CN106756961A - A kind of environmentally-friendly water-based antirust solution and preparation method thereof - Google Patents
A kind of environmentally-friendly water-based antirust solution and preparation method thereof Download PDFInfo
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- CN106756961A CN106756961A CN201611173431.3A CN201611173431A CN106756961A CN 106756961 A CN106756961 A CN 106756961A CN 201611173431 A CN201611173431 A CN 201611173431A CN 106756961 A CN106756961 A CN 106756961A
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- defoamer
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/48—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 not containing phosphates, hexavalent chromium compounds, fluorides or complex fluorides, molybdates, tungstates, vanadates or oxalates
- C23C22/50—Treatment of iron or alloys based thereon
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- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
Abstract
The invention discloses a kind of environmentally-friendly water-based antirust solution and preparation method thereof, it is made up of following mass fraction formula components：14 16 parts of phytic acid, 10 12 parts of konjac glucomannan, 24 parts of alpha-glucose pentaacetate, 46 parts of carboxymethylcellulose calcium, 35 parts of sodium alginate, 46 parts of decanedioic acid, 68 parts of triethanolamine, 24 parts of corrosion inhibiter, 23 parts of defoamer, 57 parts of tartaric acid, 7 11 parts of zinc naphthenate, 24 parts of water-base fluorocarbon emulsion, 12 parts of antioxidant, 70 100 parts of deionized water, preparation method of the present invention is simple, favorable rust preventing effect, good antirust is capable of achieving when concentration is relatively low, it is nontoxic, to human body and environmentally friendly, can be applied to hot rolled steel plate, antirust under cold-rolled steel sheet ethyl HT300 cast iron hot and humid environments.
Description
Technical field
The present invention relates to field of metal surface treatment, in particular to a kind of environmentally-friendly water-based antirust solution and its preparation side
Method.
Background technology
2013, Chinese crude steel yield accounted for the 48.5% of global proportion up to 7.79 hundred million tons, but the annual steel corrosion of China
Scrap and there are about 10,000,000 tons, so it is just and its important to develop environmentally friendly, efficient steel rust prevention product.In numerous antirust products,
Aqueous protective fluids substitute the still advantage such as solvent naphtha with its asepsis environment-protecting, with aqueous solvent, receive significant attention.
Water-based antirust be with water as solvent, add various water soluble rust inhibitors, chelating agent, film forming agent, surfactant,
A kind of aqueous rustproof that metallic article chemistry or electrochemical corrosion can be suppressed of the configuration such as stabilizer, defoamer, bactericide
Product.Aqueous protective fluids, can be by multiple product according to use condition and the difference of function, such as low alveolitoid, normal temperature type, non-nitrous acid
Salt form, long-acting type etc..Had a wide range of applications in industries such as steel and iron industry, machinery manufacturing industry, precision parts.
The content of the invention
The invention provides a kind of environmentally-friendly water-based antirust solution and preparation method thereof, preparation method of the present invention is simple, antirust
Effect is good, and good antirust is capable of achieving when concentration is relatively low, nontoxic, to human body and environmentally friendly, can be applied to hot rolled steel plate, cold
Antirust under rolled steel plate ethyl HT300 cast iron hot and humid environments.
To achieve the above object, the present invention provides following technical scheme：
A kind of environmentally-friendly water-based antirust solution and preparation method thereof, is made up of following mass fraction formula components：Phytic acid 14-16
Part, konjac glucomannan 10-12 parts, alpha-glucose pentaacetate 2-4 parts, carboxymethylcellulose calcium 4-6 parts, sodium alginate 3-5 parts, decanedioic acid 4-
6 parts, triethanolamine 6-8 parts, corrosion inhibiter 2-4 parts, defoamer 2-3 parts, tartaric acid 5-7 parts, zinc naphthenate 7-11 parts, water-based fluorocarbon
Emulsion 2-4 parts, antioxidant 1-2 parts, deionized water 70-100 parts.
