CN104293471A - Environment-friendly water-based synthetic metal machining liquid - Google Patents
Environment-friendly water-based synthetic metal machining liquid Download PDFInfo
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- CN104293471A CN104293471A CN201410526132.8A CN201410526132A CN104293471A CN 104293471 A CN104293471 A CN 104293471A CN 201410526132 A CN201410526132 A CN 201410526132A CN 104293471 A CN104293471 A CN 104293471A
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Abstract
The invention discloses an environment-friendly water-based synthetic metal machining liquid which is prepared from the following raw materials in parts by weight: 10-25 parts of triethanolamine sebacate, 5-13 parts of benzotriazole, 5-10 parts of sodium benzoate, 3-10 parts of dodecenylsuccinic acid, 5-13 parts of laurate alcohol ester, 5-10 parts of triethanolamine oleate, 5-15 parts of borate, 8-20 parts of a polyether nonionic surfactant, 5-8 parts of triethanolamine, 3-5 parts of ethylene diamine tetraacetic acid, 5-10 parts of borax, 2-5 parts of a chelating agent, 0.5-3 parts of a bactericide, 2-6 parts of a defoaming agent and 120-180 parts of water. The environment-friendly water-based synthetic metal machining liquid disclosed by the invention further has good cooling property, lubricity, anti-rust property and cleaning property, is stable in product quality, long in service period, free of mineral oil and vegetable oil as well as additives which are harmful to human bodies and pollute the environment and easily biodegraded, belongs to an environment-friendly product and has a relatively good application prospect.
Description
Technical field
The present invention relates to cutting fluid technical field, particularly relate to a kind of environmentally-friendly water-based synthetic metals cutting fluid.
Background technology
In metal cutting process, cutter incision machined material, produce cutting action, machined material is subject to pushing of cutter rake face and rubs, and along the slippage of a certain inclined-plane, produces viscous deformation, is formed and cut.In the process of cutting, cutting temperature and cutting force be made to be reduced to greatest extent, improve cutter life and workpiece size precision and surface quality, cutting fluid is an important approach, sometimes even plays decisive role.
Cutting fluid has following major function: lubrication: between the forward and backward knife face held high and workpiece, form one deck composite lubricating film, can reduce or avoid cutter to contact with direct between workpiece or chip, alleviate friction and cohere degree; Cooling effect: take away a large amount of heats, reduces the temperature of workpiece and cutter, improves tool life, reduces thermal distortion, improves working accuracy; Cleanup action: reduce the bonding of tiny chip and powder in order to cleaning and being washed away at the ash end of chip; Rust inhibition: prevent the dust of moisture, oxygen, hand perspiration, acidic substance and air from attacking metal and producing corrosion; Except above four kinds of functions, also should have good preservation stability, Antimicrobial preservative and resistance to hard water, to human body and environmentally friendly, be convenient to recovery, discharge etc.
Water based synthetic cutting fluid is that one does not contain mineral oil and vegetable and animals oils, not containing Sodium Nitrite and sulphur, chlorine type additive, the aqueous solution is Clear & Transparent, nontoxic, non-stimulated, the cooling-lubricant of free from extraneous odour.Oilness and the antiseptic property of current water base synthetic metals cutting fluid are not good enough, can not meet the requirement of society.
Summary of the invention
The present invention proposes a kind of environmentally-friendly water-based synthetic metals cutting fluid, its oilness is good, and antiseptic property is strong, and cleaning performance is good, and speed of cooling is fast.
The present invention proposes a kind of environmentally-friendly water-based synthetic metals cutting fluid, its raw material comprises by weight: sebacic acid trolamine 10-25 part, benzotriazole 5-13 part, Sodium Benzoate 5-10 part, dodecenylsuccinic acid 3-10 part, lauric acid positive alcohol ester 5-13 part, triethanolamine oleate 5-10 part, boric acid ester 5-15 part, polyether nonionic surfactant 8-20 part, trolamine 5-8 part, ethylenediamine tetraacetic acid (EDTA) 3-5 part, borax 5-10 part, sequestrant 2-5 part, sterilant 0.5-3 part, defoamer 2-6 part, water 120-180 part.
