CN109321339A - A kind of acid-cleaning plate antirust oil and preparation method thereof - Google Patents
A kind of acid-cleaning plate antirust oil and preparation method thereof Download PDFInfo
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- CN109321339A CN109321339A CN201811349697.8A CN201811349697A CN109321339A CN 109321339 A CN109321339 A CN 109321339A CN 201811349697 A CN201811349697 A CN 201811349697A CN 109321339 A CN109321339 A CN 109321339A
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/282—Esters of (cyclo)aliphatic oolycarboxylic acids
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/30—Anti-misting
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- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
Abstract
The present invention is suitable for antirust oil technical field, provides a kind of acid-cleaning plate antirust oil and preparation method thereof, wherein the acid-cleaning plate antirust oil includes the raw material of following parts by weight: 2-8 parts of octadecylamine ethylene oxide object；6-12 parts of oleyl amine；2-8 parts of methyl esters barium salt of petroleum oxidate chloroflo；1-4 parts of hexadecylene base succinate；0.2-0.8 parts of antioxidant；70-90 parts of hydrorefined mineral oils；Gained acid-cleaning plate antirust oil is adsorbed on surface of steel plate and forms oil film, and oil film adhesion is strong, high rust resistance, while having certain water-soluble cleaning action, and easy cleaning removal, significant increase aluminium processing enterprise product quality reduces production cost.In addition, meeting the latter year non-corrosive of pickled plate oiling, it is better than aqueous rustproof product.Placement 30h non-corrosive under the salt mist environment of 5% concentration sodium chloride is tested under laboratory, places non-corrosive for 24 hours under 40 DEG C of temperature, the hydrochloric acid mist environment that pH is 1.0.
Description
Technical field
The invention belongs to antirust oil technical fields more particularly to a kind of acid-cleaning plate antirust oil and preparation method thereof.
Background technique
Acid-cleaning plate be using high-quality hot rolled sheet as raw material, through pickling unit remove oxide layer, trimming, after finishing, surface matter
The intermediate products of amount and requirement (mainly cold roll forming or punching performance) between hot rolled plate and cold-reduced sheet, are parts
Hot rolled plate and the ideal substitute products of cold-reduced sheet, there is good market development prospect.
However, the corrosion of acid-cleaning plate in process is the problem always existed, the reason is that pickling lines have greatly
The acid mist HCl of amount, while including SO2, nitrogen oxide, the deep-etchings gas and various dust etc. such as carbon dioxide, for wanting
Antirust period longer steel plate is asked to put forward higher requirements, common monofilm protection is unable to reach requirement.Currently, for prevention and treatment pickling
It between the process of plate and seals corrosion up for safekeeping for a long time to mostly use antirust oil, reduce loss, although antirust oil tech in the prior art
Relative maturity, but still there are it is against corrosion ineffective, cleaning performance is unstable, unfriendly to environment the problems such as, caused to enterprise
Very big economic loss.
Summary of the invention
The embodiment of the present invention provides a kind of acid-cleaning plate antirust oil, it is intended to solve above-mentioned technical problem.
The embodiments of the present invention are implemented as follows, a kind of acid-cleaning plate antirust oil, the raw material including following parts by weight:
2-8 parts of octadecylamine ethylene oxide object；
6-12 parts of oleyl amine；
2-8 parts of methyl esters barium salt of petroleum oxidate chloroflo；
1-4 parts of hexadecylene base succinate；
0.2-0.8 parts of antioxidant；
70-90 parts of hydrorefined mineral oils.
The embodiment of the present invention also provides a kind of preparation method of acid-cleaning plate antirust oil, which comprises
By octadecylamine ethylene oxide object, oleyl amine, petroleum oxidate chloroflo methyl esters barium salt, hexadecylene base succinate, antioxidant and
Hydrorefined mineral oils weigh according to quantity, spare；
The octadecylamine ethylene oxide object, oleyl amine are mixed in proportion, the first mixed liquor is obtained, it is spare；
After the hydrorefined mineral oils and hexadecylene base succinate stirring 20-30min, described the is added while stirring
One mixed liquor, and it is to slowly warm up to 120-150 DEG C, obtain the second mixed liquor；
After second mixed liquor is stirred to react 1-2h, slow cooling sequentially adds petroleum oxidate chloroflo methyl esters to 50-70 DEG C
Barium salt, antioxidant, continue stir 30-50min to get.
