CN106118834A - A kind of service life length aluminum alloy cutting fluid and preparation method thereof - Google Patents

A kind of service life length aluminum alloy cutting fluid and preparation method thereof Download PDF

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Publication number
CN106118834A
CN106118834A CN201610456793.7A CN201610456793A CN106118834A CN 106118834 A CN106118834 A CN 106118834A CN 201610456793 A CN201610456793 A CN 201610456793A CN 106118834 A CN106118834 A CN 106118834A
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cutting fluid
service life
aluminum alloy
agent
alloy cutting
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CN106118834B (en
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雷海
李清华
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Dongguan Keze Lubricant Co
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Dongguan Keze Lubricant Co
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Abstract

The present invention relates to metalworking fluid field, be specifically related to aluminum alloy cutting fluid of length in a kind of service life and preparation method thereof.The semi-synthetic cutting fluid of the present invention is made up of 10% 30% mineral oil, 5% 15% hydramine, 5% 12% emulsifying agents, 3% 8% antirust agent, 3% 10% lubricants, 1% 4% corrosion inhibiter, 1% 4% extreme pressure agents, 0.5% 1% defoamer, 1% 3% antibacterial, inventive formulation has abandoned traditional monoethanolamine, diethanolamine, triethanolamine as pH adjusting agent, and by distinguishingly compounding pattern, make cutting fluid have more preferable stability, reduce cost simultaneously.Secondly, the present invention adjusts also by the consumption of each raw material, reduces the consumption of extreme pressure agent, and keep the effect of anticorrosion lubrication that cutting fluid is excellent, it is possible to and life-time service, the cycle of cutting fluid changing a present invention is about 1 year, environmentally friendly, human body infringement is minimum.

Description

A kind of service life length aluminum alloy cutting fluid and preparation method thereof
Technical field
The present invention relates to metalworking fluid field, be specifically related to aluminum alloy cutting fluid and the preparation thereof of length in a kind of service life Method.
Background technology
In prior art, aluminium alloy density is low, but strength ratio is higher, and plasticity is good, can be processed into various section bar, has excellent Heat-conductivity conducting and preferable corrosion resistance, widely, usage amount is only second to steel to purposes industrially, but aluminium alloy Chemism is relatively strong, quality is the softest, and viscosity is strong, the problems such as viscous cutter, variable color easily occurs, therefore process for aluminium alloy in processing The demand of special cutting fluid the most growing.
Metalworking fluid always is emphasis of concern service life, needs to add list in traditional metalworking fluid The hydramine material such as ethanolamine, triethanolamine extends the service life of cutting fluid, but also can easily cause aluminium burn into simultaneously and become The bad phenomenon such as color, and those hydramine materials have volatility, have serious zest to eyes and skin, serious harm produces Workman's is healthy.
Number of patent application be 201210444791.8 patent of invention disclose a kind of semi-synthetic cutting fluid of aluminium alloy, this is special Profit product has certain cutting protective effect, but it still uses traditional monoethanolamine, diethanolamine, triethanolamine, The most still there is the biggest restriction.Secondly, additionally using a large amount of chlorinated paraffin, chlorinated paraffin is as extreme pressure agent Principle is under high temperature to occur C-Cl bond fission, and wherein the Fe element in Cl and metal friction face reacts the FeCl3 generated It is one layer of solid lubricant film that coefficient of friction is little, shear strength is low, resistance to extreme pressure can be high, thus reaches the effect of anticorrosion lubrication. But there are two big shortcomings in it: 1, its effect is limited to alfer；2, easily produce free chloride ion, and chloride ion is to metal There is stronger corrosiveness.Although chlorinated paraffin is inexpensive, relate to environmental pollution and poison yet with processing chlorination waste liquid Sex chromosome mosaicism, therefore from the eighties in 19th century, Europe has gradually reduced chlorinated paraffin use in machining of metals liquid, Particularly Germany, is prohibitting the use of chlorinated paraffin or chloride containing wax additive 20th century.
Therefore, develop that a kind of Corrosion Protection is good and the aluminum alloy cutting fluid of the function admirable of length in service life has been to work as It is engaged in anxious.
Summary of the invention
It is an object of the invention to for above-mentioned deficiency of the prior art, it is provided that a kind of Corrosion Protection is good and uses the longevity Aluminum alloy cutting fluid of function admirable that life is long and preparation method thereof.
