CN102250676B - High-performance environmentally-friendly semisynthetic water-soluble metal working fluid - Google Patents
High-performance environmentally-friendly semisynthetic water-soluble metal working fluid Download PDFInfo
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- CN102250676B CN102250676B CN 201110160676 CN201110160676A CN102250676B CN 102250676 B CN102250676 B CN 102250676B CN 201110160676 CN201110160676 CN 201110160676 CN 201110160676 A CN201110160676 A CN 201110160676A CN 102250676 B CN102250676 B CN 102250676B
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Abstract
The invention discloses a high-performance environmentally-friendly semisynthetic water-soluble metal working fluid which is composed of an organic acid, organic amine, a corrosion inhibitor, a synthetic lubricant, a surfactant, water and a defoaming agent. By compounding the organic acid, organic amine and a specially modified synthetic polymer compound used as the lubricant with multiple corrosion inhibitors, an anticorrosion agent and the surfactant, the product has excellent lubrication property and penetration property, and can be used for greatly improving the surface finish degree and prolonging the service life of a cutter; the product has the advantages of good impure oil resistance, sterilization and corrosion prevention properties and obviously prolonged service life of the product; the product is a stable semisynthetic liquid, and can provide cooling property and cleaning property better than emulsion; and the product is environmentally-friendly, and is the high-performance environmentally-friendly semisynthetic water-soluble metal working fluid.
Description
Technical field
The present invention relates to a kind of semi-synthetic water soluble metal working fluids.
Background technology
Metal working fluid is as the fast development of matching used lubricated, the heat-eliminating medium of mechanical workout along with machining enterprise, its usage quantity grows with each passing day,, use liquid easy corrupt go bad relatively poor as traditional oil-in-water type product existence consumption bulk petroleum resource, operating environment; Though the part shortcoming of the oil-in-water type product that complete synthesis product overcomes, because lubricity is inadequate, still can not satisfying the market and process requirements.
Summary of the invention
The object of the invention is to develop a kind of lubricity, the anti-assorted good semi-synthetic water soluble metal working fluids of high-performance environment-friendly type of oiliness.
Technical solution of the present invention is:
The semi-synthetic water soluble metal working fluids of a kind of high-performance environment-friendly type, it is characterized in that: the one-tenth by following weight percent is grouped into:
Organic acid 5-30%
Organic amine 10-30%
Inhibiter 1-10%
Synthetic lubricant 5-20%
Tensio-active agent 10-30%
Water 10-30%
Defoamer 0.05 ~ 2%.
Organic acid is C
6-C
14Straight chain diatomic acid, C
8-C
18Among lipid acid, p-tert-butyl benzoic acid, p-nitrobenzoic acid, the triazines multi-carboxylic acid compounds one or more.
Organic amine is one or more in Monoethanolamine MEA BASF, diethanolamine, trolamine, monoisopropanolamine, diisopropanolamine (DIPA), tri-isopropanolamine, morpholine, dicyclohexyl amine, N-methylmorpholine, 2-ammonia 2-methyl isophthalic acid-propyl alcohol, the diethylaminoethanol.
Inhibiter is one or more in benzotriazole, methyl benzotriazazole, the 2-mercaptobenzothiazole.
Synthetic lubricant is one or more in modification trihydroxymethylpropanyl ester, pentaerythritol ester, DOPCP, the isooctyl oleate.
Tensio-active agent is one or more in aliphatic alcohol polyethenoxy (5-12) ether, alkylphenol-polyethenoxy (5-12) ether, aliphatic alcohol polyethenoxy polyethenoxy ether, alkylol amide, alcohol ether carboxylate, the sulfonate.
Defoamer is silicone emulsion, methyl-silicone oil or dimethyl silicone oil.
The present invention adopts organic acid, organic amine, special modification synthetic macromolecular compound as lubricant and composite multiple inhibiter, sanitas and tensio-active agent, product has excellent lubricity and penetrating quality, can greatly improve surface smoothness and tool life.Product has good anti-assorted oiliness energy and sterilization and anticorrosion performance, can obviously prolong the work-ing life of product.And product is stable semi-synthetic liquid, and cooling and the cleaning more excellent than emulsion can be provided.The Product Green environmental protection is a kind of high performance environmentally friendly semi-synthetic water soluble metal working fluids simultaneously.
1, this product has excellent lubricity and penetrating quality.With making formula material through composite modified high-molecular synthetic lubricant substitute mineral oil, petroleum resources have not only been saved, and the product readily biodegradable of making, lubricity (tapping moment of torsion 5% 470 Ncm) can match in excellence or beauty the frictional coefficient of 2% diluent≤0.03 with emulsion (tapping moment of torsion 5% 460 Ncm) fully.Have simultaneously good cooling and cleaning.Perviousness≤the 3s of 2% diluent.
2, this product has good anti-assorted oil and sterilization and anticorrosion performance.Development has the anti-assorted oily antimicrobial formulation of good pollution discharge capability and smear metal settling property.Smear metal settling time≤5 of product second.Service life cycle 〉=4 year.
3, this product has reliable safety and sanitation performance.The formula for a product raw material does not use and jeopardizes HUMAN HEALTH and environmental safety objectionable impurities.The biological Lethal Dose 50 LD50(mg/kg of product) 〉=5000, toxic limit medium dose LC50(mg/m
3) 〉=5000, respiratory mucosa stimulates≤0.
The invention will be further described below in conjunction with embodiment.
Embodiment
Embodiment 1:
With the component mix and blend of following weight percent, get the semi-synthetic water soluble metal working fluids product of high-performance environment-friendly type:
Chinese cassia tree diacid 4%
N-nonanoic acid 4%
Ricinolic acid 5%
Tall oil acid 5%
Trolamine 10%
Monoisopropanolamine 6%
Diethylaminoethanol 5%
Modification trihydroxymethylpropanyl ester 20%
Aliphatic alcohol polyethenoxy (9) ether 3%
Aliphatic alcohol polyethenoxy polyethenoxy ether 12%
Methyl benzotriazazole 0.5%
Silicone emulsion 0.5%
Water 25%.
Embodiment 2:
With the component mix and blend of following weight percent, get the semi-synthetic water soluble metal working fluids product of high-performance environment-friendly type:
Organic acid 5-30%(example 5%, 20%, 30%)
Organic amine 10-30%(example 10%, 20%, 30%)
Inhibiter 1-10%(example 1%, 5%, 10%)
Synthetic lubricant 5-20%(example 5%, 12%, 20%)
Tensio-active agent 10-30%(example 10%, 20%, 30%)
Water 10-30%(example 10%, 20%, 30%)
Defoamer 0.05 ~ 2%(example 0.05%, 1%, 2%).
Organic acid is C
6-C
14Straight chain diatomic acid, C
8-C
18Among lipid acid, p-tert-butyl benzoic acid, p-nitrobenzoic acid, the triazines multi-carboxylic acid compounds one or more.
Organic amine is one or more in Monoethanolamine MEA BASF, diethanolamine, trolamine, monoisopropanolamine, diisopropanolamine (DIPA), tri-isopropanolamine, morpholine, dicyclohexyl amine, N-methylmorpholine, 2-ammonia 2-methyl isophthalic acid-propyl alcohol, the diethylaminoethanol.
Inhibiter is one or more in benzotriazole, methyl benzotriazazole, the 2-mercaptobenzothiazole.
Synthetic lubricant is one or more in modification trihydroxymethylpropanyl ester, pentaerythritol ester, DOPCP, the isooctyl oleate.
Tensio-active agent is one or more in aliphatic alcohol polyethenoxy (5-12) ether, alkylphenol-polyethenoxy (5-12) ether, aliphatic alcohol polyethenoxy polyethenoxy ether, alkylol amide, alcohol ether carboxylate, the sulfonate.
Defoamer is silicone emulsion, methyl-silicone oil or dimethyl silicone oil.
Claims (1)
1. semi-synthetic water soluble metal working fluids of high-performance environment-friendly type, it is characterized in that: the one-tenth by following weight percent is grouped into:
Synthetic lubricant is one or more in modification trihydroxymethylpropanyl ester, the DOPCP; Defoamer is methyl-silicone oil or dimethyl silicone oil; Organic acid is C
6-C
14Straight chain diatomic acid, C
8-C
18Among lipid acid, p-tert-butyl benzoic acid, p-nitrobenzoic acid, the triazines multi-carboxylic acid compounds one or more; Organic amine is one or more in Monoethanolamine MEA BASF, diethanolamine, trolamine, monoisopropanolamine, diisopropanolamine (DIPA), tri-isopropanolamine, morpholine, dicyclohexyl amine, N-methylmorpholine, 2-ammonia-2-methyl isophthalic acid-propyl alcohol, the diethylaminoethanol; Inhibiter is one or more in benzotriazole, methyl benzotriazazole, the 2-mercaptobenzothiazole; Tensio-active agent is one or more in alkylol amide, the alcohol ether carboxylate.
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| CN 201110160676 CN102250676B (en) | 2011-06-15 | 2011-06-15 | High-performance environmentally-friendly semisynthetic water-soluble metal working fluid |
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| CN 201110160676 CN102250676B (en) | 2011-06-15 | 2011-06-15 | High-performance environmentally-friendly semisynthetic water-soluble metal working fluid |
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| CN102250676A CN102250676A (en) | 2011-11-23 |
| CN102250676B true CN102250676B (en) | 2013-03-27 |
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Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102618372A (en) * | 2012-02-28 | 2012-08-01 | 上海尤希路化学工业有限公司 | High performance biodegradation type metal machining protection liquid |
| CN102660368A (en) * | 2012-05-04 | 2012-09-12 | 启东尤希路化学工业有限公司 | Biodegradable hard water-resistant water-soluble metalworking liquid |
| CN102703190A (en) * | 2012-06-20 | 2012-10-03 | 上海应用技术学院 | Semisynthetic metal cutting fluid with pentaerythritol oleate serving as base oil and preparation method thereof |
| CN102733260B (en) * | 2012-06-29 | 2014-11-26 | 上海东升新材料有限公司 | Aqueous lubricant used in papermaking, and preparation method thereof |
| CN103045341A (en) * | 2013-01-08 | 2013-04-17 | 启东尤希路化学工业有限公司 | Grinding fluid for processing high-performance superhard alloy |
| CN103146468B (en) * | 2013-03-06 | 2014-07-16 | 广西大学 | Environment-friendly wet flattening solution |
| CN103242947A (en) * | 2013-05-08 | 2013-08-14 | 启东尤希路化学工业有限公司 | Water-soluble grinding fluid for high-performance bearing processing |
| JP6777972B2 (en) * | 2015-02-06 | 2020-10-28 | 出光興産株式会社 | Water-soluble metalworking oil composition and its usage |
| CN104830285A (en) * | 2015-04-23 | 2015-08-12 | 东莞市博奥润滑油有限公司 | High-frequency welded tube processing liquid |
| CN105296126A (en) * | 2015-12-02 | 2016-02-03 | 苏州捷德瑞精密机械有限公司 | Environment-friendly water-based antirust cutting fluid and preparation method thereof |
| CN108384668A (en) * | 2018-04-25 | 2018-08-10 | 上海尤希路化学工业有限公司 | High magnification dilution, the special-purpose aqueous cleaning agent of 50MPa ultra-high pressure numerical control cleaning centers |
| CN109913310A (en) * | 2019-04-24 | 2019-06-21 | 上海尤希路化学工业有限公司 | The miniature iron shot hard grind special-purpose water-based milling liquid of diameter 0.5mm-2.0mm |
| CN111423931A (en) * | 2020-05-06 | 2020-07-17 | 上海尤希路化学工业有限公司 | High-lubrication long-service-life environment-friendly semisynthetic water-soluble cutting fluid |
| CN111876228A (en) * | 2020-08-11 | 2020-11-03 | 广州洛德化工科贸有限公司 | Environment-friendly long-life cutting fluid and preparation method and application thereof |
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| CN1730633A (en) * | 2005-08-09 | 2006-02-08 | 启东尤希路化学工业有限公司 | Hard water resistant water-soluble cutting solution |
| CN1995300A (en) * | 2006-12-08 | 2007-07-11 | 中国石油化工股份有限公司 | Cutting liquor composition for metal processing |
| CN101560433A (en) * | 2009-05-11 | 2009-10-21 | 启东尤希路化学工业有限公司 | Anti-magnesium hard water anti-magnesium corrosion environmentally-friendly water soluble cutting solution |
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2011
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1730633A (en) * | 2005-08-09 | 2006-02-08 | 启东尤希路化学工业有限公司 | Hard water resistant water-soluble cutting solution |
| CN1995300A (en) * | 2006-12-08 | 2007-07-11 | 中国石油化工股份有限公司 | Cutting liquor composition for metal processing |
| CN101560433A (en) * | 2009-05-11 | 2009-10-21 | 启东尤希路化学工业有限公司 | Anti-magnesium hard water anti-magnesium corrosion environmentally-friendly water soluble cutting solution |
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| CN102250676A (en) | 2011-11-23 |
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