CN103525529B - High-performance environment-friendly water-soluble punching oil - Google Patents
High-performance environment-friendly water-soluble punching oil Download PDFInfo
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- CN103525529B CN103525529B CN201310480155.5A CN201310480155A CN103525529B CN 103525529 B CN103525529 B CN 103525529B CN 201310480155 A CN201310480155 A CN 201310480155A CN 103525529 B CN103525529 B CN 103525529B
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- 238000004080 punching Methods 0.000 title abstract description 4
- 239000000203 mixture Substances 0.000 claims description 2
- 239000003921 oil Substances 0.000 abstract description 11
- 235000019198 oils Nutrition 0.000 abstract description 11
- 150000001298 alcohols Chemical class 0.000 abstract description 5
- 150000001412 amines Chemical class 0.000 abstract description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract description 5
- 238000005660 chlorination reaction Methods 0.000 abstract description 5
- 239000000314 lubricant Substances 0.000 abstract description 5
- 239000001301 oxygen Substances 0.000 abstract description 5
- 229910052760 oxygen Inorganic materials 0.000 abstract description 5
- 235000015112 vegetable and seed oil Nutrition 0.000 abstract description 4
- 239000008158 vegetable oil Substances 0.000 abstract description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 4
- 239000000126 substance Substances 0.000 abstract description 3
- 238000010079 rubber tapping Methods 0.000 abstract description 2
- 239000005069 Extreme pressure additive Substances 0.000 abstract 2
- 239000002518 antifoaming agent Substances 0.000 abstract 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 abstract 1
- 230000001050 lubricating effect Effects 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 239000003755 preservative agent Substances 0.000 abstract 1
- 230000002335 preservative effect Effects 0.000 abstract 1
- 239000004094 surface-active agent Substances 0.000 abstract 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 10
- 239000003795 chemical substances by application Substances 0.000 description 9
- 229920002545 silicone oil Polymers 0.000 description 9
- SJRJJKPEHAURKC-UHFFFAOYSA-N N-Methylmorpholine Chemical compound CN1CCOCC1 SJRJJKPEHAURKC-UHFFFAOYSA-N 0.000 description 6
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 6
- 239000002253 acid Substances 0.000 description 6
- LVTYICIALWPMFW-UHFFFAOYSA-N diisopropanolamine Chemical compound CC(O)CNCC(C)O LVTYICIALWPMFW-UHFFFAOYSA-N 0.000 description 6
- 229940043276 diisopropanolamine Drugs 0.000 description 6
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 5
- 229920000570 polyether Polymers 0.000 description 5
- 235000013311 vegetables Nutrition 0.000 description 5
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 4
- 239000013543 active substance Substances 0.000 description 4
- 239000013530 defoamer Substances 0.000 description 4
- 150000002148 esters Chemical class 0.000 description 4
- BKIMMITUMNQMOS-UHFFFAOYSA-N nonane Chemical compound CCCCCCCCC BKIMMITUMNQMOS-UHFFFAOYSA-N 0.000 description 4
- FBUKVWPVBMHYJY-UHFFFAOYSA-N nonanoic acid Chemical compound CCCCCCCCC(O)=O FBUKVWPVBMHYJY-UHFFFAOYSA-N 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 4
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 3
- 229940058020 2-amino-2-methyl-1-propanol Drugs 0.000 description 3
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 3
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 3
- 231100000111 LD50 Toxicity 0.000 description 3
- 239000005642 Oleic acid Substances 0.000 description 3
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 3
- 239000004721 Polyphenylene oxide Substances 0.000 description 3
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 3
- SLINHMUFWFWBMU-UHFFFAOYSA-N Triisopropanolamine Chemical compound CC(O)CN(CC(C)O)CC(C)O SLINHMUFWFWBMU-UHFFFAOYSA-N 0.000 description 3
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 description 3
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 3
- 239000012964 benzotriazole Substances 0.000 description 3
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 229940049964 oleate Drugs 0.000 description 3
- -1 pentaerythritol ester Chemical class 0.000 description 3
- 239000001294 propane Substances 0.000 description 3
