CN105038926A - Pure cation strip steel cold rolling oil - Google Patents
Pure cation strip steel cold rolling oil Download PDFInfo
- Publication number
- CN105038926A CN105038926A CN201510386111.5A CN201510386111A CN105038926A CN 105038926 A CN105038926 A CN 105038926A CN 201510386111 A CN201510386111 A CN 201510386111A CN 105038926 A CN105038926 A CN 105038926A
- Authority
- CN
- China
- Prior art keywords
- steel cold
- lubricating oil
- rolled lubricating
- oil
- pure cationic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 39
- 239000010959 steel Substances 0.000 title claims abstract description 39
- 239000010731 rolling oil Substances 0.000 title abstract description 14
- 238000005097 cold rolling Methods 0.000 title abstract description 12
- 150000001768 cations Chemical class 0.000 title abstract description 5
- 239000003921 oil Substances 0.000 claims abstract description 24
- 150000002148 esters Chemical class 0.000 claims abstract description 12
- 238000004140 cleaning Methods 0.000 claims abstract description 11
- 239000007866 anti-wear additive Substances 0.000 claims abstract description 9
- 235000019198 oils Nutrition 0.000 claims description 23
- -1 imidazoline quaternary ammonium salt Chemical class 0.000 claims description 19
- 239000010687 lubricating oil Substances 0.000 claims description 15
- 241000282326 Felis catus Species 0.000 claims description 10
- 150000001412 amines Chemical class 0.000 claims description 9
- 239000003795 chemical substances by application Substances 0.000 claims description 9
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 9
- 235000013311 vegetables Nutrition 0.000 claims description 9
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 8
- 229920000570 polyether Polymers 0.000 claims description 8
- 239000002253 acid Substances 0.000 claims description 7
- 239000000654 additive Substances 0.000 claims description 7
- 230000000996 additive effect Effects 0.000 claims description 7
- IPCSVZSSVZVIGE-UHFFFAOYSA-M hexadecanoate Chemical compound CCCCCCCCCCCCCCCC([O-])=O IPCSVZSSVZVIGE-UHFFFAOYSA-M 0.000 claims description 7
- 229940059574 pentaerithrityl Drugs 0.000 claims description 7
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 6
- 239000002202 Polyethylene glycol Substances 0.000 claims description 6
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims description 6
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 claims description 6
- 239000003112 inhibitor Substances 0.000 claims description 6
- 229940049964 oleate Drugs 0.000 claims description 6
- 230000003647 oxidation Effects 0.000 claims description 6
- 238000007254 oxidation reaction Methods 0.000 claims description 6
- 229920000728 polyester Polymers 0.000 claims description 6
- 229920001223 polyethylene glycol Polymers 0.000 claims description 6
- 150000008431 aliphatic amides Chemical class 0.000 claims description 5
- IZWSFJTYBVKZNK-UHFFFAOYSA-N lauryl sulfobetaine Chemical compound CCCCCCCCCCCC[N+](C)(C)CCCS([O-])(=O)=O IZWSFJTYBVKZNK-UHFFFAOYSA-N 0.000 claims description 5
- 241000722946 Acanthocybium solandri Species 0.000 claims description 4
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 claims description 4
- 238000006116 polymerization reaction Methods 0.000 claims description 4
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims description 3
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims description 3
- QIDCRGDFWRMBJC-UHFFFAOYSA-N 2-aminoethanol;boric acid Chemical compound NCCO.OB(O)O QIDCRGDFWRMBJC-UHFFFAOYSA-N 0.000 claims description 3
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims description 3
- MRBKEAMVRSLQPH-UHFFFAOYSA-N 3-tert-butyl-4-hydroxyanisole Chemical compound COC1=CC=C(O)C(C(C)(C)C)=C1 MRBKEAMVRSLQPH-UHFFFAOYSA-N 0.000 claims description 3
- RNMDNPCBIKJCQP-UHFFFAOYSA-N 5-nonyl-7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-ol Chemical compound C(CCCCCCCC)C1=C2C(=C(C=C1)O)O2 RNMDNPCBIKJCQP-UHFFFAOYSA-N 0.000 claims description 3
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 3
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims description 3