Preferably, its raw material comprises by weight: sebacic acid trolamine 13-20 part, benzotriazole 7-10 part, Sodium Benzoate 7-9 part, dodecenylsuccinic acid 6-9 part, lauric acid positive alcohol ester 7-10 part, triethanolamine oleate 6-8 part, boric acid ester 8-13 part, polyether nonionic surfactant 12-18 part, trolamine 6-7.5 part, ethylenediamine tetraacetic acid (EDTA) 3.5-4.5 part, borax 6-8 part, sequestrant 3-4.5 part, sterilant 1.5-2.3 part, defoamer 3-4.5 part, water 135-150 part.
Preferably, its raw material comprises by weight: sebacic acid trolamine 15 parts, benzotriazole 8 parts, Sodium Benzoate 8 parts, dodecenylsuccinic acid 7 parts, the positive alcohol ester of lauric acid 9 parts, triethanolamine oleate 7.5 parts, boric acid ester 10 parts, polyether nonionic surfactant 13 parts, trolamine 7 parts, ethylenediamine tetraacetic acid (EDTA) 4 parts, borax 7.8 parts, sequestrant 4.3 parts, 2 parts, sterilant, defoamer 3.8 parts, 145 parts, water.
Preferably, described boric acid ester is triethanolamine borate, oleic diethanola mide borate ester, lauric acid diethyl amide boric acid ester, lauric acid triglycolyl amine boric acid ester, O-(N-succinimide)-1,1, one or more combination in 3,3-tetramethyl-urea Tetrafluoroboric acid ester.
Preferably, one or more combination in described sequestrant 2-hydroxy-5-sulfobenzoic acid, diethyl pentetic acid, bicine N-, N, N'-ethylenediamine disuccinic acid, water-soluble edetate, triglycollamic acid salt, MDGA, propanedioic acid, Whitfield's ointment, glycine, aspartic acid, L-glutamic acid and pyridine dicarboxylic acid.
Preferably, described sterilant is one or more the combination in MIT, hydroxyethyl perhydro-s-triazine, dicyclohexyl amine, BIT, N, N '-methylene radical dimorpholine, sodium pyrithione.
Preferably, described defoamer is one or more the combination in polyether antifoam agent, water-soluble organic silicon compounds, dimethyl silicone oil.
In the present invention, have selected sebacic acid trolamine, benzotriazole, dodecenylsuccinic acid, Sodium Benzoate as rust-preventive agent, benzotriazole good water solubility, the destruction that the increment of microorganism causes cutting fluid stability can not only be suppressed, to the rust-preventing characteristic of aluminium, iron and preservative property, and reduce cost with trolamine, dodecenylsuccinic acid, the composite cutting fluid that can significantly improve of Sodium Benzoate simultaneously; The positive alcohol ester of boric acid ester, lauric acid, triethanolamine oleate are as lubricant, boric acid ester is a kind of water based lubrication wear preventive additive of excellence, have the functions such as lubrication, wear-resistant, antirust and environmental friendliness concurrently, be a kind of excellent lubricity and extreme boundary lubrication performance, the positive alcohol ester of cooperation lauric acid, triethanolamine oleate improve its oilness; Polyether nonionic surfactant has good tackifying ability, foam is few, the materials such as hard water, acid, alkali are stablized, after coordinating with rust-preventive agent, lubricant and defoamer, cutting fluid is made to have excellent oilness, water-soluble and perviousness, with effect of tensio-active agent, oiliness improver, extreme pressure agent, improve antirust ability, decrease the consumption of each raw material; The interpolation of trolamine and ethylenediamine tetraacetic acid (EDTA) adds the stability of cutting fluid, to environment toxicological harmless effect; Borax and trolamine compatibility further increase the stability of cutting fluid, and the cutting fluid obtained because of pH value change, gel or precipitation can not occur, and has good inhibition rust inhibition to the metal such as iron, aluminium.
In the present invention, by selecting suitable component, optimize the content of component, obtain environmentally-friendly water-based synthetic metals cutting fluid, its each performance index have met or exceeded national standard, have good cooling, oilness, rust-preventing characteristic and cleaning, constant product quality simultaneously, life cycle is long, not containing mineral oil and vegetables oil, containing harmful and environment is had to the additive of pollution, readily biodegradable, belong to environmentally friendly product, there is good application prospect.
