CN102776058B - Aqueous lubricating liquid for stamping, stretching and forming cell phone battery shell, preparation method and application method thereof - Google Patents
Aqueous lubricating liquid for stamping, stretching and forming cell phone battery shell, preparation method and application method thereof Download PDFInfo
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- CN102776058B CN102776058B CN2012102585966A CN201210258596A CN102776058B CN 102776058 B CN102776058 B CN 102776058B CN 2012102585966 A CN2012102585966 A CN 2012102585966A CN 201210258596 A CN201210258596 A CN 201210258596A CN 102776058 B CN102776058 B CN 102776058B
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Abstract
The invention discloses aqueous lubricating liquid for stamping, stretching and forming a cell phone battery shell, a preparation method and an application method thereof. The lubricating liquid comprises the following raw materials: 45# transformer oil, a non-ionic emulsifying agent, aqueous extreme-pressure lubricant, boric acid, an aluminum powder sinking agent, triethanolamine, isopropanolamine, synthetic petroleum sodium sulfonate, a branched chain phosphate aluminum protecting agent, a dicarboxylate based composite anti-rust agent, a butyl ether coupling agent, a hard water resistant agent, a defoaming agent and distilled water; the lubricating liquid is excellent in lubricating performance, anti-rust performance and settling performance, and the lubricating performance, the anti-corrosion performance and the cleaning performance are matched and stabilized for a long time, the antibacterial performance is good and the service life is long, the working liquid can be circularly added, the emission of the waste liquid is reduced, the environment cannot be polluted, and all indexes of 5% of diluent reach or exceed relative indexes of GB6144-2010.
Description
Technical field
The present invention relates to a kind of metal working lubricant liquid, particularly a kind of water-based hand phone battery case punching stretch forming lubricating fluid, preparation method and using method that lubricated, cleaning, the effect such as cooling are provided man-hour that add for hand phone battery case.
Background technology
The aluminum hull of battery of mobile phone is that calendering, punching press, the stretching through the continuous several times core-pulling die forms by aluminium sheet, and in moulding process, because the modification amount of aluminium sheet is large, the heat of generation and aluminium powder are very many, cause the extreme temperatures on aluminum hull surface.This just requires lubricating oil for drawing and forming must have good cooling and lubricating and, to the settling property of aluminium powder, guarantees workpiece surface no marking mark and pull; And traditional lubricating fluid is all the oiliness drawing oil, although the oiliness drawing oil has good lubricity, cooling poor with settling property, aluminium powder is easily sneaked in drawing oil and is circulated together with drawing oil, oil darkening is dirty on the one hand, and job site is unclean, not environmental protection; Aluminium powder causes scratch to battery-shell surface on the other hand, white line and burr occur.Simultaneously, because the battery-shell surface temperature is high, the phenomenon of snap gauge, easily appear in oil product adhesion property step-down.In addition, the oil product that battery case is taken out of is more, causes serious waste, increases Financial cost.
Therefore, need a kind of water-based hand phone battery case punching stretch forming lubricating fluid, there is good cooling and lubricating, can solve effective settlement issues of aluminium powder in hand phone battery case punching stretch forming technique; Do not contain hazardous substance, can solve environmental protection and safety problem; Can solve mould because of excess Temperature, the impaired and snap gauge problem that occurs of oil-bound film.
Summary of the invention
In view of this, the object of the present invention is to provide a kind of water-based hand phone battery case punching stretch forming lubricating fluid, preparation method and using method, this lubricating fluid has good cooling and lubricating, solve effective settlement issues of aluminium powder in hand phone battery case punching stretch forming technique, guarantee workpiece surface no marking mark simultaneously and pull; In working fluid containing objectionable impuritiess such as nitrite, formaldehyde, operation site without disaster hidden-trouble, have no irritating odor, to skin toxicological harmless, non-stimulated, solve environmental protection and safety problem; Can solve mould because of excess Temperature, the impaired and snap gauge problem that occurs of oil-bound film; This lubricating fluid has excellent lubricity, rustless property and settling property, and lubricity, corrosion resistance and cleaning performance can mate for a long time and stablize, and long service life, can recycle, and reduced discharge, do not pollute the environment.
