CN105670738A - Rust-proof emulsified type metal cutting fluid - Google Patents
Rust-proof emulsified type metal cutting fluid Download PDFInfo
- Publication number
- CN105670738A CN105670738A CN201610136932.8A CN201610136932A CN105670738A CN 105670738 A CN105670738 A CN 105670738A CN 201610136932 A CN201610136932 A CN 201610136932A CN 105670738 A CN105670738 A CN 105670738A
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- acid
- oil
- emulsified type
- mixture
- metalworking fluid
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M163/00—Lubricating compositions characterised by the additive being a mixture of a compound of unknown or incompletely defined constitution and a non-macromolecular compound, each of these compounds being essential
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M167/00—Lubricating compositions characterised by the additive being a mixture of a macromolecular compound, a non-macromolecular compound and a compound of unknown or incompletely defined constitution, each of these compounds being essential
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
- C10M2229/02—Unspecified siloxanes; Silicones
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling
Abstract
The invention discloses rust-proof emulsified type metal cutting fluid which is prepared from, by weight, 40-50% of base oil, 5-15% of an anionic surfactant, 0.5-2.0% of a nonionic surfactant, 3-5% of a black metal inhibitor, 5-10% of a coupling agent, 0.5-1.0% of a copper alloy inhibiter, 3-10% of a lubricating agent, 1-2% of a bactericide, 0.2-0.5% of a defoaming agent and the balance water.The black metal inhibitor is added into the emulsified type cutting fluid formula, excellent interprocess dust-proof protection is provided, and it is ensured that corrosion is avoided before a machined workpiece is transferred to the next process; by adding the lubricating agent and the compound of the anionic and nonionic surfactants, the excellent lubricating performance and corrosion resistance and the outstanding hard water resistance are obtained; the working fluid is long in service life, contains no nitrite, phenols and other toxic and harmful substance, and is beneficial to health of environmental protection and workers.
Description
Technical field
The present invention relates to metalworking fluid technical field, particularly relate to a kind of antirust emulsified type metalworking fluid.
Background technology
Cutting fluid is that one is cut at metal, cuts, ground in the course of processing, is used for cooling down, lubricating the industrial type fluid of cutter and workpiece, multiple super strong functional auxiliary agent forms through science compound compatibility, and it is a kind of lubricant. The effect of cutting fluid has a lot; wherein lubrication, antirust, cleaning and cooling are topmost effect; thus cutting-tool's used life can be extended; prevent metal parts corrosion; take away the heat produced in the course of processing; effectively remove chip and the powder ash of part and tool surface, improve crudy, improve production efficiency.
By constituent, cutting fluid is generally divided into oil-base fluid and the big class of water base fluid two. Oil base cutting fluid cost is high and seriously polluted, and along with the development of advanced manufacturing technology, the reinforcement of people's environmental consciousness, water-base cutting fluid product occupies bigger market in recent years. In prior art, water-base cutting fluid needs to be improved further in service life, rust-preventing characteristic, stability etc., and the hard water resistance poor performance of most cutting fluid.
Summary of the invention
Present invention aims to the deficiencies in the prior art and a kind of antirust emulsified type metalworking fluid is provided.
For reaching above-mentioned purpose, the present invention is achieved through the following technical solutions.
A kind of antirust emulsified type metalworking fluid, by weight percentage, composed of the following components: base oil 40-50%, anion surfactant 5-15%, nonionic surfactant 0.5-2.0%, ferrous metal slow releasing agent 3-5%, couplant 5-10%, copper alloy corrosion inhibiter 0.5-1.0%, lubricant 3-10%, antibacterial 1-2%, defoamer 0.2-0.5%, water surplus.
Wherein, described base oil is the composite product of one or more that mineral oil, poly alpha olefin, oil-soluble gather support glycol, polyhydric alcohol esters, vegetable oil or improved plant grease.
Wherein, described anion surfactant is one or more in oleic acid, castor oil acid, dimeric dibasic acid, polyisobutylene succinic anhydride, appropriate youngster oil or tall oil acid or isomer fatty acids and the mixture of the mixture of one or more in monoethanolamine, triethanolamine, monoisopropanolamine, diisopropanolamine (DIPA), 2-amino-2-methyl-1-propanol, morpholine, N-methylmorpholine, diglycolamine and petroleum sodium sulfonate.