In the embodiment of the present invention, pass through octadecylamine ethylene oxide object, oleyl amine, petroleum oxidate chloroflo methyl esters barium salt, hexadecylene
The mutual cooperation of base succinate, antioxidant and hydrorefined mineral oils, gained acid-cleaning plate antirust oil, is adsorbed on surface of steel plate
Oil film is formed, oil film adhesion is strong, high rust resistance, while having certain water-soluble cleaning action, easy cleaning removal, greatly
Aluminium processing enterprise product quality is promoted, production cost is reduced.In addition, meeting the latter year non-corrosive of pickled plate oiling, it is better than water
Base antirust product.Placement 30h non-corrosive under the salt mist environment of 5% concentration sodium chloride is tested under laboratory, is in 40 DEG C of temperature, pH
Non-corrosive for 24 hours is placed under 1.0 hydrochloric acid mist environment.
Specific embodiment
In order to make the objectives, technical solutions, and advantages of the present invention clearer, below in conjunction with specific embodiment, to this
Invention is further elaborated.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, not
For limiting the present invention.
In embodiments of the present invention, rust-inhibiting additive selects the octadecylamine ethylene oxide object that there is excellent acid to neutralize performance
It is compounded with oleyl amine, wherein octadecylamine ethylene oxide object is the polymer of octadecylamine and ethylene oxide, and ethylene oxide number is
1-15.
In embodiments of the present invention, the weight ratio of octadecylamine ethylene oxide object and oleyl amine is preferred are as follows: 5:9 ~ 10.
In embodiments of the present invention, combined oxidation petroleum chloroflo methyl esters barium salt, it is advantageous to enhance oil film adhesion, in acid mist ring
Chloride ion is captured under border, the chloride ion of surface of steel plate is replaced and is neutralized, synergy is got, further increases the antirust of acidic fog resistance
Property.
In embodiments of the present invention, hydrorefined mineral oils (40 DEG C of viscosity are 5-68mm2/s) is added, is not easy in air
Oxidation, properties of product are stablized, are conducive to product and store for a long time, and oiling surface of steel plate oil film performance is stablized, and place 1 year non-corrosive；
Wherein, it is demonstrated experimentally that kinematic viscosity when by 40 DEG C of hydrorefined mineral oils is respectively 5mm2/s, 32mm2/s and 68mm2/
The weight ratio of s is preferably 4:2:1 compounding, gained antirust oil better effect.
In embodiments of the present invention, removal ability, the compound alkylamine addition with ethylene oxide are cleaned for road after raising
After agent, certain water-soluble cleaning action, easy cleaning removal will be got.
In embodiments of the present invention, one or more of antioxidant BHT, T501,264,626, it is demonstrated experimentally that nothing
It is combined by which kind of is chosen, it is little to antirust agent influential effect, it can be ignored.
In embodiments of the present invention, the hydrorefined mineral oils and hexadecylene base succinate are stirred into 20-30min
Afterwards, octadecylamine ethylene oxide object and oleyl amine compound are added while stirring, and is to slowly warm up to 120-150 DEG C, heating rate
Directly affect antirust agent effect, it is desirable that be heating rate be 1 ~ 2 DEG C/min；Similarly, subsequent rate of temperature fall be also 1 ~ 2 DEG C/
min。
In the embodiment of the present invention, by respectively by octadecylamine ethylene oxide object and oleyl amine and different motion viscosity plus
Hydrogen refined mineral oil compounded combination in proportion, in conjunction with special process, cooperation with petroleum oxidate chloroflo methyl esters barium salt, antioxidant,
Gained acid-cleaning plate antirust oil is adsorbed on surface of steel plate and forms oil film, and oil film adhesion is strong, high rust resistance, while having one
Fixed water-soluble cleaning action, easy cleaning removal, significant increase aluminium processing enterprise product quality reduce production cost.In addition, meeting
The latter year non-corrosive of pickled plate oiling is better than aqueous rustproof product.The salt mist environment of 5% concentration sodium chloride is tested under laboratory
Lower placement 30h non-corrosive places non-corrosive for 24 hours under 40 DEG C of temperature, the hydrochloric acid mist environment that pH is 1.0.