- 239000005642 Oleic acid Substances 0.000 claims description 3
- 235000019484 Rapeseed oil Nutrition 0.000 claims description 3
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims description 3
- BGNXCDMCOKJUMV-UHFFFAOYSA-N Tert-Butylhydroquinone Chemical compound CC(C)(C)C1=CC(O)=CC=C1O BGNXCDMCOKJUMV-UHFFFAOYSA-N 0.000 claims description 3
- 150000008052 alkyl sulfonates Chemical class 0.000 claims description 3
- 150000001408 amides Chemical class 0.000 claims description 3
- JBIROUFYLSSYDX-UHFFFAOYSA-M benzododecinium chloride Chemical compound [Cl-].CCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 JBIROUFYLSSYDX-UHFFFAOYSA-M 0.000 claims description 3
- 239000004327 boric acid Substances 0.000 claims description 3
- SXPWTBGAZSPLHA-UHFFFAOYSA-M cetalkonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 SXPWTBGAZSPLHA-UHFFFAOYSA-M 0.000 claims description 3
- 229960000228 cetalkonium chloride Drugs 0.000 claims description 3
- 235000011187 glycerol Nutrition 0.000 claims description 3
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 3
- 150000002632 lipids Chemical class 0.000 claims description 3
- 150000003014 phosphoric acid esters Chemical class 0.000 claims description 3
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 3
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 3
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 claims description 3
- 239000001294 propane Substances 0.000 claims description 3
- 210000000582 semen Anatomy 0.000 claims description 3
- 239000003549 soybean oil Substances 0.000 claims description 3
- 235000012424 soybean oil Nutrition 0.000 claims description 3
- SFVFIFLLYFPGHH-UHFFFAOYSA-M stearalkonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 SFVFIFLLYFPGHH-UHFFFAOYSA-M 0.000 claims description 3
- 238000005987 sulfurization reaction Methods 0.000 claims description 3
- 239000004250 tert-Butylhydroquinone Substances 0.000 claims description 3
- 235000019281 tert-butylhydroquinone Nutrition 0.000 claims description 3
- 125000002091 cationic group Chemical group 0.000 abstract description 2
- 230000001050 lubricating effect Effects 0.000 abstract description 2
- 239000003963 antioxidant agent Substances 0.000 abstract 1
- 230000003078 antioxidant effect Effects 0.000 abstract 1
- 235000006708 antioxidants Nutrition 0.000 abstract 1
- 239000013556 antirust agent Substances 0.000 abstract 1
- 239000012752 auxiliary agent Substances 0.000 abstract 1
- 239000010773 plant oil Substances 0.000 abstract 1
- 239000004094 surface-active agent Substances 0.000 abstract 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 8
- 239000000839 emulsion Substances 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 238000005096 rolling process Methods 0.000 description 6
- 239000002131 composite material Substances 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 3
- 238000002310 reflectometry Methods 0.000 description 3
- 239000013543 active substance Substances 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000005461 lubrication Methods 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910000746 Structural steel Inorganic materials 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000003749 cleanliness Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003974 emollient agent Substances 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 231100001261 hazardous Toxicity 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000001473 noxious effect Effects 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Landscapes
- Lubricants (AREA)
Abstract
The invention discloses pure cation strip steel cold rolling oil. The pure cation strip steel cold rolling oil is composed of a polymerized ester, a cationic surface active agent, an extreme pressure antiwear additive, a cleaning auxiliary agent, an antirust agent, an anti-oxidant, and plant oil. The pure cation strip steel cold rolling oil possesses excellent lubricating properties and cleaning properties, and is low in oil consumption.
Description
Technical field
The present invention relates to a kind of cold rolling of strip steel oil.
Background technology
Cold rolled strip is had many uses, as first-class in automobile making, electric equipment products, rolling stock, aviation, precision meter, food cans it be by carbon structural steel hot rolled strip, through the cold rolling steel plate made thickness and be less than 4mm further.In cold rolling of strip steel technological process, band steel self-deformation amount very large and also between roll and band steel severe friction produce amount of heat and iron powder, so must technological lubrication be adopted in cold rolling of strip steel process.Cold rolling of strip steel ROLLING OIL plays very important effect in cold-rolled process, strip and roll can be lubricated, reduce frictional force, prevent roll and band steel from boning because frictional force is excessive, simultaneously emulsion can also amount of heat with producing in the viscous deformation of tape transport steel and friction process, reduce roller surface temperature, improve roll working life, emulsion also has cleaning and rust inhibition concurrently in addition.
Current domestic cold rolling of strip steel operation ROLLING OIL used is mainly nonionic type ROLLING OIL and compound ROLLING OIL (positively charged ion and nonionic composite).The field maintemance of nonionic type ROLLING OIL is more convenient, and because nonionic emulsifying agent is not subject to other ion interference, emulsion granularity and stability well can maintain normal range, so the nonionic ROLLING OIL operation of rolling is more stable.But because it is poor to operation of rolling iron powder dispersive ability, easily cause a large amount of iron powder to assemble, cause on-the-spot emulsion oil slick too much, and then make to roll the residual iron rising of rear belt steel surface Residual oil, plate face reflectivity declines, thus in recent years nonionic ROLLING OIL gradually substitute by compound ROLLING OIL.The type ROLLING OIL to reduction oil consumption, improve pan cleanliness and really improve, but the index such as granularity, pH value, the stability fluctuation of emulsion is larger in actual application, field maintemance difficulty, often need the extra functional agent that adds to maintain emulsion performance in normal range, this has a strong impact on normal Rolling Production.This product is for Problems existing in current domestic nonionic and compound cold-rolled lubricating oil use procedure, and require feature according to Modern High-Speed heavy reduction rate cold-rolling process, by selecting high-performance aliphatic amine cats product, composite oilness and the fabulous synthetic ester, vegetables oil, extreme pressure anti-wear additives, dispersion agent, rust-preventive agent etc. of degradation property, obtain a kind of high-performance cationic-charge steel cold-rolled lubricating oil again.The cold rolling of strip steel oil working concentration adopted in the market is generally at 2-3%, and the oil consumption of ton steel is at 0.5 kg/tonne of steel, and more the liquid cycle is 6-12 month.This Project Product is because having excellent oilness and iron powder dispersiveness, so working concentration can be reduced to 1-2%, the oil consumption of ton steel can be reduced to below 0.2 kg/tonne of steel.
Summary of the invention
The object of the present invention is to provide the pure cationic-charge steel cold-rolled lubricating oil of a kind of high lubrication, high detergency and low oil consumption.
Technical solution of the present invention is:
A kind of pure cationic-charge steel cold-rolled lubricating oil, is characterized in that: be grouped into by the one-tenth of following weight percents:
Polyester ... .. ... .5 ~ 20%
Cats product ... .0.5 ~ 2%
Extreme pressure anti-wear additives ... .3 ~ 5%
Cleaning additive ... .1 ~ 2%
Rust-preventive agent ... .0.5 ~ 2%
Oxidation inhibitor ... .0.5 ~ 1%
Vegetables oil .... surplus.
Polyester is one or more in high molecular polymerization ester, tricarboxymethyl propane oleate, TriMethylolPropane(TMP) cetylate, TriMethylolPropane(TMP) cocinin, PETO, tetramethylolmethane cetylate, tetramethylolmethane cocinin.
Cats product is one or more in imidazoline quaternary ammonium salt, dodecyl sulfobetaine, coco amine Soxylat A 25-7, stearyl dimethyl benzyl ammonium chloride, cetalkonium chloride, dodecyl benzyl dimethyl ammonium chloride.
Extreme pressure anti-wear additives is one or more in ZDDP, olefine sulfide, sulfide aliphatic acid ester, sulfurized lard, sulfuration Oleum Gossypii semen, phosphoric acid ester.
