CN109943404A - High-grade environment-friendly type mirror finish grinding oil - Google Patents
High-grade environment-friendly type mirror finish grinding oil Download PDFInfo
- Publication number
- CN109943404A CN109943404A CN201910333094.7A CN201910333094A CN109943404A CN 109943404 A CN109943404 A CN 109943404A CN 201910333094 A CN201910333094 A CN 201910333094A CN 109943404 A CN109943404 A CN 109943404A
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- China
- Prior art keywords
- mirror finish
- base
- oil
- friendly type
- finish grinding
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
- 238000000227 grinding Methods 0.000 title claims abstract description 20
- 239000003921 oil Substances 0.000 claims abstract description 21
- 235000019198 oils Nutrition 0.000 claims abstract description 21
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 claims abstract description 13
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910052791 calcium Inorganic materials 0.000 claims abstract description 8
- 239000011575 calcium Substances 0.000 claims abstract description 8
- 150000008301 phosphite esters Chemical class 0.000 claims abstract description 8
- 229940051841 polyoxyethylene ether Drugs 0.000 claims abstract description 8
- 229920000056 polyoxyethylene ether Polymers 0.000 claims abstract description 8
- 239000003760 tallow Substances 0.000 claims abstract description 8
- MEIRRNXMZYDVDW-MQQKCMAXSA-N (2E,4E)-2,4-hexadien-1-ol Chemical compound C\C=C\C=C\CO MEIRRNXMZYDVDW-MQQKCMAXSA-N 0.000 claims abstract description 7
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims abstract description 7
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims abstract description 7
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims abstract description 7
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000005642 Oleic acid Substances 0.000 claims abstract description 7
- 235000019484 Rapeseed oil Nutrition 0.000 claims abstract description 7
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000012964 benzotriazole Substances 0.000 claims abstract description 7
- 230000018044 dehydration Effects 0.000 claims abstract description 7
- 238000006297 dehydration reaction Methods 0.000 claims abstract description 7
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000003350 kerosene Substances 0.000 claims abstract description 7
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims abstract description 7
- GGHDAUPFEBTORZ-UHFFFAOYSA-N propane-1,1-diamine Chemical compound CCC(N)N GGHDAUPFEBTORZ-UHFFFAOYSA-N 0.000 claims abstract description 7
- 230000009967 tasteless effect Effects 0.000 claims abstract description 7
- PHYFQTYBJUILEZ-IUPFWZBJSA-N triolein Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CCCCCCCC)COC(=O)CCCCCCC\C=C/CCCCCCCC PHYFQTYBJUILEZ-IUPFWZBJSA-N 0.000 claims abstract description 7
- 101000823778 Homo sapiens Y-box-binding protein 2 Proteins 0.000 claims description 6
- 238000003801 milling Methods 0.000 abstract description 5
- 235000010354 butylated hydroxytoluene Nutrition 0.000 abstract 1
- 238000000034 method Methods 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000004062 sedimentation Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 230000003746 surface roughness Effects 0.000 description 2
- 238000009825 accumulation Methods 0.000 description 1
- 231100000921 acute inhalation toxicity Toxicity 0.000 description 1
- 231100000460 acute oral toxicity Toxicity 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000003384 imaging method Methods 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 210000001533 respiratory mucosa Anatomy 0.000 description 1
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- Lubricants (AREA)
Abstract
The invention discloses a kind of high-grade environment-friendly type mirror finish grinding oils, it is made of 5# white oil, tasteless kerosene D90, two [(Z) -9- octadecylene base] phosphite esters, the calcium alkylbenzenesulfonate of base number 500, rapeseed oil, oleic acid, dehydration sorbic alcohol list olein, N- tallow base propane diamine polyoxyethylene ether, benzotriazole, 2,6-di-tert-butyl p-cresol.Product of the present invention has splendid greasy property, milling settling property, meets mirror finish needs.
Description
Technical field
The present invention relates to a kind of mirror finish grinding oils.
Background technique
Mirror grinding, which refers to, can reach minimal surface roughness (small had between two wave crest of metal surface or trough
Away from and unevenness) method for grinding.Surface of workpiece roughness (Ra)≤0.01 μm after grinding, light is like mirror surface, Ke Yiqing
Clear imaging, it is highest level-one in current machine tooling.The high-precision metal that the fields such as modern Aviation, space flight, instrument use
Workpiece (accessory of high temperature resistant, high speed on such as aircraft), requires to be processed with mirror grinding.
