CN102250677A - High-performance environment-friendly magnetic material cutting fluid - Google Patents

High-performance environment-friendly magnetic material cutting fluid Download PDF

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Publication number
CN102250677A
CN102250677A CN2011101612853A CN201110161285A CN102250677A CN 102250677 A CN102250677 A CN 102250677A CN 2011101612853 A CN2011101612853 A CN 2011101612853A CN 201110161285 A CN201110161285 A CN 201110161285A CN 102250677 A CN102250677 A CN 102250677A
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Prior art keywords
cutting fluid
magneticsubstance
performance environment
mixture
agent
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CN2011101612853A
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CN102250677B (en
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林丽静
常建忠
阿部聪
施赛泉
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QIDONG YOUXILU CHEMICAL INDUSTRY Co Ltd
Shanghai Yushiro Chemical Industry Co Ltd
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QIDONG YOUXILU CHEMICAL INDUSTRY Co Ltd
Shanghai Yushiro Chemical Industry Co Ltd
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Abstract

The invention discloses high-performance environment-friendly magnetic material cutting fluid, which consists of an antirusting agent, surfactants, a lubricating agent, a preservative, a copper corrosion inhibitor and water. In the invention, a special water soluble polymer serving as a lubricating agent is combined with various surfactants, the antirusting agent and the copper corrosion inhibitor, so the cutting liquid has high lubricating performance and antirusting performance, the yield of processed magnetic materials is high and the processing precision is high. Because the use of strong alkali such as sodium hydroxide and potassium hydroxide is avoided, the dissolution of adhesive can be prevented. Meanwhile, the cutting liquid does not contain nitrites and therefore is an environment-friendly magnetic material cutting liquid.