Cleaning additive is one or more in polyoxyethylene polyoxypropylene block polyether, EO/PO aliphatic amide block polyether, aliphatic alcohol polyethenoxy (5-20) ether, polyoxyethylene nonylphenol ether, ox polyoxyethylenated alcohol, Si Ben-80, glycerin polyoxyethylene ether, polyethylene glycol (PEG) oleate.
Rust-preventive agent is one or more in lipid acid, alkenyl succinic acid ester, alkylsulfonate, amine, acid amides boric acid monoethanolamine, sulfonic acid ammonia salt, boric acid ester, oleic acid.
Oxidation inhibitor refers to one or more in 2,6 ditertiary butyl p cresol, butyl hydroxy anisol, tertiarybutylhydroquinone.
Vegetables oil is one or more in plam oil, rapeseed oil, soybean oil, Oleum Cocois.
Advantage of the present invention:
1. formula constituent selects vegetables oil and the synthetic ester of excellent lubricating properties, more composite special extreme pressure anti-wear additives, tackifier and tensio-active agent, obtains a kind of ROLLING OIL of oilness excellence.Test through laboratory four ball: PB value (four ball) >=2078N, PD value (four ball) >=9000N.
2. formula constituent adopts dodecyl sulfobetaine that is compatible good, that have special molecular structure and coco amine Soxylat A 25-7 (coco amine carbon chain lengths is the mixed amine that C12 and C14 forms according to specified proportion) is composite does cats product.The type cats product after composite has better emulsifying capacity, iron powder dispersive ability and cleansing power than commercially available common cationic tensio-active agent; In addition for improving product cleansing power, improve belt steel surface degree of cleaning, formula have employed novel cation EO/PO aliphatic amide block polyether and does main cleaning additive.Owing to have employed the cats product compounded technology of this uniqueness, this product is iron powder dispersive ability exceptional in actual use, and surperficial oil slick is easy to reemulsification through stirring and nozzle shearing, therefore very high with the belt steel surface reflectivity after this product rolling, consume very low.This product is through client's field experiment in month, and the plate face reflectivity under equal conditions after rolling is significantly promoted to 83% by original 62%, and the oil consumption of ton steel is also reduced to 0.19 kg/tonne of steel by original 0.54 kg/tonne of steel.
3. fill a prescription select biological degradability fabulous vegetables oil and synthetic ester do main emollient component, not containing hazardous and noxious substances such as mineral oil, heavy metal, aromatic hydrocarbon, BOD(biochemical oxygen demand (BOD))/COD(chemical oxygen demand (COD)) >=0.65, waste liquid can biochemical treatment ability strong, environmental pollution is little, friendly to human and environment.
Below in conjunction with embodiment, the invention will be further described.
Embodiment
Embodiment 1:
A kind of pure cationic-charge steel cold-rolled lubricating oil, is mixed together by the composition of following weight percents:
PETO 10%
High molecular polymerization ester (or tetramethylolmethane cetylate) 10%
Dodecyl sulfobetaine 1%
Coco amine Soxylat A 25-7 0.5%
Sulfide aliphatic acid ester 3%
ZDDP0.5%
EO/PO aliphatic amide block polyether 1%
Alkenyl succinic acid ester 0.5%
2,6 ditertiary butyl p cresol 0.5%
Plam oil 50%
Oleum Cocois 23%.
Embodiment 2:
A kind of pure cationic-charge steel cold-rolled lubricating oil, is grouped into by the one-tenth of following weight percents:
Polyester ... .5 ~ 20%(example 5%, 10%, 20%)
Cats product ... 0.5 ~ 2%(example 0.5%, 1%, 2%)
Extreme pressure anti-wear additives ... 3 ~ 5%(example 3%, 4%, 5%)
Cleaning additive ... .1 ~ 2%(example 1%, 1.5%, 2%)
Rust-preventive agent ... 0.5 ~ 2%(example 0.5%, 1%, 2%)
Oxidation inhibitor ... .0.5 ~ 1%(example 0.5%, 0.8%, 2%)
Vegetables oil .... surplus.
Polyester is one or more in high molecular polymerization ester, tricarboxymethyl propane oleate, TriMethylolPropane(TMP) cetylate, TriMethylolPropane(TMP) cocinin, PETO, tetramethylolmethane cetylate, tetramethylolmethane cocinin.
Cats product is one or more in imidazoline quaternary ammonium salt, dodecyl sulfobetaine, coco amine Soxylat A 25-7, stearyl dimethyl benzyl ammonium chloride, cetalkonium chloride, dodecyl benzyl dimethyl ammonium chloride.
Extreme pressure anti-wear additives is one or more in ZDDP, olefine sulfide, sulfide aliphatic acid ester, sulfurized lard, sulfuration Oleum Gossypii semen, phosphoric acid ester.
Cleaning additive is one or more in polyoxyethylene polyoxypropylene block polyether, EO/PO aliphatic amide block polyether, aliphatic alcohol polyethenoxy (5-20) ether, polyoxyethylene nonylphenol ether, ox polyoxyethylenated alcohol, Si Ben-80, glycerin polyoxyethylene ether, polyethylene glycol (PEG) oleate.
Rust-preventive agent is one or more in lipid acid, alkenyl succinic acid ester, alkylsulfonate, amine, acid amides boric acid monoethanolamine, sulfonic acid ammonia salt, boric acid ester, oleic acid.
Oxidation inhibitor refers to one or more in 2,6 ditertiary butyl p cresol, butyl hydroxy anisol, tertiarybutylhydroquinone.
Vegetables oil is one or more in plam oil, rapeseed oil, soybean oil, Oleum Cocois.
Claims (8)
1. a pure cationic-charge steel cold-rolled lubricating oil, is characterized in that: be grouped into by the one-tenth of following weight percents:
Polyester ... .. ... .5 ~ 20%
Cats product ... .0.5 ~ 2%
Extreme pressure anti-wear additives ... .3 ~ 5%
Cleaning additive ... .1 ~ 2%
Rust-preventive agent ... .0.5 ~ 2%
Oxidation inhibitor ... .0.5 ~ 1%
Vegetables oil .... surplus.
2. pure cationic-charge steel cold-rolled lubricating oil according to claim 1, is characterized in that: polyester is one or more in high molecular polymerization ester, tricarboxymethyl propane oleate, TriMethylolPropane(TMP) cetylate, TriMethylolPropane(TMP) cocinin, PETO, tetramethylolmethane cetylate, tetramethylolmethane cocinin.
3. pure cationic-charge steel cold-rolled lubricating oil according to claim 1, is characterized in that: cats product is one or more in imidazoline quaternary ammonium salt, dodecyl sulfobetaine, coco amine Soxylat A 25-7, stearyl dimethyl benzyl ammonium chloride, cetalkonium chloride, dodecyl benzyl dimethyl ammonium chloride.
4. pure cationic-charge steel cold-rolled lubricating oil according to claim 1, is characterized in that: extreme pressure anti-wear additives is one or more in ZDDP, olefine sulfide, sulfide aliphatic acid ester, sulfurized lard, sulfuration Oleum Gossypii semen, phosphoric acid ester.
5. pure cationic-charge steel cold-rolled lubricating oil according to claim 1, is characterized in that: cleaning additive is one or more in polyoxyethylene polyoxypropylene block polyether, EO/PO aliphatic amide block polyether, aliphatic alcohol polyethenoxy (5-20) ether, polyoxyethylene nonylphenol ether, ox polyoxyethylenated alcohol, Si Ben-80, glycerin polyoxyethylene ether, polyethylene glycol (PEG) oleate.
6. pure cationic-charge steel cold-rolled lubricating oil according to claim 1, is characterized in that: rust-preventive agent is one or more in lipid acid, alkenyl succinic acid ester, alkylsulfonate, amine, acid amides boric acid monoethanolamine, sulfonic acid ammonia salt, boric acid ester, oleic acid.
7. pure cationic-charge steel cold-rolled lubricating oil according to claim 1, is characterized in that: oxidation inhibitor refers to one or more in 2,6 ditertiary butyl p cresol, butyl hydroxy anisol, tertiarybutylhydroquinone.