Water-based hand phone battery case punching stretch forming lubricating fluid of the present invention, the lubricating fluid raw material comprises following component by weight: No. 45 transformer oil of 15-50 part, 3-10 part nonionic emulsifying agent, 10-20 part water-based extreme pressure lubricant, 1-2 part boric acid, 0.5-2 part aluminium powder sinking agent, 2-5 part trolamine, 3-10 part α-amino isopropyl alcohol, 3-8 part synthetic petroleum sodium sulfonate, 0.5-1.5 part side chain phosphoric acid ester aluminium protective material, 1.5-5 part dicarboxylate base complex rust-preventive agent, 2-5 part monobutyl ether coupler, the anti-hard water agent of 0.3-1 part, 0.1-0.3 part defoamer, 8-20 part distilled water;
Described water-based extreme pressure lubricant raw material comprises following component by weight: 8-12 part tetramethylolmethane, 1-5 part hexanodioic acid, 2-6 part ricinolic acid;
Further, the lubricating fluid raw material comprises following component by weight: 50 parts of No. 45 transformer oil, 6 parts of nonionic emulsifying agents, 20 parts of water-based extreme pressure lubricants, 1.2 parts of boric acid, 1 portion of aluminium powder sinking agent, 2 parts of trolamines, 6 parts of α-amino isopropyl alcohols, 5 parts of synthetic petroleum sodium sulfonates, 1 portion of side chain phosphoric acid ester aluminium protective material, 3 parts of dicarboxylate base complex rust-preventive agent, 3 parts of monobutyl ether couplers, 1 part of anti-hard water agent, 0.2 part of defoamer, 20 parts of distilled water;
Described water-based extreme pressure lubricant raw material comprises following component by weight: 10 parts of tetramethylolmethanes, 3 parts of hexanodioic acids, 4 parts of ricinolic acids.
The present invention also discloses a kind of preparation method of water-based hand phone battery case punching stretch forming lubricating fluid, comprises the following steps:
A. prepare the water-based extreme pressure lubricant: stir and be heated to 180-200 ℃ after by weight tetramethylolmethane, hexanodioic acid and ricinolic acid being mixed, and add catalyst reaction 2-4 hour, obtain the water-based extreme pressure lubricant;
B. by weight by trolamine, boric acid stirs and is heated to 100-120 ℃ after mixing, after being incubated more than 1 hour, be cooled to below 60 ℃, then add successively by weight No. 45 transformer oil, extreme pressure lubricant, side chain phosphoric acid ester aluminium protective material, dicarboxylate base complex rust-preventive agent, the monobutyl ether coupler, the aluminium powder sinking agent, anti-hard water agent, nonionic emulsifying agent, α-amino isopropyl alcohol, it is even that the synthetic petroleum sodium sulfonate is stirred to solution, finally add distilled water and the defoamer of setting weight part to continue to be stirred to the solution homogeneous transparent, make water-based hand phone battery case punching stretch forming lubricating fluid,
Further, in step a, stir and be heated to 190 ℃ after by weight tetramethylolmethane, hexanodioic acid and ricinolic acid being mixed, and add appropriate methanesulfonic acid catalyzed agent reaction 3 hours;
Further, by weight trolamine, boric acid are stirred and are heated to 110 ℃ after mixing.
The present invention also discloses a kind of using method of water-based hand phone battery case punching stretch forming lubricating fluid, and water-based hand phone battery case punching stretch forming lubricating fluid and water are doubly diluted to use by 1:3-10;
Further, water-based hand phone battery case punching stretch forming lubricating fluid and water are doubly diluted to use by 1:7.
Beneficial effect of the present invention: water-based hand phone battery case punching stretch forming lubricating fluid of the present invention, preparation method and using method, this lubricating fluid adopts unique environment-friendly type sedimentation additive that aluminium powder is condensed, having suppressed aluminium powder is suspended in stretching liquid, aluminium powder can not sneaked in drawing oil and be circulated together with drawing oil, product glossiness is high, working space is clean, without greasy dirt; Adopt the special extreme pressure lubricant of environment-friendly type to substitute traditional synthetic ester, guaranteed the lubricity of water-based stretching liquid and the long-term stability of cleaning performance; Adopt the environment-friendly type coupler, guaranteed the stable absorption of battery-shell surface stretching liquid; Adopt the aluminium protective material, can be good at protecting aluminium; Adopt water-based stretching liquid, easily clean; This lubricating fluid has good cooling and lubricating, and workpiece surface not there will be cut and pulls, the low snap gauge phenomenon that not there will be of aluminum hull surface temperature; In working fluid containing objectionable impuritiess such as nitrite, formaldehyde, operation site without disaster hidden-trouble, have no irritating odor, to skin toxicological harmless, non-stimulated; This lubricating fluid has excellent lubricity, rustless property and settling property, and lubricity, corrosion resistance and cleaning performance can mate for a long time and stablize, the good long service life of antibacterium performance, working fluid can circulate to add and use, reduced discharge, do not polluted the environment, the indices of 5% diluent meets or exceeds the GB6144-2010 related index, concentrating the oil sump drain period is more than 12 months, and the unit oil sump drain period is more than 6 months.
Embodiment
Below in raw material in each embodiment weight be: weight part * 10KG.
Embodiment mono-
The water-based hand phone battery case punching stretch forming lubricating fluid of the present embodiment, the lubricating fluid raw material comprises following component by weight: 50 parts of No. 45 transformer oil, 6 parts of nonionic emulsifying agents, 20 parts of water-based extreme pressure lubricants, 1.2 parts of boric acid, 1 portion of aluminium powder sinking agent, 2 parts of trolamines, 6 parts of α-amino isopropyl alcohols, 5 parts of synthetic petroleum sodium sulfonates, 1 portion of side chain phosphoric acid ester aluminium protective material, 3 parts of dicarboxylate base complex rust-preventive agent, 3 parts of monobutyl ether couplers, 1 part of anti-hard water agent, 0.2 part of defoamer, 20 parts of distilled water;
Described water-based extreme pressure lubricant raw material comprises following component by weight: 10 parts of tetramethylolmethanes, 3 parts of hexanodioic acids, 4 parts of ricinolic acids.
