CN104342279A - Environment-friendly high-dispersivity permanent-magnet wire cutting solution - Google Patents
Environment-friendly high-dispersivity permanent-magnet wire cutting solution Download PDFInfo
- Publication number
- CN104342279A CN104342279A CN201410516958.6A CN201410516958A CN104342279A CN 104342279 A CN104342279 A CN 104342279A CN 201410516958 A CN201410516958 A CN 201410516958A CN 104342279 A CN104342279 A CN 104342279A
- Authority
- CN
- China
- Prior art keywords
- wire cutting
- acid
- magnet wire
- permanent magnet
- polymolecularity
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 150000001412 amines Chemical class 0.000 claims abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000004094 surface-active agent Substances 0.000 claims abstract description 4
- 239000007788 liquid Substances 0.000 claims description 16
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 10
- SJRJJKPEHAURKC-UHFFFAOYSA-N N-Methylmorpholine Chemical compound CN1CCOCC1 SJRJJKPEHAURKC-UHFFFAOYSA-N 0.000 claims description 9
- FBUKVWPVBMHYJY-UHFFFAOYSA-N nonanoic acid Chemical compound CCCCCCCCC(O)=O FBUKVWPVBMHYJY-UHFFFAOYSA-N 0.000 claims description 8
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 6
- LVTYICIALWPMFW-UHFFFAOYSA-N diisopropanolamine Chemical compound CC(O)CNCC(C)O LVTYICIALWPMFW-UHFFFAOYSA-N 0.000 claims description 6
- 229940043276 diisopropanolamine Drugs 0.000 claims description 6
- BKIMMITUMNQMOS-UHFFFAOYSA-N nonane Chemical compound CCCCCCCCC BKIMMITUMNQMOS-UHFFFAOYSA-N 0.000 claims description 6
- -1 polyoxyethylene Polymers 0.000 claims description 6
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 claims description 6
- XBPCUCUWBYBCDP-UHFFFAOYSA-N Dicyclohexylamine Chemical compound C1CCCCC1NC1CCCCC1 XBPCUCUWBYBCDP-UHFFFAOYSA-N 0.000 claims description 4
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims description 4
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 4
- SLINHMUFWFWBMU-UHFFFAOYSA-N Triisopropanolamine Chemical compound CC(O)CN(CC(C)O)CC(C)O SLINHMUFWFWBMU-UHFFFAOYSA-N 0.000 claims description 4
- 239000012964 benzotriazole Substances 0.000 claims description 4
- 229910052760 oxygen Inorganic materials 0.000 claims description 4
- 239000001301 oxygen Substances 0.000 claims description 4
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 4
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 4
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims description 3
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims description 3
- HXKKHQJGJAFBHI-UHFFFAOYSA-N 1-aminopropan-2-ol Chemical compound CC(O)CN HXKKHQJGJAFBHI-UHFFFAOYSA-N 0.000 claims description 3
- SNTWKPAKVQFCCF-UHFFFAOYSA-N 2,3-dihydro-1h-triazole Chemical compound N1NC=CN1 SNTWKPAKVQFCCF-UHFFFAOYSA-N 0.000 claims description 3
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 3
- 229940058020 2-amino-2-methyl-1-propanol Drugs 0.000 claims description 3
- BFSVOASYOCHEOV-UHFFFAOYSA-N 2-diethylaminoethanol Chemical compound CCN(CC)CCO BFSVOASYOCHEOV-UHFFFAOYSA-N 0.000 claims description 3
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims description 3
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 3
- OYHQOLUKZRVURQ-HZJYTTRNSA-N Linoleic acid Chemical compound CCCCC\C=C/C\C=C/CCCCCCCC(O)=O OYHQOLUKZRVURQ-HZJYTTRNSA-N 0.000 claims description 3
- 239000005642 Oleic acid Substances 0.000 claims description 3
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims description 3
- 239000005643 Pelargonic acid Substances 0.000 claims description 3
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 3
- 239000013543 active substance Substances 0.000 claims description 3
- 150000001408 amides Chemical class 0.000 claims description 3
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 claims description 3
- 125000003354 benzotriazolyl group Chemical group N1N=NC2=C1C=CC=C2* 0.000 claims description 3
- 150000001735 carboxylic acids Chemical class 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- 150000002191 fatty alcohols Chemical class 0.000 claims description 3
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 3
- 229960004232 linoleic acid Drugs 0.000 claims description 3
- 150000002632 lipids Chemical class 0.000 claims description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 3