8. pure cationic-charge steel cold-rolled lubricating oil according to claim 1, is characterized in that: vegetables oil is one or more in plam oil, rapeseed oil, soybean oil, Oleum Cocois.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510386111.5A CN105038926B (en) | 2015-07-03 | 2015-07-03 | Pure cation cold rolling of strip steel oil |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510386111.5A CN105038926B (en) | 2015-07-03 | 2015-07-03 | Pure cation cold rolling of strip steel oil |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105038926A true CN105038926A (en) | 2015-11-11 |
| CN105038926B CN105038926B (en) | 2017-07-18 |
Family
ID=54445902
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510386111.5A Active CN105038926B (en) | 2015-07-03 | 2015-07-03 | Pure cation cold rolling of strip steel oil |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105038926B (en) |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105624750A (en) * | 2016-03-28 | 2016-06-01 | 启东尤希路化学工业有限公司 | Defatting-free environment-friendly tin plate tempering lubricant |
| CN105733785A (en) * | 2016-04-19 | 2016-07-06 | 天津市金海利油脂有限公司 | Strip steel cold rolling emulsified oil containing boric acid ester and preparation method thereof |
| CN106566641A (en) * | 2016-10-28 | 2017-04-19 | 广东富行洗涤剂科技有限公司 | Totally-synthesized highlight waterborne cutting fluid |
| CN106833845A (en) * | 2017-01-23 | 2017-06-13 | 上海帕卡兴产化工有限公司 | A kind of tandem rolling silicon steel detergency ROLLING OIL high and preparation method thereof |
| CN106967488A (en) * | 2017-04-17 | 2017-07-21 | 奎克化学（中国）有限公司 | The metal rolled liquid and preparation method of a kind of acid and alkali-resistance |
| CN106987300A (en) * | 2017-04-17 | 2017-07-28 | 奎克化学（中国）有限公司 | It is a kind of non-maintaining to contain the metal rolled liquid of polymerizing cationically and preparation method |
| CN107090337A (en) * | 2017-05-08 | 2017-08-25 | 三河市炬峰生物能源有限公司 | A kind of biological ROLLING OIL and preparation method thereof |
| CN109321339A (en) * | 2018-11-14 | 2019-02-12 | 上海帕卡兴产化工有限公司 | A kind of acid-cleaning plate antirust oil and preparation method thereof |
| CN110144256A (en) * | 2018-02-11 | 2019-08-20 | 宝山钢铁股份有限公司 | A kind of the steel cold rolling ROLLING OIL and its application method of low peculiar smell |
| CN110317664A (en) * | 2018-03-29 | 2019-10-11 | 宝山钢铁股份有限公司 | A kind of cold rolling oil of the low peculiar smell of high-lubricity |
| CN110408456A (en) * | 2018-04-28 | 2019-11-05 | 宝山钢铁股份有限公司 | A kind of suitable single chassis reversable mill produces the cold rolling oil of high-strength steel product |
| CN114196466A (en) * | 2021-12-21 | 2022-03-18 | 安美科技股份有限公司 | New energy power battery shell drawing oil and preparation method thereof |
Citations (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02102297A (en) * | 1988-10-11 | 1990-04-13 | Yushiro Chem Ind Co Ltd | Cold rolling oil composition |
| CN1188793A (en) * | 1996-12-20 | 1998-07-29 | 花王株式会社 | Lubricating oil for water-dispersed cold rolling oil for steel and method for cold rolling steel sheet |
| JPH10298573A (en) * | 1997-05-01 | 1998-11-10 | Nippon Steel Corp | Cold roll oil composition |
| JP2000282078A (en) * | 1999-03-31 | 2000-10-10 | Sumitomo Metal Ind Ltd | Oil for cold rolling and cold rolling using the same |
| JP2004168844A (en) * | 2002-11-19 | 2004-06-17 | Nisshin Steel Co Ltd | Aqueous cold rolling oil composition |
| WO2009122875A1 (en) * | 2008-03-31 | 2009-10-08 | 出光興産株式会社 | Water-soluble metalworking lubricant |