The preparation method of the water-based hand phone battery case punching stretch forming lubricating fluid of the present embodiment comprises the following steps:
A. prepare the water-based extreme pressure lubricant: by weight tetramethylolmethane, hexanodioic acid and ricinolic acid are added in 3000L electrically heated stainless steel cauldron and stir and be heated to 190 ℃ after mixing, and add the methanesulfonic acid catalyzed agent that accounts for water-based extreme pressure lubricant gross weight 1% and react 3 hours, obtain the water-based extreme pressure lubricant;
B. by weight by trolamine, boric acid adds in 8000L electrically heated stainless steel cauldron after mixing and stirs and be heated to 110 ℃, after being incubated more than 1 hour, be cooled to below 60 ℃, then add successively by weight No. 45 transformer oil, extreme pressure lubricant, side chain phosphoric acid ester aluminium protective material, dicarboxylate base complex rust-preventive agent, the monobutyl ether coupler, the aluminium powder sinking agent, anti-hard water agent, nonionic emulsifying agent, α-amino isopropyl alcohol, it is even that the synthetic petroleum sodium sulfonate is stirred to solution, finally add distilled water and the defoamer of setting weight part to continue to be stirred to the solution homogeneous transparent, make water-based hand phone battery case punching stretch forming lubricating fluid.
The using method of the water-based hand phone battery case punching stretch forming lubricating fluid of the present embodiment, doubly dilute use by water-based hand phone battery case punching stretch forming lubricating fluid and water by 1:7.
The water-based hand phone battery case punching stretch forming lubricating fluid that the present embodiment makes is used after being watered dilution, and this lubricating fluid has good cooling and lubricating, and workpiece surface not there will be cut and pulls, the low snap gauge phenomenon that not there will be of aluminum hull surface temperature; In working fluid containing objectionable impuritiess such as nitrite, formaldehyde, operation site without disaster hidden-trouble, have no irritating odor, to skin toxicological harmless, non-stimulated; This lubricating fluid has excellent lubricity, rustless property and settling property, and lubricity, corrosion resistance and cleaning performance can mate for a long time and stablize, the good long service life of antibacterium performance, working fluid can circulate to add and use, reduced discharge, do not polluted the environment, the indices of 5% diluent meets or exceeds the GB6144-2010 related index, concentrate the oil sump drain period to surpass 15 months, the unit oil sump drain period was over 8 months.
Embodiment bis-
The water-based hand phone battery case punching stretch forming lubricating fluid of the present embodiment, the lubricating fluid raw material comprises following component by weight: 15 parts of No. 45 transformer oil, 3 parts of nonionic emulsifying agents, 10 parts of water-based extreme pressure lubricants, 1 part of boric acid, 0.5 portion of aluminium powder sinking agent, 2 parts of trolamines, 3 parts of α-amino isopropyl alcohols, 3 parts of synthetic petroleum sodium sulfonates, 0.5 portion of side chain phosphoric acid ester aluminium protective material, 1.5 parts of dicarboxylate base complex rust-preventive agent, 2 parts of monobutyl ether couplers, 0.3 part of anti-hard water agent, 0.1 part of defoamer, 8 parts of distilled water;
Described water-based extreme pressure lubricant raw material comprises following component by weight: 8 parts of tetramethylolmethanes, 1 part of hexanodioic acid, 2 parts of ricinolic acids.
The preparation method of the water-based hand phone battery case punching stretch forming lubricating fluid of the present embodiment comprises the following steps:
A. prepare the water-based extreme pressure lubricant: by weight tetramethylolmethane, hexanodioic acid and ricinolic acid are added in 3000L electrically heated stainless steel cauldron and stir and be heated to 180 ℃ after mixing, and add the methanesulfonic acid catalyzed agent that accounts for water-based extreme pressure lubricant gross weight 1% and react 2 hours, obtain extreme pressure lubricant;
B. by weight by trolamine, boric acid adds in 8000L electrically heated stainless steel cauldron after mixing and stirs and be heated to 100 ℃, be incubated and be cooled to 55 ℃ after 1.5 hours, then add successively by weight No. 45 transformer oil, extreme pressure lubricant, side chain phosphoric acid ester aluminium protective material, dicarboxylate base complex rust-preventive agent, the monobutyl ether coupler, the aluminium powder sinking agent, anti-hard water agent, nonionic emulsifying agent, α-amino isopropyl alcohol, it is even that the synthetic petroleum sodium sulfonate is stirred to solution, finally add distilled water and the defoamer of setting weight part to continue to be stirred to the solution homogeneous transparent, make water-based hand phone battery case punching stretch forming lubricating fluid.