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 3
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 3
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 3
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 claims description 3
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 3
- 150000003918 triazines Chemical class 0.000 claims description 3
- 229960004418 trolamine Drugs 0.000 claims description 3
- 230000002349 favourable effect Effects 0.000 abstract description 2
- 230000000844 anti-bacterial effect Effects 0.000 abstract 1
- 239000003899 bactericide agent Substances 0.000 abstract 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 239000003755 preservative agent Substances 0.000 abstract 1
- 230000002335 preservative effect Effects 0.000 abstract 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- 230000007797 corrosion Effects 0.000 description 4
- 238000005260 corrosion Methods 0.000 description 4
- 229910052742 iron Inorganic materials 0.000 description 4
- 238000003754 machining Methods 0.000 description 4
- 231100000111 LD50 Toxicity 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000003085 diluting agent Substances 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- ASFAFOSQXBRFMV-LJQANCHMSA-N 3-n-(2-benzyl-1,3-dihydroxypropan-2-yl)-1-n-[(1r)-1-(4-fluorophenyl)ethyl]-5-[methyl(methylsulfonyl)amino]benzene-1,3-dicarboxamide Chemical compound N([C@H](C)C=1C=CC(F)=CC=1)C(=O)C(C=1)=CC(N(C)S(C)(=O)=O)=CC=1C(=O)NC(CO)(CO)CC1=CC=CC=C1 ASFAFOSQXBRFMV-LJQANCHMSA-N 0.000 description 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 210000001533 respiratory mucosa Anatomy 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical class [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 1
- 235000010288 sodium nitrite Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
Landscapes
- Preventing Corrosion Or Incrustation Of Metals (AREA)
- Lubricants (AREA)
Abstract
The invention discloses an environment-friendly high-dispersivity permanent-magnet wire cutting solution which is composed of high-polymer carboxylic acid, organic amine, a novel surfactant, pure water and a preservative or bactericide. The wire cutting solution is friendly to human and environment, and has favorable operating performance.
Description
Technical field
The present invention relates to a kind of permanent magnet wire cutting liquid.
Background technology
Use traditional free abrasive processing mode to add man-hour, because chip powder not easily disperses, suspension is poor, easily sticks to machine and tool surface, affects machining; Also there is a large amount of solid particulate waste in working fluid simultaneously, increase quantity discharged.
Metal permanent magnet is a kind of special Material Processing, and base characteristic is hard and crisp, the very easily oxidized corrosion in surface.Conventional cutting liquid due to antirust corrosion-resistant can be poor, use namely because of oxidizing reaction after the short period, cause liquid brown, processing characteristics declines, work-ing life short (liquid cost is changed in increase); Simultaneously because of very easily oxidizing reaction, the serious corrosion of work piece is caused to be scrapped.
The wire cutting liquid that current machining industry uses, containing toxic substances such as Sodium Nitrites, can be detrimental to health and environmental safety in formula.
Summary of the invention
The object of the present invention is to provide a kind of environmentally friendly polymolecularity permanent magnet wire cutting liquid to human and environment close friend, favorable working performance.
Technical solution of the present invention is:
A kind of environmentally friendly polymolecularity permanent magnet wire cutting liquid, is characterized in that: be made up of the component of following weight percents:
Polymeric carboxylic 10 ~ 30%
Organic amine 20-40%
Novel surfactant 1 ~ 20%
Pure water 35 ~ 65%
Sanitas or sterilant 0 ~ 5%.
Described polymeric carboxylic is that long-chain carboxylic acid is as one or more in sad, pelargonic acid, sebacic acid, hexanodioic acid, nonane diacid, bay diacid, C8-C18 lipid acid, oleic acid, linolic acid, triazines multi-carboxylic acid compounds.