- 239000002699 waste material Substances 0.000 description 3
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 2
- HXKKHQJGJAFBHI-UHFFFAOYSA-N 1-aminopropan-2-ol Chemical compound CC(O)CN HXKKHQJGJAFBHI-UHFFFAOYSA-N 0.000 description 2
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- BFSVOASYOCHEOV-UHFFFAOYSA-N 2-diethylaminoethanol Chemical compound CCN(CC)CCO BFSVOASYOCHEOV-UHFFFAOYSA-N 0.000 description 2
- SFAAOBGYWOUHLU-UHFFFAOYSA-N 2-ethylhexyl hexadecanoate Chemical compound CCCCCCCCCCCCCCCC(=O)OCC(CC)CCCC SFAAOBGYWOUHLU-UHFFFAOYSA-N 0.000 description 2
- NSPMIYGKQJPBQR-UHFFFAOYSA-N 4H-1,2,4-triazole Chemical class C=1N=CNN=1 NSPMIYGKQJPBQR-UHFFFAOYSA-N 0.000 description 2
- SAUIGQBKPDQYHL-QXMHVHEDSA-N 6-methylheptyl (z)-octadec-9-enoate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCCCCCC(C)C SAUIGQBKPDQYHL-QXMHVHEDSA-N 0.000 description 2
- XBPCUCUWBYBCDP-UHFFFAOYSA-N Dicyclohexylamine Chemical compound C1CCCCC1NC1CCCCC1 XBPCUCUWBYBCDP-UHFFFAOYSA-N 0.000 description 2
- OYHQOLUKZRVURQ-HZJYTTRNSA-N Linoleic acid Chemical compound CCCCC\C=C/C\C=C/CCCCCCCC(O)=O OYHQOLUKZRVURQ-HZJYTTRNSA-N 0.000 description 2
- 239000005643 Pelargonic acid Substances 0.000 description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 2
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 150000002191 fatty alcohols Chemical class 0.000 description 2
- 229960004232 linoleic acid Drugs 0.000 description 2
- 150000002632 lipids Chemical class 0.000 description 2
- 238000003754 machining Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 150000004702 methyl esters Chemical class 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- QYDYPVFESGNLHU-KHPPLWFESA-N methyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC QYDYPVFESGNLHU-KHPPLWFESA-N 0.000 description 2
- REIUXOLGHVXAEO-UHFFFAOYSA-N pentadecan-1-ol Chemical compound CCCCCCCCCCCCCCCO REIUXOLGHVXAEO-UHFFFAOYSA-N 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
- 229920003216 poly(methylphenylsiloxane) Polymers 0.000 description 2
- 229920000056 polyoxyethylene ether Polymers 0.000 description 2
- 229940051841 polyoxyethylene ether Drugs 0.000 description 2
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 2
- 235000012424 soybean oil Nutrition 0.000 description 2
- 239000003549 soybean oil Substances 0.000 description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 2
- 238000005987 sulfurization reaction Methods 0.000 description 2
- 239000003760 tallow Substances 0.000 description 2
- 150000003918 triazines Chemical class 0.000 description 2
- 229960004418 trolamine Drugs 0.000 description 2
- ASFAFOSQXBRFMV-LJQANCHMSA-N 3-n-(2-benzyl-1,3-dihydroxypropan-2-yl)-1-n-[(1r)-1-(4-fluorophenyl)ethyl]-5-[methyl(methylsulfonyl)amino]benzene-1,3-dicarboxamide Chemical compound N([C@H](C)C=1C=CC(F)=CC=1)C(=O)C(C=1)=CC(N(C)S(C)(=O)=O)=CC=1C(=O)NC(CO)(CO)CC1=CC=CC=C1 ASFAFOSQXBRFMV-LJQANCHMSA-N 0.000 description 1
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- 229910001018 Cast iron Inorganic materials 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000002199 base oil Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 208000028659 discharge Diseases 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 231100001261 hazardous Toxicity 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000001473 noxious effect Effects 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 210000001533 respiratory mucosa Anatomy 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
Landscapes
- Lubricants (AREA)
Abstract
The invention discloses a high-performance environment-friendly water-soluble punching oil which is composed of high-polymer carboxylic acid, organic amine, higher alcohols, a surfactant, vegetable oil or synthetic lubricant, a vulcanizing extreme pressure additive, a chlorination extreme pressure additive, pure water, a defoaming agent and a preservative. The punching oil has superhigh lubricating property; after the product is diluted by 30 times, the tapping torque is less than or equal to 3000 N.cm, the cutter life is long, and the single batch cutter part processing quantity is greater than or equal to 300000. When adopting design formula of excellent-biodegradability vegetable oil (or synthetic fat) and other assistants, after the product is diluted by 30 times, the BOD/COD (biochemical oxygen demand/chemical oxygen demand) is greater than or equal to 0.6.
Description
Technical field
The present invention relates to the high-performance environment protection type water-soluble flush force feed used in the processing of a kind of metal stamping.
Background technology
The pure oiliness punching oil that tradition uses (makes base oil with mineral oil, composite extreme pressure agent and the blending of multiple auxiliary agent form, not moisture, use can not be diluted), due to its technology and mature preparation process, lubricate, antirust, corrosion resistance is excellent, is widely used in the machining enterprise in the fields such as automobile, motorcycle, engineering machinery for a long time to the punch machining process of the metal materials such as steel, cast iron, aluminium alloy.But also there are some important drawbacks in it.One is that pure Oily preparation consumes bulk petroleum resource, and price is expensive, and use cost is high: two is there is disaster hidden-trouble, poor stability: three is that the waste liquid discharged not easily processes, serious environment pollution.Last century the nineties, the developed country such as Japanese, American-European has researched and developed successfully water-soluble flush force feed in succession, compared with pure Oily preparation, significantly reduce petroleum resource consumption, produce and use cost low, there is not disaster hidden-trouble, waste liquid easily processes, and environmental pollution is little, is subject to market favor, be expected to progressively replace pure Oily preparation, become the main product of future market.Since entering the new millennium, domestic also have some enterprises in succession to succeed in developing water-soluble flush force feed, but all undesirable (subject matter is: lubricity is poor, affects cutter life and workpiece surface quality; Biodegradable performance is poor, the waste liquid not easily biochemical treatment of discharge; Containing hazardous and noxious substances in formula, safety and sanitation are of poor quality), thus greatly constrain its applying (especially high-end market) in market.
Summary of the invention
The object of the present invention is to provide the high-performance environment protection type water-soluble flush force feed of a kind of lubricity by force, to human and environment safety.
Technical solution of the present invention is:
A kind of high-performance environment protection type water-soluble flush force feed, is characterized in that: be grouped into by the one-tenth of following weight percents:
Polymeric carboxylic 3 ~ 10%
Organic amine 5 ~ 20%
Higher alcohols 1 ~ 10%
Tensio-active agent 1 ~ 20%
Vegetables oil or synthetic lubricant 10 ~ 30%
Sulfurized extreme pressure agent 10 ~ 30%
Chlorination extreme pressure agent 5 ~ 15%
Pure water 5 ~ 25%
Defoamer 0 ~ 0.5%
Sanitas or sterilant 0 ~ 5%.
Described polymeric carboxylic is sad, pelargonic acid, sebacic acid, hexanodioic acid, nonane diacid, bay diacid, C
8~ C
18one or more in lipid acid, oleic acid, linolic acid, triazines multi-carboxylic acid compounds.
Described organic amine is one or more in Monoethanolamine MEA BASF, diethanolamine, trolamine, monoisopropanolamine, diisopropanolamine (DIPA), tri-isopropanolamine, morpholine, dicyclohexyl amine, N-methylmorpholine, 2-amino-2-methyl-1-propanol, Diethylaminoethanol.
Described higher alcohols is C
8~ C
10straight chain alcohol, C
12~ C
13straight chain alcohol or isomery alcohol, C
14~ C
15straight chain alcohol or isomery alcohol in one or more.
Described tensio-active agent is one or more in fatty alcohol-polyoxyethylene ether (5 ~ 12), Fatty alcohol polyoxyethylene polyoxypropylene ether, alkylol amide, aliphatic alcohol polyethenoxy ester (5 ~ 12), sulfonate.
Described vegetables oil or synthetic lubricant are one or more in sirasimeyu, soybean oil, plam oil, Oleum Cocois, suet, tricarboxymethyl propane oleate, pentaerythritol ester, isooctyl oleate, Witconol 2301, hexanodioic acid dibutyl ester, Wickenol 155.
Described sulfurized extreme pressure agent is one or more in olefine sulfide, methyl ester, sulfuration tallow fatty acid, vulcanized vegetable oil.
Described chlorination extreme pressure agent is clorafin.
Described defoamer is one or more in dimethyl silicone oil, diethyl silicone oil, methyl phenyl silicone oil, ammonia alkyl silicone oil, polyether silicone oil, polyethers.
Described sanitas is one or more in benzotriazole, methyl benzotriazazole, 1H-1,2,4-triazoles.
The present invention has superpower lubricity; When product dilutes 30 times of uses, its tapping torque≤3000N.cm, cutter life is long, single batch of tool sharpening part amount >=300000.Select vegetables oil (or synthetic fat) and other auxiliary agent component designs that biodegradable performance is excellent, when product dilutes 30 times of uses, its BOD(biological oxygen demand (BOD))/COD(chemical oxygen demand) >=0.6.Select that environmentally safe and HUMAN HEALTH is harmless, the alternative raw material component design of excellent property, product biological Lethal Dose 50 LD50>=5000mg/kg, toxic limit medium dose LC50>=5000mg/m
3, respiratory mucosa stimulates≤1 grade.
Below in conjunction with embodiment, the invention will be further described.
Embodiment
Embodiment 1:
A kind of high-performance environment protection type water-soluble flush force feed, is mixed by the composition of following weight percents:
Month silicon diacid 5%
Oleic acid 5%
2-amino-2-methyl-1-propanol 11%
Diisopropanolamine (DIPA) 3%
Tri-isopropanolamine 3%
Alkylol amide 4%
Polyoxyethylene poly-oxygen propylene aether 2%
Pure water 13.4%
Pentadecanol 2%
Tricarboxymethyl propane oleate 10%
Plam oil 10%
Polyether silicone oil 0.5%
Benzotriazole 0.1%
Clorafin 5%
Olefine sulfide 26%.
Embodiment 2:
A kind of high-performance environment protection type water-soluble flush force feed, is grouped into by the one-tenth of following weight percents:
Polymeric carboxylic 3 ~ 10%(example 3%, 7%, 10%)
Organic amine 5 ~ 20%(example 5%, 13%, 20%)
Higher alcohols 1 ~ 10%(example 1%, 5%, 10%)
Tensio-active agent 1 ~ 20%(example 1%, 10%, 20%)
Vegetables oil or synthetic lubricant 10 ~ 30%(example 10%, 20%, 30%)
Sulfurized extreme pressure agent 10 ~ 30%(example 10%, 20%, 30%)
Chlorination extreme pressure agent 5 ~ 15%(example 5%, 10%, 15%)
Pure water 5 ~ 25%(example 5%, 15%, 25%)
Defoamer 0 ~ 0.5%(example 0.1%, 0.3%, 0.5%)
Sanitas or sterilant 0 ~ 5%(example 1%, 3%, 5%).
Described polymeric carboxylic is sad, pelargonic acid, sebacic acid, hexanodioic acid, nonane diacid, bay diacid, C
8~ C
18one or more in lipid acid, oleic acid, linolic acid, triazines multi-carboxylic acid compounds.
Described organic amine is one or more in Monoethanolamine MEA BASF, diethanolamine, trolamine, monoisopropanolamine, diisopropanolamine (DIPA), tri-isopropanolamine, morpholine, dicyclohexyl amine, N-methylmorpholine, 2-amino-2-methyl-1-propanol, Diethylaminoethanol.
Described higher alcohols is C
8~ C
10straight chain alcohol, C
12~ C
13straight chain alcohol or isomery alcohol, C
14~ C
15straight chain alcohol or isomery alcohol in one or more.
Described tensio-active agent is one or more in fatty alcohol-polyoxyethylene ether (5 ~ 12), Fatty alcohol polyoxyethylene polyoxypropylene ether, alkylol amide, aliphatic alcohol polyethenoxy ester (5 ~ 12), sulfonate.
