CN103981008B - The water base Honing process liquid of high-performance environment-friendly type - Google Patents
The water base Honing process liquid of high-performance environment-friendly type Download PDFInfo
- Publication number
- CN103981008B CN103981008B CN201410219549.XA CN201410219549A CN103981008B CN 103981008 B CN103981008 B CN 103981008B CN 201410219549 A CN201410219549 A CN 201410219549A CN 103981008 B CN103981008 B CN 103981008B
- Authority
- CN
- China
- Prior art keywords
- process liquid
- water base
- friendly type
- honing process
- performance environment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000007788 liquid Substances 0.000 title claims abstract description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 14
- 238000000034 method Methods 0.000 title claims abstract description 9
- 239000000314 lubricant Substances 0.000 abstract description 8
- 150000001412 amines Chemical class 0.000 abstract description 7
- 239000000428 dust Substances 0.000 abstract description 7
- -1 inhibiter Substances 0.000 abstract description 7
- 239000004094 surface-active agent Substances 0.000 abstract description 7
- 239000013530 defoamer Substances 0.000 abstract description 5
- 150000007524 organic acids Chemical class 0.000 abstract description 5
- 238000005187 foaming Methods 0.000 abstract description 4
- 230000000149 penetrating effect Effects 0.000 abstract description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 12
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 10
- 231100000111 LD50 Toxicity 0.000 description 6
- 238000010790 dilution Methods 0.000 description 6
- 239000012895 dilution Substances 0.000 description 6
- 229910052742 iron Inorganic materials 0.000 description 6
- 229920001451 polypropylene glycol Polymers 0.000 description 5
- YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical compound C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- LVTYICIALWPMFW-UHFFFAOYSA-N diisopropanolamine Chemical compound CC(O)CNCC(C)O LVTYICIALWPMFW-UHFFFAOYSA-N 0.000 description 4
- 229940043276 diisopropanolamine Drugs 0.000 description 4
- 229920002545 silicone oil Polymers 0.000 description 4
- AYRBHTOSHJHALD-UHFFFAOYSA-N 1-amino-2-methylpropan-1-ol Chemical compound CC(C)C(N)O AYRBHTOSHJHALD-UHFFFAOYSA-N 0.000 description 3
- GIAFURWZWWWBQT-UHFFFAOYSA-N 2-(2-aminoethoxy)ethanol Chemical compound NCCOCCO GIAFURWZWWWBQT-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- 239000004721 Polyphenylene oxide Substances 0.000 description 3
- 239000003085 diluting agent Substances 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- 239000006260 foam Substances 0.000 description 3
- 238000009775 high-speed stirring Methods 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 230000035515 penetration Effects 0.000 description 3
- 229920000570 polyether Polymers 0.000 description 3
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 3
- 229920001296 polysiloxane Polymers 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- HXKKHQJGJAFBHI-UHFFFAOYSA-N 1-aminopropan-2-ol Chemical compound CC(O)CN HXKKHQJGJAFBHI-UHFFFAOYSA-N 0.000 description 2
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- OTLNPYWUJOZPPA-UHFFFAOYSA-N 4-nitrobenzoic acid Chemical compound OC(=O)C1=CC=C([N+]([O-])=O)C=C1 OTLNPYWUJOZPPA-UHFFFAOYSA-N 0.000 description 2
- KDVYCTOWXSLNNI-UHFFFAOYSA-N 4-t-Butylbenzoic acid Chemical compound CC(C)(C)C1=CC=C(C(O)=O)C=C1 KDVYCTOWXSLNNI-UHFFFAOYSA-N 0.000 description 2
- 241000282376 Panthera tigris Species 0.000 description 2
- SLINHMUFWFWBMU-UHFFFAOYSA-N Triisopropanolamine Chemical compound CC(O)CN(CC(C)O)CC(C)O SLINHMUFWFWBMU-UHFFFAOYSA-N 0.000 description 2
- 239000013543 active substance Substances 0.000 description 2
- 239000012964 benzotriazole Substances 0.000 description 2
- 125000003354 benzotriazolyl group Chemical group N1N=NC2=C1C=CC=C2* 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 150000002632 lipids Chemical class 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- TZBAVQKIEKDGFH-UHFFFAOYSA-N n-[2-(diethylamino)ethyl]-1-benzothiophene-2-carboxamide;hydrochloride Chemical compound [Cl-].C1=CC=C2SC(C(=O)NCC[NH+](CC)CC)=CC2=C1 TZBAVQKIEKDGFH-UHFFFAOYSA-N 0.000 description 2
- FBUKVWPVBMHYJY-UHFFFAOYSA-N nonanoic acid Chemical compound CCCCCCCCC(O)=O FBUKVWPVBMHYJY-UHFFFAOYSA-N 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 229940093429 polyethylene glycol 6000 Drugs 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 210000001533 respiratory mucosa Anatomy 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 2
- 231100000331 toxic Toxicity 0.000 description 2
- 230000002588 toxic effect Effects 0.000 description 2
- 241000522254 Cassia Species 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 235000010288 sodium nitrite Nutrition 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
Landscapes
- Lubricants (AREA)
Abstract
The invention discloses the water base Honing process liquid of a kind of high-performance environment-friendly type, be made up of organic acid, organic amine, synthetic lubricant, novel surfactant, inhibiter, water, defoamer.The present invention has excellent lubricity, foaming properties, abrasive dust separate and subside performance, penetrating quality.