The purpose of the present invention is achieved through the following technical solutions:
A kind of service life length aluminum alloy cutting fluid, comprise the following raw materials by weight percent:
Mineral oil 10%-30%
Hydramine 5%-15%
Emulsifying agent 5%-12%
Antirust agent 3%-8%
Lubricant 3%-10%
Corrosion inhibiter 1%-4%
Extreme pressure agent 1%-4%
Defoamer 0.5%-1%
Antibacterial 1%-3%
Surplus is water；
Wherein said hydramine is in diglycolamine, N methyldiethanol amine, 2-amino-2-methyl-1-propanol and diisopropanolamine (DIPA) At least one.Preferably, described hydramine is by diglycolamine, N methyldiethanol amine, 2-amino-2-methyl-1-propanol At least one compounds with diisopropanolamine (DIPA) and forms.Diglycolamine to cobalt metal dissolving well below other amine, to aluminum metal stain Corrode low, thus extend cutting element service life；N methyldiethanol amine, 2-amino-2-methyl-1-propanol, diisopropanol Amine can play the effects such as inhibition, emulsifying, regulation pH.Inventive formulation has abandoned traditional monoethanolamine, diethanolamine, three ethanol Amine is as pH adjusting agent, and by distinguishingly compounding pattern, makes cutting fluid have more preferable stability, reduce cost simultaneously.Its Secondary, the present invention adjusts also by the consumption of each raw material, reduces the consumption of extreme pressure agent, and keeps the anticorrosion lubrication that cutting fluid is excellent Effect.
Wherein, described mineral oil is naphthenic mineral oil or paraffin base mineral oil.
Wherein, described emulsifying agent is made up of nonionic surfactant and anion surfactant；Described nonionic table Face activating agent is at least one in fatty alcohol-polyoxyethylene ether, alkoxyl alcohol ether, fatty acid amide, and described anionic surface is lived Property agent is petroleum sodium sulfonate.Nonionic surfactant stability is high, is susceptible to strong electrolyte impact, is not easy to by Acidity of Aikalinity shadow Ring, good with anion surfactant compatibility, and by using specific surfactant, be conducive to improving emulsifying agent and divide Dissipate, emulsifying, the effect of moistening, solve traditional semi-synthetic cutting fluid wettability difference problem.
Wherein, described emulsifying agent is by nonionic surfactant and the ratio of anion surfactant 2:1 by weight Mixing composition.Preferably, described emulsifying agent is by fatty alcohol-polyoxyethylene ether and the ratio mixing of petroleum sodium sulfonate 2:1 by weight Composition, or be made up of the ratio mixing of alkoxyl alcohol ether and petroleum sodium sulfonate 2:1 by weight.
Wherein, described antirust agent includes borate, also includes in lauric acid, DC11, SL-AH At least one.Preferably, described antirust agent is by lauric acid: DC11: SL-AH: borate is by weight 2: The ratio mixing composition of 1:2:3, or by SL-AH: borate forms by weight the ratio mixing of 1:2, or by 11 Carbon dicarboxylic acid: SL-AH: borate is by weight the ratio mixing composition of 1:1:3.The rust-preventing characteristic of single antirust agent Can be undesirable, good synergism can reduce the consumption of additive, but the most all antirust agent all has work of mutually promoting With, some even can produce retroaction, this is because containing kinds of surface activating agent, antirust agent isopolarity molecule in cutting fluid, Their polarity is different, the most different to metal surface absorbability, and some Molecular Adsorption ability is strong but non-film is the finest and close, has A little Molecular Adsorption are indifferent but film forming fine and close.Only polar group and nonpolar group to these polar molecules carries out suitable putting down Weighing apparatus just can make polar group firmly adsorb in metal surface, and antirust agent just can show good rustless property.The Laurel of the present invention Acid, DC11, SL-AH not only can meet antirust effect, or outstanding lubricant, oiliness improver, surface Activating agent, and environmentally friendly, form compounding pattern with borate, it is possible to reduce antirust agent desired concn, reduce reagent and use Measure and improve antirust ability.And borate can metal friction surface formed adsorbed film, and by hydrolysis or and its It forms deposition film with agent generation friction chemical reaction, has excellent extreme boundary lubrication function, the extreme pressure of this formula system collaborative Agent, effectively reduces its consumption, promotes the preservative efficacy of cutting fluid.
