China
- Prior art keywords
- rust
- type metal
- proof type
- agent
- cleaning agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
- C23G1/04—Cleaning or pickling metallic material with solutions or molten salts with acid solutions using inhibitors
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
Abstract
The invention discloses a kind of rust-proof type metal cleaner, cleaning agent raw material includes following components by mass percentage：Surfactant 10-15%, antirust agent 10-20%, dispersant 5-10%, antiseptic 3-5%, remaining adds to 100% for deionized water；The surfactant is two kinds or two or more compounds in RhodacleanEFC, RhodacleanMSC, Antarox17R4, Antarox 17R2；Using specific surfactant and antirust agent as main component, it is synergistic, it is a kind of low foam, high antirust, low energy consumption, impurities removal oil type industry aqueous cleaning agent, meet in modern mechanical processing to workpiece surface cleanliness requirements, its waste liquid is through filtering, precipitation or centrifuge remove removal of impurities oil and solid impurity after can reuse again, to reduce injury of the industrial cleaning agent to environment, high-efficiency environment friendly cloth pollutes environment.The rust-proof type metal cleaner of the present invention, the industrial cleaning agent meet cleaning showers requirement in factory's examination with computer, and workpiece degreasing rate is up to 99.8 or more %, and the workpiece rust prevention during manufacture phase was more than 7 days.
Description
Technical field
The present invention relates to a kind of cleaning agent, more particularly to a kind of rust-proof type metal cleaner.
Background technology
In mechanical industry production, either part process and assemble, or seal packet up for safekeeping in heat treatment, plating and product
When dress and unpacking, metal surface will be cleaned.The dirt for being attached to metal surface has various acid, alkali, salt, dust, throwing
The solids fouls such as light cream, cutting fluid, hand perspiration, various greases or liquid dirt.These dirts have water-soluble, also there is oil-soluble
, if not cleaning up, being smoothed out for each manufacturing procedure of metal is not only influenced, but also can cause or accelerate metal erosion,
Product quality is reduced, is shortened the working life.Metal surface cleaning agent has aqueous cleaning agent, solvent cleaner, alkaline cleaner.It is molten
Agent cleaning agent is divided into petroleum solvent cleaning agent and chlorinated hydrocarbon solvent cleaning agent.Petroleum solvent cleaning agent has very strong dirt-removing power,
It is easy to clean the dirt of metal surface, but inflammable and explosive, it is volatile, there is stronger irritation to human central nervous, and easily
Make metal rusting.Meanwhile mass energy is wasted, cause environmental pollution.Chlorinated hydrocarbon solvent cleaning agent cleaning ability is extremely strong, it is easy to
The oily dirt of metal surface is cleaned, but this kind of solvent toxicity is big, it is harmful, it is commonly used in closed cleaning.Aqueous-base cleaning
Agent is using water the characteristics of being good polar solvent, then the wetting by surfactant and osmosis, and pollutant is made to exist
The adhesive force of metal surface weakens, then assists cleaning means that pollutant is made faster to be detached from metal surface, achievees the effect that decontamination.Water
Based cleaning agent is safe and environment-friendly, cheap, and required chemical composition is all easier to obtain, and is to be widely popularized at present therefore
Metal cleaner.The main component of water base metal cleaning agent is surfactant and inorganic assistant；To avoid metal from cleaning
Corrosion occurs in the process with the storage after cleaning in the process, inhibition antirust agent need to be added, common corrosion inhibiter has inorganic oxidation film
Corrosion inhibiter, inorganic precipitation film corrosion inhibiter and organic adsorption film corrosion inhibiter.Inorganic oxide film corrosion inhibiter, inorganic precipitation film corrosion inhibiter are equal
Be using inorganic metal ion metal surface formed film, be attached to metal surface, achieve the effect that inhibition, but if metal from
Sub- density is too small or pH value changes, and is easy to form micro cell in metal surface breakage, has aggravated the corruption of metal surface instead
Erosion.Although therefore safe to use by force using common aqueous cleaning agent cleaning ability, there are probelem in two aspects：On the one hand
It is easy that cleaned workpiece is made to get rusty, on the other hand due to there is foam, is unable to cleaning showers.
Invention content
It is a kind of low foam, Gao Fang in view of this, the purpose of the present invention is to provide a kind of rust-proof type metal cleaner
Rust, low energy consumption, impurities removal oil type industry aqueous cleaning agent meet in modern mechanical processing to workpiece surface cleanliness requirements, waste liquid
Through filtering, precipitation or centrifuge go removal of impurities oil and solid impurity after can reuse again, to reduce industrial cleaning agent to environment
Injury, high-efficiency environment friendly is free from environmental pollution.