The index of GB6144 and the test index of embodiment of the present invention product are as shown in subscript:
Embodiment
Below in conjunction with specific embodiment, the present invention is described in detail; should understand; embodiment is only for illustration of the present invention, instead of for limiting the present invention, any amendment, equivalent replacement etc. made on basis of the present invention is all in protection scope of the present invention.
In a particular embodiment, environmentally-friendly water-based synthetic metals cutting fluid of the present invention, in its raw material, the weight part of sebacic acid trolamine can be 10.4, 11, 12.3, 13, 13.5, 14, 14.1, 15, 15.2, 16, 16.9, 18, 19, 20, 21.3, 22, 23.5, 24.5 parts, the weight part of benzotriazole can be 5.6, 6, 6.2, 7, 7.3, 8, 8.1, 9, 9.5, 10, 10.3, 11, 11.5, 12, 12.7 parts, the weight part of Sodium Benzoate can be 5.4, 6, 6.7, 7, 7.3, 8, 8.4, 9, 9.5 parts, the weight part of dodecenylsuccinic acid can be 3.4, 4, 4.1, 5, 5.6, 6, 6.4, 7, 7.8, 8, 9, 9.5 parts, the weight part of the positive alcohol ester of lauric acid can be 5.4, 6, 6.5, 7, 7.2, 8, 8.3, 9, 9.9, 10, 11, 11.5, 12, 12.5 parts, the weight part of triethanolamine oleate can be 5.6, 6, 6.3, 7, 7.5, 8, 8.2, 9, 9.4 parts, the weight part of boric acid ester can be 5.4, 6, 6.7, 8, 8.4, 10, 11, 13, 13.5, 14, 14.2 parts, the weight part of polyether nonionic surfactant can be 8.5, 9, 10, 11.2, 13, 13.5, 14, 15, 15.6, 16.8, 17, 18, 19, 19.5 parts, the weight part of trolamine can be 5.6, 6, 6.2, 7, 7.2, 7.8 parts, the weight part of ethylenediamine tetraacetic acid (EDTA) can be 3.2, 3.8, 4, 4.3, 4.7 parts, the weight part of borax can be 5.6, 6, 6.3, 7, 7.5, 8, 8.4, 9, 9.2 parts, the weight part of sequestrant can be 2.3, 3, 3.5, 3.9, 4, 4.2, 4.8 parts, the weight part of sterilant can be 0.6, 0.7, 0.8, 0.9, 1.2, 1.3, 1.5, 2, 2.1, 2.3, 2.5, 2.8 parts, the weight part of defoamer can be 2.6, 3, 3.4, 4, 4.3, 5, 5.2, 5.8 parts, the weight part of water can be 123.5, 125, 128, 135.4, 140.3, 144, 145, 148, 150.7, 152.3, 155, 156, 157, 162, 163.5, 165.4, 170, 172, 173.5, 174.2, 175, 176, 177, 178.9 part.
Embodiment 1
Environmentally-friendly water-based synthetic metals cutting fluid of the present invention, its raw material comprises by weight: sebacic acid trolamine 10.8 parts, benzotriazole 12 parts, Sodium Benzoate 7.6 parts, dodecenylsuccinic acid 9 parts, the positive alcohol ester of lauric acid 12.3 parts, triethanolamine oleate 6 parts, boric acid ester 12.5 parts, polyether nonionic surfactant 8.9 parts, trolamine 5.8 parts, ethylenediamine tetraacetic acid (EDTA) 4.3 parts, borax 5.6 parts, sequestrant 3.6 parts, 2.6 parts, sterilant, defoamer 4 parts, 160 parts, water.
Embodiment 2
Environmentally-friendly water-based synthetic metals cutting fluid of the present invention, its raw material comprises by weight: sebacic acid trolamine 10 parts, benzotriazole 13 parts, Sodium Benzoate 5 parts, dodecenylsuccinic acid 10 parts, the positive alcohol ester of lauric acid 5 parts, triethanolamine oleate 10 parts, lauric acid triglycolyl amine boric acid ester 15 parts, polyether nonionic surfactant 20 parts, trolamine 5 parts, ethylenediamine tetraacetic acid (EDTA) 3 parts, borax 10 parts, sequestrant 2 parts, 3 parts, sterilant, defoamer 2 parts, 180 parts, water.