Description
Technical field
The present invention relates to a kind of water base Honing process liquid.
Background technology
Honing is a kind of under low cutting speed operating mode, to the skin processing of workpiece surface, its objective is the dimensional precision in order to effectively improve workpiece, geometrical precision, reduces the surfaceness of workpiece.For obtaining good lubricant effect, for a long time, the Honing process liquid of supporting application, all adopts oil based on the mineral oil of deep refining substantially, adds multiple auxiliary agent agent blending and forms.Because oil-base fluid exists potential safety hazard (smolder, mist of oil, easily catch fire) and workpiece not easy cleaning, less economical etc. outstanding drawback, so excellent, the security of cooled cleaning performance and better economy water base fluid substitute just gradually at present.But honing water base fluid commercially available at present also exists some problems fails to solve.One is oilness undesirable (during 3% concentration, coefficientoffrictionμ > 0.15), and cause workpiece dimensional precision, geometrical precision poor, surfaceness is high; Two is that foaming properties, abrasive dust settleability are poor, and foam time >=30s(high-speed stirring 10000 revs/min, stops after stirring 5min), abrasive dust settling time >=40s (adding 1%200 order iron powders in 3% diluent); Three is poor permeability (3% concentration, 100 order iron particle sizes, penetration time >=25s), four is contain the toxic substances such as Sodium Nitrite in formula constituent, is detrimental to health.
Summary of the invention
The object of the present invention is to provide a kind of easily manufactured, the water base Honing process liquid of high-performance environment-friendly type of excellent performance.
Technical solution of the present invention is:
The water base Honing process liquid of a kind of high-performance environment-friendly type, is characterized in that: be grouped into by the one-tenth of following weight percents:
Organic acid 5-15%
Organic amine 10-20%
Synthetic lubricant 10-20%
Novel surfactant 1-10%
Inhibiter 1-3%
Water 30-50%
Defoamer 0-3%; .
Above-mentioned each amounts of components sum is 100%.
Organic acid is C
6-C
14straight chain diatomic acid, C
8-C
10one or more in lipid acid, p-tert-butyl benzoic acid, p-nitrobenzoic acid or sulfamic acid compound.
Organic amine be Monoethanolamine MEA BASF, monoisopropanolamine, diisopropanolamine (DIPA), tri-isopropanolamine, N, N-bis-polyoxyethylene N-ring in amine, the amino 2-methylpropanol of 2-, 2-(2-amino ethoxy) ethanol one or more.
Inhibiter is benzotriazole, methyl benzotriazazole tiger 2-mercaptobenzothiazole.
Synthetic lubricant is one or more in Macrogol 4000, polyethylene glycol 6000, polypropylene glycol 2000, polypropylene glycol 4000, modified fatty acid ester.
Novel surfactant is one or more in polyoxyethylene polyoxypropylene block polyether, glycerin polyoxyethylene polyethenoxy ether, polyvinylamine, isomery alcohol ether.
Defoamer is one or more in silicone emulsion, methyl-silicone oil, dimethyl silicone oil.
Advantage of the present invention is:
1, this product has excellent lubricity.Select new type water-solubility synthetic lubricant, make product 3% concentration dilution liquid frictional coefficient≤0.03.
2, this product has excellent foaming properties and abrasive dust settling property.Select novel high polymer tensio-active agent, make product 3% concentration dilution liquid, foam time≤6s(high-speed stirring 10000 revs/min, stir after 5min and stop), abrasive dust separate and subside time≤20s(2% diluent in add 1%200 order iron powders).
3, this product has excellent penetrating quality, selects novel surfactant, makes the penetration time≤5s(100 order iron particle size of product 3% concentration dilution liquid).
4, this product has reliable safety and sanitation performance.Formula for a product raw material does not use and jeopardizes HUMAN HEALTH and environmental safety objectionable impurities.The biological Lethal Dose 50 LD50(mg/kg of product)>=5000, toxic limit medium dose LC50(mg/m
3)>=5000, respiratory mucosa stimulates≤1 grade.
Below in conjunction with embodiment, the invention will be further described.
Embodiment
Embodiment 1:
By the component mix and blend of following weight percents, obtain product:
Chinese cassia tree diacid 3%
Sebacic acid 3%
Sad 4%
N-nonanoic acid 3%
The amino 2-methylpropanol 7% of 2-
2-(2-amino ethoxy) ethanol 6%
Polypropylene glycol 20008%
Polyoxyethylene polyoxypropylene block polyether 15%
Polyvinylamine 2%
Isomery alcohol ether 2%
Methyl benzotriazazole 0.5%
Silicone emulsion 0.5%
Water 46%.
This product has excellent lubricity.Select new type water-solubility synthetic lubricant, make product 3% concentration dilution liquid frictional coefficient≤0.03.This product has excellent foaming properties and abrasive dust settling property.Select novel high polymer tensio-active agent, make product 3% concentration dilution liquid, foam time≤6s(high-speed stirring 10000 revs/min, stir after 5min and stop), abrasive dust separate and subside time≤20s(2% diluent in add 1%200 order iron powders).This product has excellent penetrating quality, selects novel surfactant, makes the penetration time≤5s(100 order iron particle size of product 3% concentration dilution liquid).This product has reliable safety and sanitation performance.Formula for a product raw material does not use and jeopardizes HUMAN HEALTH and environmental safety objectionable impurities.The biological Lethal Dose 50 LD50(mg/kg of product)>=5000, toxic limit medium dose LC50(mg/m
3)>=5000, respiratory mucosa stimulates≤1 grade.
Embodiment 2:
The water base Honing process liquid of a kind of high-performance environment-friendly type, is grouped into by the one-tenth of following weight percents:
Organic acid 5-15%(example 5%, 10%, 15%)
Organic amine 10-20%(example 10%, 15%, 20%)
Synthetic lubricant 10-20%(example 10%, 15%, 20%)
Novel surfactant 1-10%(example 1%, 5%, 10%)
Inhibiter 1-3%(example 1%, 2%, 3%)
Water 30-50%(example 30%, 40%, 50%)
Defoamer 0-3%(example 1%, 2%, 3%); .
Above-mentioned each amounts of components sum is 100%.
Organic acid is C
6-C
14straight chain diatomic acid, C
8-C
10one or more in lipid acid, p-tert-butyl benzoic acid, p-nitrobenzoic acid or sulfamic acid compound.
Organic amine be Monoethanolamine MEA BASF, monoisopropanolamine, diisopropanolamine (DIPA), tri-isopropanolamine, N, N-bis-polyoxyethylene N-ring in amine, the amino 2-methylpropanol of 2-, 2-(2-amino ethoxy) ethanol one or more.
Inhibiter is benzotriazole, methyl benzotriazazole tiger 2-mercaptobenzothiazole.
Synthetic lubricant is one or more in Macrogol 4000, polyethylene glycol 6000, polypropylene glycol 2000, polypropylene glycol 4000, modified fatty acid ester.
Novel surfactant is one or more in polyoxyethylene polyoxypropylene block polyether, glycerin polyoxyethylene polyethenoxy ether, polyvinylamine, isomery alcohol ether.
Defoamer is one or more in silicone emulsion, methyl-silicone oil, dimethyl silicone oil.