Description

High-performance environment-friendly type magneticsubstance cutting fluid
Technical field
The present invention relates to the cutting fluid used in a kind of magneticsubstance course of processing.
Background technology:
To the cutting of magneticsubstance (alloys such as samarium, cobalt, neodymium), ground finish, tradition is used mostly is the oiliness cutting fluid.Though oiliness cutting fluid lubricity is good, in use there are many drawbacks such as mist of oil, inflammable, contaminate environment.Therefore present many enterprises used instead water-soluble metalworking liquid to magneticsubstance cut, ground finish.
Be the machining quality (i.e. Qie Pian smooth finish and planeness) of guaranteeing magneticsubstance, the work-ing life (reducing production costs) that prolongs cutter, this just requires the lubricity of used water-soluble metalworking liquid will get well (being that frictional coefficient is little), rustless property will be got well (can not produce corrosion to workpiece and machining tool in the course of processing).
Be convenient processing, during the magneticsubstance machining, usually all be to be that binding agent is fixed on the anchor clamps with wax with the magneticsubstance workpiece, carry out machining by outer round-bladed knife sheet, interior round-bladed knife sheet and wire cutting machine then, this just requires used water-soluble metalworking liquid to the influence of binding agent little (do not make its very fast dissolving, cause workpiece to come off).
But the performance quality of the at present commercially available water-soluble metalworking liquid that is used for the magneticsubstance machining is unsatisfactory, main drawback: the one, lubricity relatively poor (frictional coefficient is big), cause the inaccessible processing requirement of processed workpiece planeness and smooth finish, cutter life is short, influences production cost; The 2nd, the rust-preventive agent that adds in the cutting fluid influences the adhesive property (soak the back binding agent and easily dissolve, cause workpiece easily to come off) of binding agent; The 3rd, contain objectionable impuritiess such as Sodium Nitrite in the prescription, jeopardize environmental safety and HUMAN HEALTH.
Summary of the invention
The high-performance environment-friendly type magneticsubstance cutting fluid that the object of the present invention is to provide a kind of high lubricity, anti-workpiece to come off.
Technical solution of the present invention is:
A kind of high-performance environment-friendly type magneticsubstance cutting fluid is characterized in that: be made up of following component in percentage by weight:
Figure BDA0000068544110000021
Rust-preventive agent is one or more and Monoethanolamine MEA BASF, diethanolamine, the trolamine in the organic acid, p-tert-butyl benzoic acid, p-nitrobenzoic acid of boric acid, carbon number 8~18, the mixture of one or more formation in the Yi Bingchunan, and the pH value of mixture is 8~9.
Tensio-active agent is the mixture of one or more formation in the organic acid of carbon number 8~18 and Monoethanolamine MEA BASF, diethanolamine, trolamine, the Yi Bingchunan, and the pH value of mixture is 8~9; Or tensio-active agent is aliphatic alcohol polyethenoxy (5~12) ether or alkylphenol-polyethenoxy (5~12) ether.
Lubricant is a polyoxyethylene polyoxypropylene block ether; Sanitas is one or more in 1,2 benzothiazole-3-ketone, 1,2 benzisothiazole, the s-triazine; Copper inhibitor is benzotriazole, tolyltriazole, 1H-1,2, and one or more in 4-triazole, the alpha-mercapto benzothiazole.
The present invention adopts special water-soluble polymers as lubricant, and composite kinds of surface promoting agent, rust-preventive agent and copper inhibitor make this product have excellent oilness and rust-preventing characteristic, processing magnetic material yield rate and working accuracy height.Because the present invention does not use highly basic such as sodium hydroxide, potassium hydroxide, therefore can prevent the dissolving of binding agent.Product does not contain nitrite simultaneously, and environmental protection is a kind of eco-friendly magneticsubstance cutting fluid.
1, this product has excellent lubricating properties.This project product 5% diluent frictional coefficient is compared with commercially available product less than 0.201, reduces 20% on year-on-year basis; This project of use product machining, compared with use commercially available prod greater than 7 days cutter life, improves 40% on year-on-year basis.
Sample This product Commercially available product
Coefficientoffriction 0.201 0.261
Cutter life 7 days 5 days
2, this product can guarantee that wax is that binding agent soaks 3 hours non-whitenings, do not dissolve in this product 5% diluent, and workpiece does not come off.
Figure BDA0000068544110000031
3, this product safety health, reliable in quality.Prescription does not use objectionable impuritiess such as Sodium Nitrite, the biological Lethal Dose 50 LD50>5000mg/kg of product, biological toxic limit medium dose LC50>5000mg/m 3, apnea road mucous membrane irritation is to the human and environment close friend.
The invention will be further described below in conjunction with embodiment.
Embodiment
Embodiment 1:
Each component of following weight percent is mixed stirring, makes high-performance environment-friendly type magneticsubstance cutting fluid product:
Embodiment 2:
Each component of following weight percent is mixed stirring, makes high-performance environment-friendly type magneticsubstance cutting fluid product:
Figure BDA0000068544110000042
Figure BDA0000068544110000051
Rust-preventive agent is one or more and Monoethanolamine MEA BASF, diethanolamine, the trolamine in the organic acid (sad, the oleic acid of example, bay diacid), p-tert-butyl benzoic acid, p-nitrobenzoic acid of boric acid, carbon number 8~18, the mixture of one or more formation in the Yi Bingchunan, and the blended ratio is that to make the pH value of mixture be 8~9.
Tensio-active agent is the mixture of one or more formation in organic acid (sad, the oleic acid of example, bay diacid) and Monoethanolamine MEA BASF, diethanolamine, trolamine, the Yi Bingchunan of carbon number 8~18, and the blended ratio is that to make the pH value of mixture be 8~9; Or tensio-active agent is aliphatic alcohol polyethenoxy (5~12) ether or alkylphenol-polyethenoxy (5~12) ether.
Lubricant is a polyoxyethylene polyoxypropylene block ether; Sanitas is one or more in 1,2 benzothiazole-3-ketone, 1,2 benzisothiazole, the s-triazine; Copper inhibitor is benzotriazole, tolyltriazole, 1H-1,2, and one or more in 4-triazole, the alpha-mercapto benzothiazole.

Claims (4)

1. high-performance environment-friendly type magneticsubstance cutting fluid is characterized in that: be made up of following component in percentage by weight:
Rust-preventive agent 20~40%
Tensio-active agent 5~20%
Lubricant 5~30%
Sanitas 0.2~5%
Copper inhibitor 0.2~1.0%
Water surplus.
2. high-performance environment-friendly type magneticsubstance cutting fluid according to claim 1, it is characterized in that: rust-preventive agent is one or more and Monoethanolamine MEA BASF, diethanolamine, the trolamine in the organic acid, p-tert-butyl benzoic acid, p-nitrobenzoic acid of boric acid, carbon number 8~18, the mixture of one or more formation in the Yi Bingchunan, and the pH value of mixture is 8 ~ 9.
3. high-performance environment-friendly type magneticsubstance cutting fluid according to claim 1, it is characterized in that: tensio-active agent is the mixture of one or more formation in the organic acid of carbon number 8~18 and Monoethanolamine MEA BASF, diethanolamine, trolamine, the Yi Bingchunan, and the pH value of mixture is 8 ~ 9; Or tensio-active agent is aliphatic alcohol polyethenoxy (5~12) ether or alkylphenol-polyethenoxy (5~12) ether.
4. according to claim 1,2 or 3 described high-performance environment-friendly type magneticsubstance cutting fluids, it is characterized in that: lubricant is a polyoxyethylene polyoxypropylene block ether; Sanitas is one or more in 1,2 benzothiazole-3-ketone, 1,2 benzisothiazole, the s-triazine; Copper inhibitor is benzotriazole, tolyltriazole, 1H-1,2, and one or more in 4-triazole, the alpha-mercapto benzothiazole.
CN 201110161285 2011-06-15 2011-06-15 High-performance environment-friendly magnetic material cutting fluid Active CN102250677B (en)

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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102660367A (en) * 2012-04-24 2012-09-12 长春工业大学 Producing method of water-soluble drawing oil for stamping carbon steel sheets
CN102876441A (en) * 2012-09-24 2013-01-16 广西大学 Environment-friendly titanium alloy microemulsion cutting liquid
CN103881798A (en) * 2012-12-19 2014-06-25 上海工程技术大学 Water-soluble silicon cutting fluid and its application thereof
CN104342279A (en) * 2014-09-30 2015-02-11 上海尤希路化学工业有限公司 Environment-friendly high-dispersivity permanent-magnet wire cutting solution
CN104947098A (en) * 2015-05-29 2015-09-30 焦占付 Hot galvanizing chromium-free passivation agent and preparation method thereof
CN106590907A (en) * 2016-12-07 2017-04-26 上海应用技术大学 Graphene-containing metal cutting fluid and preparation method thereof
CN107446685A (en) * 2017-07-27 2017-12-08 江苏捷达油品有限公司 High-lubricity cutting fluid
CN107603721A (en) * 2017-07-27 2018-01-19 江苏捷达油品有限公司 high cooling cutting fluid
CN111876228A (en) * 2020-08-11 2020-11-03 广州洛德化工科贸有限公司 Environment-friendly long-life cutting fluid and preparation method and application thereof

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100999691A (en) * 2006-12-27 2007-07-18 江苏科技大学 Rust-proof cutting fluid
CN101240221A (en) * 2008-02-29 2008-08-13 益田润石(北京)化工有限公司 Water-soluble total synthesis metal processing liquid composition
CN101560433A (en) * 2009-05-11 2009-10-21 启东尤希路化学工业有限公司 Anti-magnesium hard water anti-magnesium corrosion environmentally-friendly water soluble cutting solution
CN101591584A (en) * 2009-06-30 2009-12-02 山东卡松石化有限公司 Water-base lubricant and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100999691A (en) * 2006-12-27 2007-07-18 江苏科技大学 Rust-proof cutting fluid
CN101240221A (en) * 2008-02-29 2008-08-13 益田润石(北京)化工有限公司 Water-soluble total synthesis metal processing liquid composition
CN101560433A (en) * 2009-05-11 2009-10-21 启东尤希路化学工业有限公司 Anti-magnesium hard water anti-magnesium corrosion environmentally-friendly water soluble cutting solution
CN101591584A (en) * 2009-06-30 2009-12-02 山东卡松石化有限公司 Water-base lubricant and preparation method thereof

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102660367A (en) * 2012-04-24 2012-09-12 长春工业大学 Producing method of water-soluble drawing oil for stamping carbon steel sheets
CN102876441A (en) * 2012-09-24 2013-01-16 广西大学 Environment-friendly titanium alloy microemulsion cutting liquid
CN102876441B (en) * 2012-09-24 2013-10-30 广西大学 Environment-friendly titanium alloy microemulsion cutting liquid
CN103881798A (en) * 2012-12-19 2014-06-25 上海工程技术大学 Water-soluble silicon cutting fluid and its application thereof
CN104342279A (en) * 2014-09-30 2015-02-11 上海尤希路化学工业有限公司 Environment-friendly high-dispersivity permanent-magnet wire cutting solution
CN104947098A (en) * 2015-05-29 2015-09-30 焦占付 Hot galvanizing chromium-free passivation agent and preparation method thereof
CN106590907A (en) * 2016-12-07 2017-04-26 上海应用技术大学 Graphene-containing metal cutting fluid and preparation method thereof
CN107446685A (en) * 2017-07-27 2017-12-08 江苏捷达油品有限公司 High-lubricity cutting fluid
CN107603721A (en) * 2017-07-27 2018-01-19 江苏捷达油品有限公司 high cooling cutting fluid
CN111876228A (en) * 2020-08-11 2020-11-03 广州洛德化工科贸有限公司 Environment-friendly long-life cutting fluid and preparation method and application thereof

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