The using method of the water-based hand phone battery case punching stretch forming lubricating fluid of the present embodiment, doubly dilute use by water-based hand phone battery case punching stretch forming lubricating fluid and water by 1:3.
The water-based hand phone battery case punching stretch forming lubricating fluid that the present embodiment makes is used after being watered dilution, and this lubricating fluid has good cooling and lubricating, and workpiece surface not there will be cut and pulls, the low snap gauge phenomenon that not there will be of aluminum hull surface temperature; In working fluid containing objectionable impuritiess such as nitrite, formaldehyde, operation site without disaster hidden-trouble, have no irritating odor, to skin toxicological harmless, non-stimulated; This lubricating fluid has excellent lubricity, rustless property and settling property, and lubricity, corrosion resistance and cleaning performance can mate for a long time and stablize, the good long service life of antibacterium performance, working fluid can circulate to add and use, reduced discharge, do not polluted the environment, the indices of 5% diluent meets or exceeds the GB6144-2010 related index, concentrate the oil sump drain period to surpass 12 months, the unit oil sump drain period was over 6 months.
Embodiment tri-
The water-based hand phone battery case punching stretch forming lubricating fluid of the present embodiment, the lubricating fluid raw material comprises following component by weight: 50 parts of No. 45 transformer oil, 10 parts of nonionic emulsifying agents, 20 parts of water-based extreme pressure lubricants, 2 parts of boric acid, 2 portions of aluminium powder sinking agents, 5 parts of trolamines, 10 parts of α-amino isopropyl alcohols, 8 parts of synthetic petroleum sodium sulfonates, 1.5 portions of side chain phosphoric acid ester aluminium protective materials, 5 parts of dicarboxylate base complex rust-preventive agent, 5 parts of monobutyl ether couplers, 1 part of anti-hard water agent, 0.3 part of defoamer, 20 parts of distilled water;
Described water-based extreme pressure lubricant raw material comprises following component by weight: 12 parts of tetramethylolmethanes, 5 parts of hexanodioic acids, 6 parts of ricinolic acids.
The preparation method of the water-based hand phone battery case punching stretch forming lubricating fluid of the present embodiment comprises the following steps:
A. prepare the water-based extreme pressure lubricant: by weight tetramethylolmethane, hexanodioic acid and ricinolic acid are added in 3000L electrically heated stainless steel cauldron and stir and be heated to 200 ℃ after mixing, and add the methanesulfonic acid catalyzed agent that accounts for water-based extreme pressure lubricant gross weight 1% and react 4 hours, obtain extreme pressure lubricant;
B. by weight by trolamine, boric acid adds in 8000L electrically heated stainless steel cauldron after mixing and stirs and be heated to 120 ℃, be incubated and be cooled to 50 ℃ after 2 hours, then add successively by weight No. 45 transformer oil, extreme pressure lubricant, side chain phosphoric acid ester aluminium protective material, dicarboxylate base complex rust-preventive agent, the monobutyl ether coupler, the aluminium powder sinking agent, anti-hard water agent, nonionic emulsifying agent, α-amino isopropyl alcohol, it is even that the synthetic petroleum sodium sulfonate is stirred to solution, finally add distilled water and the defoamer of setting weight part to continue to be stirred to the solution homogeneous transparent, make water-based hand phone battery case punching stretch forming lubricating fluid.
The using method of the water-based hand phone battery case punching stretch forming lubricating fluid of the present embodiment, doubly dilute use by water-based hand phone battery case punching stretch forming lubricating fluid and water by 1:10.
The water-based hand phone battery case punching stretch forming lubricating fluid that the present embodiment makes is used after being watered dilution, and this lubricating fluid has good cooling and lubricating, and workpiece surface not there will be cut and pulls, the low snap gauge phenomenon that not there will be of aluminum hull surface temperature; In working fluid containing objectionable impuritiess such as nitrite, formaldehyde, operation site without disaster hidden-trouble, have no irritating odor, to skin toxicological harmless, non-stimulated; This lubricating fluid has excellent lubricity, rustless property and settling property, and lubricity, corrosion resistance and cleaning performance can mate for a long time and stablize, the good long service life of antibacterium performance, working fluid can circulate to add and use, reduced discharge, do not polluted the environment, the indices of 5% diluent meets or exceeds the GB6144-2010 related index, concentrate the oil sump drain period for reaching 15 months, the unit oil sump drain period is for reaching 8 months.
Embodiment tetra-
The water-based hand phone battery case punching stretch forming lubricating fluid of the present embodiment, the lubricating fluid raw material comprises following component by weight: 15 parts of No. 45 transformer oil, 10 parts of nonionic emulsifying agents, 20 parts of water-based extreme pressure lubricants, 1 part of boric acid, 0.5 portion of aluminium powder sinking agent, 2 parts of trolamines, 10 parts of α-amino isopropyl alcohols, 8 parts of synthetic petroleum sodium sulfonates, 0.5 portion of side chain phosphoric acid ester aluminium protective material, 1.5 parts of dicarboxylate base complex rust-preventive agent, 5 parts of monobutyl ether couplers, 0.3 part of anti-hard water agent, 0.1 part of defoamer, 20 parts of distilled water;
Described water-based extreme pressure lubricant raw material comprises following component by weight: 8 parts of tetramethylolmethanes, 5 parts of hexanodioic acids, 6 parts of ricinolic acids.