Embodiment 1
Acid-cleaning plate antirust oil, the raw material including following parts by weight: 2 parts of octadecylamine ethylene oxide object；6 parts of oleyl amine；Petroleum oxidate
2 parts of chloroflo methyl esters barium salt；1 part of hexadecylene base succinate；0.2 part of antioxidant；70 parts of hydrorefined mineral oils.
By octadecylamine ethylene oxide object, oleyl amine, petroleum oxidate chloroflo methyl esters barium salt, hexadecylene base succinate, antioxidant
And hydrorefined mineral oils weigh according to quantity, it is spare；The octadecylamine ethylene oxide object, oleyl amine are mixed in proportion, obtained
First mixed liquor, it is spare；After the hydrorefined mineral oils and hexadecylene base succinate stirring 20min, while stirring
First mixed liquor is added, and is to slowly warm up to 120 DEG C, heating rate is 1 DEG C/min, obtains the second mixed liquor；To described
After two mixed liquors are stirred to react 1h, for slow cooling to 50 DEG C, rate of temperature fall is 1 DEG C/min, sequentially adds petroleum oxidate chloroflo first
Ester barium salt, antioxidant, continue stir 30min to get.
Embodiment 2
Acid-cleaning plate antirust oil, the raw material including following parts by weight: 8 parts of octadecylamine ethylene oxide object；12 parts of oleyl amine；Petroleum oxidate
8 parts of chloroflo methyl esters barium salt；4 parts of hexadecylene base succinate；0.8 part of antioxidant；90 parts of hydrorefined mineral oils.
By octadecylamine ethylene oxide object, oleyl amine, petroleum oxidate chloroflo methyl esters barium salt, hexadecylene base succinate, antioxidant
And hydrorefined mineral oils weigh according to quantity, it is spare；The octadecylamine ethylene oxide object, oleyl amine are mixed in proportion, obtained
First mixed liquor, it is spare；After the hydrorefined mineral oils and hexadecylene base succinate stirring 30min, while stirring
First mixed liquor is added, and is to slowly warm up to 150 DEG C, heating rate is 2 DEG C/min, obtains the second mixed liquor；To described
After two mixed liquors are stirred to react 2h, for slow cooling to 70 DEG C, rate of temperature fall is 2 DEG C/min, sequentially adds petroleum oxidate chloroflo first
Ester barium salt, antioxidant, continue stir 50min to get.
Embodiment 3
Acid-cleaning plate antirust oil, the raw material including following parts by weight: 4 parts of octadecylamine ethylene oxide object；8 parts of oleyl amine；Petroleum oxidate
4 parts of chloroflo methyl esters barium salt；2 parts of hexadecylene base succinate；0.4 part of antioxidant；75 parts of hydrorefined mineral oils.
By octadecylamine ethylene oxide object, oleyl amine, petroleum oxidate chloroflo methyl esters barium salt, hexadecylene base succinate, antioxidant
And hydrorefined mineral oils weigh according to quantity, it is spare；The octadecylamine ethylene oxide object, oleyl amine are mixed in proportion, obtained
First mixed liquor, it is spare；After the hydrorefined mineral oils and hexadecylene base succinate stirring 25min, while stirring
First mixed liquor is added, and is to slowly warm up to 130 DEG C, heating rate is 1 DEG C/min, obtains the second mixed liquor；To described
After two mixed liquors are stirred to react 1.5h, for slow cooling to 55 DEG C, rate of temperature fall is 1 DEG C/min, sequentially adds petroleum oxidate chloroflo
Methyl esters barium salt, antioxidant, continue stir 35min to get.