| CN101724498A (en) * | 2009-10-23 | 2010-06-09 | 启东市合成化工厂有限公司 | Emulsified steel plate cold-rolling lubrication oil |
| JP2011132427A (en) * | 2009-12-25 | 2011-07-07 | Kyodo Yushi Co Ltd | Cold rolling oil composition for magnetic steel sheet, and rolling method |
| JP4829425B2 (en) * | 2000-07-10 | 2011-12-07 | ユシロ化学工業株式会社 | Water-soluble cold rolling oil for steel sheet |
| CN102803451A (en) * | 2009-06-16 | 2012-11-28 | 尤希路化学工业有限公司 | Metal rolling oil composition |
| CN103589491A (en) * | 2013-11-29 | 2014-02-19 | 广州机械科学研究院有限公司 | Lubricating material for cold rolling and its preparation method and use |
-
2015
- 2015-07-03 CN CN201510386111.5A patent/CN105038926B/en active Active
Patent Citations (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02102297A (en) * | 1988-10-11 | 1990-04-13 | Yushiro Chem Ind Co Ltd | Cold rolling oil composition |
| CN1188793A (en) * | 1996-12-20 | 1998-07-29 | 花王株式会社 | Lubricating oil for water-dispersed cold rolling oil for steel and method for cold rolling steel sheet |
| JPH10298573A (en) * | 1997-05-01 | 1998-11-10 | Nippon Steel Corp | Cold roll oil composition |
| JP2000282078A (en) * | 1999-03-31 | 2000-10-10 | Sumitomo Metal Ind Ltd | Oil for cold rolling and cold rolling using the same |
| JP4829425B2 (en) * | 2000-07-10 | 2011-12-07 | ユシロ化学工業株式会社 | Water-soluble cold rolling oil for steel sheet |
| JP2004168844A (en) * | 2002-11-19 | 2004-06-17 | Nisshin Steel Co Ltd | Aqueous cold rolling oil composition |
| WO2009122875A1 (en) * | 2008-03-31 | 2009-10-08 | 出光興産株式会社 | Water-soluble metalworking lubricant |
| CN102803451A (en) * | 2009-06-16 | 2012-11-28 | 尤希路化学工业有限公司 | Metal rolling oil composition |
| CN101724498A (en) * | 2009-10-23 | 2010-06-09 | 启东市合成化工厂有限公司 | Emulsified steel plate cold-rolling lubrication oil |
| JP2011132427A (en) * | 2009-12-25 | 2011-07-07 | Kyodo Yushi Co Ltd | Cold rolling oil composition for magnetic steel sheet, and rolling method |
| CN103589491A (en) * | 2013-11-29 | 2014-02-19 | 广州机械科学研究院有限公司 | Lubricating material for cold rolling and its preparation method and use |
Cited By (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105624750B (en) * | 2016-03-28 | 2017-12-12 | 启东尤希路化学工业有限公司 | Exempt from degreasing environment-friendly type tin plate leveling precision |
| CN105624750A (en) * | 2016-03-28 | 2016-06-01 | 启东尤希路化学工业有限公司 | Defatting-free environment-friendly tin plate tempering lubricant |
| CN105733785A (en) * | 2016-04-19 | 2016-07-06 | 天津市金海利油脂有限公司 | Strip steel cold rolling emulsified oil containing boric acid ester and preparation method thereof |
| CN106566641A (en) * | 2016-10-28 | 2017-04-19 | 广东富行洗涤剂科技有限公司 | Totally-synthesized highlight waterborne cutting fluid |
| CN106566641B (en) * | 2016-10-28 | 2019-07-02 | 广东富行洗涤剂科技有限公司 | A kind of fully synthetic highlight water-based cutting fluid |
| CN106833845A (en) * | 2017-01-23 | 2017-06-13 | 上海帕卡兴产化工有限公司 | A kind of tandem rolling silicon steel detergency ROLLING OIL high and preparation method thereof |
| CN106987300A (en) * | 2017-04-17 | 2017-07-28 | 奎克化学（中国）有限公司 | It is a kind of non-maintaining to contain the metal rolled liquid of polymerizing cationically and preparation method |
| CN106967488A (en) * | 2017-04-17 | 2017-07-21 | 奎克化学（中国）有限公司 | The metal rolled liquid and preparation method of a kind of acid and alkali-resistance |
| CN106987300B (en) * | 2017-04-17 | 2019-12-13 | 奎克化学（中国）有限公司 | Maintenance-free metal rolling liquid containing polymeric cations and preparation method thereof |
| CN107090337A (en) * | 2017-05-08 | 2017-08-25 | 三河市炬峰生物能源有限公司 | A kind of biological ROLLING OIL and preparation method thereof |