Wherein, one or both during described lubricant is tall oil acid and self emulsifying ester.Preferably, described lubricant by The ratio mixing composition of tall oil acid and self emulsifying ester 1:1 by weight.Self emulsifying ester, tall oil acid are except having excellent profit Slip energy, also has good emulsibility, biological degradability and hypotoxicity, with petroleum sodium sulfonate, the fatty alcohol polyoxy of the present invention Vinyl Ether, alkoxyl alcohol ether, fatty acid amide compound use, it is possible to effectively reduce oil water interfacial tension, give the present invention cutting The good lubricity of liquid and excellent cooling.
Wherein, described corrosion inhibiter is at least one in triazole derivative, molybdate, siloxanes, specifically, can use wide The COINFAL A127 of Zhou meter Qi Chemical Co., Ltd. and the RC5820 of Rhein chemistry, these two kinds of corrosion inhibiter are without in current industry The traditional phosphorus used and silicate, it is possible to provide emulsifying and lubricating function, can reduce the consumption of other surfactants in formula, And by forming one layer of form compact and stable thin film in metal surface, effectively protect various aluminium alloys.
Wherein, described extreme pressure agent includes fat-based phosphate ester.The fat-based phosphate ester of the present invention can neutralize with hydramine Reaction produces fat-based phosphate ester ammonium salt, and this phosphate ester ammonium salt not only increases four ball extreme pressure properties of cutting fluid of the present invention, also Improve ladder nurse and agree extreme pressure property, the most just can manifest the extreme pressure property of its excellence, and not there is element sulphur, therefore Non-ferrous metal will not be caused corrosion.
Preferably, described extreme pressure agent is mixed by weight the ratio of 3:1 with dithiocarbamate by fat-based phosphate ester It is combined into, introduces sulfur-containing extreme-pressure additive, the fewest for Al-alloy metal side effect, but the metal sulfide film generated is more resistant to high temperature, Both is compounding collaborative, can increase substantially non-oxidizability and the wear resistence of cutting fluid.
Wherein, described defoamer is organic silicon defoamer.
Wherein, described antibacterial is 2, in 6-thebaine, BIT and iodopropynyl formic acid At least one in butyl ester.Preferably, described antibacterial by 2, the one in 6-thebaine, BIT and iodine For propynylbutylcarbamate mixing composition.One of subject matter affecting cutting fluid service life is microbial growth, makes Cutting fluid goes bad smelly, and the present invention, by the complex role of hydramine with antibacterial, effectively suppresses the breeding of microorganism.
Present invention also offers the preparation method of the aluminum alloy cutting fluid of length in a kind of service life: add successively in mineral oil Enter hydramine, emulsifying agent, antirust agent, lubricant, corrosion inhibiter, extreme pressure agent, defoamer, antibacterial and water, mixing and stirring, to obtain final product Aluminum alloy cutting fluid to length in described a kind of service life.
Beneficial effects of the present invention: 1, the present invention selects specific emulsifying agent, with mineral oil, hydramine, antirust agent, lubrication Agent, corrosion inhibiter, extreme pressure agent, defoamer, antibacterial carry out reasonable compatibility, make product of the present invention have longer service life, and Realize its excellent Corrosion Protection；2, the present invention uses hydramine and corrosion inhibiter can effectively prevent corrosion of aluminium alloy variable color, Simultaneously as have excellent pH stability and antibiotic property, substantially prolongs the service life of cutting fluid；3, the present invention uses nothing Chlorine extreme pressure agent, produces at production process non-toxic gas, reduces the damage to human body, and the present invention is made by the compatibility of each composition With, reduce the consumption of extreme pressure agent, environmentally friendly.
Detailed description of the invention
The invention will be further described with the following Examples.
Embodiment 1
The present embodiment a kind of service life length aluminum alloy cutting fluid, comprise the following raw materials by weight percent:
Mineral oil 10%
Hydramine 15%
Emulsifying agent 5%
Antirust agent 8%
Lubricant 10%
Corrosion inhibiter 4%
Extreme pressure agent 4%
Defoamer 0.5%
Antibacterial 1%
Surplus is water；
Described mineral oil is naphthenic mineral oil；
Described hydramine is mixed by weight the ratio of 1:2 by diglycolamine and diisopropanolamine (DIPA) and forms；
Described emulsifying agent is made up of the ratio mixing of fatty alcohol-polyoxyethylene ether and petroleum sodium sulfonate 2:1 by weight；
Described antirust agent is by lauric acid: DC11: SL-AH: borate is by weight the ratio of 2:1:2:3 Mixing composition；
Described lubricant is made up of the ratio mixing of tall oil acid and self emulsifying ester 1:1 by weight；
Described corrosion inhibiter is the COINFAL A127 of Guangzhou meter Qi Chemical Co., Ltd.；
Described extreme pressure agent is fat-based phosphate ester；
Described defoamer is organic silicon defoamer；
Described antibacterial is by 2,6-thebaine and the ratio mixing group of iodopropynyl butyl formate 1:1 by weight Become.