Claims (1)
1. the water base Honing process liquid of high-performance environment-friendly type, is characterized in that: be grouped into by the one-tenth of following weight percents:
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410219549.XA CN103981008B (en) | 2014-05-23 | 2014-05-23 | The water base Honing process liquid of high-performance environment-friendly type |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410219549.XA CN103981008B (en) | 2014-05-23 | 2014-05-23 | The water base Honing process liquid of high-performance environment-friendly type |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103981008A CN103981008A (en) | 2014-08-13 |
| CN103981008B true CN103981008B (en) | 2015-12-02 |
Family
ID=51273179
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410219549.XA Active CN103981008B (en) | 2014-05-23 | 2014-05-23 | The water base Honing process liquid of high-performance environment-friendly type |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103981008B (en) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104388956A (en) * | 2014-10-14 | 2015-03-04 | 东莞市四辉表面处理科技有限公司 | Plane grinding detergent |
| CN104818100A (en) * | 2015-03-18 | 2015-08-05 | 启东尤希路化学工业有限公司 | Environment-friendly and low-cost special grinding fluid for steel ball hard grinding |
| CN104830285A (en) * | 2015-04-23 | 2015-08-12 | 东莞市博奥润滑油有限公司 | High-frequency welded tube processing liquid |
| CN104911015B (en) * | 2015-06-30 | 2018-05-29 | 陕西航宇化工有限公司 | A kind of grinding fluid and preparation method thereof |
| CN105802581A (en) * | 2016-03-28 | 2016-07-27 | 启东尤希路化学工业有限公司 | Waterborne grinding fluid for sapphire wafer processing |
| CN106367188A (en) * | 2016-08-12 | 2017-02-01 | 浙江模德石化有限公司 | Water-soluble processing solution for slicing of hard and brittle material and preparation method thereof |
| CN106381209A (en) * | 2016-08-23 | 2017-02-08 | 蚌埠精科机床制造有限公司 | A preparing method of a water-based cutting fluid specially used for honing |
| CN106675751B (en) * | 2016-12-20 | 2020-04-10 | 广东山之风环保科技有限公司 | Glass cutting fluid |
| CN107987942A (en) * | 2017-11-24 | 2018-05-04 | 重庆信人科技发展有限公司 | A kind of water base high molecular grinding fluid |
| CN109913310A (en) * | 2019-04-24 | 2019-06-21 | 上海尤希路化学工业有限公司 | The miniature iron shot hard grind special-purpose water-based milling liquid of diameter 0.5mm-2.0mm |
| CN114317075B (en) * | 2021-12-03 | 2023-04-11 | 广东红日星实业有限公司 | Cutting fluid and preparation method and application thereof |
| CN115340900B (en) * | 2021-12-31 | 2024-02-13 | 福建嘉富顿环保科技有限公司 | Environment-friendly water-based honing liquid and preparation method thereof |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7645727B2 (en) * | 2004-05-03 | 2010-01-12 | Gm Global Technology Operations, Inc. | Gear cutting oil |
| CN103045341A (en) * | 2013-01-08 | 2013-04-17 | 启东尤希路化学工业有限公司 | Grinding fluid for processing high-performance superhard alloy |
-
2014
- 2014-05-23 CN CN201410219549.XA patent/CN103981008B/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN103981008A (en) | 2014-08-13 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103981008B (en) | The water base Honing process liquid of high-performance environment-friendly type | |
| CN102250673B (en) | Environment-friendly emulsion cutting oil with high lubricity and high permeability for metal working | |
| CN102250676B (en) | High-performance environmentally-friendly semisynthetic water-soluble metal working fluid | |
| CN108277077A (en) | A kind of anti-rust water-based fully synthetic ferrous metal working fluid of high hardness | |
| CN103046066B (en) | High-performance and environment-friendly water-based cleaning agent | |
| CN103525529B (en) | High-performance environment-friendly water-soluble punching oil | |
| CN106479654A (en) | Aqueous cutting fluid | |
| CN103525533B (en) | Full-synthetic glass grinding fluid | |
| CN104450105B (en) | A kind of low smell low toxicity glass cutting liquid | |
| CN109825199A (en) | A kind of environmentally protective polishing fluid and preparation method thereof | |
| CN104087404A (en) | High-cleanliness economical microemulsion metal cutting fluid | |
| CN103351932B (en) | A kind of transparent water soluble cutting fluid and preparation method thereof | |
| CN104403774A (en) | Water-based cutting fluid and preparation method thereof | |
| CN103045341A (en) | Grinding fluid for processing high-performance superhard alloy | |
| CN103740452A (en) | Environment-friendly cooling liquid for diamond wire cutting and preparation method thereof | |
| CN102618372A (en) | High performance biodegradation type metal machining protection liquid | |
| CN106675751B (en) | Glass cutting fluid | |
| CN104762127A (en) | Nano aqueous completely-synthetic environmental-friendly metal working fluid | |
| CN108559605A (en) | A kind of preparation method of environmentally protective mine hydraulic support fluid | |
| CN106590907A (en) | Graphene-containing metal cutting fluid and preparation method thereof | |
| CN106118838A (en) | Circulation and stress can be diluted and use photovoltaic silicon wafer wire cutting liquid | |
| CN104818100A (en) | Environment-friendly and low-cost special grinding fluid for steel ball hard grinding | |
| CN104342279B (en) | Environmentally friendly polymolecularity permanent magnet wire cutting liquid | |
| CN106566625A (en) | Vegetable oil-based titanium alloy emulsification processing liquid | |
| CN103242947A (en) | Water-soluble grinding fluid for high-performance bearing processing |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |