CN103242941B - High-quality trace lubricant oil for near-dry cutting - Google Patents
High-quality trace lubricant oil for near-dry cutting Download PDFInfo
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- CN103242941B CN103242941B CN201310138039.5A CN201310138039A CN103242941B CN 103242941 B CN103242941 B CN 103242941B CN 201310138039 A CN201310138039 A CN 201310138039A CN 103242941 B CN103242941 B CN 103242941B
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- dry cutting
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- 238000005520 cutting process Methods 0.000 title claims abstract description 25
- 239000000314 lubricant Substances 0.000 title abstract 4
- 239000010687 lubricating oil Substances 0.000 claims description 12
- 150000002148 esters Chemical class 0.000 abstract description 11
- 239000003921 oil Substances 0.000 abstract description 10
- 235000019198 oils Nutrition 0.000 abstract description 10
- 239000000463 material Substances 0.000 abstract description 7
- 230000015556 catabolic process Effects 0.000 abstract description 5
- 238000006731 degradation reaction Methods 0.000 abstract description 5
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- 238000003754 machining Methods 0.000 abstract description 5
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- 238000007254 oxidation reaction Methods 0.000 abstract description 5
- 235000015112 vegetable and seed oil Nutrition 0.000 abstract description 5
- 239000008158 vegetable oil Substances 0.000 abstract description 5
- 229910000838 Al alloy Inorganic materials 0.000 abstract description 3
- 229910001018 Cast iron Inorganic materials 0.000 abstract description 3
- 229910000831 Steel Inorganic materials 0.000 abstract description 3
- 239000010959 steel Substances 0.000 abstract description 3
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 238000005461 lubrication Methods 0.000 abstract 1
- 239000006078 metal deactivator Substances 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 description 8
- 239000002184 metal Substances 0.000 description 8
- 239000002253 acid Substances 0.000 description 7
- 229920005862 polyol Polymers 0.000 description 6
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 6
- 239000002173 cutting fluid Substances 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 5
- 238000012545 processing Methods 0.000 description 5
- 239000007866 anti-wear additive Substances 0.000 description 4
- 230000032050 esterification Effects 0.000 description 4
- 238000005886 esterification reaction Methods 0.000 description 4
- ZWRUINPWMLAQRD-UHFFFAOYSA-N nonan-1-ol Chemical compound CCCCCCCCCO ZWRUINPWMLAQRD-UHFFFAOYSA-N 0.000 description 4
- BKIMMITUMNQMOS-UHFFFAOYSA-N nonane Chemical compound CCCCCCCCC BKIMMITUMNQMOS-UHFFFAOYSA-N 0.000 description 4
- -1 polyol ester Chemical class 0.000 description 4
- BWDBEAQIHAEVLV-UHFFFAOYSA-N 6-methylheptan-1-ol Chemical compound CC(C)CCCCCO BWDBEAQIHAEVLV-UHFFFAOYSA-N 0.000 description 3
- 231100000111 LD50 Toxicity 0.000 description 3
- 235000019484 Rapeseed oil Nutrition 0.000 description 3
- 244000269722 Thea sinensis Species 0.000 description 3
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 3
- 239000012964 benzotriazole Substances 0.000 description 3
- JEJCUBGTTOKYHG-UHFFFAOYSA-N boric acid;4,5-dihydro-1h-imidazole Chemical compound OB(O)O.C1CN=CN1 JEJCUBGTTOKYHG-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 235000009569 green tea Nutrition 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 229940059574 pentaerithrityl Drugs 0.000 description 3
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 3
- ZEMPKEQAKRGZGQ-AAKVHIHISA-N 2,3-bis[[(z)-12-hydroxyoctadec-9-enoyl]oxy]propyl (z)-12-hydroxyoctadec-9-enoate Chemical compound CCCCCCC(O)C\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CC(O)CCCCCC)COC(=O)CCCCCCC\C=C/CC(O)CCCCCC ZEMPKEQAKRGZGQ-AAKVHIHISA-N 0.000 description 2
- SNTWKPAKVQFCCF-UHFFFAOYSA-N 2,3-dihydro-1h-triazole Chemical compound N1NC=CN1 SNTWKPAKVQFCCF-UHFFFAOYSA-N 0.000 description 2
- YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 description 2
- PLLBRTOLHQQAQQ-UHFFFAOYSA-N 8-methylnonan-1-ol Chemical compound CC(C)CCCCCCCO PLLBRTOLHQQAQQ-UHFFFAOYSA-N 0.000 description 2
- 240000002234 Allium sativum Species 0.000 description 2
- 235000004359 Artemisia pontica Nutrition 0.000 description 2
- 235000003261 Artemisia vulgaris Nutrition 0.000 description 2
- 239000004440 Isodecyl alcohol Substances 0.000 description 2
- MBDKGXAMSZIDKF-VJIACCKLSA-N N-oleoyl-L-serine Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)N[C@@H](CO)C(O)=O MBDKGXAMSZIDKF-VJIACCKLSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 2
- 244000273928 Zingiber officinale Species 0.000 description 2
- 239000000443 aerosol Substances 0.000 description 2
- 235000009508 confectionery Nutrition 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 238000006735 epoxidation reaction Methods 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 235000004611 garlic Nutrition 0.000 description 2
- 238000005984 hydrogenation reaction Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 2
- 150000003077 polyols Chemical class 0.000 description 2
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 2
- 239000003549 soybean oil Substances 0.000 description 2
- 235000012424 soybean oil Nutrition 0.000 description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical group OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 2
- 235000020238 sunflower seed Nutrition 0.000 description 2
- 150000003712 vitamin E derivatives Chemical class 0.000 description 2
- 206010048768 Dermatosis Diseases 0.000 description 1
- 206010028980 Neoplasm Diseases 0.000 description 1
- 208000018569 Respiratory Tract disease Diseases 0.000 description 1
- 208000008784 apnea Diseases 0.000 description 1
- 201000011510 cancer Diseases 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 231100000017 mucous membrane irritation Toxicity 0.000 description 1
- 229940049964 oleate Drugs 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 150000008442 polyphenolic compounds Chemical class 0.000 description 1
- 235000013824 polyphenols Nutrition 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 238000010079 rubber tapping Methods 0.000 description 1
- 208000017520 skin disease Diseases 0.000 description 1
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- 230000002588 toxic effect Effects 0.000 description 1
- 238000007514 turning Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Abstract
The invention discloses high-quality trace lubricant oil for near-dry cutting. The high-quality trace lubricant oil for near-dry cutting is composed of modified vegetable oil, synthesized ester, an extreme pressure anti-wear agent, a metal deactivator, a degradation accelerant and a natural oxidation inhibitor. The product is unconventional high-grade trace lubricant oil and ultra-strong in lubrication performance, and is mainly applied to a near-dry cutting machining process for the materials of steel, cast iron, aluminium alloy and the like.
Description
Technical field
The present invention relates to a kind of high-quality near dry cutting micro lubricating oil.
Background technology
Cutting is traditional machining mode that machinery industry uses.For reaching good lubricated, cooling, cleaning, antirust and chip removal effect, tool life, improves workpiece surface quality, need to use a large amount of cutting fluids to be cast in cutting zone.A large amount of uses of cutting fluid, in improving machining effect, have also caused very outstanding negative impact.The one, consume bulk petroleum resource, increase user's production cost; The 2nd, the waste liquid of discharge is difficult for processing, and prolonged stay, in water and soil, destroys ecotope; The 3rd, in cutting fluid, contain the objectionable impuritiess such as Sodium Nitrite, easily bring out cancer, respiratory tract disease and multiple dermatosis, threaten HUMAN HEALTH.In the face of the tendency of the day of chemical greenization and human social in the urgent need to, near dry cutting new technology should be given birth to luckily in the beginning of this century.So-called near dry cutting, millimicro meter level aerosol will be formed exactly after the pressurized air of certain pressure and micro lubricating oil mixed aerosol, spray at a high speed cutting zone, form one deck oil film, contact interface to cutter and workpiece, cutter and smear metal is lubricated, reducing friction, restrain temperature rise, reduce tool wear, prevent that smear metal end from adhering on cutter and (be conducive to chip removal).Cutter, workpiece and smear metal after processing are all dried, and have exempted post-processed.Clean smear metal is through overdraft recoverable.Environmentally safe and HUMAN HEALTH does not affect.And whole system is simple in structure, to selecting also without particular requirement of cutter, lathe and workpiece material.This is that a kind of cutting fluid usage quantity is minimum, resource utilization is the highest, environmental pollution and Health Impact minimum, can overcome wet cutting drawback, the Green Machining new technology that can reach same cutting effect and be easy to apply again, is to traditional machining mode great innovation.The enterprise of Germany existing 35% adopts near dry cutting new technology at present, is secondly Japan, and Ye You minority scientific research institution of China, colleges and universities and enterprise are in research and development near dry cutting new technology.
The matching used cutting fluid of near dry cutting is the exigent micro lubricating oil of a kind of unconventional performance quality.Due to technique, the reason such as backward in technique, the lubricating oil that domestic-developed is produced at present, its technical feature gap compared with the developed country such as Japanese, German is larger, and the complete processing that far can not meet near dry cutting requires and the environmental friendliness requirement (required higher-grade lubricating oil all will rely on import) of people's growing interest.
Summary of the invention
The object of the present invention is to provide a kind of biodegradability good, be mainly used in the high-quality near dry cutting micro lubricating oil of the near dry cutting complete processing of the materials such as steel, cast iron, aluminium alloy.
Technical solution of the present invention is:
A kind of high-quality near dry cutting micro lubricating oil, is characterized in that: be made up of weight components:
Modified vegetable oil 10～40%
Synthetic ester 40～70%
Extreme pressure anti-wear additives 1～10%
Metal passivator 0.2～5%
Degradation of promoter 0.2～5%
Natural oxidation inhibitor 0～3%.
Modified vegetable oil refers to rapeseed oil, soybean oil, sunflower seed oil, Viscotrol C, sweet oil, the resultant of plam oil after hydrogenation, esterification, epoxidation, boronation modification.
Synthetic ester is dibasic acid esters and/or polyol ester; Described dibasic acid esters is the generation ester by hexanodioic acid, nonane diacid, sebacic acid di-carboxylic acid and 2-Ethylhexyl Alcohol, isooctyl alcohol, nonyl alcohol, isodecyl alcohol; Polyol ester is the amyl-based polyol of neopentyl glycol, TriMethylolPropane(TMP), tetramethylolmethane and the esterification products of longer chain fatty acid.
Extreme pressure anti-wear additives is Imidazoline Borate.
Metal passivator is butanedioic acid derivative, benzotriazole, methyl benzotriazazole, 1H-1,2, one or more in 4-triazole.
Degradation of promoter is one or more in N-oleoyl L-Ala, N-oleoyl Serine.
Natural oxidation inhibitor is tea-polyphenol or the vitamin-E class material extracting from green tea, ginger or garlic.
This product is a kind of unconventional higher-grade micro lubricating oil, is mainly used in the near dry cutting complete processing of the materials such as steel, cast iron, aluminium alloy, major advantage:
1, there is superpower lubricity.After tested, the tapping moment of torsion≤250N.cm of product.
2, there is excellent biodegradability.After tested, biological degradability BOD/COD >=0.998 of product.
3, there is reliable hygienic safety quality.After tested, the biological Lethal Dose 50 LD50 >=5000mg/kg of product, toxic limit medium dose LC50 >=5000mg/m3, apnea road mucous membrane irritation.
4, suitable material and technique are extensive, consumption rate minimum (conventional cutting, turning usage quantity≤3ml/h).
Below in conjunction with embodiment, the invention will be further described.
Embodiment
Embodiment 1:
A kind of high-quality near dry cutting micro lubricating oil, is characterized in that: form mix and blend by weight components, make product:
Hydrogenated rapeseed oil 20%
Methyl ricinolcic acid 18%
Positive pentaerythritol tetran-haptanoate 17%
Tricarboxymethyl propane oleate 30%
Sebacic acid two isooctyl alcohol esters 12.5%
Imidazoline Borate 0.8%
Green tea polyphenol 0.5%
Benzotriazole 0.2%
N-oleoyl L-Ala 1%.
Embodiment 2:
A kind of high-quality near dry cutting micro lubricating oil, is made up of weight components:
Modified vegetable oil 10～40%(example 10%, 25%, 40%)
Synthetic ester 40～70%(example 40%, 55%, 70%)
Extreme pressure anti-wear additives 1～10%(example 1%, 5%, 10%)
Metal passivator 0.2～5%(example 0.2%, 3%, 40%)
Degradation of promoter 0.2～5%(example 0.2%, 3%, 5%)
Natural oxidation inhibitor 0～3%(example 1%, 2%, 3%).
Modified vegetable oil refers to rapeseed oil, soybean oil, sunflower seed oil, Viscotrol C, sweet oil, the resultant of plam oil after hydrogenation, esterification, epoxidation, boronation modification.
Synthetic ester is dibasic acid esters and/or polyol ester; Described dibasic acid esters is the generation ester by hexanodioic acid, nonane diacid, sebacic acid di-carboxylic acid and 2-Ethylhexyl Alcohol, isooctyl alcohol, nonyl alcohol, isodecyl alcohol; Polyol ester is the amyl-based polyol of neopentyl glycol, TriMethylolPropane(TMP), tetramethylolmethane and the esterification products of longer chain fatty acid.
Extreme pressure anti-wear additives is Imidazoline Borate.
Metal passivator is butanedioic acid derivative, benzotriazole, methyl benzotriazazole, 1H-1,2, one or more in 4-triazole.
Degradation of promoter is one or more in N-oleoyl L-Ala, N-oleoyl Serine.
Natural oxidation inhibitor is tea-polyphenol or the vitamin-E class material extracting from green tea, ginger or garlic.
Claims (1)
1. a high-quality near dry cutting micro lubricating oil, is characterized in that: be made up of weight components:
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201310138039.5A CN103242941B (en) | 2013-04-21 | 2013-04-21 | High-quality trace lubricant oil for near-dry cutting |
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| CN201310138039.5A CN103242941B (en) | 2013-04-21 | 2013-04-21 | High-quality trace lubricant oil for near-dry cutting |
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| Publication Number | Publication Date |
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| CN103242941A CN103242941A (en) | 2013-08-14 |
| CN103242941B true CN103242941B (en) | 2014-08-27 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL1041960B1 (en) * | 2016-06-29 | 2018-01-05 | Holland Novochem Technical Coatings Bv | Catalytically active radical scavengers based on allylic-hydrogen functionalities |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105087109A (en) * | 2014-05-05 | 2015-11-25 | 东莞市海纳润滑油有限公司 | Fully effective lubricating oil containing rhenium tungsten alloy |
| CN105175698A (en) * | 2014-05-26 | 2015-12-23 | 广州米奇化工有限公司 | Castor oil modified multi-functional lubricant and preparation method thereof |
| CN106147927B (en) * | 2015-03-26 | 2019-04-23 | 王九 | A kind of preparation method of boronation Rap Oil -based green lubrication additive |
| CN106675713B (en) * | 2016-08-26 | 2019-05-17 | 上海金兆节能科技有限公司 | Dedicated micro lubricating oil of food engineering and preparation method thereof |
| CN107629831A (en) * | 2017-09-22 | 2018-01-26 | 东莞安默琳机械制造技术有限公司 | A kind of cutting oil for low-temperature trace lubrication |
| CN107955695A (en) * | 2017-12-25 | 2018-04-24 | 三达奥克化学股份有限公司 | The micro processing oil of easily biological-degradable aluminium and production method |
| CN109825345B (en) * | 2019-02-19 | 2021-12-24 | 上海金兆节能科技有限公司 | High-temperature-resistant lubricant and preparation method thereof |
| CN109810761B (en) * | 2019-02-19 | 2021-12-10 | 上海金兆节能科技有限公司 | Degradable trace lubricating oil and preparation method thereof |
| CN110331024A (en) * | 2019-07-29 | 2019-10-15 | 杭州电子科技大学 | A kind of environmental protection wearproof lubricant and preparation method thereof |
| CN111117750A (en) * | 2019-12-24 | 2020-05-08 | 上海阿道润滑科技有限公司 | Trace lubricating oil, preparation method and supply device thereof |
| CN112226267A (en) * | 2020-11-12 | 2021-01-15 | 中国石油化工股份有限公司 | Extreme pressure trace lubricating cutting oil composition, preparation method and application thereof |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2001005916A1 (en) * | 1999-07-21 | 2001-01-25 | Dainippon Ink And Chemicals, Inc. | Extreme-pressure additive, process for producing the same, cutting fluid, and grinding fluid |
| CN102002419A (en) * | 2010-11-29 | 2011-04-06 | 上海通快实业有限公司 | Biodegradable quasi dry cutting oil and preparation method thereof |
| CN102031190A (en) * | 2010-12-28 | 2011-04-27 | 东莞太平洋博高润滑油有限公司 | Cutting oil and preparation method thereof |
| CN103045341A (en) * | 2013-01-08 | 2013-04-17 | 启东尤希路化学工业有限公司 | Grinding fluid for processing high-performance superhard alloy |
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2013
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL1041960B1 (en) * | 2016-06-29 | 2018-01-05 | Holland Novochem Technical Coatings Bv | Catalytically active radical scavengers based on allylic-hydrogen functionalities |
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