Embodiment 3
Environmentally-friendly water-based synthetic metals cutting fluid of the present invention, its raw material comprises by weight: sebacic acid trolamine 25 parts, benzotriazole 5 parts, Sodium Benzoate 10 parts, dodecenylsuccinic acid 3 parts, the positive alcohol ester of lauric acid 13 parts, triethanolamine oleate 5 parts, O-(N-succinimide)-1, 1, 3, 3-tetramethyl-urea Tetrafluoroboric acid 3 parts, triethanolamine borate 2 parts, polyether nonionic surfactant 8 parts, trolamine 8 parts, ethylenediamine tetraacetic acid (EDTA) 5 parts, borax 5 parts, bicine N-1 part, aspartic acid 2 parts, diethyl pentetic acid 2 parts, MIT 0.5 part, polyether antifoam agent 4 parts, dimethyl silicone oil 1 part, 120 parts, water.
Embodiment 4
Environmentally-friendly water-based synthetic metals cutting fluid of the present invention, its raw material comprises by weight: sebacic acid trolamine 15 parts, benzotriazole 8 parts, Sodium Benzoate 8 parts, dodecenylsuccinic acid 7 parts, the positive alcohol ester of lauric acid 9 parts, triethanolamine oleate 7.5 parts, boric acid ester 10 parts, polyether nonionic surfactant 13 parts, trolamine 7 parts, ethylenediamine tetraacetic acid (EDTA) 4 parts, borax 7.8 parts, Whitfield's ointment 4.3 parts, 1,2-benzisothiazole-3-ketone 1.5 parts, N, N '-methylene radical dimorpholine 0.5 part, dimethyl silicone oil 3.8 parts, 145 parts, water.
Embodiment 5
Environmentally-friendly water-based synthetic metals cutting fluid of the present invention, its raw material comprises by weight: sebacic acid trolamine 19.3 parts, benzotriazole 10.4 parts, Sodium Benzoate 6.6 parts, dodecenylsuccinic acid 3.4 parts, the positive alcohol ester of lauric acid 6.8 parts, triethanolamine oleate 8 parts, boric acid ester 5.3 parts, polyether nonionic surfactant 9.8 parts, trolamine 6 parts, ethylenediamine tetraacetic acid (EDTA) 4.1 parts, borax 7.3 parts, sequestrant 3.7 parts, 1.9 parts, sterilant, defoamer 2.6 parts, 155 parts, water;
Wherein, described boric acid ester is triethanolamine borate, oleic diethanola mide borate ester, lauric acid diethyl amide boric acid ester, lauric acid triglycolyl amine boric acid ester, O-(N-succinimide)-1, the combination of 1,3,3-tetramethyl-urea Tetrafluoroboric acid ester; Described sequestrant is the combination of 2-hydroxy-5-sulfobenzoic acid, bicine N-, water-soluble edetate, MDGA, propanedioic acid, glycine, L-glutamic acid; Described sterilant is the combination of MIT, hydroxyethyl perhydro-s-triazine, dicyclohexyl amine, BIT, N, N '-methylene radical dimorpholine, sodium pyrithione; Described defoamer is the combination of polyether antifoam agent, water-soluble organic silicon compounds, dimethyl silicone oil.
Claims (7)
1. an environmentally-friendly water-based synthetic metals cutting fluid, it is characterized in that, its raw material comprises by weight: sebacic acid trolamine 10-25 part, benzotriazole 5-13 part, Sodium Benzoate 5-10 part, dodecenylsuccinic acid 3-10 part, lauric acid positive alcohol ester 5-13 part, triethanolamine oleate 5-10 part, boric acid ester 5-15 part, polyether nonionic surfactant 8-20 part, trolamine 5-8 part, ethylenediamine tetraacetic acid (EDTA) 3-5 part, borax 5-10 part, sequestrant 2-5 part, sterilant 0.5-3 part, defoamer 2-6 part, water 120-180 part.
