CN104277904A - Environment-friendly rust-proof water-based cutting fluid - Google Patents
Environment-friendly rust-proof water-based cutting fluid Download PDFInfo
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- CN104277904A CN104277904A CN201410498807.2A CN201410498807A CN104277904A CN 104277904 A CN104277904 A CN 104277904A CN 201410498807 A CN201410498807 A CN 201410498807A CN 104277904 A CN104277904 A CN 104277904A
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Abstract
The invention discloses an environment-friendly rust-proof water-based cutting fluid, comprising the following components in parts by weight: 10-25 parts of alkylol amine or alkylol amine salt, 5-10 parts of silicate, 15-30 parts of sodium borate, 8-20 parts of sodium tungstate, 25-50 parts of boracic acid, 5-15 parts of sodium gluconate, 30-60 parts of a lubricating agent, 3-10 parts of a defoaming agent, 3-8 parts of a sterilizing agent, 3-6 parts of a pH modifier and 50-85 parts of water. The environment-friendly rust-proof water-based cutting fluid disclosed by the invention has cooling, cleaning and lubricating functions, and is environmentally friendly, long in service life, excellent in anti-corrosion performance and strong in stability.
Description
Technical field
The present invention relates to cutting fluid technical field, particularly relate to a kind of environment-friendly antirust water-base cutting fluid.
Background technology
Cutting fluid is that one is cut at metal, cuts, ground in the course of processing, be used for cooling, lubrication cutter and the industrial type fluid of workpiece, formed through science compound compatibility by multiple super strong functional auxiliary agent, possess good cooling performance, lubricity, environmental protection, rustless property, cleaning function, anti-corrosion function simultaneously.By moiety, cutting fluid is divided into oil-base fluid and the large class of water base fluid two usually.Oil base cutting fluid cost is high and seriously polluted, and thus, water-base cutting fluid product occupies larger market in recent years.In prior art, water-base cutting fluid can not meet the needs of society in work-ing life, rust-preventing characteristic, stability etc., needs to be improved further.
Summary of the invention
The present invention proposes a kind of environment-friendly antirust water-base cutting fluid, it is except having cooling, cleaning, lubricating function, and environmental protection, long service life, high rust resistance, stability are strong.
The present invention proposes a kind of environment-friendly antirust water-base cutting fluid, its composition comprises by weight: hydramine or alcohol amine salt 10-25 part, silicate 5-10 part, borax 15-30 part, sodium wolframate 8-20 part, boric acid 25-50 part, Sunmorl N 60S 5-15 part, lubricant 30-60 part, defoamer 3-10 part, sterilant 3-8 part, pH adjusting agent 3-6 part, water 50-85 part.
Preferably: its composition comprises by weight: hydramine or alcohol amine salt 15-20 part, silicate 7-10 part, borax 22-28 part, sodium wolframate 12-15 part, boric acid 30-38 part, Sunmorl N 60S 10-14 part, lubricant 45-55 part, defoamer 5-8 part, sterilant 4-6 part, pH adjusting agent 3.8-4.5 part, water 60-75 part.
Preferably, its composition comprises by weight: hydramine or 18 parts, alcohol amine salt, silicate 8 parts, borax 25 parts, sodium wolframate 13 parts, boric acid 35 parts, Sunmorl N 60S 12 parts, lubricant 50 parts, defoamer 5.8 parts, 5.5 parts, sterilant, pH adjusting agent 4 parts, 70 parts, water.
Preferably, described hydramine is one or more the combination in fumaric acid trolamine, sebacic acid trolamine, SL-AH trolamine, N-decoyl L-glutamic acid trolamine, N-Sarkosyl L trolamine.
Preferably, described hydramine is N-decoyl L-glutamic acid trolamine.
Preferably, described hydramine is N-Sarkosyl L trolamine.
Preferably, described lubricant is one or more the combination in sulfonated castor oil, amine hydroxybenzene, sulphonated oleic acid.
Preferably, described sterilant is MIT, poly-Hydroxypropyldimonium Chloride, hydroxyethyl perhydro-s-triazine, the chloro-3-methylphenol of 4-, 1, one or more combination in 2-benzisothiazole-3-ketone, N, N '-methylene radical dimorpholine, CMIT.