Described organic amine is one or more in Monoethanolamine MEA BASF, diethanolamine, trolamine, monoisopropanolamine, diisopropanolamine (DIPA), tri-isopropanolamine, morpholine, dicyclohexyl amine, N-methylmorpholine, 2-amino-2-methyl-1-propanol, Diethylaminoethanol.
Described tensio-active agent is one or more in fatty alcohol-polyoxyethylene ether (5 ~ 12), Fatty alcohol polyoxyethylene polyoxypropylene ether, polyoxyethylene poly-oxygen propylene aether (5 ~ 12), alkylol amide, aliphatic alcohol polyethenoxy ester (5 ~ 12), sulfonate.
Described anticorrosive agent is benzotriazole, methyl benzotriazazole, 1H-1, one or more in 2,4-triazole.
The present invention is applied in machining industry to the partition machining that hard brittle material carries out in bonded-abrasive mode such as metal permanent magnet, glass quartz be quartzy, ceramic.
Adopt bonded-abrasive processing mode (substituting the free abrasive processing mode that tradition uses), good dispersity (chip powder can for a long time equably dispersion suspension in working fluid, chip settling time >=5min).
There is excellent rustless property (3.3% diluent iron filings antirust >=120 hours), corrosion resistance (brown iron ion content≤10ppm), service life cycle long (> 100 days).
Safety and sanitation quality is high.Adopt that biodegradability is high, alternative material component design to human and environment close friend, product biological Lethal Dose 50 LD50 >=5000mg/kg, toxic limit medium dose LC50 >=5000mn/m3, respiratory mucosa stimulates≤1 grade.
Below in conjunction with embodiment, the invention will be further described.
Embodiment
Embodiment 1:
A kind of environmentally friendly polymolecularity permanent magnet wire cutting liquid is the product obtained by weight components mix and blend:
Bay diacid 4%
Tri-isopropanolamine 30%
Alkylol amide 4%
Polyoxyethylene poly-oxygen propylene aether 1%
Pure water 43.7%
Dicyclohexyl amine 2%
Benzotriazole 0.3%
N-nonanoic acid 15%.
Polymeric carboxylic bay diacid is adopted in the present embodiment, as highly effective antirust inhibiter, there is excellent rust-preventing characteristic (3.3% diluent iron filings antirust >=120 hours) and erosion resistance (brown iron ion content≤10ppm), working fluid can be made to use not brown for a long time, service life cycle long (> 100 days), not only reduce and change liquid cost, and also ensure that the quality of work piece.
Embodiment 2:
A kind of environmentally friendly polymolecularity permanent magnet wire cutting liquid, is made up of the component of following weight percents:
Polymeric carboxylic 10 ~ 30%(example 10%, 20%, 30%)
Organic amine 20-40%(example 20%, 30%, 40%)
Novel surfactant 1 ~ 20%(example 1%, 10%, 20%)
Pure water 35 ~ 65%(example 35%, 50%, 65%)
Sanitas or sterilant 0 ~ 5%(example 1%, 2%, 5%).
Described polymeric carboxylic is that long-chain carboxylic acid is as one or more in sad, pelargonic acid, sebacic acid, hexanodioic acid, nonane diacid, bay diacid, C8-C18 lipid acid, oleic acid, linolic acid, triazines multi-carboxylic acid compounds.
Described organic amine is one or more in Monoethanolamine MEA BASF, diethanolamine, trolamine, monoisopropanolamine, diisopropanolamine (DIPA), tri-isopropanolamine, morpholine, dicyclohexyl amine, N-methylmorpholine, 2-amino-2-methyl-1-propanol, Diethylaminoethanol.
Described tensio-active agent is one or more in fatty alcohol-polyoxyethylene ether (5 ~ 12), Fatty alcohol polyoxyethylene polyoxypropylene ether, polyoxyethylene poly-oxygen propylene aether (5 ~ 12), alkylol amide, aliphatic alcohol polyethenoxy ester (5 ~ 12), sulfonate.
Described anticorrosive agent is benzotriazole, methyl benzotriazazole, 1H-1, one or more in 2,4-triazole.
Claims (5)
1. an environmentally friendly polymolecularity permanent magnet wire cutting liquid, is characterized in that: be made up of the component of following weight percents:
Polymeric carboxylic 10 ~ 30%
Organic amine 20-40%
Novel surfactant 1 ~ 20%
Pure water 35 ~ 65%
Sanitas or sterilant 0 ~ 5%.