2. environmentally-friendly water-based synthetic metals cutting fluid according to claim 1, it is characterized in that, its raw material comprises by weight: sebacic acid trolamine 13-20 part, benzotriazole 7-10 part, Sodium Benzoate 7-9 part, dodecenylsuccinic acid 6-9 part, lauric acid positive alcohol ester 7-10 part, triethanolamine oleate 6-8 part, boric acid ester 8-13 part, polyether nonionic surfactant 12-18 part, trolamine 6-7.5 part, ethylenediamine tetraacetic acid (EDTA) 3.5-4.5 part, borax 6-8 part, sequestrant 3-4.5 part, sterilant 1.5-2.3 part, defoamer 3-4.5 part, water 135-150 part.
3. environmentally-friendly water-based synthetic metals cutting fluid according to claim 1 or 2, it is characterized in that, its raw material comprises by weight: sebacic acid trolamine 15 parts, benzotriazole 8 parts, Sodium Benzoate 8 parts, dodecenylsuccinic acid 7 parts, the positive alcohol ester of lauric acid 9 parts, triethanolamine oleate 7.5 parts, boric acid ester 10 parts, polyether nonionic surfactant 13 parts, trolamine 7 parts, ethylenediamine tetraacetic acid (EDTA) 4 parts, borax 7.8 parts, sequestrant 4.3 parts, 2 parts, sterilant, defoamer 3.8 parts, 145 parts, water.
4. environmentally-friendly water-based synthetic metals cutting fluid according to any one of claim 1-3, it is characterized in that, described boric acid ester is triethanolamine borate, oleic diethanola mide borate ester, lauric acid diethyl amide boric acid ester, lauric acid triglycolyl amine boric acid ester, O-(N-succinimide)-1,1, one or more combination in 3,3-tetramethyl-urea Tetrafluoroboric acid ester.
5. environmentally-friendly water-based synthetic metals cutting fluid according to any one of claim 1-4, it is characterized in that, one or more combination in described sequestrant 2-hydroxy-5-sulfobenzoic acid, diethyl pentetic acid, bicine N-, N, N'-ethylenediamine disuccinic acid, water-soluble edetate, triglycollamic acid salt, MDGA, propanedioic acid, Whitfield's ointment, glycine, aspartic acid, L-glutamic acid and pyridine dicarboxylic acid.
6. environmentally-friendly water-based synthetic metals cutting fluid according to any one of claim 1-5, it is characterized in that, described sterilant is MIT, hydroxyethyl perhydro-s-triazine, dicyclohexyl amine, 1, one or more combination in 2-benzisothiazole-3-ketone, N, N '-methylene radical dimorpholine, sodium pyrithione.
7. environmentally-friendly water-based synthetic metals cutting fluid according to any one of claim 1-6, is characterized in that, described defoamer is one or more the combination in polyether antifoam agent, water-soluble organic silicon compounds, dimethyl silicone oil.
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| CN104774679A (en) * | 2015-04-30 | 2015-07-15 | 蓝思科技（长沙）有限公司 | Environment-friendly water-based sapphire cutting fluid |
| CN104830408A (en) * | 2015-06-07 | 2015-08-12 | 烟台顺隆化工科技有限公司 | Emulsified metal cutting fluid |
| CN104911015A (en) * | 2015-06-30 | 2015-09-16 | 陕西航宇化工有限公司 | Honing solution and preparation method thereof |
| CN105132110A (en) * | 2015-09-08 | 2015-12-09 | 四会市格鲁森润滑技术有限公司 | Semi-synthesis cleaning antirust liquid and preparation process thereof |
| CN106190481A (en) * | 2016-07-13 | 2016-12-07 | 天长市润达金属防锈助剂有限公司 | A kind of magnalium cutting fluid with excellent abrasion resistant extreme-pressure performance |
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| CN107022402A (en) * | 2016-01-29 | 2017-08-08 | 比亚迪股份有限公司 | A kind of corrosion-resistant cutting fluid and preparation method thereof |
| CN107353995A (en) * | 2017-07-23 | 2017-11-17 | 武汉诺通润滑科技有限公司 | A kind of environment-friendly type fully synthetic cutting fluid and preparation method thereof |
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| CN104830408A (en) * | 2015-06-07 | 2015-08-12 | 烟台顺隆化工科技有限公司 | Emulsified metal cutting fluid |
| CN104911015A (en) * | 2015-06-30 | 2015-09-16 | 陕西航宇化工有限公司 | Honing solution and preparation method thereof |
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