Embodiment 4
Acid-cleaning plate antirust oil, the raw material including following parts by weight: 6 parts of octadecylamine ethylene oxide object；10 parts of oleyl amine；Petroleum oxidate
6 parts of chloroflo methyl esters barium salt；3 parts of hexadecylene base succinate；0.6 part of antioxidant；85 parts of hydrorefined mineral oils.
By octadecylamine ethylene oxide object, oleyl amine, petroleum oxidate chloroflo methyl esters barium salt, hexadecylene base succinate, antioxidant
And hydrorefined mineral oils weigh according to quantity, it is spare；The octadecylamine ethylene oxide object, oleyl amine are mixed in proportion, obtained
First mixed liquor, it is spare；After the hydrorefined mineral oils and hexadecylene base succinate stirring 30min, while stirring
First mixed liquor is added, and is to slowly warm up to 140 DEG C, heating rate is 2 DEG C/min, obtains the second mixed liquor；To described
After two mixed liquors are stirred to react 1-2h, for slow cooling to 65 DEG C, rate of temperature fall is 2 DEG C/min, sequentially adds petroleum oxidate chloroflo
Methyl esters barium salt, antioxidant, continue stir 45min to get.
Embodiment 5
Acid-cleaning plate antirust oil, the raw material including following parts by weight: 5 parts of octadecylamine ethylene oxide object；9 parts of oleyl amine；Petroleum oxidate
5 parts of chloroflo methyl esters barium salt；2.5 parts of hexadecylene base succinate；0.5 part of antioxidant；80 parts of hydrorefined mineral oils.
By octadecylamine ethylene oxide object, oleyl amine, petroleum oxidate chloroflo methyl esters barium salt, hexadecylene base succinate, antioxidant
And hydrorefined mineral oils weigh according to quantity, it is spare；The octadecylamine ethylene oxide object, oleyl amine are mixed in proportion, obtained
First mixed liquor, it is spare；After the hydrorefined mineral oils and hexadecylene base succinate stirring 25min, while stirring
First mixed liquor is added, and is to slowly warm up to 135 DEG C, heating rate is 1 DEG C/min, obtains the second mixed liquor；To described
After two mixed liquors are stirred to react 1.5h, for slow cooling to 60 DEG C, rate of temperature fall is 1 DEG C/min, sequentially adds petroleum oxidate chloroflo
Methyl esters barium salt, antioxidant, continue stir 40min to get.
Comparative example 1
Other than petroleum oxidate chloroflo methyl esters barium salt is replaced with petroleum oxidate chloroflo methyl esters calcium salt, remaining component and technique item
Part is consistent with embodiment 5.
Comparative example 2
In addition to being free of oleyl amine, and the parts by weight of oleyl amine are replaced outer, remaining component and technique item by octadecylamine ethylene oxide object
Part is consistent with embodiment 5.
Comparative example 3
Kinematic viscosity 32mm when using 40 DEG C entirely in addition to hydrorefined mineral oils2Outside/s, remaining component and process conditions are equal
It is consistent with embodiment 5.
By the acid-cleaning plate antirust oil performance prepared in embodiment 1-5 and comparative example 1-3 and its applied to the work of acid-cleaning plate
It is measured with effect, test result is as follows shown in table 1.
The performance measurement of 1 acid-cleaning plate antirust oil of table
To sum up, the performance test results of acid-cleaning plate cleaning rust-proof oil prepared by 1-5 according to embodiments of the present invention and comparative example 1-3
It is found that acid-cleaning plate antirust oil high rust resistance prepared by 1-5 of the embodiment of the present invention, the salt fog ring in 5% concentration sodium chloride
30h non-corrosive is placed under border, places non-corrosive for 24 hours under 40 DEG C of temperature, the hydrochloric acid mist environment that pH is 1.0；Meanwhile having one
Fixed water-soluble cleaning action, cleaning performance is excellent, and 100% cleaning degree, rustless property and cleaning performance effect are reached in 3min
It is substantially better than the impact of performance of comparative example 1-3.
It is worth noting that, big for hot rolling acid-cleaning steel plate surface roughness, environment is harsh when pickling produces, there are chlorine from
In son and acid atmosphere, the present invention by respectively by octadecylamine ethylene oxide object and oleyl amine and different motion viscosity plus hydrogen
Refined mineral oil compounded combination in proportion, in conjunction with special process, cooperation with petroleum oxidate chloroflo methyl esters barium salt, antioxidant, institute
Acid-cleaning plate antirust oil, be adsorbed on surface of steel plate and form oil film, with excellent antiacid mist performance and anti-chlorine ion rust-preventing characteristic and
Cleaning performance.In addition, according to embodiments of the present invention 5 and comparative example 1-3 is it is found that the embodiment of the present invention uses octadecylamine ethylene oxide
Object and oleyl amine compound and the hydrorefined mineral oils of different motion viscosity compounded combination in proportion plays centainly system
Synergistic effect is significant to the rustless property influence of gained acid-cleaning plate antirust oil.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all in essence of the invention
Made any modifications, equivalent replacements, and improvements etc., should all be included in the protection scope of the present invention within mind and principle.
Claims (10)
1. a kind of acid-cleaning plate antirust oil, which is characterized in that the raw material including following parts by weight:
2-8 parts of octadecylamine ethylene oxide object；
6-12 parts of oleyl amine；
2-8 parts of methyl esters barium salt of petroleum oxidate chloroflo；
1-4 parts of hexadecylene base succinate；
0.2-0.8 parts of antioxidant；
70-90 parts of hydrorefined mineral oils.
2. acid-cleaning plate antirust oil as described in claim 1, which is characterized in that the raw material including following parts by weight:
4-6 parts of octadecylamine ethylene oxide object；
8-10 parts of oleyl amine；
4-6 parts of methyl esters barium salt of petroleum oxidate chloroflo；
2-3 parts of hexadecylene base succinate；
0.4-0.6 parts of antioxidant；
75-85 parts of hydrorefined mineral oils.
3. acid-cleaning plate antirust oil as described in claim 1, which is characterized in that the raw material including following parts by weight:
5 parts of octadecylamine ethylene oxide object；
9 parts of oleyl amine；
5 parts of barium salt of petroleum oxidate chloroflo methyl esters；
2.5 parts of hexadecylene base succinate；
0.5 part of antioxidant；
80 parts of hydrorefined mineral oils.
4. acid-cleaning plate antirust oil as described in claim 1, which is characterized in that the weight of the octadecylamine ethylene oxide object and oleyl amine
Amount ratio are as follows: 5:9 ~ 10.
5. acid-cleaning plate antirust oil as described in claim 1, which is characterized in that the antioxidant is BHT, T501,264,626
One or more of.
6. acid-cleaning plate antirust oil as described in claim 1, which is characterized in that the hydrorefined mineral oils are by hydrofinishing mine
Kinematic viscosity at 40 DEG C of object oil is respectively 5mm2/s、32mm2/ s and 68mm2/ s mixing composition.
7. acid-cleaning plate antirust oil as claimed in claim 6, which is characterized in that movement at 40 DEG C of the hydrorefined mineral oils
Viscosity is respectively 5mm2/s、32mm2/ s and 68mm2The weight ratio of/s are as follows: 4:2:1.
8. a kind of preparation method of the acid-cleaning plate antirust oil as described in any one of claim 1-7 claim, which is characterized in that
The described method includes:
By octadecylamine ethylene oxide object, oleyl amine, petroleum oxidate chloroflo methyl esters barium salt, hexadecylene base succinate, antioxidant and
Hydrorefined mineral oils weigh according to quantity, spare；
The octadecylamine ethylene oxide object, oleyl amine are mixed in proportion, the first mixed liquor is obtained, it is spare；
After the hydrorefined mineral oils and hexadecylene base succinate stirring 20-30min, described the is added while stirring
One mixed liquor, and it is to slowly warm up to 120-150 DEG C, obtain the second mixed liquor；
After second mixed liquor is stirred to react 1-2h, slow cooling sequentially adds petroleum oxidate chloroflo methyl esters to 50-70 DEG C
Barium salt, antioxidant, continue stir 30-50min to get.
9. the preparation method of acid-cleaning plate antirust oil as claimed in claim 8, which is characterized in that the heating rate be 1 ~ 2 DEG C/
min。
10. the preparation method of acid-cleaning plate antirust oil as claimed in claim 8, which is characterized in that the rate of temperature fall is 1 ~ 2
℃/min。
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Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101016497A (en) * | 2007-03-05 | 2007-08-15 | 中国石油化工集团公司 | Electrostatic spraying antirust oil |
| CN101139540A (en) * | 2007-08-27 | 2008-03-12 | 吕秋玲 | Air accumulator seal oil modifier |
| US20120141681A1 (en) * | 2010-12-01 | 2012-06-07 | Empire Technology Development Llc | Compositions comprising reverse micelles and methods for their use |
| CN103087808A (en) * | 2012-10-12 | 2013-05-08 | 布兰诺工业包装材料(上海)有限公司 | Fast-drying hard film rust preventive oil and preparation method thereof |
| CN103450969A (en) * | 2012-05-30 | 2013-12-18 | 修建东 | Salt mist-resistant thin-layer soft film anti-rust oil composition |
| CN104263475A (en) * | 2014-09-12 | 2015-01-07 | 广州中机实业有限公司 | Environment-friendly electrostatic spraying antirust oil and preparation method thereof |
| CN104531299A (en) * | 2014-12-17 | 2015-04-22 | 江苏鑫露新材料股份有限公司 | High-efficiency and environment-friendly anti-rust oil for a long-acting iron casting |
| CN105038926A (en) * | 2015-07-03 | 2015-11-11 | 上海尤希路化学工业有限公司 | Pure cation strip steel cold rolling oil |
| CN107723695A (en) * | 2017-10-16 | 2018-02-23 | 辽宁科技大学 | A kind of hot rolling acid-cleaning steel plate water-based antirust and preparation method thereof |
| CN108641798A (en) * | 2018-03-30 | 2018-10-12 | 天长市润达金属防锈助剂有限公司 | A kind of environmental protection semi-synthetic metalworking fluid of high lubrication, Thief zone |
-
2018
- 2018-11-14 CN CN201811349697.8A patent/CN109321339A/en active Pending
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101016497A (en) * | 2007-03-05 | 2007-08-15 | 中国石油化工集团公司 | Electrostatic spraying antirust oil |
| CN101139540A (en) * | 2007-08-27 | 2008-03-12 | 吕秋玲 | Air accumulator seal oil modifier |
| US20120141681A1 (en) * | 2010-12-01 | 2012-06-07 | Empire Technology Development Llc | Compositions comprising reverse micelles and methods for their use |
| CN103450969A (en) * | 2012-05-30 | 2013-12-18 | 修建东 | Salt mist-resistant thin-layer soft film anti-rust oil composition |
| CN103087808A (en) * | 2012-10-12 | 2013-05-08 | 布兰诺工业包装材料(上海)有限公司 | Fast-drying hard film rust preventive oil and preparation method thereof |
| CN104263475A (en) * | 2014-09-12 | 2015-01-07 | 广州中机实业有限公司 | Environment-friendly electrostatic spraying antirust oil and preparation method thereof |
| CN104531299A (en) * | 2014-12-17 | 2015-04-22 | 江苏鑫露新材料股份有限公司 | High-efficiency and environment-friendly anti-rust oil for a long-acting iron casting |
| CN105038926A (en) * | 2015-07-03 | 2015-11-11 | 上海尤希路化学工业有限公司 | Pure cation strip steel cold rolling oil |
| CN107723695A (en) * | 2017-10-16 | 2018-02-23 | 辽宁科技大学 | A kind of hot rolling acid-cleaning steel plate water-based antirust and preparation method thereof |
| CN108641798A (en) * | 2018-03-30 | 2018-10-12 | 天长市润达金属防锈助剂有限公司 | A kind of environmental protection semi-synthetic metalworking fluid of high lubrication, Thief zone |
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