The rust-proof type metal cleaner of the present invention, cleaning agent raw material include following components by mass percentage：Surface-active
Agent 10-15%, antirust agent 10-20%, dispersant 5-10%, antiseptic 3-5%, remaining adds to 100% for deionized water；
The surfactant is in RhodacleanEFC, RhodacleanMSC, Antarox17R4, Antarox17R2
Two kinds or two or more compounds；
The antirust agent is C11-C14Dicarboxylic acids, C11-C14Tricarboxylic acid, modified inclined silication ethanol amine, isomery alcohol
Three kinds or three kinds or more compounds in amine, AMP-95, NEUF715；
Further, cleaning agent raw material includes following components by mass percentage：Surfactant 13%, antirust agent 15%,
Dispersant 7%, antiseptic 4%, remaining adds to 100% for deionized water；
Further, the dispersant be Sodium Polyacrylate, sodium gluconate, two kinds or two kinds in nitrilotriacetic acid with
Upper compound.
Further, the antiseptic is the mixture of morpholine derivative and 1,2-benzisothiazolin-3-one (BIT)；
Further, the morpholine derivative and the mass ratio of 1,2-benzisothiazolin-3-one are 3:2.
Beneficial effects of the present invention：The rust-proof type metal cleaner of the present invention, belongs to aqueous cleaning agent, with specific surface
Activating agent and antirust agent are main component, synergistic, are that a kind of low foam, high antirust, low energy consumption, impurities removal oil type industry are water base
Cleaning agent meets to workpiece surface cleanliness requirements in modern mechanical processing, and waste liquid is through filtering, precipitation or centrifugation removal
After miscellaneous oil and solid impurity can reuse again, to reduce injury of the industrial cleaning agent to environment, high-efficiency environment friendly cloth pollutes environment.This
The rust-proof type metal cleaner of invention, the industrial cleaning agent meet cleaning showers requirement, workpiece degreasing in factory's examination with computer
Rate is up to 99.8 or more %, and the workpiece rust prevention during manufacture phase was more than 7 days.
Specific implementation mode
The rust-proof type metal cleaner of the present embodiment, cleaning agent raw material include following components by mass percentage：It lives on surface
Property agent 10-15%, antirust agent 10-20%, dispersant 5-10%, antiseptic 3-5%, remaining adds to 100% for deionized water；
The surfactant is in RhodacleanEFC, RhodacleanMSC, Antarox17R4, Antarox17R2
Two kinds or two or more compounds；Rhodoclean EFC&MSC are the enol compounding agents of Solvay companies production, are branch
Effective substitute of chain fatty alcohol ether, excellent hard-surface cleaning and wettability, to ph stability；Antarox17R4/
17R2 belongs to nonionic surfactant, and ingredient is epoxy ethane-epoxy propane block compound.
The antirust agent is C11-C14Dicarboxylic acids, C11-C14Tricarboxylic acid, modified inclined silication ethanol amine, isomery alcohol
Three kinds or three kinds or more compounds in amine, AMP-95, NEUF715；AMP-95 contains 5% moisture content -2- amino -2- first
Base -1- propyl alcohol, which is current minority, has one of low molecular weight and overbasic industrial amine.
In the present embodiment, cleaning agent raw material includes following components by mass percentage：Surfactant 13%, antirust agent
15%, dispersant 7%, antiseptic 4%, remaining adds to 100% for deionized water；For preferred embodiments.
In the present embodiment, the dispersant is two kinds or two in Sodium Polyacrylate, sodium gluconate, nitrilotriacetic acid
Kind or more compound.
In the present embodiment, the antiseptic is the mixture of morpholine derivative and 1,2-benzisothiazolin-3-one.
In the present embodiment, the mass ratio of the morpholine derivative and 1,2-benzisothiazolin-3-one is 3:2.
Embodiment one
The rust-proof type metal cleaner of the present embodiment, cleaning agent raw material include following components by mass percentage：It lives on surface
Property agent 10%, antirust agent 10%, dispersant 5%, antiseptic 3%, remaining adds to 100% for deionized water；
In the present embodiment, the surfactant is RhodacleanEFC and the mixture of RhodacleanMSC；Institute
It is C to state antirust agent11-C14Dicarboxylic acids and C11-C14Tricarboxylic acid mixture；The dispersant be Sodium Polyacrylate and
The mixture of sodium gluconate；The antiseptic is the mixture of morpholine derivative and 1,2-benzisothiazolin-3-one, described
The mass ratio of morpholine derivative and 1,2- benzisothiazole-3-ketones is 3:2.
