CN104087404A - High-cleanliness economical microemulsion metal cutting fluid - Google Patents
High-cleanliness economical microemulsion metal cutting fluid Download PDFInfo
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- CN104087404A CN104087404A CN201410367711.2A CN201410367711A CN104087404A CN 104087404 A CN104087404 A CN 104087404A CN 201410367711 A CN201410367711 A CN 201410367711A CN 104087404 A CN104087404 A CN 104087404A
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Abstract
The invention relates to a cutting fluid used for metal processing and a preparation method thereof and in particular relates to a high-cleanliness economical microemulsion metal cutting fluid. The high-cleanliness economical microemulsion metal cutting fluid comprises the following raw material components in percentage by weight: 15-20% of base oil, 10-15% of alkaline retention agent, 5-10% of surfactant, 5-10% of antirust agent, 5-15% of emulsifying agent, 0.5-2% of corrosion inhibition agent, 5-10% of extreme pressure agent, 0.1-0.2% of defoaming agent, 1-2% of sterilizing agent and the balance of water. The preparation method of the high-cleanliness economical microemulsion metal cutting fluid comprises the following steps: adding the alkaline retention agent, the surfactant, the antirust agent, the emulsifying agent, the corrosion inhibition agent, the extreme pressure agent, the defoaming agent, the sterilizing agent, water and the like into base oil, and uniformly mixing and stirring. Compared with the prior art, the preparation method of the high-cleanliness economical microemulsion metal cutting fluid has the advantages that product quality and operating environment can be improved, processing efficiency is improved, durability of a cutter is enhanced, and cost for replenishing and managing cutting fluid is reduced, so that obvious economic benefit is obtained.
Description
[technical field]
The present invention relates to cutting fluid of metal processing use and preparation method thereof, specifically a kind of abrasive, economical microemulsified metal working fluid.
[background technology]
The working method of metal is various, and wherein metal cutting processing is the most common, most widely used one in metal processing.According to the different requirements of the shape of workpiece, precision and surface quality, metal cutting processing can be divided into car, milling, brill, plane, boring, hinge, broaching, gear cutting, screw thread processing and grinding etc.Cutting fluid is the important supplementary material of metal cutting processing, conventionally can be divided into being cooled to main water-soluble metal cutting fluid and to lubricate as main pure oiliness metal working fluid.Compared with oiliness cutting fluid, it is better that water-soluble metalworking liquid has cooling performance, and cost is lower, to advantages such as operating environment less pollutions.In cutting fluid use procedure, owing to sneaking into impurity such as frittering bits, abrasive dust, emery wheel end and dust, have a strong impact on workpiece surface roughness, reduce the work-ing life of cutter and emery wheel, and lathe leakage of oil and misoperation also can shorten the life cycle of cutting fluid.
Therefore, select cutting fluid must carry out comprehensive economic analysis, by buying the economic benefit of the evaluation cutting fluid that all many-sides such as life cycle, the waste treatment expense of cutting fluid of raising, cutting fluid of consume expense, production efficiency of overhead charges, cutting tool of expense, cutting fluid of cutting fluid are correct.
[summary of the invention]
Object of the present invention is exactly will solve above-mentioned deficiency and a kind of abrasive, economical microemulsified metal working fluid are provided, can improve quality product and operating environment, improved working (machining) efficiency, extended cutter durability, reduced that cutting fluid is supplemented and the expense of management, thereby can bring significant economic benefit.
Design for achieving the above object a kind of abrasive, economical microemulsified metal working fluid, wherein each feed composition counts by weight percentage, and its composition and content are as follows:
Described base oil is the one in paraffinic based oil or naphthene base crude oil.
Described alkaline retention agent is α-amino isopropyl alcohol, trolamine, monoethanolamine, 2-amino, one or more in 2-methylpropanol.
Described tensio-active agent is the mixture of petroleum sodium sulfonate and fatty alcohol-polyoxyethylene ether.
Described rust-preventive agent is one or more the mixture in boric acid, sebacic acid, lauric acid, sulfonic acid ammonia salt, boric acid ester and oleic acid.