Described vegetables oil or synthetic lubricant are one or more in sirasimeyu, soybean oil, plam oil, Oleum Cocois, suet, tricarboxymethyl propane oleate, pentaerythritol ester, isooctyl oleate, Witconol 2301, hexanodioic acid dibutyl ester, Wickenol 155.
Described sulfurized extreme pressure agent is one or more in olefine sulfide, methyl ester, sulfuration tallow fatty acid, vulcanized vegetable oil.
Described chlorination extreme pressure agent is clorafin.
Described defoamer is one or more in dimethyl silicone oil, diethyl silicone oil, methyl phenyl silicone oil, ammonia alkyl silicone oil, polyether silicone oil, polyethers.
Described sanitas is one or more in benzotriazole, methyl benzotriazazole, 1H-1,2,4-triazoles.
Claims (1)
1. a high-performance environment protection type water-soluble flush force feed, is characterized in that: be mixed by the composition of following weight percents:
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CN104694234A (en) * | 2015-03-18 | 2015-06-10 | 启东尤希路化学工业有限公司 | High-performance environmentally-friendly medium- and long-period antirust punching oil |
CN104830409A (en) * | 2015-04-01 | 2015-08-12 | 瑞虹电子(昆山)有限公司 | Connection elastic plate stamping lubricating oil and preparation method thereof |
CN104928000A (en) * | 2015-07-03 | 2015-09-23 | 上海尤希路化学工业有限公司 | Multipurpose carbon-deposition-free environmental-friendly water soluble drawing lubricant |
CN107629844A (en) * | 2016-07-18 | 2018-01-26 | 天津市澳路浦润滑科技股份有限公司 | A kind of aluminum alloy plate materials water-soluble flush force feed |
CN106675714B (en) * | 2016-08-26 | 2019-12-10 | 上海金兆节能科技有限公司 | volatile trace lubricating oil and preparation method thereof |
CN107974338A (en) * | 2017-11-24 | 2018-05-01 | 东莞市伟思化学科技有限公司 | A kind of fully synthetic aqueous stamping oil of carbon steel and preparation method thereof |
CN108251194A (en) * | 2017-12-25 | 2018-07-06 | 柳州智臻智能机械有限公司 | A kind of mechanical processing is with lubricator and preparation method thereof |
CN108359522A (en) * | 2018-02-05 | 2018-08-03 | 镇江艾润润滑油有限公司 | A kind of Biostatic type metal working fluid and preparation method thereof |
CN108865382A (en) * | 2018-08-20 | 2018-11-23 | 东莞市伟思化学科技有限公司 | A kind of stainless steel plant base water-soluble flush pressure oil and preparation method thereof |
CN109679752B (en) * | 2019-01-29 | 2021-10-15 | 汉能(青岛)润滑科技有限公司 | Degradable lubricating oil adopting permeation layer technology and preparation method thereof |
CN109797035A (en) * | 2019-02-19 | 2019-05-24 | 华彦汽车零部件(江苏)有限公司 | A kind of high-performance punching press oil formula |
CN110951532B (en) * | 2019-12-23 | 2022-03-11 | 苏州铱诺化学材料有限公司 | Water-based stamping oil for aluminum fins and preparation method thereof |
CN111763559A (en) * | 2020-07-30 | 2020-10-13 | 东莞市鹏润压铸材料科技有限公司 | Environment-friendly water-based plunger punch lubricating liquid |
CN112080334B (en) * | 2020-09-22 | 2023-01-06 | 湖北诚祥科技有限公司 | Novel water-soluble punching oil |
CN115521825B (en) * | 2022-11-07 | 2023-11-21 | 季华实验室 | Water-based stamping liquid and preparation method and application thereof |
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EP2161327A1 (en) * | 2008-09-05 | 2010-03-10 | Cognis IP Management GmbH | Emulsifiers for metal working fluids |
CN102618372A (en) * | 2012-02-28 | 2012-08-01 | 上海尤希路化学工业有限公司 | High performance biodegradation type metal machining protection liquid |
CN103046066B (en) * | 2013-01-08 | 2014-08-27 | 上海尤希路化学工业有限公司 | High-performance and environment-friendly water-based cleaning agent |
CN103275795B (en) * | 2013-05-24 | 2016-08-31 | 上海金兆节能科技有限公司 | Organic molybdenum trace lubricant |
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