Embodiment 2
The present embodiment a kind of service life length aluminum alloy cutting fluid, comprise the following raw materials by weight percent:
Mineral oil 30%
Hydramine 5%
Emulsifying agent 12%
Antirust agent 3%
Lubricant 3%
Corrosion inhibiter 1%
Extreme pressure agent 1%
Defoamer 1%
Antibacterial 3%
Surplus is water；
Described hydramine forms by mixing by weight the ratio of 2:3 with diisopropanolamine (DIPA) in 2-amino-2-methyl-1-propanol；
Wherein, described mineral oil is paraffin base mineral oil；
Described emulsifying agent is made up of the ratio mixing of alkoxyl alcohol ether and petroleum sodium sulfonate 2:1 by weight；
Described antirust agent is made up of the ratio mixing of SL-AH and borate 1:2 by weight；
Described lubricant is tall oil acid；
Described corrosion inhibiter is the RC5820 of Rhein chemistry；
Described extreme pressure agent is fat-based phosphate ester；
Described defoamer is organic silicon defoamer
Described antibacterial is mixed with the ratio of 2:1 by weight in iodopropynyl butyl formate by BIT It is combined into.
Embodiment 3
The present embodiment a kind of service life length aluminum alloy cutting fluid, comprise the following raw materials by weight percent:
Mineral oil 20%
Hydramine 10%
Emulsifying agent 9%
Antirust agent 5%
Lubricant 6%
Corrosion inhibiter 2%
Extreme pressure agent 2%
Defoamer 1%
Antibacterial 2%
Surplus is water；
Described hydramine is made up of the ratio mixing of N methyldiethanol amine and diisopropanolamine (DIPA) 1:1 by weight；
Wherein, described mineral oil is paraffin base mineral oil；
Described emulsifying agent is made up of the ratio mixing of fatty acid amide and petroleum sodium sulfonate 2:1 by weight；
Described antirust agent is by DC11: SL-AH: borate forms by weight the ratio mixing of 1:1:3；
Described lubricant is self emulsifying ester；
Described corrosion inhibiter is the COINFAL A127 of Guangzhou meter Qi Chemical Co., Ltd.；
Described extreme pressure agent is by fat-based phosphate ester；
Described defoamer is organic silicon defoamer
Described antibacterial is 2,6-thebaine and the ratio mixing group of iodopropynyl butyl formate 1:1 by weight Become.
Embodiment 4
The present embodiment a kind of service life length aluminum alloy cutting fluid, comprise the following raw materials by weight percent:
Mineral oil 25%
Hydramine 7%
Emulsifying agent 10%
Antirust agent 7%
Lubricant 4%
Corrosion inhibiter 3%
Extreme pressure agent 2.5%
Defoamer 0.8%
Antibacterial 1.5%
Surplus is water；
Described hydramine is made up of the ratio mixing of diglycolamine, N methyldiethanol amine and diisopropanolamine (DIPA) 1:1:1 by weight；
Wherein, described mineral oil is naphthenic mineral oil；
Described emulsifying agent is mixed by the ratio of fatty alcohol-polyoxyethylene ether, alkoxyl alcohol ether and petroleum sodium sulfonate 1:2:1 by weight It is combined into；
Described antirust agent is made up of by weight the ratio mixing of 2:1:3 lauric acid, DC11, borate；
Described lubricant is made up of in the ratio mixing by weight 4:1 tall oil acid and self emulsifying ester；
Described corrosion inhibiter is made up of by weight the ratio mixing of 1:2 BTA, sodium molybdate；
Described extreme pressure agent is mixed by weight the ratio of 3:1 by fat-based phosphate ester and dithiocarbamate and forms；
Described defoamer is organic silicon defoamer；
Described antibacterial by 2,6-thebaine, BIT and iodopropynyl butyl formate by weight Ratio mixing composition than 1:1:2.