Described emulsifying agent is one or more the mixture in animal oleic acid, vegetable oil acid, polymerization oleic acid, isomery hexadecanol and tall oil acid.
Described inhibiter is the one in 124 Triazole, methyl benzotriazole, phosphoric acid ester.
Described extreme pressure agent is one or more the mixture in phosphoric acid ester, sulfide aliphatic acid ester, chlorine-containing polymer.
Described defoamer is silicone emulsion, modification dimethyl siloxane or polyethers.
Described sterilant is the one in triazines, methylisothiazolinone, methyl benzoate.
Compared with the existing technology, tool has the following advantages in the present invention:
(1) due to multiple hydramine and lauric interaction, make cutting fluid demonstrate good cleaning performance, can the iron filings on lathe, greasy dirt, greasy filth be cleaned very totally;
(2) add tensio-active agent, rust-preventive agent, inhibiter, extreme pressure agent, so there are splendid cooling, preservative property, made cutting fluid between cutter and metal, have good lubricity, improved working accuracy and surface smoothness.Its residue is solubility oil in water emulsion, is convenient to clean, and makes machine keep clean;
(3), owing to not containing the materials such as nitrite, heavy metal, therefore harmless while use, non-environmental-pollution, is convenient to management;
(4) cutting fluid of the present invention is concentrated type product, and working fluid can dilute 10-15 and doubly use, and has greatly saved stoste usage quantity.
[embodiment]
Below in conjunction with embodiment, the present invention is done to following further illustrating:
Embodiment 1
A kind of abrasive, economical microemulsified metal working fluid, wherein each feed composition counts by weight percentage, and its composition and content are as follows:
Wherein, base oil is paraffinic based oil; Alkalescence retention agent is α-amino isopropyl alcohol, trolamine, monoethanolamine, 2-amino, one or more in 2-methylpropanol, as be the mixture of α-amino isopropyl alcohol, trolamine; Tensio-active agent is the mixture of petroleum sodium sulfonate, fatty alcohol-polyoxyethylene ether; Rust-preventive agent is one or more the mixture in boric acid, sebacic acid, lauric acid, sulfonic acid ammonia salt, boric acid ester and oleic acid, as is the mixture of boric acid, lauric acid, sulfonic acid ammonia salt; Emulsifying agent is one or more the mixture in animal oleic acid, vegetable oil acid, polymerization oleic acid, isomery hexadecanol and tall oil acid, as is animal oleic acid, vegetable oil acid, polymerization oleic acid; Inhibiter is 124 Triazole; Extreme pressure agent is one or more the mixture in phosphoric acid ester, sulfide aliphatic acid ester, chlorine-containing polymer, as is the mixture of sulfide aliphatic acid ester, chlorine-containing polymer; Defoamer is silicone emulsion; Sterilant is triazines.
Embodiment 2
A kind of abrasive, economical microemulsified metal working fluid, wherein each feed composition counts by weight percentage, and its composition and content are as follows:
Wherein, base oil is naphthene base crude oil; Alkalescence retention agent is monoethanolamine, 2-amino, the mixture of 2-methylpropanol; Tensio-active agent is the mixture of petroleum sodium sulfonate, fatty alcohol-polyoxyethylene ether; Rust-preventive agent is the mixture of sebacic acid, lauric acid, oleic acid composition; Emulsifying agent is the mixture of vegetable oil acid, polymerization oleic acid, tall oil acid; Inhibiter is methyl benzotriazole; Extreme pressure agent is the mixture of phosphoric acid ester, chlorine-containing polymer; Defoamer is modification dimethyl siloxane; Sterilant is methylisothiazolinone.
Embodiment 3
Wherein, base oil is paraffinic based oil; Alkalescence retention agent is α-amino isopropyl alcohol; Tensio-active agent is the mixture of petroleum sodium sulfonate, fatty alcohol-polyoxyethylene ether; Rust-preventive agent is the mixture of sulfonic acid ammonia salt, boric acid ester; Emulsifying agent is the mixture of isomery hexadecanol and tall oil acid; Inhibiter is phosphoric acid ester; Extreme pressure agent is sulfide aliphatic acid ester; Defoamer is polyethers; Sterilant is methyl benzoate.
