CN104694234A - High-performance environmentally-friendly medium- and long-period antirust punching oil - Google Patents
High-performance environmentally-friendly medium- and long-period antirust punching oil Download PDFInfo
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- CN104694234A CN104694234A CN201510117670.6A CN201510117670A CN104694234A CN 104694234 A CN104694234 A CN 104694234A CN 201510117670 A CN201510117670 A CN 201510117670A CN 104694234 A CN104694234 A CN 104694234A
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Abstract
The invention discloses a high-performance environmentally-friendly medium- and long-period antirust punching oil. The high-performance environmentally-friendly medium- and long-period antirust punching oil comprises a synthetic lubricant, an anti-wear reagent at extreme pressure, a metal deactivator, a surface active agent, refined mineral oil, and refined solvent oil. The punching oil is antirust, high in cleaning performance, sanitary and safe.
Description
Background technology
The present invention relates to a kind of antirust punching oil.
Background technology
Punch process adopts precision die, and directly process close to finished product accuracy or directly process finished product, workpiece accuracy can reach micron order, and stamping parts is compared with foundry goods, has thin, even, light, strong feature.For meeting environment protection requirement, reducing chemical and using, having trended towards reducing fewer and fewerily and cut ground finish, therefore along with the quick growth of China's automobile, household electrical appliances, IT industry, the demand of high precision stamping parts has been grown with each passing day.
For improving the working accuracy of stamping parts, extending die life, requiring that matching used punching oil must have excellent lubricity, rustless property and by cleaning performance.Its lubricity of punching oil commercially available at present can meet the service requirements of user substantially.But also there are three problems demand to solve.One is that the salt fog resistance of product, wet-hot aging performance are poor, and the atmospheric exposure test time is short, can not meet the antirust requirement under stamping parts stored for extended periods condition; Two are products is the lubricity requirement meeting punch process, and viscosity is higher, thicker at the oil film of stamping parts Surface Creation, causes poor-performing capable of washing; Three is generally contain the hazardous and noxious substances such as chlorine, heavy metal in formula constituent, is detrimental to health and environmental safety.Thus make applying of product be restricted (especially in high-end market).
Summary of the invention
The object of the present invention is to provide a kind of antirust, cleaning performance good, the medium-term and long-term antirust punching oil of the high-performance environment-friendly type of hygienic safety.
Technical solution of the present invention is:
The medium-term and long-term antirust punching oil of a kind of high-performance environment-friendly type, is characterized in that: be grouped into by the one-tenth of following weight percents:
Synthetic lubricant ... 5 ~ 10%
Rust-preventive agent ... 10 ~ 25%
Extreme pressure anti-wear additives ... 1 ~ 10%
Metal passivator ... 0.2 ~ 1%
Tensio-active agent ... 1 ~ 3%
Refined mineral oil ... 10 ~ 30%
Solvent-refined oil ... 30-~ 60%
Above-mentioned each amounts of components sum is 100%.
Synthetic lubricant is improved plant grease and/or polyol ester.Improved plant grease is that rapeseed oil, soybean oil, sunflower seed oil, Viscotrol C, palm wet goods vegetables oil are through the modified resultant of hydrogenation, esterification, boronation.Polyol ester is the esterification products of the amyl-based polyols such as neopentyl glycol, TriMethylolPropane(TMP), tetramethylolmethane and longer chain fatty acid
Rust-preventive agent is the calcium soap of petroleum sodium sulfonate, calcium mahogany sulfonate, petroleum oxidate acid calcium salt, petroleum oxidate acid ammonium salt, petroleum oxidate acid esters, laurylene base fourth ニ acid, lanolin or lanolin.
Extreme pressure anti-wear additives is Imidazoline Borate, zinc dialkyl dithiophosphate or phosphoric acid ester.
Metal passivator is butanedioic acid derivative, benzotriazole, methyl benzotriazazole, 1H-1 or 2,4-triazole.