Embodiment two
The rust-proof type metal cleaner of the present embodiment, cleaning agent raw material include following components by mass percentage：It lives on surface
Property agent 15%, antirust agent 20%, dispersant 10%, antiseptic 5%, remaining adds to 100% for deionized water；
In the present embodiment, the surfactant is the mixture of RhodacleanMSC and Antarox17R4；It is described anti-
Rust agent is C11-C14Tricarboxylic acid and modified inclined silication ethanol amine mixture；The dispersant is sodium gluconate and nitrilo
The mixture of triacetic acid；The antiseptic is the mixture of morpholine derivative and 1,2-benzisothiazolin-3-one, the morpholine
The mass ratio of derivative and 1,2- benzisothiazole-3-ketones is 3:2.
Embodiment three
The rust-proof type metal cleaner of the present embodiment, cleaning agent raw material include following components by mass percentage：It lives on surface
Property agent 10%, antirust agent 20%, dispersant 5%, antiseptic 5%, remaining adds to 100% for deionized water；
In the present embodiment, the surfactant be RhodacleanEFC, RhodacleanMSC, Antarox17R4 and
Antar:The mixture of ox 17R2；The antirust agent is C11-C14Dicarboxylic acids, C11-C14Tricarboxylic acid and isomery hydramine
Mixture；The dispersant is the mixture of Sodium Polyacrylate, sodium gluconate and nitrilotriacetic acid；The antiseptic be
The mixture of quinoline derivant and 1,2-benzisothiazolin-3-one, the morpholine derivative and 1,2-benzisothiazolin-3-one
Mass ratio be 3：2.
Example IV
The rust-proof type metal cleaner of the present embodiment, cleaning agent raw material include following components by mass percentage：It lives on surface
Property agent 15%, antirust agent 10%, dispersant 10%, antiseptic 3%, remaining adds to 100% for deionized water；
In the present embodiment, the surfactant is the mixture of Antarox17R4 and Antarox 17R2；The antirust
Agent is C11-C14Dicarboxylic acids, C11-C14Tricarboxylic acid AMP-95 and NEUF715 mixture；The dispersant is poly- third
The mixture of olefin(e) acid sodium and nitrilotriacetic acid；The antiseptic is the mixed of morpholine derivative and 1,2- benzisothiazole-3-ketones
The mass ratio of conjunction object, the morpholine derivative and 1,2-benzisothiazolin-3-one is 3:2.
Embodiment five
The rust-proof type metal cleaner of the present embodiment, cleaning agent raw material include following components by mass percentage：It lives on surface
Property agent 12%, antirust agent 17%, dispersant 6%, antiseptic 4%, remaining adds to 100% for deionized water；
In the present embodiment, the surfactant is the mixture of RhodacleanEFC and Antarox 17R2；It is described anti-
Rust agent is C11-C14Dicarboxylic acids, C11-C14Tricarboxylic acid, AMP-95 and NEUF715 mixture；The dispersant is poly-
The mixture of sodium acrylate, sodium gluconate and nitrilotriacetic acid；The antiseptic is morpholine derivative and 1,2- benzisothias
The mass ratio of the mixture of oxazoline -3- ketone, the morpholine derivative and 1,2-benzisothiazolin-3-one is 3:2.
Embodiment six
The rust-proof type metal cleaner of the present embodiment, cleaning agent raw material include following components by mass percentage：It lives on surface
Property agent 13%, antirust agent 15%, dispersant 7%, antiseptic 4%, remaining adds to 100% for deionized water；
In the present embodiment, the surfactant is the mixture of RhodacleanMSC and Antarox 17R2；It is described anti-
Rust agent is C11-C14Dicarboxylic acids, C11-C14Tricarboxylic acid, modified inclined silication ethanol amine, isomery hydramine, AMP-95 and
The mixture of NEUF715；The dispersant is the mixture of Sodium Polyacrylate, sodium gluconate and nitrilotriacetic acid；It is described anti-
Microbial inoculum is the mixture of morpholine derivative and 1,2-benzisothiazolin-3-one, the morpholine derivative and 1,2- benzisothias
The mass ratio of oxazoline -3- ketone is 3:2.
In above-described embodiment, NEUF715 is Hefei promise Thailand novel corrosion inhibitor.