The preparation method of the water-based hand phone battery case punching stretch forming lubricating fluid of the present embodiment comprises the following steps:
A. prepare the water-based extreme pressure lubricant: by weight tetramethylolmethane, hexanodioic acid and ricinolic acid are added in 3000L electrically heated stainless steel cauldron and stir and be heated to 190 ℃ after mixing, and add the methanesulfonic acid catalyzed agent that accounts for water-based extreme pressure lubricant gross weight 1% and react 2.5 hours, obtain extreme pressure lubricant; (ask the contriver to provide, thanks)
B. by weight by trolamine, boric acid adds in 8000L electrically heated stainless steel cauldron after mixing and stirs and be heated to 105 ℃, be incubated and be cooled to 45 ℃ after 1.8 hours, then add successively by weight No. 45 transformer oil, extreme pressure lubricant, side chain phosphoric acid ester aluminium protective material, dicarboxylate base complex rust-preventive agent, the monobutyl ether coupler, the aluminium powder sinking agent, anti-hard water agent, nonionic emulsifying agent, α-amino isopropyl alcohol, it is even that the synthetic petroleum sodium sulfonate is stirred to solution, finally add distilled water and the defoamer of setting weight part to continue to be stirred to the solution homogeneous transparent, make water-based hand phone battery case punching stretch forming lubricating fluid.
The using method of the water-based hand phone battery case punching stretch forming lubricating fluid of the present embodiment, doubly dilute use by water-based hand phone battery case punching stretch forming lubricating fluid and water by 1:5.
The water-based hand phone battery case punching stretch forming lubricating fluid that the present embodiment makes is used after being watered dilution, and this lubricating fluid has good cooling and lubricating, and workpiece surface not there will be cut and pulls, the low snap gauge phenomenon that not there will be of aluminum hull surface temperature; In working fluid containing objectionable impuritiess such as nitrite, formaldehyde, operation site without disaster hidden-trouble, have no irritating odor, to skin toxicological harmless, non-stimulated; This lubricating fluid has excellent lubricity, rustless property and settling property, and lubricity, corrosion resistance and cleaning performance can mate for a long time and stablize, the good long service life of antibacterium performance, working fluid can circulate to add and use, reduced discharge, do not polluted the environment, the indices of 5% diluent meets or exceeds the GB6144-2010 related index, concentrate the oil sump drain period to reach 13 months), the unit oil sump drain period reaches 7 months.
Embodiment five
The water-based hand phone battery case punching stretch forming lubricating fluid of the present embodiment, the lubricating fluid raw material comprises following component by weight: No. 45 transformer oil of 15-50 part, 3-10 part nonionic emulsifying agent, 10-20 part water-based extreme pressure lubricant, 1-2 part boric acid, 0.5-2 portion aluminium powder sinking agent, 2-5 part trolamine, 3-10 part α-amino isopropyl alcohol, 3-8 part synthetic petroleum sodium sulfonate, 0.5-1.5 portion side chain phosphoric acid ester aluminium protective material, 1.5-5 part dicarboxylate base complex rust-preventive agent, 2-5 part monobutyl ether coupler, 0.3-1 part anti-hard water agent, 0.1-0.3 part defoamer, 8-20 part distilled water,
Described water-based extreme pressure lubricant raw material comprises following component by weight: 8-12 part tetramethylolmethane, 1-5 part hexanodioic acid, 2-6 part ricinolic acid.
The preparation method of the water-based hand phone battery case punching stretch forming lubricating fluid of the present embodiment comprises the following steps:
A. prepare the water-based extreme pressure lubricant: by weight tetramethylolmethane, hexanodioic acid and ricinolic acid are added in 3000L electrically heated stainless steel cauldron and stir and be heated to 195 ℃ after mixing, and add the methanesulfonic acid catalyzed agent that accounts for water-based extreme pressure lubricant gross weight 1% and react 3.5 hours, obtain extreme pressure lubricant;
B. by weight by trolamine, boric acid adds in 8000L electrically heated stainless steel cauldron after mixing and stirs and be heated to 110 ℃, be incubated and be cooled to 40 ℃ after 2.5 hours, then add successively by weight No. 45 transformer oil, extreme pressure lubricant, side chain phosphoric acid ester aluminium protective material, dicarboxylate base complex rust-preventive agent, the monobutyl ether coupler, the aluminium powder sinking agent, anti-hard water agent, nonionic emulsifying agent, α-amino isopropyl alcohol, it is even that the synthetic petroleum sodium sulfonate is stirred to solution, finally add distilled water and the defoamer of setting weight part to continue to be stirred to the solution homogeneous transparent, make water-based hand phone battery case punching stretch forming lubricating fluid.