Embodiment 4
Wherein, base oil is naphthene base crude oil; Alkalescence retention agent is trolamine; Tensio-active agent is the mixture of petroleum sodium sulfonate, fatty alcohol-polyoxyethylene ether; Rust-preventive agent is sulfonic acid ammonia salt; Emulsifying agent is animal oleic acid; Inhibiter is 124 Triazole; Extreme pressure agent is chlorine-containing polymer; Defoamer is silicone emulsion; Sterilant is triazines.
Embodiment 5
Wherein, base oil is paraffinic based oil; Alkalescence retention agent is 2-amino, 2-methylpropanol; Tensio-active agent is the mixture of petroleum sodium sulfonate, fatty alcohol-polyoxyethylene ether; Rust-preventive agent is boric acid; Emulsifying agent is polymerization oleic acid; Inhibiter is methyl benzotriazole; Extreme pressure agent is phosphoric acid ester; Defoamer is modification dimethyl siloxane; Sterilant is methylisothiazolinone.
In the present invention, the preparation method of this abrasive, economical microemulsified metal working fluid, comprise the steps: in base oil, add alkaline retention agent, tensio-active agent, rust-preventive agent, emulsifying agent, inhibiter, extreme pressure agent, defoamer, sterilant, water etc., mixing and stirring, obtains abrasive, economical microemulsified metal working fluid.
The abrasive of above-described embodiment gained, the performance index of economical microemulsified metal working fluid see the following form:
As seen from the above table, abrasive of the present invention, economical microemulsified metal working fluid be good compared with large-temperature range internal stability, performance with long preservation period; And after 20 times of stoste dilutions, data presentation abrasive of the present invention, economical microemulsified metal working fluid all have high-performance at aspects such as stability, oilness, rust-preventing characteristic, cooling, antifoam performances.
The present invention is not subject to the restriction of above-mentioned embodiment, and other any do not deviate from change, the modification done under spirit of the present invention and principle, substitutes, combination, simplify, and all should be equivalent substitute mode, within being included in protection scope of the present invention.
Claims (10)
1. abrasive, an economical microemulsified metal working fluid, wherein each feed composition counts by weight percentage, and its composition and content are as follows:
2. abrasive as claimed in claim 1, economical microemulsified metal working fluid, is characterized in that: described base oil is the one in paraffinic based oil or naphthene base crude oil.
3. abrasive as claimed in claim 1 or 2, economical microemulsified metal working fluid, is characterized in that: described alkaline retention agent is α-amino isopropyl alcohol, trolamine, monoethanolamine, 2-amino, one or more in 2-methylpropanol.
4. abrasive as claimed in claim 3, economical microemulsified metal working fluid, is characterized in that: described tensio-active agent is the mixture of petroleum sodium sulfonate and fatty alcohol-polyoxyethylene ether.
5. abrasive as claimed in claim 4, economical microemulsified metal working fluid, is characterized in that: described rust-preventive agent is one or more the mixture in boric acid, sebacic acid, lauric acid, sulfonic acid ammonia salt, boric acid ester and oleic acid.
6. abrasive as claimed in claim 5, economical microemulsified metal working fluid, is characterized in that: described emulsifying agent is one or more the mixture in animal oleic acid, vegetable oil acid, polymerization oleic acid, isomery hexadecanol and tall oil acid.
7. abrasive as claimed in claim 6, economical microemulsified metal working fluid, is characterized in that: described inhibiter is the one in 124 Triazole, methyl benzotriazole, phosphoric acid ester.
8. abrasive as claimed in claim 7, economical microemulsified metal working fluid, is characterized in that: described extreme pressure agent is one or more the mixture in phosphoric acid ester, sulfide aliphatic acid ester, chlorine-containing polymer.
9. abrasive as claimed in claim 8, economical microemulsified metal working fluid, is characterized in that: described defoamer is silicone emulsion, modification dimethyl siloxane or polyethers.