Further：It is made up of following mass fraction formula components：14 parts of phytic acid, 10 parts of konjac glucomannan, alpha-glucose pentaacetate 2
Part, 4 parts of carboxymethylcellulose calcium, 3 parts of sodium alginate, 4 parts of decanedioic acid, 6 parts of triethanolamine, 2 parts of corrosion inhibiter, 2 parts of defoamer, winestone
5 parts of acid, 7 parts of zinc naphthenate, 2 parts of water-base fluorocarbon emulsion, 1 part of antioxidant, 70 parts of deionized water.
Further：It is made up of following mass fraction formula components：15 parts of phytic acid, 11 parts of konjac glucomannan, alpha-glucose pentaacetate 3
Part, 5 parts of carboxymethylcellulose calcium, 4 parts of sodium alginate, 5 parts of decanedioic acid, 7 parts of triethanolamine, 3 parts of corrosion inhibiter, 2.5 parts of defoamer, wine
6 parts of stone acid, 9 parts of zinc naphthenate, 3 parts of water-base fluorocarbon emulsion, 1.5 parts of antioxidant, 85 parts of deionized water.
Further：It is made up of following mass fraction formula components：16 parts of phytic acid, 12 parts of konjac glucomannan, alpha-glucose pentaacetate 4
Part, 6 parts of carboxymethylcellulose calcium, 5 parts of sodium alginate, 6 parts of decanedioic acid, 8 parts of triethanolamine, 4 parts of corrosion inhibiter, 3 parts of defoamer, winestone
7 parts of acid, 11 parts of zinc naphthenate, 4 parts of water-base fluorocarbon emulsion, 2 parts of antioxidant, 100 parts of deionized water.
Further：Preparation method of the present invention has following steps：
Step one, phytic acid, konjac glucomannan, alpha-glucose pentaacetate, carboxymethylcellulose calcium, deionized water are mixed it is equal
It is even, obtain mixed solution；
Step 2, the mixed solution that step one is obtained is warming up to 40-50 DEG C, adds sodium alginate, decanedioic acid, three ethanol
Amine, tartaric acid, zinc naphthenate, water-base fluorocarbon emulsion, under the power of 400-1000W, ultrasonic 30-60min；
Step 3, it is continuously heating to 70-80 DEG C, adds corrosion inhibiter, defoamer, antioxidant, stir, obtains into
Product.
The beneficial effects of the invention are as follows：Preparation method of the present invention is simple, favorable rust preventing effect, is capable of achieving when concentration is relatively low good
Good antirust, it is nontoxic, to human body and environmentally friendly, can be applied to hot rolled steel plate, cold-rolled steel sheet ethyl HT300 cast irons hot and humid
Antirust under environment.
Specific embodiment
Below in conjunction with the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described,
Obviously, described embodiment is only a part of embodiment of the invention, rather than whole embodiments.Based in the present invention
Embodiment, the every other embodiment that those of ordinary skill in the art are obtained under the premise of creative work is not made, all
Belong to the scope of protection of the invention.
Embodiment one：
A kind of environmentally-friendly water-based antirust solution is made up of following mass fraction formula components：Phytic acid 14-16 parts, konjac glucomannan 10-
12 parts, alpha-glucose pentaacetate 2-4 parts, carboxymethylcellulose calcium 4-6 parts, sodium alginate 3-5 parts, decanedioic acid 4-6 parts, triethanolamine
6-8 parts, corrosion inhibiter 2-4 parts, defoamer 2-3 parts, tartaric acid 5-7 parts, zinc naphthenate 7-11 parts, water-base fluorocarbon emulsion 2-4 parts, it is anti-
Oxidant 1-2 parts, deionized water 70-100 parts.
Embodiment two：
A kind of environmentally-friendly water-based antirust solution is made up of following mass fraction formula components：14 parts of phytic acid, 10 parts of konjac glucomannan, Portugal
Grape sugar 2 parts of pentaacetate, 4 parts of carboxymethylcellulose calcium, 3 parts of sodium alginate, 4 parts of decanedioic acid, 6 parts of triethanolamine, 2 parts of corrosion inhibiter,
2 parts of defoamer, 5 parts of tartaric acid, 7 parts of zinc naphthenate, 2 parts of water-base fluorocarbon emulsion, 1 part of antioxidant, 70 parts of deionized water.