2. environmentally friendly polymolecularity permanent magnet wire cutting liquid according to claim 1, is characterized in that: described polymeric carboxylic is that long-chain carboxylic acid is as one or more in sad, pelargonic acid, sebacic acid, hexanodioic acid, nonane diacid, bay diacid, C8-C18 lipid acid, oleic acid, linolic acid, triazines multi-carboxylic acid compounds.
3. environmentally friendly polymolecularity permanent magnet wire cutting liquid according to claim 1, is characterized in that: described organic amine is one or more in Monoethanolamine MEA BASF, diethanolamine, trolamine, monoisopropanolamine, diisopropanolamine (DIPA), tri-isopropanolamine, morpholine, dicyclohexyl amine, N-methylmorpholine, 2-amino-2-methyl-1-propanol, Diethylaminoethanol.
4. environmentally friendly polymolecularity permanent magnet wire cutting liquid according to claim 1, is characterized in that: described tensio-active agent is one or more in fatty alcohol-polyoxyethylene ether (5 ~ 12), Fatty alcohol polyoxyethylene polyoxypropylene ether, polyoxyethylene poly-oxygen propylene aether (5 ~ 12), alkylol amide, aliphatic alcohol polyethenoxy ester (5 ~ 12), sulfonate.
5. environmentally friendly polymolecularity permanent magnet wire cutting liquid according to claim 1, is characterized in that: described anticorrosive agent is benzotriazole, methyl benzotriazazole, 1H-1, one or more in 2,4-triazole.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410516958.6A CN104342279B (en) | 2014-09-30 | 2014-09-30 | Environmentally friendly polymolecularity permanent magnet wire cutting liquid |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410516958.6A CN104342279B (en) | 2014-09-30 | 2014-09-30 | Environmentally friendly polymolecularity permanent magnet wire cutting liquid |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104342279A true CN104342279A (en) | 2015-02-11 |
| CN104342279B CN104342279B (en) | 2016-08-24 |
Family
ID=52498744
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410516958.6A Active CN104342279B (en) | 2014-09-30 | 2014-09-30 | Environmentally friendly polymolecularity permanent magnet wire cutting liquid |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104342279B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106118838A (en) * | 2016-06-22 | 2016-11-16 | 上海尤希路化学工业有限公司 | Circulation and stress can be diluted and use photovoltaic silicon wafer wire cutting liquid |
| CN107841371A (en) * | 2017-11-07 | 2018-03-27 | 北京工业大学 | A kind of preparation method of fully synthetic crystal cutting fluid |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007262275A (en) * | 2006-03-29 | 2007-10-11 | Hitachi Metals Ltd | Processing liquid for abrasive grain-fixed wire saw |
| CN102250677A (en) * | 2011-06-15 | 2011-11-23 | 启东尤希路化学工业有限公司 | High-performance environment-friendly magnetic material cutting fluid |
| CN102618372A (en) * | 2012-02-28 | 2012-08-01 | 上海尤希路化学工业有限公司 | High performance biodegradation type metal machining protection liquid |
-
2014
- 2014-09-30 CN CN201410516958.6A patent/CN104342279B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007262275A (en) * | 2006-03-29 | 2007-10-11 | Hitachi Metals Ltd | Processing liquid for abrasive grain-fixed wire saw |
| CN102250677A (en) * | 2011-06-15 | 2011-11-23 | 启东尤希路化学工业有限公司 | High-performance environment-friendly magnetic material cutting fluid |
| CN102618372A (en) * | 2012-02-28 | 2012-08-01 | 上海尤希路化学工业有限公司 | High performance biodegradation type metal machining protection liquid |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106118838A (en) * | 2016-06-22 | 2016-11-16 | 上海尤希路化学工业有限公司 | Circulation and stress can be diluted and use photovoltaic silicon wafer wire cutting liquid |
| CN107841371A (en) * | 2017-11-07 | 2018-03-27 | 北京工业大学 | A kind of preparation method of fully synthetic crystal cutting fluid |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104342279B (en) | 2016-08-24 |
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