10. abrasive as claimed in claim 9, economical microemulsified metal working fluid, is characterized in that: described sterilant is the one in triazines, methylisothiazolinone, methyl benzoate.
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| CN104327925A (en) * | 2014-10-21 | 2015-02-04 | 苏州市宝玛数控设备有限公司 | Line-cutting emulsion liquid |
| CN104479833A (en) * | 2014-12-17 | 2015-04-01 | 江苏鑫露新材料股份有限公司 | High-efficiency safe environment-friendly all-synthetic cutting fluid and preparation method thereof |
| CN104560344A (en) * | 2014-10-09 | 2015-04-29 | 金寨县宏拓机电有限责任公司 | Lubricant and preparation method thereof |
| CN104607891A (en) * | 2014-12-24 | 2015-05-13 | 苏州三骏工具科技有限公司 | Preparation method for integral tungsten steel milling cutter |
| CN105001964A (en) * | 2015-07-02 | 2015-10-28 | 武汉航天航科石油化学有限公司 | Microemulsified cutting fluid |
| CN105018209A (en) * | 2015-06-24 | 2015-11-04 | 柳州市邕达工配厂 | Cutting fluid |
| CN105132114A (en) * | 2015-10-13 | 2015-12-09 | 太仓市和准电子科技有限公司 | Cutting fluid for hardware processing |
| CN105154197A (en) * | 2015-08-26 | 2015-12-16 | 开封市奥科宝特种油剂有限公司 | Plant-oil-based micro-emulsion cutting fluid with high oil content |
| CN105154198A (en) * | 2015-08-26 | 2015-12-16 | 开封市奥科宝特种油剂有限公司 | Novel biodegradable vegetable-oil-based water-soluble cutting fluid |
| CN105219506A (en) * | 2015-10-13 | 2016-01-06 | 太仓市和准电子科技有限公司 | A kind of five metals manufacturing milk agent |
| CN105820864A (en) * | 2016-04-18 | 2016-08-03 | 和县隆盛精密机械有限公司 | Cutting working liquid for numerically-controlled machine tool and preparation method of cutting working liquid |
| CN105861135A (en) * | 2016-04-14 | 2016-08-17 | 上海禾泰特种润滑科技股份有限公司 | Environment-friendly metal cutting liquid and preparing method thereof |
| CN106118834A (en) * | 2016-06-22 | 2016-11-16 | 东莞市科泽润滑油有限公司 | A kind of service life length aluminum alloy cutting fluid and preparation method thereof |
| CN106190480A (en) * | 2016-07-13 | 2016-12-07 | 天长市润达金属防锈助剂有限公司 | A kind of anti-rust metal cutting fluid of high lubricating property |
| CN106190479A (en) * | 2016-07-13 | 2016-12-07 | 天长市润达金属防锈助剂有限公司 | The magnesium alloy cutting fluid that a kind of low bubble cooling performance is good |
| CN106244295A (en) * | 2016-07-13 | 2016-12-21 | 天长市润达金属防锈助剂有限公司 | A kind of extreme boundary lubrication metalworking fluid |
| CN106281612A (en) * | 2016-08-10 | 2017-01-04 | 天长市润达金属防锈助剂有限公司 | A kind of semi-synthetic cutting fluid |
| CN106675744A (en) * | 2016-12-27 | 2017-05-17 | 长沙艾森设备维护技术有限公司 | Water-based metal rust inhibitor |
| CN106694969A (en) * | 2017-03-03 | 2017-05-24 | 潘勇 | Automobile headlight lampshade bright surface machining method and cutting fluid for machining method |
| CN107099367A (en) * | 2017-06-08 | 2017-08-29 | 广州市联诺化工科技有限公司 | A kind of floorboard with high oil content, environment-friendly water-based semi-synthetic cutting fluid of high anti-friction performance and preparation method thereof |
| CN107868693A (en) * | 2017-11-24 | 2018-04-03 | 重庆信人科技发展有限公司 | A kind of strong inhibition micro-emulsion cutting fluid |
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| CN111218324A (en) * | 2020-03-03 | 2020-06-02 | 诺而曼环保科技（江苏）有限公司 | Ultra-high-content micro-emulsified cutting fluid for machining |