Tensio-active agent is polyoxyethylene poly-oxygen propylene aether, phosphonic acid ester, dehydration sorbic alcohol oleic acid ester or MMB.
Refined mineral oil is white oil, 150SN or bright stock.
Solvent-refined oil is tasteless kerosene, aviation kerosene or solvent oil.
The present invention has excellent lubricity and rustless property.After tested, the last non seizure load PB > 2500N of product, sintering load PD value > 9800N, salt fog resistance time >=168hr, wet-heat resisting time >=960hr, atmospheric exposure test time > 300 days, indoor rust-proof life >=1 year of stamping parts.Have excellent in cleaning performance.After tested, product in oil film thickness≤1.0 μm of stamping parts Surface Creation, cleaning rate >=99%.There is reliable hygienic safety quality.Biological Lethal Dose 50 LD50 >=5000mg/kg, toxic limit medium dose LC50 >=5000mg/m3, respiratory mucosa stimulates≤1.
Below in conjunction with embodiment, the invention will be further described.
Embodiment
Embodiment 1:
By the component mix and blend of following weight percents, obtain the medium-term and long-term antirust punching oil of high-performance environment-friendly type:
Witconol 2301 5%
PETO 3%
Petroleum oxidate acid calcium salt 8%
Calcium mahogany sulfonate 3%
Petroleum oxidate acid esters 5%
Lanolin 0.5%
Imidazoline Borate 2%
Benzotriazole 0.2%
MMB 2%
150SN 15%
Tasteless kerosene 56.3%
Embodiment 2:
The medium-term and long-term antirust punching oil of a kind of high-performance environment-friendly type, is grouped into by the one-tenth of following weight percents:
Synthetic lubricant ... 5 ~ 10%(example 5%, 7%, 10%)
Rust-preventive agent ... 10 ~ 25%(example 10%, 17%, 25%)
Extreme pressure anti-wear additives ... 1 ~ 10%(example 1%, 7%, 10%)
Metal passivator ... 0.2 ~ 1%(example 0.2%, 0.5%, 1%)
Tensio-active agent ... 1 ~ 3%(example 1%, 2%, 3%)
Refined mineral oil ... 10 ~ 30%(example 10%, 20%, 30%)
Solvent-refined oil ... 30-~ 60%(example 30%, 45%, 60%)
Above-mentioned each amounts of components sum is 100%.
Synthetic lubricant is improved plant grease and/or polyol ester.Improved plant grease is that rapeseed oil, soybean oil, sunflower seed oil, Viscotrol C, palm wet goods vegetables oil are through the modified resultant of hydrogenation, esterification, boronation.Polyol ester is the esterification products of the amyl-based polyols such as neopentyl glycol, TriMethylolPropane(TMP), tetramethylolmethane and longer chain fatty acid
Rust-preventive agent is the calcium soap of petroleum sodium sulfonate, calcium mahogany sulfonate, petroleum oxidate acid calcium salt, petroleum oxidate acid ammonium salt, petroleum oxidate acid esters, laurylene base fourth ニ acid, lanolin or lanolin.
Extreme pressure anti-wear additives is Imidazoline Borate, zinc dialkyl dithiophosphate or phosphoric acid ester.
Metal passivator is butanedioic acid derivative, benzotriazole, methyl benzotriazazole, 1H-1 or 2,4-triazole.
Tensio-active agent is polyoxyethylene poly-oxygen propylene aether, phosphonic acid ester, dehydration sorbic alcohol oleic acid ester or MMB.
Refined mineral oil is white oil, 150SN or bright stock.
Solvent-refined oil is tasteless kerosene, aviation kerosene or solvent oil.