The using method of the water-based hand phone battery case punching stretch forming lubricating fluid of the present embodiment, doubly dilute use by water-based hand phone battery case punching stretch forming lubricating fluid and water by 1:10.
The water-based hand phone battery case punching stretch forming lubricating fluid that the present embodiment makes is used after being watered dilution, and this lubricating fluid has good cooling and lubricating, and workpiece surface not there will be cut and pulls, the low snap gauge phenomenon that not there will be of aluminum hull surface temperature; In working fluid containing objectionable impuritiess such as nitrite, formaldehyde, operation site without disaster hidden-trouble, have no irritating odor, to skin toxicological harmless, non-stimulated; This lubricating fluid has excellent lubricity, rustless property and settling property, and lubricity, corrosion resistance and cleaning performance can mate for a long time and stablize, the good long service life of antibacterium performance, working fluid can circulate to add and use, reduced discharge, do not polluted the environment, the indices of 5% diluent meets or exceeds the GB6144-2010 related index, concentrate the oil sump drain period to reach 14 months, the unit oil sump drain period reaches 7 months.
Embodiment six
The water-based hand phone battery case punching stretch forming lubricating fluid of this enforcement, the lubricating fluid raw material comprises following component by weight: 50 parts of No. 45 transformer oil, 10 parts of nonionic emulsifying agents, 10 parts of water-based extreme pressure lubricants, 2 parts of boric acid, 0.5 portion of aluminium powder sinking agent, 2 parts of trolamines, 10 parts of α-amino isopropyl alcohols, 8 parts of synthetic petroleum sodium sulfonates, 0.5 portion of side chain phosphoric acid ester aluminium protective material, 1.5 parts of dicarboxylate base complex rust-preventive agent, 5 parts of monobutyl ether couplers, 1 part of anti-hard water agent, 0.1 part of defoamer, 20 parts of distilled water;
Described water-based extreme pressure lubricant raw material comprises following component by weight: 12 parts of tetramethylolmethanes, 1 part of hexanodioic acid, 2 parts of ricinolic acids.
The preparation method of the water-based hand phone battery case punching stretch forming lubricating fluid of the present embodiment comprises the following steps:
A. prepare the water-based extreme pressure lubricant: by weight tetramethylolmethane, hexanodioic acid and ricinolic acid are added in 3000L electrically heated stainless steel cauldron and stir and be heated to 200 ℃ after mixing, and add the methanesulfonic acid catalyzed agent that accounts for water-based extreme pressure lubricant gross weight 1% and react 3 hours, obtain extreme pressure lubricant;
B. by weight by trolamine, boric acid adds in 8000L electrically heated stainless steel cauldron after mixing and stirs and be heated to 115 ℃, be incubated and be cooled to 58 ℃ after 1.5 hours, then add successively by weight No. 45 transformer oil, extreme pressure lubricant, side chain phosphoric acid ester aluminium protective material, dicarboxylate base complex rust-preventive agent, the monobutyl ether coupler, the aluminium powder sinking agent, anti-hard water agent, nonionic emulsifying agent, α-amino isopropyl alcohol, it is even that the synthetic petroleum sodium sulfonate is stirred to solution, finally add distilled water and the defoamer of setting weight part to continue to be stirred to the solution homogeneous transparent, make water-based hand phone battery case punching stretch forming lubricating fluid.
The using method of the water-based hand phone battery case punching stretch forming lubricating fluid of the present embodiment, doubly dilute use by water-based hand phone battery case punching stretch forming lubricating fluid and water by 1:7.
The water-based hand phone battery case punching stretch forming lubricating fluid that the present embodiment makes is used after being watered dilution, and this lubricating fluid has good cooling and lubricating, and workpiece surface not there will be cut and pulls, the low snap gauge phenomenon that not there will be of aluminum hull surface temperature; In working fluid containing objectionable impuritiess such as nitrite, formaldehyde, operation site without disaster hidden-trouble, have no irritating odor, to skin toxicological harmless, non-stimulated; This lubricating fluid has excellent lubricity, rustless property and settling property, and lubricity, corrosion resistance and cleaning performance can mate for a long time and stablize, the good long service life of antibacterium performance, working fluid can circulate to add and use, reduced discharge, do not polluted the environment, the indices of 5% diluent meets or exceeds the GB6144-2010 related index, concentrate the oil sump drain period to surpass 14 months, the unit oil sump drain period was over 6 months.
Embodiment seven
The water-based hand phone battery case punching stretch forming lubricating fluid of the present embodiment, the lubricating fluid raw material comprises following component by weight: 30 parts of No. 45 transformer oil, 7 parts of nonionic emulsifying agents, 20 parts of water-based extreme pressure lubricants, 1-2 part boric acid, 2 portions of aluminium powder sinking agents, 3 parts of trolamines, 7 parts of α-amino isopropyl alcohols, 8 parts of synthetic petroleum sodium sulfonates, 1 portion of side chain phosphoric acid ester aluminium protective material, 3 parts of dicarboxylate base complex rust-preventive agent, 5 parts of monobutyl ether couplers, 1 part of anti-hard water agent, 0.3 part of defoamer, 15 parts of distilled water;
Described water-based extreme pressure lubricant raw material comprises following component by weight: 10 parts of tetramethylolmethanes, 3 parts of hexanodioic acids, 6 parts of ricinolic acids.