Preferably, its composition comprises by weight: N-decoyl L-glutamic acid trolamine 10 parts, N-Sarkosyl L trolamine 8 parts, water glass 8 parts, borax 25 parts, sodium wolframate 13 parts, boric acid 35 parts, Sunmorl N 60S 12 parts, sulphonated oleic acid 50 parts, defoamer 5.8 parts, CMIT 5.5 parts, pH adjusting agent 4 parts, 70 parts, water.
In the present invention, using hydramine or alcohol amine salt as rust-inhibiting additive, itself and boric acid can generate hydramine boric acid ester, hydrophilic group in hydramine boric acid ester can be adsorbed on metallic surface, hydrophobic group can form layer protecting film at metallic surface, oxygen and metal is isolated, plays antirust effect; Coordinate with silicate, borax, sodium wolframate, glucose sodium saccharate the rust protection function further increasing cutting fluid, and effectively prevent etching problem; Coordinate the performance further increasing cutting fluid after adding lubricant, sterilant and pH adjusting agent, improve quality product, turnover staging life after the intermetallic composite coating stage is completed, anticorrosion time lengthening, eliminate the technique that secondary smears anticorrosion grease, reduce production cost, solve a corrosion difficult problem; Not containing carcinogenic substance in the water-base cutting fluid of environment-friendly antirust described in the present invention, environmentally friendly; There is excellent oilness, cleaning, cooling and rust-preventing characteristic, in process of metal working, use this cutting fluid can significantly improve the quality of product, improve working (machining) efficiency, there is very high economic benefit.
Embodiment
Below in conjunction with specific embodiment, the present invention is described in detail; should understand; embodiment is only for illustration of the present invention, instead of for limiting the present invention, any amendment, equivalent replacement etc. made on basis of the present invention is all in protection scope of the present invention.
In a particular embodiment, environment-friendly antirust water-base cutting fluid of the present invention, in its composition, the weight part of hydramine or alcohol amine salt can be 10.5, 12, 13, 14.6, 16, 17, 18, 19, 22, 23, 24.2 parts, the weight part of silicate can be 5.5, 6, 7, 7.8, 8, 9, 9.3 parts, the weight part of borax can be 15.6, 16, 17, 19, 19.6, 20, 21, 22, 23, 24.5, 25.6, 27, 28, 29.3 parts, the weight part of sodium wolframate can be 8.6, 9, 10, 12, 14, 15.3, 16, 17, 18, 18.9, 19.1 parts, the weight part of boric acid can be 25.5, 28, 29, 31, 34, 35, 35.2, 36, 38, 40, 42, 43, 44.6, 46, 47, 49.3 parts, the weight part of Sunmorl N 60S can be 5.2, 6, 7, 8, 9, 9.2, 10, 11.3, 12, 12.8, 13, 14, 14.6 parts, the weight part of lubricant can be 31, 32, 33, 34.5, 36, 37, 38, 39, 40, 42, 43, 45, 48, 49.3, 50.2, 51, 53, 57, 58.4 parts, the weight part of defoamer can be 4, 5, 6, 7, 8, 8.3, 9, 9.4 parts, the weight part of sterilant can be 3.5, 4, 5, 6, 6.8, 7.3 parts, the weight part of pH adjusting agent can be 3.5, 4, 5, 5.3, 5.8 parts, the weight part of water can be 52, 53.6, 54, 55, 56, 57, 58, 59, 60, 62, 63.5, 65, 66, 68.9, 70, 72, 75, 76.3, 78, 80, 82.1, 83, 84, 84.6 parts.
Embodiment 1
Environment-friendly antirust water-base cutting fluid of the present invention, its composition comprises by weight: hydramine or 25 parts, alcohol amine salt, silicate 5 parts, borax 30 parts, sodium wolframate 20 parts, boric acid 25 parts, Sunmorl N 60S 15 parts, lubricant 30 parts, defoamer 10 parts, 3 parts, sterilant, pH adjusting agent 6 parts, 85 parts, water.
Embodiment 2
Environment-friendly antirust water-base cutting fluid of the present invention, its composition comprises by weight: fumaric acid trolamine 10 parts, silicate 5 parts, borax 15 parts, sodium wolframate 8 parts, boric acid 50 parts, Sunmorl N 60S 5 parts, amine hydroxybenzene 25 parts, sulfonated castor oil 35 parts, defoamer 3 parts, N, N '-methylene radical dimorpholine 3 parts, BIT 5 parts, pH adjusting agent 3 parts, 50 parts, water.