To obtain very high workpiece precision and very small surface roughness, and effective protection grinding knife tool, extend
Its service life, it is desirable that matching used grinding oil will not only have extremely strong greasy property (friction coefficient μ≤0.018), and
And to have splendid milling dispersing and settling performance (milling easily dispersed and sunk in the solution, the sedimentation time≤5s, no plate
Block accumulation).Secondly, the strength with chemicals greenization, environmentally friendly construction promotes, it is desirable that matching used grinding oil one
Surely there is very high safety and sanitation quality, it is harmless, it is environmentally friendly.Due to technique, backward in technique etc. are many,
Presently commercially available mirror grinding oil is also unsatisfactory, it is difficult to meet high-end market demand (height needed for country's high-end market at present
Grade, environment-friendly type mirror grinding oil are essentially all by import).
Summary of the invention
That the purpose of the present invention is to provide a kind of greasy properties is good, settleability is good, operating environment is excellent, the hygienic matter of product safety
Measure high mirror finish grinding oil.
The technical solution of the invention is as follows:
A kind of high-grade environment-friendly type mirror finish grinding oil, it is characterized in that: being mixed by the component of following mass percent:
5# white oil 5 ~ 10%
Tasteless kerosene D90 40 ~ 55%
Two [(Z) -9- octadecylene base] phosphite esters 8 ~ 15%
The calcium alkylbenzenesulfonate 10 ~ 20% of base number 500
Rapeseed oil 2 ~ 4%
Oleic acid 2 ~ 6%
Dehydration sorbic alcohol list olein 1 ~ 3%
N- tallow base propane diamine polyoxyethylene ether 5 ~ 15%
Benzotriazole 0.3 ~ 1%
DBPC 2,6 ditertiary butyl p cresol 0.5 ~ 2%.
The high-grade environment-friendly type mirror finish grinding oil, is mixed by the component of following mass percent:
5# white oil 7%
Tasteless kerosene D90 47%
Two [(Z) -9- octadecylene base] phosphite esters 12%
The calcium alkylbenzenesulfonate 15% of base number 500
Rapeseed oil 2.5%
Oleic acid 3%
Dehydration sorbic alcohol list olein 2%
N- tallow base propane diamine polyoxyethylene ether 10%
Benzotriazole 0.5%
DBPC 2,6 ditertiary butyl p cresol 1%.
The present invention selects calcium alkylbenzenesulfonate (base number 500), two [(Z) -9- octadecylene base] phosphite esters, N- tallow base the third two
The compatibilities such as amine polyoxyethylene ether make the greasy property of product, milling dispersing and settling performance obtain higher promotion and (survey through laboratory
Examination, coefficient of friction≤0.018, sedimentation time≤5s).
Raw material does not use the harmful substance for jeopardizing human health and Environmental security in the present invention, makes the safety and sanitation matter of product
Amount be increased dramatically (through detecting, product acute oral toxicity LD50 >=5000mg/kg, acute inhalation toxicity LC50 >=
5000mg/m3, respiratory mucosa stimulus intensity are 0 grade).
Product has splendid greasy property, milling settling property, meets mirror finish needs.
Below with reference to embodiment, the invention will be further described.
Specific embodiment
Embodiment 1:
A kind of high-grade environment-friendly type mirror finish grinding oil, is stirred by the component of following mass percent and is made:
5# white oil 8.6%
Tasteless kerosene D90 43%
Two [(Z) -9- octadecylene base] phosphite esters 12%
The calcium alkylbenzenesulfonate 15% of base number 500
Rapeseed oil 2%
Oleic acid 6%
Dehydration sorbic alcohol list olein 1%
N- tallow base propane diamine polyoxyethylene ether 11%
Benzotriazole 0.3%
DBPC 2,6 ditertiary butyl p cresol 1.1%.
Embodiment 2:
A kind of high-grade environment-friendly type mirror finish grinding oil, is stirred by the component of following mass percent and is made:
5# white oil 7%
Tasteless kerosene D90 47%
Two [(Z) -9- octadecylene base] phosphite esters 12%
The calcium alkylbenzenesulfonate 15% of base number 500
Rapeseed oil 2.5%
Oleic acid 3%
Dehydration sorbic alcohol list olein 2%
N- tallow base propane diamine polyoxyethylene ether 10%
Benzotriazole 0.5%
DBPC 2,6 ditertiary butyl p cresol 1%.
Claims (2)
1. a kind of high-grade environment-friendly type mirror finish grinding oil, it is characterized in that: being mixed by the component of following mass percent:
5# white oil 5 ~ 10%
Tasteless kerosene D90 40 ~ 55%
Two [(Z) -9- octadecylene base] phosphite esters 8 ~ 15%
The calcium alkylbenzenesulfonate 10 ~ 20% of base number 500
Rapeseed oil 2 ~ 4%
Oleic acid 2 ~ 6%
Dehydration sorbic alcohol list olein 1 ~ 3%
N- tallow base propane diamine polyoxyethylene ether 5 ~ 15%
Benzotriazole 0.3 ~ 1%
DBPC 2,6 ditertiary butyl p cresol 0.5 ~ 2%.