The preparation method of the water-based hand phone battery case punching stretch forming lubricating fluid of the present embodiment comprises the following steps:
A. prepare the water-based extreme pressure lubricant: by weight tetramethylolmethane, hexanodioic acid and ricinolic acid are added in 3000L electrically heated stainless steel cauldron and stir and be heated to 180 ℃ after mixing, and add the methanesulfonic acid catalyzed agent that accounts for water-based extreme pressure lubricant gross weight 1% and react 2 hours, obtain extreme pressure lubricant;
B. by weight by trolamine, boric acid adds in 8000L electrically heated stainless steel cauldron after mixing and stirs and be heated to 100 ℃, be incubated and be cooled to 35 ℃ after 3 hours, then add successively by weight No. 45 transformer oil, extreme pressure lubricant, side chain phosphoric acid ester aluminium protective material, dicarboxylate base complex rust-preventive agent, the monobutyl ether coupler, the aluminium powder sinking agent, anti-hard water agent, nonionic emulsifying agent, α-amino isopropyl alcohol, it is even that the synthetic petroleum sodium sulfonate is stirred to solution, finally add distilled water and the defoamer of setting weight part to continue to be stirred to the solution homogeneous transparent, make water-based hand phone battery case punching stretch forming lubricating fluid.
The using method of the water-based hand phone battery case punching stretch forming lubricating fluid of the present embodiment, doubly dilute use by water-based hand phone battery case punching stretch forming lubricating fluid and water by 1:8.
The water-based hand phone battery case punching stretch forming lubricating fluid that the present embodiment makes is used after being watered dilution, and this lubricating fluid has good cooling and lubricating, and workpiece surface not there will be cut and pulls, the low snap gauge phenomenon that not there will be of aluminum hull surface temperature; In working fluid containing objectionable impuritiess such as nitrite, formaldehyde, operation site without disaster hidden-trouble, have no irritating odor, to skin toxicological harmless, non-stimulated; This lubricating fluid has excellent lubricity, rustless property and settling property, and lubricity, corrosion resistance and cleaning performance can mate for a long time and stablize, the good long service life of antibacterium performance, working fluid can circulate to add and use, reduced discharge, do not polluted the environment, the indices of 5% diluent meets or exceeds the GB6144-2010 related index, concentrating the oil sump drain period is 15 months, and the unit oil sump drain period is 7 months.
In above-described embodiment, described nonionic emulsifying agent adopts polyoxyethylene nonylphenol ether; Described aluminium powder sinking agent adopts the Dismulgan77(Shanghai waffle work company limited of shaking); Described anti-hard water agent adopts EDETATE DISODIUM, described defoamer adopts Foam Ban MS575, and described monobutyl ether coupler adopts diethylene glycol monobutyl ether, in above-described embodiment, composition in above various component there is no impact to lubricating fluid character after replacing, thereby can realize goal of the invention.
As can be seen here, the water-based hand phone battery case punching stretch forming lubricating fluid made of the present invention is used after being watered dilution, the energy water is (1:3～1:10) dilution in proportion, this lubricating fluid has good cooling and lubricating, workpiece surface not there will be cut and pulls, the low snap gauge phenomenon that not there will be of aluminum hull surface temperature; In working fluid containing objectionable impuritiess such as nitrite, formaldehyde, operation site without disaster hidden-trouble, have no irritating odor, to skin toxicological harmless, non-stimulated; This lubricating fluid has excellent lubricity, rustless property and settling property, and lubricity, corrosion resistance and cleaning performance can mate for a long time and stablize, the good long service life of antibacterium performance, working fluid can circulate to add and use, reduced discharge, do not pollute the environment, the indices of 5% diluent meets or exceeds the GB6144-2010 related index.And for above technique effect, the proportioning of embodiment mono-and processing parameter, result of use is best, obviously is better than other embodiment, is the best.
Finally explanation is, above embodiment is only unrestricted in order to technical scheme of the present invention to be described, although with reference to preferred embodiment, the present invention is had been described in detail, those of ordinary skill in the art is to be understood that, can modify or be equal to replacement technical scheme of the present invention, and not breaking away from aim and the scope of technical solution of the present invention, it all should be encompassed in the middle of claim scope of the present invention.
Claims (7)
1. a water-based hand phone battery case punching stretch forming lubricating fluid, it is characterized in that: the lubricating fluid raw material comprises following component by weight: No. 45 transformer oil of 15-50 part, 3-10 part nonionic emulsifying agent, 10-20 part water-based extreme pressure lubricant, 1-2 part boric acid, 0.5-2 portion aluminium powder sinking agent, 2-5 part trolamine, 3-10 part α-amino isopropyl alcohol, 3-8 part synthetic petroleum sodium sulfonate, 0.5-1.5 portion side chain phosphoric acid ester aluminium protective material, 1.5-5 part dicarboxylate base complex rust-preventive agent, 2-5 part monobutyl ether coupler, 0.3-1 part anti-hard water agent, 0.1-0.3 part defoamer, 8-20 part distilled water,
Described water-based extreme pressure lubricant raw material comprises following component by weight: 8-12 part tetramethylolmethane, 1-5 part hexanodioic acid, 2-6 part ricinolic acid.
2. water-based hand phone battery case punching stretch forming lubricating fluid according to claim 1, it is characterized in that: the lubricating fluid raw material comprises following component by weight: 50 parts of No. 45 transformer oil, 6 parts of nonionic emulsifying agents, 20 parts of water-based extreme pressure lubricants, 1.2 parts of boric acid, 1 portion of aluminium powder sinking agent, 2 parts of trolamines, 6 parts of α-amino isopropyl alcohols, 5 parts of synthetic petroleum sodium sulfonates, 1 portion of side chain phosphoric acid ester aluminium protective material, 3 parts of dicarboxylate base complex rust-preventive agent, 3 parts of monobutyl ether couplers, 1 part of anti-hard water agent, 0.2 part of defoamer, 20 parts of distilled water;
Described water-based extreme pressure lubricant raw material comprises following component by weight: 10 parts of tetramethylolmethanes, 3 parts of hexanodioic acids, 4 parts of ricinolic acids.
3. the preparation method of a water-based hand phone battery case punching stretch forming lubricating fluid claimed in claim 1 is characterized in that: comprise the following steps:
A. prepare the water-based extreme pressure lubricant: stir and be heated to 180-200 ℃ after by weight tetramethylolmethane, hexanodioic acid and ricinolic acid being mixed, and add catalyst reaction 2-4 hour, make the water-based extreme pressure lubricant;
B. by weight by trolamine, boric acid stirs and is heated to 100-120 ℃ after mixing, after being incubated more than 1 hour, be cooled to below 60 ℃, then add successively by weight No. 45 transformer oil, extreme pressure lubricant, side chain phosphoric acid ester aluminium protective material, dicarboxylate base complex rust-preventive agent, the monobutyl ether coupler, the aluminium powder sinking agent, anti-hard water agent, nonionic emulsifying agent, α-amino isopropyl alcohol, it is even that the synthetic petroleum sodium sulfonate is stirred to solution, finally add distilled water and the defoamer of setting weight part to continue to be stirred to the solution homogeneous transparent, make water-based hand phone battery case punching stretch forming lubricating fluid.
4. the preparation method of water-based hand phone battery case punching stretch forming lubricating fluid according to claim 3, it is characterized in that: in step a, stir and be heated to 190 ℃ after by weight tetramethylolmethane, hexanodioic acid and ricinolic acid being mixed, and add appropriate methanesulfonic acid catalyzed agent reaction 3 hours.
5. the preparation method of water-based hand phone battery case punching stretch forming lubricating fluid according to claim 4, is characterized in that: by weight trolamine, boric acid are stirred and be heated to 110 ℃ after mixing.
6. the using method of a water-based hand phone battery case punching stretch forming lubricating fluid claimed in claim 1, is characterized in that: water-based hand phone battery case punching stretch forming lubricating fluid and water are doubly diluted to use by 1:3-10.
7. the using method of water-based hand phone battery case punching stretch forming lubricating fluid according to claim 6, is characterized in that: water-based hand phone battery case punching stretch forming lubricating fluid and water are doubly diluted to use by 1:7.
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| CN105175698A (en) * | 2014-05-26 | 2015-12-23 | 广州米奇化工有限公司 | Castor oil modified multi-functional lubricant and preparation method thereof |
| CN104212534B (en) * | 2014-09-28 | 2016-12-07 | 广州米奇化工有限公司 | A kind of multi-functional extreme-pressure lubricant and preparation method thereof |
| CN105219492A (en) * | 2015-09-16 | 2016-01-06 | 安徽贝利机械制造有限公司 | A kind of rig lubricating oil and preparation method thereof |
| CN109735388B (en) * | 2018-12-29 | 2021-11-09 | 广州科卢斯流体科技有限公司 | Environment-friendly water-based aluminum foil stamping fluid |
| CN111808659A (en) * | 2020-05-29 | 2020-10-23 | 安美科技股份有限公司 | Water-based aluminum wire drawing liquid and use method thereof |
| CN113481041A (en) * | 2021-07-22 | 2021-10-08 | 东莞市卓骏润滑科技有限公司 | Water-based cooling lubricating liquid for stamping thick plates of automobiles, preparation method and use method thereof |
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Address after: Guangdong Province, Dongguan City Industrial Road 523808 Songshan Lake Science and Technology Industrial Park No. 6 Patentee after: AMER LUBRICANT TECHNOLOGY CO., LTD. Address before: 523808 Guangdong province Dongguan City Songshan Lake Science and Technology Industrial Park Road No. 6 Patentee before: Dongguan Amer Lubricant Technology Co., Ltd. |