Embodiment 3
Environment-friendly antirust water-base cutting fluid of the present invention, its composition comprises by weight: N-decoyl L-glutamic acid trolamine 10 parts, N-Sarkosyl L trolamine 8 parts, water glass 8 parts, borax 25 parts, sodium wolframate 13 parts, boric acid 35 parts, Sunmorl N 60S 12 parts, sulphonated oleic acid 50 parts, defoamer 5.8 parts, CMIT 5.5 parts, pH adjusting agent 4 parts, 70 parts, water.
Embodiment 4
Environment-friendly antirust water-base cutting fluid of the present invention, its composition comprises by weight: hydramine or 15 parts, alcohol amine salt, silicate 7 parts, borax 18 parts, sodium wolframate 9 parts, boric acid 33 parts, Sunmorl N 60S 10 parts, lubricant 50 parts, defoamer 6 parts, 4 parts, sterilant, pH adjusting agent 5.6 parts, 55.5 parts, water; Wherein, described hydramine is fumaric acid trolamine, and described lubricant is Viscotrol C, and described sterilant is poly-Hydroxypropyldimonium Chloride.
Embodiment 5
Environment-friendly antirust water-base cutting fluid of the present invention, its composition comprises by weight: hydramine or 22 parts, alcohol amine salt, silicate 9 parts, borax 25 parts, sodium wolframate 13 parts, boric acid 45.5 parts, Sunmorl N 60S 12.3 parts, lubricant 50 parts, defoamer 6 parts, 3.4 parts, sterilant, pH adjusting agent 5.3 parts, 56.9 parts, water; Wherein, described hydramine is the combination of sebacic acid trolamine, SL-AH trolamine and N-decoyl L-glutamic acid trolamine; Described lubricant is the combination of sulfonated castor oil, amine hydroxybenzene and sulphonated oleic acid, described sterilant is MIT, poly-Hydroxypropyldimonium Chloride, hydroxyethyl perhydro-s-triazine, the chloro-3-methylphenol of 4-, 1, the combination of 2-benzisothiazole-3-ketone, N, N '-methylene radical dimorpholine, CMIT.
Claims (9)
1. an environment-friendly antirust water-base cutting fluid, it is characterized in that, its composition comprises by weight: hydramine or alcohol amine salt 10-25 part, silicate 5-10 part, borax 15-30 part, sodium wolframate 8-20 part, boric acid 25-50 part, Sunmorl N 60S 5-15 part, lubricant 30-60 part, defoamer 3-10 part, sterilant 3-8 part, pH adjusting agent 3-6 part, water 50-85 part.
2. environment-friendly antirust water-base cutting fluid according to claim 1, it is characterized in that, its composition comprises by weight: hydramine or alcohol amine salt 15-20 part, silicate 7-10 part, borax 22-28 part, sodium wolframate 12-15 part, boric acid 30-38 part, Sunmorl N 60S 10-14 part, lubricant 45-55 part, defoamer 5-8 part, sterilant 4-6 part, pH adjusting agent 3.8-4.5 part, water 60-75 part.
3. environment-friendly antirust water-base cutting fluid according to claim 1 or 2, it is characterized in that, its composition comprises by weight: hydramine or 18 parts, alcohol amine salt, silicate 8 parts, borax 25 parts, sodium wolframate 13 parts, boric acid 35 parts, Sunmorl N 60S 12 parts, lubricant 50 parts, defoamer 5.8 parts, 5.5 parts, sterilant, pH adjusting agent 4 parts, 70 parts, water.
4. environment-friendly antirust water-base cutting fluid according to any one of claim 1-3, it is characterized in that, described hydramine is one or more the combination in fumaric acid trolamine, sebacic acid trolamine, SL-AH trolamine, N-decoyl L-glutamic acid trolamine, N-Sarkosyl L trolamine.
5. environment-friendly antirust water-base cutting fluid according to claim 4, it is characterized in that, described hydramine is N-decoyl L-glutamic acid trolamine.
6. environment-friendly antirust water-base cutting fluid according to claim 4, it is characterized in that, described hydramine is N-Sarkosyl L trolamine.