2. high-grade environment-friendly type mirror finish grinding oil according to claim 1, it is characterized in that:
It is mixed by the component of following mass percent:
5# white oil 7%
Tasteless kerosene D90 47%
Two [(Z) -9- octadecylene base] phosphite esters 12%
The calcium alkylbenzenesulfonate 15% of base number 500
Rapeseed oil 2.5%
Oleic acid 3%
Dehydration sorbic alcohol list olein 2%
N- tallow base propane diamine polyoxyethylene ether 10%
Benzotriazole 0.5%
DBPC 2,6 ditertiary butyl p cresol 1%.
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CN201910333094.7A CN109943404A (en) | 2019-04-24 | 2019-04-24 | High-grade environment-friendly type mirror finish grinding oil |
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CN201910333094.7A CN109943404A (en) | 2019-04-24 | 2019-04-24 | High-grade environment-friendly type mirror finish grinding oil |
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CN109943404A true CN109943404A (en) | 2019-06-28 |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110423640A (en) * | 2019-07-22 | 2019-11-08 | 湖北爱国石化有限公司 | A kind of hard-alloy grinding oil and preparation method thereof |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH09296195A (en) * | 1996-05-07 | 1997-11-18 | Nippon Oil Co Ltd | Oil agent composition for cutting/grinding process |
CN102660360A (en) * | 2012-05-04 | 2012-09-12 | 启东尤希路化学工业有限公司 | Superfine oil for abrasive machining of high-lubrication and high-water-separability bearing |
CN104694234A (en) * | 2015-03-18 | 2015-06-10 | 启东尤希路化学工业有限公司 | High-performance environmentally-friendly medium- and long-period antirust punching oil |
CN106833846A (en) * | 2017-01-23 | 2017-06-13 | 上海帕卡兴产化工有限公司 | One kind exempts from degreasing autobody sheet and cleans oil and preparation method thereof with punching press |
CN107267267A (en) * | 2017-07-10 | 2017-10-20 | 上海尤希路化学工业有限公司 | Anti- double exposure, peace and quiet, environment-friendly type bearing grinding special oil |
CN108467769A (en) * | 2018-04-25 | 2018-08-31 | 上海尤希路化学工业有限公司 | High lubrication, high frequency time, environment-friendly type crawler belt bearing pin chain punch process special oil |
CN109468157A (en) * | 2018-11-08 | 2019-03-15 | 希玛石油制品(镇江)有限公司 | A kind of no chlorine environmental-protecting type stainless steel molding oil and preparation method thereof |
-
2019
- 2019-04-24 CN CN201910333094.7A patent/CN109943404A/en active Pending
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH09296195A (en) * | 1996-05-07 | 1997-11-18 | Nippon Oil Co Ltd | Oil agent composition for cutting/grinding process |
CN102660360A (en) * | 2012-05-04 | 2012-09-12 | 启东尤希路化学工业有限公司 | Superfine oil for abrasive machining of high-lubrication and high-water-separability bearing |
CN104694234A (en) * | 2015-03-18 | 2015-06-10 | 启东尤希路化学工业有限公司 | High-performance environmentally-friendly medium- and long-period antirust punching oil |
CN106833846A (en) * | 2017-01-23 | 2017-06-13 | 上海帕卡兴产化工有限公司 | One kind exempts from degreasing autobody sheet and cleans oil and preparation method thereof with punching press |
CN107267267A (en) * | 2017-07-10 | 2017-10-20 | 上海尤希路化学工业有限公司 | Anti- double exposure, peace and quiet, environment-friendly type bearing grinding special oil |
CN108467769A (en) * | 2018-04-25 | 2018-08-31 | 上海尤希路化学工业有限公司 | High lubrication, high frequency time, environment-friendly type crawler belt bearing pin chain punch process special oil |
CN109468157A (en) * | 2018-11-08 | 2019-03-15 | 希玛石油制品(镇江)有限公司 | A kind of no chlorine environmental-protecting type stainless steel molding oil and preparation method thereof |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110423640A (en) * | 2019-07-22 | 2019-11-08 | 湖北爱国石化有限公司 | A kind of hard-alloy grinding oil and preparation method thereof |
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RJ01 | Rejection of invention patent application after publication |
Application publication date: 20190628 |
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