Embodiment three：
A kind of environmentally-friendly water-based antirust solution is made up of following mass fraction formula components：15 parts of phytic acid, 11 parts of konjac glucomannan, Portugal
Grape sugar 3 parts of pentaacetate, 5 parts of carboxymethylcellulose calcium, 4 parts of sodium alginate, 5 parts of decanedioic acid, 7 parts of triethanolamine, 3 parts of corrosion inhibiter,
2.5 parts of defoamer, 6 parts of tartaric acid, 9 parts of zinc naphthenate, 3 parts of water-base fluorocarbon emulsion, 1.5 parts of antioxidant, 85 parts of deionized water.
Example IV：
A kind of environmentally-friendly water-based antirust solution is made up of following mass fraction formula components：16 parts of phytic acid, 12 parts of konjac glucomannan, Portugal
Grape sugar 4 parts of pentaacetate, 6 parts of carboxymethylcellulose calcium, 5 parts of sodium alginate, 6 parts of decanedioic acid, 8 parts of triethanolamine, 4 parts of corrosion inhibiter,
3 parts of defoamer, 7 parts of tartaric acid, 11 parts of zinc naphthenate, 4 parts of water-base fluorocarbon emulsion, 2 parts of antioxidant, 100 parts of deionized water.
Embodiment five：
A kind of preparation method preparation method of environmentally-friendly water-based antirust solution comprises the following steps：
Step one, phytic acid, konjac glucomannan, alpha-glucose pentaacetate, carboxymethylcellulose calcium, deionized water are mixed it is equal
It is even, obtain mixed solution；
Step 2, the mixed solution that step one is obtained is warming up to 40-50 DEG C, adds sodium alginate, decanedioic acid, three ethanol
Amine, tartaric acid, zinc naphthenate, water-base fluorocarbon emulsion, under the power of 400-1000W, ultrasonic 30-60min；
Step 3, it is continuously heating to 70-80 DEG C, adds corrosion inhibiter, defoamer, antioxidant, stir, obtains into
Product.
Moreover, it will be appreciated that although the present specification is described in terms of embodiments, not each implementation method is only wrapped
Containing an independent technical scheme, this narrating mode of specification is only that for clarity, those skilled in the art should
Specification an as entirety, the technical scheme in each embodiment can also be formed into those skilled in the art through appropriately combined
May be appreciated other embodiment.
Claims (5)
1. a kind of environmentally-friendly water-based antirust solution, it is characterised in that：It is made up of following mass fraction formula components：
Phytic acid 14-16 parts, konjac glucomannan 10-12 parts, alpha-glucose pentaacetate 2-4 parts, carboxymethylcellulose calcium 4-6 parts, sodium alginate
3-5 parts, decanedioic acid 4-6 parts, triethanolamine 6-8 parts, corrosion inhibiter 2-4 parts, defoamer 2-3 parts, tartaric acid 5-7 parts, zinc naphthenate
7-11 parts, water-base fluorocarbon emulsion 2-4 parts, antioxidant 1-2 parts, deionized water 70-100 parts.
2. a kind of environmentally-friendly water-based antirust solution according to claim 1, it is characterised in that：It is formulated into by following mass fraction
It is grouped into：
14 parts of phytic acid, 10 parts of konjac glucomannan, 2 parts of alpha-glucose pentaacetate, 4 parts of carboxymethylcellulose calcium, 3 parts of sodium alginate, decanedioic acid 4
Part, 6 parts of triethanolamine, 2 parts of corrosion inhibiter, 2 parts of defoamer, 5 parts of tartaric acid, 7 parts of zinc naphthenate, 2 parts of water-base fluorocarbon emulsion, antioxygen
1 part of agent, 70 parts of deionized water.
3. a kind of environmentally-friendly water-based antirust solution according to claim 1, it is characterised in that：It is formulated into by following mass fraction
It is grouped into：
15 parts of phytic acid, 11 parts of konjac glucomannan, 3 parts of alpha-glucose pentaacetate, 5 parts of carboxymethylcellulose calcium, 4 parts of sodium alginate, decanedioic acid 5
It is part, 7 parts of triethanolamine, 3 parts of corrosion inhibiter, 2.5 parts of defoamer, 6 parts of tartaric acid, 9 parts of zinc naphthenate, 3 parts of water-base fluorocarbon emulsion, anti-
1.5 parts of oxidant, 85 parts of deionized water.