7. environment-friendly antirust water-base cutting fluid according to any one of claim 1-6, is characterized in that, described lubricant is one or more the combination in sulfonated castor oil, amine hydroxybenzene, sulphonated oleic acid.
8. environment-friendly antirust water-base cutting fluid according to any one of claim 1-7, it is characterized in that, described sterilant is MIT, poly-Hydroxypropyldimonium Chloride, hydroxyethyl perhydro-s-triazine, the chloro-3-methylphenol of 4-, 1, one or more combination in 2-benzisothiazole-3-ketone, N, N '-methylene radical dimorpholine, CMIT.
9. environment-friendly antirust water-base cutting fluid according to any one of claim 1-8, it is characterized in that, its composition comprises by weight: N-decoyl L-glutamic acid trolamine 10 parts, N-Sarkosyl L trolamine 8 parts, water glass 8 parts, borax 25 parts, sodium wolframate 13 parts, boric acid 35 parts, Sunmorl N 60S 12 parts, sulphonated oleic acid 50 parts, defoamer 5.8 parts, CMIT 5.5 parts, pH adjusting agent 4 parts, 70 parts, water.
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
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CN104611110A (en) * | 2015-01-29 | 2015-05-13 | 安徽铖友汽车零部件制造有限公司 | Cutting fluid for machine tool |
CN105349233A (en) * | 2014-08-21 | 2016-02-24 | 上海立美化学有限公司 | Cutting fluid and preparation method thereof |
CN107345170A (en) * | 2017-07-12 | 2017-11-14 | 安徽凯密克企业管理咨询有限公司 | A kind of preparation method of car parts antirust oil |
CN113105829A (en) * | 2021-02-26 | 2021-07-13 | 重庆勃润防锈技术有限公司 | Fully synthetic water-based polishing solution |
WO2022205911A1 (en) * | 2021-03-31 | 2022-10-06 | 煤炭科学技术研究院有限公司 | Protective liquid for hydraulic system, preparation method therefor and use of thereof |
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CN102757853A (en) * | 2012-05-31 | 2012-10-31 | 天长市润达金属防锈助剂有限公司 | Metal cutting fluid with high extreme pressure resistance |
CN103450998A (en) * | 2012-05-30 | 2013-12-18 | 修建东 | Hard-water resistance completely-synthesized cutting fluid and preparation method thereof |
CN103740452A (en) * | 2013-12-20 | 2014-04-23 | 开封恒锐新金刚石制品有限公司 | Environment-friendly cooling liquid for diamond wire cutting and preparation method thereof |
CN103820197A (en) * | 2014-03-04 | 2014-05-28 | 西南大学 | Full-synthetic metal cutting liquid |
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CN1746281A (en) * | 2004-09-06 | 2006-03-15 | 大连广汇化学有限公司 | Environmental-protective water-base synthesized cutting fluid |
CN103450998A (en) * | 2012-05-30 | 2013-12-18 | 修建东 | Hard-water resistance completely-synthesized cutting fluid and preparation method thereof |
CN102757853A (en) * | 2012-05-31 | 2012-10-31 | 天长市润达金属防锈助剂有限公司 | Metal cutting fluid with high extreme pressure resistance |
CN103740452A (en) * | 2013-12-20 | 2014-04-23 | 开封恒锐新金刚石制品有限公司 | Environment-friendly cooling liquid for diamond wire cutting and preparation method thereof |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
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CN105349233A (en) * | 2014-08-21 | 2016-02-24 | 上海立美化学有限公司 | Cutting fluid and preparation method thereof |
CN104611110A (en) * | 2015-01-29 | 2015-05-13 | 安徽铖友汽车零部件制造有限公司 | Cutting fluid for machine tool |
CN107345170A (en) * | 2017-07-12 | 2017-11-14 | 安徽凯密克企业管理咨询有限公司 | A kind of preparation method of car parts antirust oil |
CN113105829A (en) * | 2021-02-26 | 2021-07-13 | 重庆勃润防锈技术有限公司 | Fully synthetic water-based polishing solution |
WO2022205911A1 (en) * | 2021-03-31 | 2022-10-06 | 煤炭科学技术研究院有限公司 | Protective liquid for hydraulic system, preparation method therefor and use of thereof |
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Application publication date: 20150114 |