Embodiment 5
The present embodiment a kind of service life length aluminum alloy cutting fluid, comprise the following raw materials by weight percent:
Mineral oil 15%
Hydramine 12%
Emulsifying agent 7%
Antirust agent 4%
Lubricant 4%
Corrosion inhibiter 2%
Extreme pressure agent 3%
Defoamer 0.6%
Antibacterial 2.3%
Surplus is water；
Described hydramine is by diglycolamine, N methyldiethanol amine, 2-amino-2-methyl-1-propanol and diisopropanolamine (DIPA) by weight Ratio mixing composition than 1:2:2:3；
Wherein, described mineral oil is paraffin base mineral oil；
Described emulsifying agent is mixed by the ratio of fatty alcohol-polyoxyethylene ether, fatty acid amide and petroleum sodium sulfonate 3:2:2 by weight It is combined into；
Described antirust agent is made up of the ratio mixing of DC11, SL-AH and borate 1:2:1 by weight；
Described lubricant is self emulsifying ester；
Described corrosion inhibiter is that sodium molybdate and silica alkanone are in the ratio mixing composition by weight 1:1；
Described extreme pressure agent is mixed by weight the ratio of 2:1 by fat-based phosphate ester and dithiocarbamate and forms；
Described defoamer is organic silicon defoamer；
Described antibacterial be 2,6-thebaine, BIT and iodopropynyl butyl formate by weight The ratio mixing composition of 1:2:3.
Embodiment 6
The present embodiment a kind of service life length aluminum alloy cutting fluid, comprise the following raw materials by weight percent:
Mineral oil 12%
Hydramine 14%
Emulsifying agent 7%
Antirust agent 7%
Lubricant 6%
Corrosion inhibiter 1.5%
Extreme pressure agent 3.5%
Defoamer 0.9%
Antibacterial 1.8%
Surplus is water；
Described hydramine is pressed by diglycolamine, N methyldiethanol amine, 2-amino-2-methyl-1-propanol weigh with diisopropanolamine (DIPA) The amount ratio mixing composition than 1:1:3:2；
Wherein, described mineral oil is naphthenic mineral oil；
Described emulsifying agent is by fatty alcohol-polyoxyethylene ether, alkoxyl alcohol ether, fatty acid amide and petroleum sodium sulfonate weight ratio 2:1: The ratio mixing composition of 1:2；
Described antirust agent is by the ratio of lauric acid, DC11, SL-AH and borate 3:1:3:4 by weight Mixing composition；
Described lubricant is made up of the ratio mixing of tall oil acid and self emulsifying ester 1:3 by weight；
Described corrosion inhibiter is made up of by weight the ratio mixing of 2:2:3 BTA, sodium molybdate, silica alkanone；
Described extreme pressure agent is mixed by weight the ratio of 1:1 by fat-based phosphate ester and dithiocarbamate and forms；
Described defoamer is organic silicon defoamer；
Described antibacterial by 2,6-thebaine, BIT and iodopropynyl butyl formate by weight Ratio mixing composition than 1:1:1.
Embodiment 7
The present embodiment a kind of service life length aluminum alloy cutting fluid, comprise the following raw materials by weight percent:
Mineral oil 28%
Hydramine 13%
Emulsifying agent 10%
Antirust agent 4.5%
Lubricant 8.5%
Corrosion inhibiter 3.2%
Extreme pressure agent 2.2%
Defoamer 0.75%
Antibacterial 2.6%
Surplus is water；
Described hydramine is by diglycolamine, N methyldiethanol amine, 2-amino-2-methyl-1-propanol and diisopropanolamine (DIPA) by weight Ratio mixing composition than 3:2:1:5；
Wherein, described mineral oil is paraffin base mineral oil；
Described emulsifying agent is by fatty alcohol-polyoxyethylene ether, alkoxyl alcohol ether, fatty acid amide and petroleum sodium sulfonate by weight 1: The ratio mixing composition of 1:2:2；
Described antirust agent is made up of the ratio mixing of lauric acid, SL-AH and borate 1:1:2 by weight；
Described lubricant is made up of the ratio mixing of tall oil acid and self emulsifying ester 3:2 by weight；
Described corrosion inhibiter is made up of by weight the ratio mixing of 1:3:3 BTA, sodium molybdate, silica alkanone；
Described extreme pressure agent is mixed by weight the ratio of 3:2 by fat-based phosphate ester and dithiocarbamate and forms；
Described defoamer is organic silicon defoamer；
Described antibacterial by 2,6-thebaine, BIT and iodopropynyl butyl formate by weight Ratio mixing composition than 1:1:4.