Wherein, described nonionic surfactant is the composite product of one or more of amide-type, aliphatic acid polyethenoxy polyoxypropylene ester, Fatty alcohol polyoxyethylene polyoxypropylene ether or number of different types ether carboxylic acids.
Wherein, described ferrous metal corrosion inhibitors is one or more mixture of one or more with monoethanolamine, in triethanolamine, monoisopropanolamine, diisopropanolamine (DIPA), 2-amino-2-methyl-1-propanol, morpholine, N-methylmorpholine or diglycolamine of boric acid, p-tert-butyl benzoic acid, Nitrodracylic acid, triazines multi-carboxylic acid compounds, ε-different pelargonyl group amino acid derivativges, ten to ten two carbon dicarboxylic acids apoplexy due to endogenous wind.
Wherein, described couplant is the mixture of one or more in isopropanol, propylene glycol, ethylene glycol monobutyl ether, diethylene glycol monobutyl ether, propylene glycol monobutyl ether, spans or isomery aliphatic alcohols.
Wherein, described copper alloy corrosion inhibiter is the mixture of one or more in benzotriazole, imidazoline, thiadiazoles polysulfide or methyl benzotriazole or benzotriazole sodium salt, methyl benzotriazole sodium salt, thiadiazoles sodium salt.
Wherein, described lubricant is the mixture of one or more in high molecular polymerization esters, modified vegetable oil, self emulsifying esters modification product.
Wherein, described antibacterial is the mixture of one or more of hexahydrotriazine, morpholine derivative, iodopropynyl butyl formate, 3-di-2-ethylhexylphosphine oxide (5-methyl oxazolidine) or isothiazolone apoplexy due to endogenous wind, and described defoamer is emulsified silicone oil.
The invention have the benefit that the processing that the present invention is directed to ferrous metal parts, it is added in emulsified cutting fluid formula by ferrous metal corrosion inhibitors, there is provided excellent rust prevention during manufacture protection, it is ensured that corrosion will not occur processing work before the next process that circulates; By add lubricant and multiple anion, nonionic surfactant composite; there is the greasy property of excellence, anti-corrupt ability and prominent resistance to hard water ability; working solution long service life; and without the poisonous and harmful substance such as nitrite, phenols, the health of environmental conservation and workman is favourable.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention will be described.
A kind of antirust emulsified type metalworking fluid, by weight percentage, composed of the following components: base oil 40-50%, anion surfactant 5-15%, nonionic surfactant 0.5-2.0%, ferrous metal slow releasing agent 3-5%, couplant 5-10%, copper alloy corrosion inhibiter 0.5-1.0%, lubricant 3-10%, antibacterial 1-2%, defoamer 0.2-0.5%, water surplus.
Embodiment one
A kind of antirust emulsified type metalworking fluid, by weight percentage, composed of the following components: base oil 40%, anion surfactant 5%, nonionic surfactant 0.5%, ferrous metal slow releasing agent 3%, couplant 5%, copper alloy corrosion inhibiter 0.5%, lubricant 3%, antibacterial 1%, defoamer 0.2%, water 41.8%.
Embodiment two
A kind of antirust emulsified type metalworking fluid, by weight percentage, composed of the following components: base oil 50%, anion surfactant 15%, nonionic surfactant 2%, ferrous metal slow releasing agent 5%, couplant 10%, copper alloy corrosion inhibiter 1%, lubricant 10%, antibacterial 2%, defoamer 0.5%, water 4.5%.
Embodiment three
A kind of antirust emulsified type metalworking fluid, by weight percentage, composed of the following components: base oil 43%, anion surfactant 10%, nonionic surfactant 1%, ferrous metal slow releasing agent 3.5%, couplant 6%, copper alloy corrosion inhibiter 0.65%, lubricant 5%, antibacterial 1.3%, defoamer 0.3%, water 29.25%.
Embodiment four
A kind of antirust emulsified type metalworking fluid, by weight percentage, composed of the following components: base oil 48%, anion surfactant 14%, nonionic surfactant 1.7%, ferrous metal slow releasing agent 4.5%, couplant 8%, copper alloy corrosion inhibiter 0.85%, lubricant 8%, antibacterial 1.7%, defoamer 0.4%, water 12.85%.
Further, described base oil is the composite product of one or more that mineral oil, poly alpha olefin, oil-soluble gather support glycol, polyhydric alcohol esters, vegetable oil or improved plant grease, improves its adhesive force.
Further, described anion surfactant is one or more in oleic acid, castor oil acid, dimeric dibasic acid, polyisobutylene succinic anhydride, appropriate youngster oil or tall oil acid or isomer fatty acids and the mixture of the mixture of one or more in monoethanolamine, triethanolamine, monoisopropanolamine, diisopropanolamine (DIPA), 2-amino-2-methyl-1-propanol, morpholine, N-methylmorpholine, diglycolamine and petroleum sodium sulfonate, and it has anti-rotten effect.
Further, described nonionic surfactant is the composite product of one or more of amide-type, aliphatic acid polyethenoxy polyoxypropylene ester, Fatty alcohol polyoxyethylene polyoxypropylene ether or number of different types ether carboxylic acids, and it has resistance to hard water effect.
Further; described ferrous metal corrosion inhibitors is one or more mixture of one or more with monoethanolamine, in triethanolamine, monoisopropanolamine, diisopropanolamine (DIPA), 2-amino-2-methyl-1-propanol, morpholine, N-methylmorpholine or diglycolamine of boric acid, p-tert-butyl benzoic acid, Nitrodracylic acid, triazines multi-carboxylic acid compounds, ε-different pelargonyl group amino acid derivativges, ten to ten two carbon dicarboxylic acids apoplexy due to endogenous wind, and it has rust inhibition.
Further, described couplant is the mixture of one or more in isopropanol, propylene glycol, ethylene glycol monobutyl ether, diethylene glycol monobutyl ether, propylene glycol monobutyl ether, spans or isomery aliphatic alcohols, energy wetted workpieces and detecting head surface, mobility, viscosity and adhesive force are suitable, are not difficult to clean.
Further, described copper alloy corrosion inhibiter is the mixture of one or more in benzotriazole, imidazoline, thiadiazoles polysulfide or methyl benzotriazole or benzotriazole sodium salt, methyl benzotriazole sodium salt, thiadiazoles sodium salt, improves its antirust and non-oxidizability.
Further, described lubricant is the mixture of one or more in high molecular polymerization esters, modified vegetable oil, self emulsifying esters or modified product, and it has high lubricant effect.
Further, described antibacterial is the mixture of one or more of hexahydrotriazine, morpholine derivative, iodopropynyl butyl formate, 3-di-2-ethylhexylphosphine oxide (5-methyl oxazolidine) or isothiazolone apoplexy due to endogenous wind, described defoamer is emulsified silicone oil, and it has the effect of sterilization.
Above content is only presently preferred embodiments of the present invention, for those of ordinary skill in the art, according to the thought of the present invention, all will change in specific embodiments and applications, and this specification content should not be construed as limitation of the present invention.
Claims (9)
1. an antirust emulsified type metalworking fluid, it is characterized in that, by weight percentage, composed of the following components: base oil 40-50%, anion surfactant 5-15%, nonionic surfactant 0.5-2.0%, ferrous metal slow releasing agent 3-5%, couplant 5-10%, copper alloy corrosion inhibiter 0.5-1.0%, lubricant 3-10%, antibacterial 1-2%, defoamer 0.2-0.5%, water surplus.
2. the antirust emulsified type metalworking fluid of one according to claim 1, it is characterised in that: described base oil is the composite product of one or more that mineral oil, poly alpha olefin, oil-soluble gather support glycol, polyhydric alcohol esters, vegetable oil or improved plant grease.
3. the antirust emulsified type metalworking fluid of one according to claim 1, it is characterised in that: described anion surfactant is one or more in oleic acid, castor oil acid, dimeric dibasic acid, polyisobutylene succinic anhydride, appropriate youngster oil or tall oil acid or isomer fatty acids and the mixture of the mixture of one or more in monoethanolamine, triethanolamine, monoisopropanolamine, diisopropanolamine (DIPA), 2-amino-2-methyl-1-propanol, morpholine, N-methylmorpholine, diglycolamine and petroleum sodium sulfonate.
4. the antirust emulsified type metalworking fluid of one according to claim 1, it is characterised in that: described nonionic surfactant is the composite product of one or more of amide-type, aliphatic acid polyethenoxy polyoxypropylene ester, Fatty alcohol polyoxyethylene polyoxypropylene ether or number of different types ether carboxylic acids.
5. the antirust emulsified type metalworking fluid of one according to claim 1, it is characterised in that: described ferrous metal corrosion inhibitors is one or more mixture of one or more with monoethanolamine, in triethanolamine, monoisopropanolamine, diisopropanolamine (DIPA), 2-amino-2-methyl-1-propanol, morpholine, N-methylmorpholine or diglycolamine of boric acid, p-tert-butyl benzoic acid, Nitrodracylic acid, triazines multi-carboxylic acid compounds, ε-different pelargonyl group amino acid derivativges, ten to ten two carbon dicarboxylic acids apoplexy due to endogenous wind.
6. the antirust emulsified type metalworking fluid of one according to claim 1, it is characterised in that: described couplant is the mixture of one or more in isopropanol, propylene glycol, ethylene glycol monobutyl ether, diethylene glycol monobutyl ether, propylene glycol monobutyl ether, spans or isomery aliphatic alcohols.
7. the antirust emulsified type metalworking fluid of one according to claim 1, it is characterised in that: described copper alloy corrosion inhibiter is the mixture of one or more in benzotriazole, imidazoline, thiadiazoles polysulfide or methyl benzotriazole or benzotriazole sodium salt, methyl benzotriazole sodium salt, thiadiazoles sodium salt.
8. the antirust emulsified type metalworking fluid of one according to claim 1, it is characterised in that: described lubricant is the mixture of one or more in high molecular polymerization esters, modified vegetable oil, self emulsifying esters modification product.
9. the antirust emulsified type metalworking fluid of one according to claim 1, it is characterized in that: described antibacterial is the mixture of one or more of hexahydrotriazine, morpholine derivative, iodopropynyl butyl formate, 3-di-2-ethylhexylphosphine oxide (5-methyl oxazolidine) or isothiazolone apoplexy due to endogenous wind, and described defoamer is emulsified silicone oil.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610136932.8A CN105670738A (en) | 2016-03-11 | 2016-03-11 | Rust-proof emulsified type metal cutting fluid |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610136932.8A CN105670738A (en) | 2016-03-11 | 2016-03-11 | Rust-proof emulsified type metal cutting fluid |
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| CN105670738A true CN105670738A (en) | 2016-06-15 |
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| CN201610136932.8A Pending CN105670738A (en) | 2016-03-11 | 2016-03-11 | Rust-proof emulsified type metal cutting fluid |
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Cited By (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107474907A (en) * | 2017-10-09 | 2017-12-15 | 东莞市德虏克新材料科技有限公司 | A kind of metalworking fluid |
| CN107723072A (en) * | 2017-11-13 | 2018-02-23 | 东莞市晶索润滑科技有限公司 | Working fluid for kirsite |
| CN107761106A (en) * | 2017-09-29 | 2018-03-06 | 中国石油化工股份有限公司 | Aqueous protective fluids and application thereof |
| CN108774575A (en) * | 2018-05-28 | 2018-11-09 | 广东富行洗涤剂科技有限公司 | A kind of non-oil modified cutting fluid with cleaning function |
| CN108822933A (en) * | 2018-06-01 | 2018-11-16 | 广东富行洗涤剂科技有限公司 | One Albatra metal fully synthetic cutting fluid |
| CN108843973A (en) * | 2018-05-31 | 2018-11-20 | 中国石油集团川庆钻探工程有限公司长庆井下技术作业公司 | A kind of coiled tubing friction reducer and preparation method and application |
| CN109370742A (en) * | 2018-12-08 | 2019-02-22 | 太仓美信新材料有限公司 | It is a kind of to contain the lubricating oil and preparation method thereof that ingredient is proposed from plant |
| CN109608358A (en) * | 2018-11-08 | 2019-04-12 | 洛斯石油（浙江）有限公司 | The formula and production method of more function amides |