4. a kind of environmentally-friendly water-based antirust solution according to claim 1, it is characterised in that：It is formulated into by following mass fraction
It is grouped into：
16 parts of phytic acid, 12 parts of konjac glucomannan, 4 parts of alpha-glucose pentaacetate, 6 parts of carboxymethylcellulose calcium, 5 parts of sodium alginate, decanedioic acid 6
It is part, 8 parts of triethanolamine, 4 parts of corrosion inhibiter, 3 parts of defoamer, 7 parts of tartaric acid, 11 parts of zinc naphthenate, 4 parts of water-base fluorocarbon emulsion, anti-
2 parts of oxidant, 100 parts of deionized water.
5. a kind of a kind of preparation method of environmentally-friendly water-based antirust solution according to claim 1, it is characterised in that：Including such as
Lower step：
Step one, by phytic acid, konjac glucomannan, alpha-glucose pentaacetate, carboxymethylcellulose calcium, deionized water mixing and stirring, obtain
To mixed solution；
Step 2, the mixed solution that step one is obtained is warming up to 40-50 DEG C, add sodium alginate, decanedioic acid, triethanolamine,
Tartaric acid, zinc naphthenate, water-base fluorocarbon emulsion, under the power of 400-1000W, ultrasonic 30-60min；
Step 3, it is continuously heating to 70-80 DEG C, adds corrosion inhibiter, defoamer, antioxidant, stir, obtains finished product.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201611173431.3A CN106756961A (en) | 2016-12-19 | 2016-12-19 | A kind of environmentally-friendly water-based antirust solution and preparation method thereof |
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| CN201611173431.3A CN106756961A (en) | 2016-12-19 | 2016-12-19 | A kind of environmentally-friendly water-based antirust solution and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108048830A (en) * | 2017-12-22 | 2018-05-18 | 刘珍 | A kind of inactivating treatment liquid for being used to promote metal surface corrosion resistant characteristic |
| CN110923682A (en) * | 2019-12-20 | 2020-03-27 | 苏颖仪 | Surface rust-proof treatment process for mechanical parts |
Citations (4)
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|---|---|---|---|---|
| CN104357848A (en) * | 2014-11-14 | 2015-02-18 | 无锡伊佩克科技有限公司 | Environment-friendly steel surface anti-rust agent and preparation method thereof |
| CN105463469A (en) * | 2015-11-24 | 2016-04-06 | 苏州盖德精细材料有限公司 | Environment-friendly water-based antirust liquid formula and application thereof |
| CN105543851A (en) * | 2015-12-08 | 2016-05-04 | 佛山华清智业环保科技有限公司 | Eco-friendly antirust agent |
| CN105907196A (en) * | 2016-06-29 | 2016-08-31 | 沈敏华 | Water-based antirust agent |
-
2016
- 2016-12-19 CN CN201611173431.3A patent/CN106756961A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104357848A (en) * | 2014-11-14 | 2015-02-18 | 无锡伊佩克科技有限公司 | Environment-friendly steel surface anti-rust agent and preparation method thereof |
| CN105463469A (en) * | 2015-11-24 | 2016-04-06 | 苏州盖德精细材料有限公司 | Environment-friendly water-based antirust liquid formula and application thereof |
| CN105543851A (en) * | 2015-12-08 | 2016-05-04 | 佛山华清智业环保科技有限公司 | Eco-friendly antirust agent |
| CN105907196A (en) * | 2016-06-29 | 2016-08-31 | 沈敏华 | Water-based antirust agent |
Non-Patent Citations (2)
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| 张康夫等: "《防锈材料应用手册》", 30 June 2004, 化学工业出版社 * |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108048830A (en) * | 2017-12-22 | 2018-05-18 | 刘珍 | A kind of inactivating treatment liquid for being used to promote metal surface corrosion resistant characteristic |
| CN110923682A (en) * | 2019-12-20 | 2020-03-27 | 苏颖仪 | Surface rust-proof treatment process for mechanical parts |
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Application publication date: 20170531 |