Embodiment 8
The present embodiment a kind of service life length aluminum alloy cutting fluid, comprise the following raw materials by weight percent:
Mineral oil 17%
Hydramine 11%
Emulsifying agent 9%
Antirust agent 5%
Lubricant 5%
Corrosion inhibiter 3%
Extreme pressure agent 1%
Defoamer 0.9%
Antibacterial 3%
Surplus is water；
Described hydramine is by diglycolamine, N methyldiethanol amine, 2-amino-2-methyl-1-propanol and diisopropanolamine (DIPA) by weight Ratio mixing composition than 1:2:1:2；
Wherein, described mineral oil is naphthenic mineral oil；
Described emulsifying agent is made up of the ratio mixing of fatty alcohol-polyoxyethylene ether and petroleum sodium sulfonate 1:1 by weight；
Described antirust agent is made up of the ratio mixing of lauric acid and borate 1:2 by weight；
Described lubricant is mixed by the ratio of tall oil acid and self emulsifying ester 1:1 by weight and forms；
Described corrosion inhibiter is sodium molybdate；
Described extreme pressure agent is mixed by weight the ratio of 3:1 by fat-based phosphate ester and dithiocarbamate and forms；
Described defoamer is organic silicon defoamer；
Described antibacterial by 2,6-thebaine, BIT and iodopropynyl butyl formate by weight Ratio mixing composition than 3:1:2.
Embodiment 1-8 respectively by be sequentially added in mineral oil hydramine, emulsifying agent, antirust agent, lubricant, corrosion inhibiter, Extreme pressure agent, defoamer, antibacterial and water, mixing and stirring, i.e. obtain the aluminium alloy cutting of length in described a kind of service life Liquid.
Embodiment 1-8 is carried out GB/T6144 and GB/T7919 test, obtains GB/T6144 test table (following table).
The cutting fluid of embodiment 1-8 is the most chloride, nitrite, phenol, by the test of GB/T6144 " synthetic cutting fluid " With the toxicity test of GB/T7919, anti-rust and corrosionproperties is excellent, especially applies antiseptic effect on aluminium alloy notable, it is possible to long-term Using, through client feedback, the cycle of the cutting fluid changing a present invention is about 1 year, environmentally friendly, human body infringement pole Little.
Last it should be noted that, above example is only in order to illustrate technical scheme, rather than the present invention is protected Protecting the restriction of scope, although having made to explain to the present invention with reference to preferred embodiment, those of ordinary skill in the art should Work as understanding, technical scheme can be modified or equivalent, without deviating from the reality of technical solution of the present invention Matter and scope.

Claims (10)

1. one kind service life length aluminum alloy cutting fluid, it is characterised in that: comprise the following raw materials by weight percent:
Mineral oil 10%-30%
Hydramine 5%-15%
Emulsifying agent 5%-12%
Antirust agent 3%-8%
Lubricant 3%-10%
Corrosion inhibiter 1%-4%
Extreme pressure agent 1%-4%
Defoamer 0.5%-1%
Antibacterial 1%-3%
Surplus is water；
Wherein said hydramine is in diglycolamine, N methyldiethanol amine, 2-amino-2-methyl-1-propanol and diisopropanolamine (DIPA) At least one.
A kind of service life the most according to claim 1 length aluminum alloy cutting fluid, it is characterised in that: described mineral oil is Naphthenic mineral oil or paraffin base mineral oil.
A kind of service life the most according to claim 1 length aluminum alloy cutting fluid, it is characterised in that: described emulsifying agent by Nonionic surfactant and anion surfactant composition；Described nonionic surfactant is aliphatic alcohol polyethenoxy At least one in ether, alkoxyl alcohol ether, fatty acid amide, described anion surfactant is petroleum sodium sulfonate.
A kind of service life the most according to claim 3 length aluminum alloy cutting fluid, it is characterised in that: described emulsifying agent by The ratio mixing composition of nonionic surfactant and anion surfactant 2:1 by weight.
A kind of service life the most according to claim 1 length aluminum alloy cutting fluid, it is characterised in that: described antirust agent bag Include borate, also include at least one in lauric acid, DC11, SL-AH.
A kind of service life the most according to claim 1 length aluminum alloy cutting fluid, it is characterised in that: described lubricant is One or both in tall oil acid and self emulsifying ester.
A kind of service life the most according to claim 1 length aluminum alloy cutting fluid, it is characterised in that: described extreme pressure agent bag Include fat-based phosphate ester.
A kind of service life the most according to claim 1 length aluminum alloy cutting fluid, it is characterised in that: described defoamer is Organic silicon defoamer.
A kind of service life the most according to claim 1 length aluminum alloy cutting fluid, it is characterised in that: described antibacterial is At least one in 2,6-thebaine, BIT and in iodopropynyl butyl formate.
10. described in claim 1-9 any one a kind of service life length the preparation method of aluminum alloy cutting fluid, its feature It is: in mineral oil, be sequentially added into hydramine, emulsifying agent, antirust agent, lubricant, corrosion inhibiter, extreme pressure agent, defoamer, antibacterial And water, mixing and stirring, i.e. obtain the aluminum alloy cutting fluid of length in described a kind of service life.
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Cited By (23)

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Publication number Priority date Publication date Assignee Title
CN106590882A (en) * 2016-12-20 2017-04-26 武汉航天航科石油化学有限公司 Emulsion cutting fluid
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Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101240218A (en) * 2008-02-29 2008-08-13 益田润石（北京）化工有限公司 Emulsification type metal cutting liquor composition
CN101240217A (en) * 2008-02-29 2008-08-13 益田润石（北京）化工有限公司 Micro-emulsion type metal cutting liquor composition
CN102492533A (en) * 2011-11-28 2012-06-13 上海应用技术学院 Hard water-resistant semi-synthetic metal cutting fluid and preparation method thereof
CN102618358A (en) * 2012-03-06 2012-08-01 上海应用技术学院 Green micro-emulsification metal machining liquid and preparation method thereof
CN102643708A (en) * 2012-04-13 2012-08-22 广州市联诺化工科技有限公司 High-oil-content environment-friendly aqueous cutting fluid and preparing method thereof
CN102660364A (en) * 2012-04-17 2012-09-12 广州市联诺化工科技有限公司 Non-phosphorus non-silicon aluminum alloy cutting fluid and preparation method thereof
CN102925269A (en) * 2012-11-09 2013-02-13 上海应用技术学院 Aluminum alloy semisynthesis cutting liquid and preparation method thereof
CN103468382A (en) * 2013-08-30 2013-12-25 广州机械科学研究院有限公司 Boron-free chlorine-free formaldehyde-free microemulsified cutting fluid and application thereof
CN104087404A (en) * 2014-07-29 2014-10-08 马思特（上海）化学有限公司 High-cleanliness economical microemulsion metal cutting fluid

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101240218A (en) * 2008-02-29 2008-08-13 益田润石（北京）化工有限公司 Emulsification type metal cutting liquor composition
CN101240217A (en) * 2008-02-29 2008-08-13 益田润石（北京）化工有限公司 Micro-emulsion type metal cutting liquor composition
CN102492533A (en) * 2011-11-28 2012-06-13 上海应用技术学院 Hard water-resistant semi-synthetic metal cutting fluid and preparation method thereof
CN102618358A (en) * 2012-03-06 2012-08-01 上海应用技术学院 Green micro-emulsification metal machining liquid and preparation method thereof
CN102643708A (en) * 2012-04-13 2012-08-22 广州市联诺化工科技有限公司 High-oil-content environment-friendly aqueous cutting fluid and preparing method thereof
CN102660364A (en) * 2012-04-17 2012-09-12 广州市联诺化工科技有限公司 Non-phosphorus non-silicon aluminum alloy cutting fluid and preparation method thereof
CN102925269A (en) * 2012-11-09 2013-02-13 上海应用技术学院 Aluminum alloy semisynthesis cutting liquid and preparation method thereof
CN103468382A (en) * 2013-08-30 2013-12-25 广州机械科学研究院有限公司 Boron-free chlorine-free formaldehyde-free microemulsified cutting fluid and application thereof
CN104087404A (en) * 2014-07-29 2014-10-08 马思特（上海）化学有限公司 High-cleanliness economical microemulsion metal cutting fluid

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CN110951533B (en) * 2019-12-05 2022-04-26 金雪驰科技（马鞍山）有限公司 Long-acting micro-emulsified cutting fluid for metal processing and preparation method thereof
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WO2023050609A1 (en) * 2021-09-30 2023-04-06 安美科技股份有限公司 Metal processing cutting fluid and preparation method therefor
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