| CN107090337B (en) * | 2017-05-08 | 2020-06-09 | 三河市炬峰生物能源有限公司 | Biological rolling oil and preparation method thereof |
| CN110144256A (en) * | 2018-02-11 | 2019-08-20 | 宝山钢铁股份有限公司 | A kind of the steel cold rolling ROLLING OIL and its application method of low peculiar smell |
| CN110317664B (en) * | 2018-03-29 | 2022-03-18 | 宝山钢铁股份有限公司 | High-lubricity low-odor cold rolling oil |
| CN110317664A (en) * | 2018-03-29 | 2019-10-11 | 宝山钢铁股份有限公司 | A kind of cold rolling oil of the low peculiar smell of high-lubricity |
| CN110408456A (en) * | 2018-04-28 | 2019-11-05 | 宝山钢铁股份有限公司 | A kind of suitable single chassis reversable mill produces the cold rolling oil of high-strength steel product |
| CN109321339A (en) * | 2018-11-14 | 2019-02-12 | 上海帕卡兴产化工有限公司 | A kind of acid-cleaning plate antirust oil and preparation method thereof |
| CN114196466A (en) * | 2021-12-21 | 2022-03-18 | 安美科技股份有限公司 | New energy power battery shell drawing oil and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105038926B (en) | 2017-07-18 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105038926A (en) | Pure cation strip steel cold rolling oil | |
| CN102757848B (en) | Water-soluble rolling liquid composition and application thereof | |
| CN104164283B (en) | Micro emulsion metalworking fluid | |
| CN102746924B (en) | Aluminium hot-rolling oil | |
| CN100523154C (en) | Composition of cold rolling sheet rolling oil | |
| CN102839038B (en) | Additive composition for producing emulsified oil, preparation method of additive composition and application of additive composition | |
| CN102757852B (en) | Rolling lubricant composition and usage thereof | |
| CN101993770B (en) | Lubricating agent for high-speed wire drawing and preparation method thereof | |
| CN102807912A (en) | Micro-emulsified cutting fluid production additive package and preparation method and application thereof | |
| CN103666660A (en) | Automobile part drawing oil composition and use thereof | |
| CN106459823A (en) | Water-soluble metal working oil and coolant for metal working | |
| CN104450120A (en) | Semi-synthetic metal wire drawing lubricant liquid and preparation method thereof | |
| CN101613634B (en) | High-property water-based emulsion cutting fluid composite | |
| CN104073327A (en) | Emulsified cutting fluid, cutting diluent and preparation and application methods thereof | |
| CN108570341A (en) | A kind of belt steel rolling oil and its production method | |
| CN105733785A (en) | Strip steel cold rolling emulsified oil containing boric acid ester and preparation method thereof | |
| CN104312694A (en) | Compressor oil composition and preparation method thereof | |
| CN102776058B (en) | Aqueous lubricating liquid for stamping, stretching and forming cell phone battery shell, preparation method and application method thereof | |
| JP2014105252A (en) | Grease composition | |
| CN103242933A (en) | Synthesized metal cutting fluid taking poly-alpha olefin as base oil and preparation method thereof | |
| CN103351932A (en) | Transparent water-based cutting fluid and preparation method therefor | |
| CN103740455B (en) | Water base lubricant that a kind of zinc-coated wire is for drawing processing and preparation method thereof | |
| CN112625778B (en) | Special oil composition for 75W-90 viscosity grade urban rail gear box | |
| CN101955843B (en) | Emulsified cutting fluid complexing agent | |
| CN103725365A (en) | Water-based hydraulic fluid composition |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |