CN111218324A - Ultra-high-content micro-emulsified cutting fluid for machining - Google Patents

Ultra-high-content micro-emulsified cutting fluid for machining Download PDF

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Publication number
CN111218324A
CN111218324A CN202010138413.1A CN202010138413A CN111218324A CN 111218324 A CN111218324 A CN 111218324A CN 202010138413 A CN202010138413 A CN 202010138413A CN 111218324 A CN111218324 A CN 111218324A
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sulfonate
cutting fluid
barium
ferrous metals
petroleum
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吴爱平
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Rema Environmental Protection Technology Jiangsu Co ltd
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Rema Environmental Protection Technology Jiangsu Co ltd
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M167/00Lubricating compositions characterised by the additive being a mixture of a macromolecular compound, a non-macromolecular compound and a compound of unknown or incompletely defined constitution, each of these compounds being essential
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/12Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • C10M2207/126Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids monocarboxylic
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40Fatty vegetable or animal oils
    • C10M2207/402Castor oils
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/104Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/109Polyethers, i.e. containing di- or higher polyoxyalkylene groups esterified
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2215/042Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/02Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
    • C10M2219/024Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of esters, e.g. fats
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044Sulfonic acids, Derivatives thereof, e.g. neutral salts
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2227/00Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
    • C10M2227/06Organic compounds derived from inorganic acids or metal salts
    • C10M2227/061Esters derived from boron

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

The invention discloses an ultra-high content microemulsion cutting fluid for machining, which is compounded by the following raw materials in percentage by weight and comprises the following components: 4-8% of polyether; ricinoleic acid synthetic fat 9-13% oleic soap 3-7%; 2-6% of polycarboxylic acid; 10-12% of triethanolamine; 0.3 to 1 percent of bactericide; 2-5% of vulcanized lard oil; 3-4% of borate; 3-8% of polyethylene glycol ester; 2-7% of hydrophilic surfactant; 3-8% of petroleum sodium sulfonate, barium petroleum sulfonate and barium dinonyl naphthalene sulfonate; the microemulsified cutting fluid disclosed by the invention has excellent extreme pressure lubrication effect, 6% of working fluid can be used for tapping fine teeth through stainless steel blind holes and extruding fine teeth through aluminum alloy blind holes, has excellent rust prevention effect on ferrous metals and non-oxidation effect on non-ferrous metals, effectively solves the contradiction during simultaneous processing of the ferrous metals and the non-ferrous metals, and has the service life of half a year.