Finally illustrate, the above examples are only used to illustrate the technical scheme of the present invention and are not limiting, although with reference to compared with
Good embodiment describes the invention in detail, it will be understood by those of ordinary skill in the art that, it can be to the skill of the present invention
Art scheme is modified or replaced equivalently, and without departing from the objective and range of technical solution of the present invention, should all be covered at this
In the right of invention.
Claims (5)
1. a kind of rust-proof type metal cleaner, it is characterised in that：Cleaning agent raw material includes following components by mass percentage：Surface
Activating agent 10-15%, antirust agent 10-20%, dispersant 5-10%, antiseptic 3-5%, remaining adds to 100% for deionized water；
The surfactant is two in RhodacleanEFC, RhodacleanMSC, Antarox17R4, Antarox17R2
Kind or two or more compounds；
The antirust agent is C11-C14Dicarboxylic acids, C11-C14Tricarboxylic acid, modified inclined silication ethanol amine, isomery hydramine,
Three kinds or three kinds or more compounds in AMP-95, NEUF715.
2. rust-proof type metal cleaner according to claim 1, it is characterised in that：Cleaning agent raw material wraps by mass percentage
Include following components：Surfactant 13%, antirust agent 15%, dispersant 7%, antiseptic 4%, remaining is added to for deionized water
100%.
3. rust-proof type metal cleaner according to claim 2, it is characterised in that：The dispersant be Sodium Polyacrylate,
Two kinds in sodium gluconate, nitrilotriacetic acid or two or more compounds.
4. rust-proof type metal cleaner according to claim 3, it is characterised in that：The antiseptic be morpholine derivative and
The mixture of 1,2- benzisothiazole-3-ketones.
5. rust-proof type metal cleaner according to claim 4, it is characterised in that：The morpholine derivative and 1,2- benzos
The mass ratio of isothiazoline -3- ketone is 3:2.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811000395.XA CN108754508B (en) | 2018-08-30 | 2018-08-30 | Rust-proof type metal cleaner |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811000395.XA CN108754508B (en) | 2018-08-30 | 2018-08-30 | Rust-proof type metal cleaner |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN108754508A true CN108754508A (en) | 2018-11-06 |
| CN108754508B CN108754508B (en) | 2019-10-08 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811000395.XA Active CN108754508B (en) | 2018-08-30 | 2018-08-30 | Rust-proof type metal cleaner |
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| CN (1) | CN108754508B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109825838A (en) * | 2019-04-10 | 2019-05-31 | 上海福岛新材料科技有限公司 | A kind of high cleanliness metal cleaner and the method prolonged its service life |
| CN110042397A (en) * | 2019-05-24 | 2019-07-23 | 南京工业大学 | A kind of water-based antirust agent and preparation method thereof |
| CN113186542A (en) * | 2021-04-30 | 2021-07-30 | 重庆勃润防锈技术有限公司 | Rinsing-free industrial cleaning agent and preparation and use methods thereof |
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| US5614027A (en) * | 1994-09-23 | 1997-03-25 | Church & Dwight Co., Inc. | Metal cleaner with novel anti-corrosion system |
| CN102660752A (en) * | 2012-05-09 | 2012-09-12 | 上海福岛化工科技发展有限公司 | Environment-friendly efficient bubble-free cleaning agent |
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2018
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Patent Citations (4)
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| US5614027A (en) * | 1994-09-23 | 1997-03-25 | Church & Dwight Co., Inc. | Metal cleaner with novel anti-corrosion system |
| CN102660752A (en) * | 2012-05-09 | 2012-09-12 | 上海福岛化工科技发展有限公司 | Environment-friendly efficient bubble-free cleaning agent |
| CN103757652A (en) * | 2013-12-24 | 2014-04-30 | 长沙艾森设备维护技术有限公司 | Wheel set and gear case cleaning agent for high-speed rails and use method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109825838A (en) * | 2019-04-10 | 2019-05-31 | 上海福岛新材料科技有限公司 | A kind of high cleanliness metal cleaner and the method prolonged its service life |
| CN110042397A (en) * | 2019-05-24 | 2019-07-23 | 南京工业大学 | A kind of water-based antirust agent and preparation method thereof |
| CN113186542A (en) * | 2021-04-30 | 2021-07-30 | 重庆勃润防锈技术有限公司 | Rinsing-free industrial cleaning agent and preparation and use methods thereof |
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| Publication number | Publication date |
|---|---|
| CN108754508B (en) | 2019-10-08 |
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