Claims (8)
1. the medium-term and long-term antirust punching oil of high-performance environment-friendly type, is characterized in that: be grouped into by the one-tenth of following weight percents:
Synthetic lubricant ... 5 ~ 10%
Rust-preventive agent ... 10 ~ 25%
Extreme pressure anti-wear additives ... 1 ~ 10%
Metal passivator ... 0.2 ~ 1%
Tensio-active agent ... 1 ~ 3%
Refined mineral oil ... 10 ~ 30%
Solvent-refined oil ... 30-~ 60%
Above-mentioned each amounts of components sum is 100%.
2. the medium-term and long-term antirust punching oil of high-performance environment-friendly type according to claim 1, is characterized in that: synthetic lubricant is improved plant grease and/or polyol ester.
3. the medium-term and long-term antirust punching oil of high-performance environment-friendly type according to claim 1, is characterized in that: rust-preventive agent is the calcium soap of petroleum sodium sulfonate, calcium mahogany sulfonate, petroleum oxidate acid calcium salt, petroleum oxidate acid ammonium salt, petroleum oxidate acid esters, laurylene base fourth ニ acid, lanolin or lanolin.
4. the medium-term and long-term antirust punching oil of high-performance environment-friendly type according to claim 1, is characterized in that: extreme pressure anti-wear additives is Imidazoline Borate, zinc dialkyl dithiophosphate or phosphoric acid ester.
5. the medium-term and long-term antirust punching oil of high-performance environment-friendly type according to claim 1, is characterized in that: metal passivator is butanedioic acid derivative, benzotriazole, methyl benzotriazazole, 1H-1 or 2,4-triazole.
6. the medium-term and long-term antirust punching oil of high-performance environment-friendly type according to claim 1, is characterized in that: tensio-active agent is polyoxyethylene poly-oxygen propylene aether, phosphonic acid ester, dehydration sorbic alcohol oleic acid ester or MMB.
7. the medium-term and long-term antirust punching oil of high-performance environment-friendly type according to claim 1, is characterized in that: refined mineral oil is white oil, 150SN or bright stock.
8. the medium-term and long-term antirust punching oil of high-performance environment-friendly type according to claim 1, is characterized in that: solvent-refined oil is tasteless kerosene, aviation kerosene or solvent oil.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510117670.6A CN104694234A (en) | 2015-03-18 | 2015-03-18 | High-performance environmentally-friendly medium- and long-period antirust punching oil |
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| CN201510117670.6A CN104694234A (en) | 2015-03-18 | 2015-03-18 | High-performance environmentally-friendly medium- and long-period antirust punching oil |
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| CN201510117670.6A Pending CN104694234A (en) | 2015-03-18 | 2015-03-18 | High-performance environmentally-friendly medium- and long-period antirust punching oil |
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Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105296085A (en) * | 2015-10-19 | 2016-02-03 | 中国石油化工股份有限公司 | Stamping oil composition and application thereof |
| CN105733765A (en) * | 2016-01-26 | 2016-07-06 | 深圳市鑫昌龙新材料科技股份有限公司 | Environment-friendly cleaning-free antirust punching oil |
| CN106190498A (en) * | 2016-07-26 | 2016-12-07 | 中国石油化工股份有限公司 | Punching oil compositions and application thereof |
| CN106635306A (en) * | 2016-09-21 | 2017-05-10 | 广西大学 | Composition for bidery metal sheet stamping lubricant |