Description

Ultra-high-content micro-emulsified cutting fluid for machining
Technical Field
The invention relates to the field of cutting fluid, in particular to ultra-high-content micro-emulsified cutting fluid for machining.
Background
The cutting fluid is generally a working fluid used for taking away heat generated in a cutting area in time to reduce cutting temperature, prolong the service life of a cutter and improve the processing precision of a workpiece in the mechanical processing process of the material. The cutting fluid usually has the functions of lubrication, cooling, cleaning, rust prevention and the like, but the prior cutting fluid cannot realize the simultaneous processing of ferrous metals and nonferrous metals and has the problem of short service life.
Disclosure of Invention
The invention aims to provide the ultra-high-content micro-emulsified cutting fluid for machining, which can realize the simultaneous machining of ferrous metals and nonferrous metals.
The technical scheme adopted by the invention for solving the technical problems is as follows: the ultra-high content micro-emulsified cutting fluid for machining is compounded by the following raw materials in percentage by weight:
Figure BDA0002398148750000011
further, the method comprises the following steps: the proportion of the petroleum sodium sulfonate, the petroleum barium sulfonate and the barium dinonyl naphthalene sulfonate is 45: 40: 15.
further, the method comprises the following steps: the petroleum sodium sulfonate, the petroleum barium sulfonate and the barium dinonylnaphthalene sulfonate are compounded at the temperature of 55 ℃.
Further, the method comprises the following steps: the composite material is compounded by the following raw materials in percentage by weight:
Figure BDA0002398148750000012
Figure BDA0002398148750000021
wherein:
the proportion of petroleum sodium sulfonate, petroleum barium sulfonate and barium dinonyl naphthalene sulfonate is 45: 40: 15.
the invention has the beneficial effects that: the microemulsified cutting fluid disclosed by the invention has excellent extreme pressure lubrication effect, 6% of working fluid can tap fine teeth through stainless steel blind holes, squeeze teeth through aluminum alloy blind holes, has excellent rust prevention effect on ferrous metals and non-oxidation effect on non-ferrous metals, effectively solves the contradiction when ferrous metals and non-ferrous metals are simultaneously processed, and has a service life as long as half a year.
Detailed Description
The present invention will be described in detail with reference to the following embodiments so that the above objects, features and advantages of the invention can be understood more clearly. In the following description, numerous specific details are set forth in order to provide a thorough understanding of the present invention. This invention may, however, be embodied in many different forms and should not be construed as limited to the embodiments set forth herein.
The invention discloses an ultra-high content microemulsion cutting fluid for machining, which is compounded by the following raw materials in percentage by weight and comprises the following components:
Figure BDA0002398148750000022
Figure BDA0002398148750000031
wherein:
the proportion of petroleum sodium sulfonate, petroleum barium sulfonate and barium dinonyl naphthalene sulfonate is 45: 40: 15, and compounding at 55 ℃;
the base oil is used for lubrication and as a carrier;
the polyether is used as an emulsifier and has a lubricating effect;
the synthetic ricinoleic acid ester has the functions of lubrication and extreme pressure;
the oleic acid soap has the following functions: lubrication, rust prevention and emulsification;
the function of the polycarboxylic acid is rust prevention;
the triethanolamine (80% content) has the functions of rust prevention, lubrication, pH adjustment and maintenance;
the bactericide has the function of antisepsis;
the vulcanized lard has the functions of lubrication and extreme pressure;
the boric acid ester has the functions of lubrication and aluminum protection;
the polyethylene glycol ester has the function of lubrication;
the hydrophilic surfactant functions in emulsification and HLB adjustment;
the compounding effect of the petroleum sodium sulfonate, the petroleum barium sulfonate and the dinonyl barium naphthalene sulfonate is rust prevention.
The microemulsified cutting fluid disclosed by the invention has excellent extreme pressure lubrication effect, 6% of working fluid can tap fine teeth through stainless steel blind holes, squeeze teeth through aluminum alloy blind holes, has excellent rust prevention effect on ferrous metals and non-oxidation effect on non-ferrous metals, effectively solves the contradiction when ferrous metals and non-ferrous metals are simultaneously processed, and has a service life as long as half a year.
The following are specific examples:
the first embodiment is as follows:
Figure BDA0002398148750000032
Figure BDA0002398148750000041
wherein:
the proportion of petroleum sodium sulfonate, petroleum barium sulfonate and barium dinonyl naphthalene sulfonate is 45: 40: 15, and compounding at 55 DEG C
Example two:
Figure BDA0002398148750000042
wherein:
the proportion of petroleum sodium sulfonate, petroleum barium sulfonate and barium dinonyl naphthalene sulfonate is 45: 40: 15, and compounding at 55 DEG C
Example three:
Figure BDA0002398148750000043
Figure BDA0002398148750000051
wherein:
the proportion of petroleum sodium sulfonate, petroleum barium sulfonate and barium dinonyl naphthalene sulfonate is 45: 40: 15, and compounding at 55 ℃.
The following are experimental data for cutting fluids using the above composition:
Figure BDA0002398148750000052
the above-mentioned embodiments are intended to illustrate the objects, technical solutions and advantages of the present invention in further detail, and it should be understood that the above-mentioned embodiments are only exemplary embodiments of the present invention, and are not intended to limit the present invention, and any modifications, equivalents, improvements and the like made within the spirit and principle of the present invention should be included in the protection scope of the present invention.

Claims (4)

1. The ultra-high-content micro-emulsified cutting fluid for machining is characterized by being compounded from the following raw materials in percentage by weight:
Figure FDA0002398148740000011
2. the ultra-high content microemulsion cutting fluid for machining according to claim 1, wherein the ratio of sodium petroleum sulfonate, barium petroleum sulfonate and barium dinonylnaphthalene sulfonate is 45: 40: 15.
3. the ultra-high content microemulsion cutting fluid for machining according to claim 2, wherein the petroleum sodium sulfonate, the petroleum barium sulfonate and the dinonylnaphthalene barium sulfonate are compounded at 55 ℃.
4. The ultra-high content microemulsion cutting fluid for machining according to claim 3, which is prepared by compounding the following raw materials in percentage by weight:
Figure FDA0002398148740000012
Figure FDA0002398148740000021
wherein:
the proportion of petroleum sodium sulfonate, petroleum barium sulfonate and barium dinonyl naphthalene sulfonate is 45: 40: 15.
CN202010138413.1A 2020-03-03 2020-03-03 Ultra-high-content micro-emulsified cutting fluid for machining Pending CN111218324A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111662772A (en) * 2020-06-28 2020-09-15 苏州德韬科技有限公司 Semisynthetic water-soluble cutting fluid for machining

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1362281A (en) * 2001-01-05 2002-08-07 中国石油化工股份有限公司 Emulsifier for metal-machining emulsified oil and emulsified oil composition
CN104087404A (en) * 2014-07-29 2014-10-08 马思特(上海)化学有限公司 High-cleanliness economical microemulsion metal cutting fluid
CN108285824A (en) * 2017-12-22 2018-07-17 上海康达新能源材料有限公司 A kind of hard brittle material multi-wire saw coolant liquid

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1362281A (en) * 2001-01-05 2002-08-07 中国石油化工股份有限公司 Emulsifier for metal-machining emulsified oil and emulsified oil composition
CN104087404A (en) * 2014-07-29 2014-10-08 马思特(上海)化学有限公司 High-cleanliness economical microemulsion metal cutting fluid
CN108285824A (en) * 2017-12-22 2018-07-17 上海康达新能源材料有限公司 A kind of hard brittle material multi-wire saw coolant liquid

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111662772A (en) * 2020-06-28 2020-09-15 苏州德韬科技有限公司 Semisynthetic water-soluble cutting fluid for machining

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Application publication date: 20200602