| CN110747049A (en) * | 2019-11-05 | 2020-02-04 | 浙江渤威能源科技有限公司 | High-pressure low-foam universal cutting fluid for metal processing of numerical control machine tool and preparation method thereof |
| CN110819429A (en) * | 2019-11-25 | 2020-02-21 | 上海森帝润滑技术有限公司 | Emulsified cutting fluid |
| CN111484891A (en) * | 2020-04-26 | 2020-08-04 | 北美防锈技术（上海）有限公司 | Emulsified anti-rust oil |
| CN111763559A (en) * | 2020-07-30 | 2020-10-13 | 东莞市鹏润压铸材料科技有限公司 | Environment-friendly water-based plunger punch lubricating liquid |
| CN112322373A (en) * | 2020-11-10 | 2021-02-05 | 武汉市诺思特电子科技有限公司 | Formula of emulsified cutting fluid |
| CN112940833A (en) * | 2021-02-09 | 2021-06-11 | 上海应用技术大学 | Long-life environment-friendly cutting fluid and preparation method thereof |
| CN113563948A (en) * | 2020-12-14 | 2021-10-29 | 汉能（青岛）润滑科技有限公司 | Degradable antirust lubricant composition applied to metal cutting fluid |
| CN114317084A (en) * | 2021-12-31 | 2022-04-12 | 广州米奇化工有限公司 | Cutting fluid and application thereof |
| CN114381319A (en) * | 2020-10-20 | 2022-04-22 | 中国石油天然气股份有限公司 | Emulsified oil for copper and copper alloy wire drawing and preparation method thereof |
| CN114525166A (en) * | 2021-12-21 | 2022-05-24 | 西安思凯石化科技有限公司 | Formula and preparation method of environment-friendly emulsion special for copper and copper alloy |
| CN114644956A (en) * | 2022-04-29 | 2022-06-21 | 泰伦特生物工程股份有限公司 | Dy-Fe alloy wire cutting fluid and preparation method and use method thereof |
| CN115651744A (en) * | 2022-08-22 | 2023-01-31 | 安徽启明表面技术有限公司 | Environment-friendly microemulsion cutting fluid |
| CN115820330A (en) * | 2022-12-21 | 2023-03-21 | 广东红日星实业有限公司 | Cutting fluid and preparation method and application thereof |
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Cited By (26)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107761106A (en) * | 2017-09-29 | 2018-03-06 | 中国石油化工股份有限公司 | Aqueous protective fluids and application thereof |
| CN107761106B (en) * | 2017-09-29 | 2019-11-15 | 中国石油化工股份有限公司 | Aqueous protective fluids and application thereof |
| CN107474907A (en) * | 2017-10-09 | 2017-12-15 | 东莞市德虏克新材料科技有限公司 | A kind of metalworking fluid |
| CN107723072B (en) * | 2017-11-13 | 2020-10-09 | 东莞市晶索润滑科技有限公司 | Processing liquid for zinc alloy |
| CN107723072A (en) * | 2017-11-13 | 2018-02-23 | 东莞市晶索润滑科技有限公司 | Working fluid for kirsite |
| CN108774575A (en) * | 2018-05-28 | 2018-11-09 | 广东富行洗涤剂科技有限公司 | A kind of non-oil modified cutting fluid with cleaning function |
| CN108843973A (en) * | 2018-05-31 | 2018-11-20 | 中国石油集团川庆钻探工程有限公司长庆井下技术作业公司 | A kind of coiled tubing friction reducer and preparation method and application |
| CN108822933A (en) * | 2018-06-01 | 2018-11-16 | 广东富行洗涤剂科技有限公司 | One Albatra metal fully synthetic cutting fluid |
| CN109608358A (en) * | 2018-11-08 | 2019-04-12 | 洛斯石油（浙江）有限公司 | The formula and production method of more function amides |
| CN109370742A (en) * | 2018-12-08 | 2019-02-22 | 太仓美信新材料有限公司 | It is a kind of to contain the lubricating oil and preparation method thereof that ingredient is proposed from plant |
| CN110747049A (en) * | 2019-11-05 | 2020-02-04 | 浙江渤威能源科技有限公司 | High-pressure low-foam universal cutting fluid for metal processing of numerical control machine tool and preparation method thereof |
| CN110819429B (en) * | 2019-11-25 | 2022-02-22 | 上海森帝润滑技术有限公司 | Emulsified cutting fluid |
| CN110819429A (en) * | 2019-11-25 | 2020-02-21 | 上海森帝润滑技术有限公司 | Emulsified cutting fluid |
| CN111484891A (en) * | 2020-04-26 | 2020-08-04 | 北美防锈技术（上海）有限公司 | Emulsified anti-rust oil |
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| CN114381319B (en) * | 2020-10-20 | 2023-06-30 | 中国石油天然气股份有限公司 | Emulsified oil for copper and copper alloy wire drawing and preparation method thereof |
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Application publication date: 20160615 |