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- 2014-07-29 CN CN201410367711.2A patent/CN104087404A/en active Pending
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| CN104327925A (en) * | 2014-10-21 | 2015-02-04 | 苏州市宝玛数控设备有限公司 | Line-cutting emulsion liquid |
| CN104479833A (en) * | 2014-12-17 | 2015-04-01 | 江苏鑫露新材料股份有限公司 | High-efficiency safe environment-friendly all-synthetic cutting fluid and preparation method thereof |
| CN104607891A (en) * | 2014-12-24 | 2015-05-13 | 苏州三骏工具科技有限公司 | Preparation method for integral tungsten steel milling cutter |
| CN105018209A (en) * | 2015-06-24 | 2015-11-04 | 柳州市邕达工配厂 | Cutting fluid |
| CN105001964A (en) * | 2015-07-02 | 2015-10-28 | 武汉航天航科石油化学有限公司 | Microemulsified cutting fluid |
| CN105154197A (en) * | 2015-08-26 | 2015-12-16 | 开封市奥科宝特种油剂有限公司 | Plant-oil-based micro-emulsion cutting fluid with high oil content |
| CN105154198A (en) * | 2015-08-26 | 2015-12-16 | 开封市奥科宝特种油剂有限公司 | Novel biodegradable vegetable-oil-based water-soluble cutting fluid |
| CN105132114A (en) * | 2015-10-13 | 2015-12-09 | 太仓市和准电子科技有限公司 | Cutting fluid for hardware processing |
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| CN105861135A (en) * | 2016-04-14 | 2016-08-17 | 上海禾泰特种润滑科技股份有限公司 | Environment-friendly metal cutting liquid and preparing method thereof |
| CN105861135B (en) * | 2016-04-14 | 2019-10-22 | 上海禾泰特种润滑科技股份有限公司 | Green metal cutting fluid and preparation method thereof |
| CN105820864A (en) * | 2016-04-18 | 2016-08-03 | 和县隆盛精密机械有限公司 | Cutting working liquid for numerically-controlled machine tool and preparation method of cutting working liquid |
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| CN106244295A (en) * | 2016-07-13 | 2016-12-21 | 天长市润达金属防锈助剂有限公司 | A kind of extreme boundary lubrication metalworking fluid |
| CN106190479A (en) * | 2016-07-13 | 2016-12-07 | 天长市润达金属防锈助剂有限公司 | The magnesium alloy cutting fluid that a kind of low bubble cooling performance is good |
| CN106190480A (en) * | 2016-07-13 | 2016-12-07 | 天长市润达金属防锈助剂有限公司 | A kind of anti-rust metal cutting fluid of high lubricating property |
| CN106281612A (en) * | 2016-08-10 | 2017-01-04 | 天长市润达金属防锈助剂有限公司 | A kind of semi-synthetic cutting fluid |
| CN106675744A (en) * | 2016-12-27 | 2017-05-17 | 长沙艾森设备维护技术有限公司 | Water-based metal rust inhibitor |
| CN106694969A (en) * | 2017-03-03 | 2017-05-24 | 潘勇 | Automobile headlight lampshade bright surface machining method and cutting fluid for machining method |
| CN107099367A (en) * | 2017-06-08 | 2017-08-29 | 广州市联诺化工科技有限公司 | A kind of floorboard with high oil content, environment-friendly water-based semi-synthetic cutting fluid of high anti-friction performance and preparation method thereof |
| CN107868693A (en) * | 2017-11-24 | 2018-04-03 | 重庆信人科技发展有限公司 | A kind of strong inhibition micro-emulsion cutting fluid |
| CN111218324A (en) * | 2020-03-03 | 2020-06-02 | 诺而曼环保科技（江苏）有限公司 | Ultra-high-content micro-emulsified cutting fluid for machining |
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Application publication date: 20141008 |