| CN106675730A (en) * | 2016-12-23 | 2017-05-17 | 诺泰生物科技(合肥)有限公司 | Volatile steel pipe expanding oil and preparation method thereof |
| CN107418692A (en) * | 2017-05-24 | 2017-12-01 | 安徽省瀚海新材料股份有限公司 | A kind of sintered NdFeB isostatic pressed oil |
| CN107629844A (en) * | 2016-07-18 | 2018-01-26 | 天津市澳路浦润滑科技股份有限公司 | A kind of aluminum alloy plate materials water-soluble flush force feed |
| CN108531255A (en) * | 2018-05-28 | 2018-09-14 | 湖北三环化学新材料股份有限公司 | A kind of punching press cleaning rust-proof oil and preparation method thereof |
| CN108822940A (en) * | 2018-07-26 | 2018-11-16 | 郑州市欧普士科技有限公司 | A kind of long-life viscosity oil film rust preventive oil and preparation method thereof |
| CN108841432A (en) * | 2018-05-28 | 2018-11-20 | 湖北三环化学新材料股份有限公司 | A kind of degradable punching oil of food-grade and preparation method thereof |
| CN109943404A (en) * | 2019-04-24 | 2019-06-28 | 上海尤希路化学工业有限公司 | High-grade environment-friendly type mirror finish grinding oil |
| CN109971533A (en) * | 2019-04-25 | 2019-07-05 | 上海尤希路化学工业有限公司 | Robot precise thin-wall bearing is heat-treated low VOC antirust oil |
| CN111073737A (en) * | 2019-12-01 | 2020-04-28 | 苏州福瑞斯德新材料科技有限公司 | Anti-rust oil without containing heavy metal |
| CN114317080A (en) * | 2021-12-29 | 2022-04-12 | 安美科技股份有限公司 | Ultra-precise machine tool spindle oil and preparation method thereof |
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Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105296085A (en) * | 2015-10-19 | 2016-02-03 | 中国石油化工股份有限公司 | Stamping oil composition and application thereof |
| CN105296085B (en) * | 2015-10-19 | 2018-10-26 | 中国石油化工股份有限公司 | Punching press fluid composition and application thereof |
| CN105733765A (en) * | 2016-01-26 | 2016-07-06 | 深圳市鑫昌龙新材料科技股份有限公司 | Environment-friendly cleaning-free antirust punching oil |
| CN107629844A (en) * | 2016-07-18 | 2018-01-26 | 天津市澳路浦润滑科技股份有限公司 | A kind of aluminum alloy plate materials water-soluble flush force feed |
| CN106190498A (en) * | 2016-07-26 | 2016-12-07 | 中国石油化工股份有限公司 | Punching oil compositions and application thereof |
| CN106635306A (en) * | 2016-09-21 | 2017-05-10 | 广西大学 | Composition for bidery metal sheet stamping lubricant |
| CN106675730A (en) * | 2016-12-23 | 2017-05-17 | 诺泰生物科技(合肥)有限公司 | Volatile steel pipe expanding oil and preparation method thereof |
| CN107418692A (en) * | 2017-05-24 | 2017-12-01 | 安徽省瀚海新材料股份有限公司 | A kind of sintered NdFeB isostatic pressed oil |
| CN108531255A (en) * | 2018-05-28 | 2018-09-14 | 湖北三环化学新材料股份有限公司 | A kind of punching press cleaning rust-proof oil and preparation method thereof |
| CN108841432A (en) * | 2018-05-28 | 2018-11-20 | 湖北三环化学新材料股份有限公司 | A kind of degradable punching oil of food-grade and preparation method thereof |
| CN108822940A (en) * | 2018-07-26 | 2018-11-16 | 郑州市欧普士科技有限公司 | A kind of long-life viscosity oil film rust preventive oil and preparation method thereof |
| CN109943404A (en) * | 2019-04-24 | 2019-06-28 | 上海尤希路化学工业有限公司 | High-grade environment-friendly type mirror finish grinding oil |
| CN109971533A (en) * | 2019-04-25 | 2019-07-05 | 上海尤希路化学工业有限公司 | Robot precise thin-wall bearing is heat-treated low VOC antirust oil |
| CN111073737A (en) * | 2019-12-01 | 2020-04-28 | 苏州福瑞斯德新材料科技有限公司 | Anti-rust oil without containing heavy metal |
| CN114317080A (en) * | 2021-12-29 | 2022-04-12 | 安美科技股份有限公司 | Ultra-precise machine tool spindle oil and preparation method thereof |
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