CN105038926B - Pure cation cold rolling of strip steel oil - Google Patents
Pure cation cold rolling of strip steel oil Download PDFInfo
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- CN105038926B CN105038926B CN201510386111.5A CN201510386111A CN105038926B CN 105038926 B CN105038926 B CN 105038926B CN 201510386111 A CN201510386111 A CN 201510386111A CN 105038926 B CN105038926 B CN 105038926B
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- oil
- cold rolling
- strip steel
- rolling
- cation
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- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 27
- 239000010959 steel Substances 0.000 title claims abstract description 27
- 238000005097 cold rolling Methods 0.000 title claims abstract description 17
- 150000001768 cations Chemical class 0.000 title abstract description 11
- 239000000203 mixture Substances 0.000 claims description 4
- 239000003921 oil Substances 0.000 abstract description 18
- 235000019198 oils Nutrition 0.000 abstract description 18
- 235000015112 vegetable and seed oil Nutrition 0.000 abstract description 8
- 239000008158 vegetable oil Substances 0.000 abstract description 8
- 239000000654 additive Substances 0.000 abstract description 7
- 230000000996 additive effect Effects 0.000 abstract description 7
- 239000007866 anti-wear additive Substances 0.000 abstract description 7
- 239000003093 cationic surfactant Substances 0.000 abstract description 7
- 238000004140 cleaning Methods 0.000 abstract description 7
- 239000013556 antirust agent Substances 0.000 abstract description 6
- 239000003963 antioxidant agent Substances 0.000 abstract description 5
- 230000003078 antioxidant effect Effects 0.000 abstract description 5
- 229920000728 polyester Polymers 0.000 abstract description 5
- 238000005461 lubrication Methods 0.000 abstract description 3
- 150000001412 amines Chemical class 0.000 description 11
- 150000002148 esters Chemical class 0.000 description 11
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 9
- 238000000034 method Methods 0.000 description 9
- 239000010731 rolling oil Substances 0.000 description 9
- -1 aliphatic amine cation Chemical class 0.000 description 8
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 6
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 6
- 229920000570 polyether Polymers 0.000 description 6
- 230000008569 process Effects 0.000 description 6
- 239000004721 Polyphenylene oxide Substances 0.000 description 5
- 239000002253 acid Substances 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- 239000000839 emulsion Substances 0.000 description 5
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 5
- 238000005096 rolling process Methods 0.000 description 5
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 4
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 4
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 4
- 239000005642 Oleic acid Substances 0.000 description 4
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 4
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 4
- IZWSFJTYBVKZNK-UHFFFAOYSA-N lauryl sulfobetaine Chemical compound CCCCCCCCCCCC[N+](C)(C)CCCS([O-])(=O)=O IZWSFJTYBVKZNK-UHFFFAOYSA-N 0.000 description 4
- 241000722946 Acanthocybium solandri Species 0.000 description 3
- 101000823778 Homo sapiens Y-box-binding protein 2 Proteins 0.000 description 3
- 235000019482 Palm oil Nutrition 0.000 description 3
- 239000003240 coconut oil Substances 0.000 description 3
- 235000019864 coconut oil Nutrition 0.000 description 3
- 238000013329 compounding Methods 0.000 description 3
- IPCSVZSSVZVIGE-UHFFFAOYSA-M hexadecanoate Chemical compound CCCCCCCCCCCCCCCC([O-])=O IPCSVZSSVZVIGE-UHFFFAOYSA-M 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000002540 palm oil Substances 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- 238000002310 reflectometry Methods 0.000 description 3
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 2
- LYHRWZZRJPWGCP-UHFFFAOYSA-N 2-ethyl-2-(hydroxymethyl)propane-1,3-diol;hexadecanoic acid Chemical compound CCC(CO)(CO)CO.CCCCCCCCCCCCCCCC(O)=O LYHRWZZRJPWGCP-UHFFFAOYSA-N 0.000 description 2
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- 235000019484 Rapeseed oil Nutrition 0.000 description 2
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 2
- BGNXCDMCOKJUMV-UHFFFAOYSA-N Tert-Butylhydroquinone Chemical compound CC(C)(C)C1=CC(O)=CC=C1O BGNXCDMCOKJUMV-UHFFFAOYSA-N 0.000 description 2
- GTTSNKDQDACYLV-UHFFFAOYSA-N Trihydroxybutane Chemical compound CCCC(O)(O)O GTTSNKDQDACYLV-UHFFFAOYSA-N 0.000 description 2
- 230000003213 activating effect Effects 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 150000008052 alkyl sulfonates Chemical class 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- JBIROUFYLSSYDX-UHFFFAOYSA-M benzododecinium chloride Chemical compound [Cl-].CCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 JBIROUFYLSSYDX-UHFFFAOYSA-M 0.000 description 2
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 2
- 239000004327 boric acid Substances 0.000 description 2
- SXPWTBGAZSPLHA-UHFFFAOYSA-M cetalkonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 SXPWTBGAZSPLHA-UHFFFAOYSA-M 0.000 description 2
- 229960000228 cetalkonium chloride Drugs 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 235000012343 cottonseed oil Nutrition 0.000 description 2
- 239000002385 cottonseed oil Substances 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 238000012423 maintenance Methods 0.000 description 2
- 229940049964 oleate Drugs 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 229920000056 polyoxyethylene ether Polymers 0.000 description 2
- 229940051841 polyoxyethylene ether Drugs 0.000 description 2
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 2
- 239000001294 propane Substances 0.000 description 2
- 239000003549 soybean oil Substances 0.000 description 2
- 235000012424 soybean oil Nutrition 0.000 description 2
- 238000005987 sulfurization reaction Methods 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 239000004250 tert-Butylhydroquinone Substances 0.000 description 2
- 235000019281 tert-butylhydroquinone Nutrition 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910000746 Structural steel Inorganic materials 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 210000000481 breast Anatomy 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 230000003749 cleanliness Effects 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000003974 emollient agent Substances 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 230000001050 lubricating effect Effects 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 239000012875 nonionic emulsifier Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 235000013324 preserved food Nutrition 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Abstract
The invention discloses a kind of pure cation cold rolling of strip steel oil, it is made up of polyester, cationic surfactant, extreme pressure anti-wear additives, cleaning additive, antirust agent, antioxidant, vegetable oil.The present invention has the characteristics of high lubrication, high detergency and low oil consumption.
Description
Technical field
The present invention relates to a kind of cold rolling of strip steel oil.
Background technology
Cold-strip steel has many uses, such as automobile making, electric equipment products, rolling stock, aviation, precision instrument, canned food
It is, by carbon structural steel hot rolled strip, the steel plate that thickness is less than 4mm to be made by further cold rolling Deng it.In cold rolling of strip steel
In technical process, strip self-deformation amount is very big and severe friction produces amount of heat and iron powder between roll and strip,
So technological lubrication must be used during cold rolling of strip steel.Cold rolling of strip steel ROLLING OIL plays very important work in cold-rolled process
With, can lube plate band and roll, reduce frictional force, prevent that roll and strip from bonding because frictional force is excessive, while emulsion
The amount of heat produced in strip plastic deformation and friction process can also be taken away, roller surface temperature is reduced, improving roll makes
With the life-span, emulsion also has cleaning and anti-rust action concurrently in addition.
ROLLING OIL used by country's cold rolling of strip steel process is mainly nonionic type ROLLING OIL and compound ROLLING OIL at present（Sun
Ion and nonionic compounding）.Nonionic type ROLLING OIL on-site maintenance is more convenient, because nonionic emulsifier is difficult by other
Ion interference, emulsion granularity and stability can maintain normal range (NR) well, so nonionic ROLLING OIL was rolled
Journey is more stable.But because it is poor to operation of rolling iron powder dispersibility, easily cause a large amount of iron powders to be assembled, cause live breast
Change liquid oil slick excessive, and then make it that rolling the residual iron of rear belt steel surface Residual oil rises, plate face reflectivity declines, so nonionic in recent years
ROLLING OIL is gradually substituted by compound ROLLING OIL.The type ROLLING OIL has one really to reduction oil consumption, improvement pan cleanliness
It is fixed to improve, but the fluctuation of the index such as the granularity of emulsion, pH value, stability is larger in actual application, and on-site maintenance is stranded
Hardly possible is, it is necessary to which often extra add function additive to maintain emulsion performance in normal range (NR), and this has a strong impact on normal Rolling Production.
The problem of this product during domestic nonionic and compound cold-rolled lubricating oil use at present for existing, and according to the big pressure of Modern High-Speed
Lower rate cold-rolling process requires feature, by selecting high-performance aliphatic amine cation surfactant, then compounds lubricity and degraded
Property fabulous synthetic ester, vegetable oil, extreme pressure anti-wear additives, dispersant, antirust agent etc., obtain a kind of high-performance cation cold rolling of strip steel
Oil.The oily concentration of cold rolling of strip steel used in the market is general in 2-3%, and the oil consumption of ton steel is in 0.5 kg/tonne of steel, more liquid week
Phase is 6-12 months.This Project Product is because with excellent lubricity and iron powder dispersiveness, so concentration can be reduced to
1-2%, ton steel oil consumption can be reduced to below 0.2 kg/tonne of steel.
The content of the invention
It is an object of the invention to provide a kind of high lubrication, high detergency and the pure cation cold rolling of strip steel of low oil consumption
Oil.
The present invention technical solution be：
A kind of pure cation cold rolling of strip steel oil, it is characterized in that：It is made up of the composition of following weight percents：
Polyester ... ... ... ... ... .. ... ... .5~20%
Cationic surfactant ... ... ... ... ... .0.5~2%
Extreme pressure anti-wear additives ... ... ... ... ... ... .3~5%
Cleaning additive ... ... ... ... ... ... ... .1~2%
Antirust agent ... ... ... ... ... ... ... .0.5~2%
Antioxidant ... ... ... ... ... ... ... .0.5~1%
Vegetable oil ... ... ... ... ... ... ... surpluses.
Polyester is high molecular polymerization ester, tricarboxymethyl propane oleate, trimethylolpropane palmitate, trihydroxy methyl
Propane cocinin, PETO, pentaerythrite palmitate, one kind in pentaerythrite cocinin or several
Kind.
Cationic surfactant is imidazoline quaternary ammonium salt, dodecyl sulfobetaine, coco amine APEO, ten
In eight zephirans, cetalkonium chloride, dodecyl benzyl dimethyl ammonium chloride
It is one or more of.
During extreme pressure anti-wear additives are ZDDP, olefine sulfide, sulfide aliphatic acid ester, sulfurized lard, sulfuration cottonseed oil, phosphate
It is one or more of.
Cleaning additive is polyoxyethylene polyoxypropylene block polyether, EO/PO fatty amines block polyether, aliphatic alcohol polyethenoxy
（5-20）Ether, NPE, ox alcohol APEO, Si Ben -80, glycerin polyoxyethylene ether, polyethylene glycol oleic acid
One or more in ester.
Antirust agent be aliphatic acid, alkenyl succinic acid ester, alkylsulfonate, amine, acid amides boric acid MEA, sulfonic acid ammonia salt,
One or more in borate, oleic acid.
Antioxidant refers to one in DBPC 2,6 ditertiary butyl p cresol, butylated hydroxyarisol, tert-butylhydroquinone
Plant or several.
Vegetable oil is the one or more in palm oil, rapeseed oil, soybean oil, coconut oil.
Advantages of the present invention：
1. formula constituent selects the vegetable oil and synthetic ester of excellent lubricating properties, then compounds special extreme pressure anti-wear additives, increasing
Stick and surfactant, obtain a kind of excellent ROLLING OIL of lubricity.Tested through laboratory four ball method：PB values（Four ball method）
>=2078N, PD value（Four ball method）≥9000N.
2. formula constituent is using compatible good, dodecyl sulfobetaine and cocounut oil with special molecular structure
Amine APEO (coco amine carbon chain lengths are the mixed amine that C12 and C14 is constituted according to special ratios) compounding does cation form
Face activating agent.The type cationic surfactant after compounding has more preferable emulsification than commercially available common cationic surfactant
Ability, iron powder dispersibility and cleansing power；In addition to improve product cleansing power, improve belt steel surface cleannes, formula is adopted
Main cleaning additive is done with novel cation EO/PO fatty amine block polyethers.As a result of this unique cation form
Face activating agent compounded technology, product iron powder dispersibility exceptional, and surface oil slick process in actual use
Stirring and nozzle shearing are easy to emulsify again, therefore very high with the belt steel surface reflectivity after product rolling, consume very low.
The plate face reflectivity that the product passes through after being rolled under client's field experiment in one month, equal conditions is substantially improved by original 62%
To 83%, and the oil consumption of ton steel is also reduced to 0.19 kg/tonne of steel by 0.54 kg/tonne of original steel.
3. formula does main emollient component from the fabulous vegetable oil of biological degradability and synthetic ester, without mineral oil, again
The poisonous and harmful substances such as metal, aromatic hydrocarbon, BOD（Biochemical oxygen demand (BOD)）/COD（COD）>=0.65, the biochemical place of waste liquid
Reason ability is strong, and environmental pollution is small, friendly to human and environment.
With reference to embodiment, the invention will be further described.
Embodiment
Embodiment 1：
A kind of pure cation cold rolling of strip steel oil, is mixed together by the composition of following weight percents：
PETO 10%
High molecular polymerization ester（Or pentaerythrite palmitate） 10%
Dodecyl sulfobetaine 1%
Coco amine APEO 0.5%
Sulfide aliphatic acid ester 3%
ZDDP 0.5%
EO/PO fatty amines block polyether 1%
Alkenyl succinic acid ester 0.5%
DBPC 2,6 ditertiary butyl p cresol 0.5%
Palm oil 50%
Coconut oil 23%.
Embodiment 2：
A kind of pure cation cold rolling of strip steel oil, is made up of the composition of following weight percents：
Polyester ... ... ... ... ... 5~20%（Example 5%, 10%, 20%）
Cationic surfactant ... ... 0.5~2%（Example 0.5%, 1%, 2%）
Extreme pressure anti-wear additives ... ... ... ... 3~5%（Example 3%, 4%, 5%）
Cleaning additive ... ... ... ... 1~2%（Example 1%, 1.5%, 2%）
Antirust agent ... ... ... ... ... 0.5~2%（Example 0.5%, 1%, 2%）
Antioxidant ... ... ... ... ... 0.5~1%（Example 0.5%, 0.8%, 2%）
Vegetable oil ... ... ... ... ... surplus.
Polyester is high molecular polymerization ester, tricarboxymethyl propane oleate, trimethylolpropane palmitate, trihydroxy methyl
Propane cocinin, PETO, pentaerythrite palmitate, one kind in pentaerythrite cocinin or several
Kind.
Cationic surfactant is imidazoline quaternary ammonium salt, dodecyl sulfobetaine, coco amine APEO, ten
In eight zephirans, cetalkonium chloride, dodecyl benzyl dimethyl ammonium chloride
It is one or more of.
During extreme pressure anti-wear additives are ZDDP, olefine sulfide, sulfide aliphatic acid ester, sulfurized lard, sulfuration cottonseed oil, phosphate
It is one or more of.
Cleaning additive is polyoxyethylene polyoxypropylene block polyether, EO/PO fatty amines block polyether, aliphatic alcohol polyethenoxy
（5-20）Ether, NPE, ox alcohol APEO, Si Ben -80, glycerin polyoxyethylene ether, polyethylene glycol oleic acid
One or more in ester.
Antirust agent be aliphatic acid, alkenyl succinic acid ester, alkylsulfonate, amine, acid amides boric acid MEA, sulfonic acid ammonia salt,
One or more in borate, oleic acid.
Antioxidant refers to one in DBPC 2,6 ditertiary butyl p cresol, butylated hydroxyarisol, tert-butylhydroquinone
Plant or several.
Vegetable oil is the one or more in palm oil, rapeseed oil, soybean oil, coconut oil.
Claims (1)
1. a kind of cold rolling of strip steel oil, it is characterized in that：It is made up of the composition of following weight percents：
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| CN201510386111.5A CN105038926B (en) | 2015-07-03 | 2015-07-03 | Pure cation cold rolling of strip steel oil |
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|---|---|---|---|
| CN201510386111.5A CN105038926B (en) | 2015-07-03 | 2015-07-03 | Pure cation cold rolling of strip steel oil |
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| CN105038926A CN105038926A (en) | 2015-11-11 |
| CN105038926B true CN105038926B (en) | 2017-07-18 |
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| WO2009122875A1 (en) * | 2008-03-31 | 2009-10-08 | 出光興産株式会社 | Water-soluble metalworking lubricant |
| CN102803451A (en) * | 2009-06-16 | 2012-11-28 | 尤希路化学工业有限公司 | Metal rolling oil composition |
| CN101724498A (en) * | 2009-10-23 | 2010-06-09 | 启东市合成化工厂有限公司 | Emulsified steel plate cold-rolling lubrication oil |
| JP2011132427A (en) * | 2009-12-25 | 2011-07-07 | Kyodo Yushi Co Ltd | Cold rolling oil composition for magnetic steel sheet, and rolling method |
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