CN102660360A - Superfine oil for abrasive machining of high-lubrication and high-water-separability bearing - Google Patents

Superfine oil for abrasive machining of high-lubrication and high-water-separability bearing Download PDF

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Publication number
CN102660360A
CN102660360A CN2012101355350A CN201210135535A CN102660360A CN 102660360 A CN102660360 A CN 102660360A CN 2012101355350 A CN2012101355350 A CN 2012101355350A CN 201210135535 A CN201210135535 A CN 201210135535A CN 102660360 A CN102660360 A CN 102660360A
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China
Prior art keywords
oil
moisture
processing
essential oil
lubricated
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CN2012101355350A
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Chinese (zh)
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CN102660360B (en
Inventor
林丽静
阿部聪
常建忠
俞威
蔡志宏
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QIDONG YOUXILU CHEMICAL INDUSTRY Co Ltd
Shanghai Yushiro Chemical Industry Co Ltd
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QIDONG YOUXILU CHEMICAL INDUSTRY Co Ltd
Shanghai Yushiro Chemical Industry Co Ltd
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Abstract

The invention discloses superfine oil for abrasive machining of a high-lubrication and high-water-separability bearing. The superfine oil consists of mineral oil, polymeric carboxylic acid, organic amine, a surfactant, a synthetic lubricant, an anticorrosive agent, an extreme-pressure additive and an antioxidant. The superfine oil has an excellent lubricating property, a Bouton tester is used for testing, and a friction coefficient value of raw oil is less than or equal to 0.1; the superfine oil has excellent water separability, and the separation time of oil and water is less than or equal to 10 min (50 ml of sample is added into 50 ml of water, and the mixture is turned for 10 times); and raw materials in a formula are not toxic and harmful substances which influence the environmental safety and human health, the biological median lethal dose LD50 of the product is more than or equal to 5,000 mg/kg, the median lethal concentration LC50 is more than or equal to 5,000 mg/m<3>, the respiratory mucosa irritation is less than or equal to class 1, and the superfine oil has reliable safety and sanitation quality.

Description

Height is lubricated, high-moisture is used ultra essential oil from the processing of property bearing grinding
Technical field
The present invention relates to a kind of bearing grinding processing with ultra essential oil.
Background technology
Chinese Economy Development has promoted the demand of a large amount of high precision, high reliability bearing, has also laid good basis for the stable development of bearing industry.At present the product internal structure parameter of zanjon seal ball bearing of China and external advanced company much at one, yet the vibration and noise level of this series products of China but differs greatly with external product.A large amount of both at home and abroad tests show: retainer, lasso, processing quality have influence in various degree to bear vibration, and its major influence factors is the circularity, percent ripple, surfaceness, surperficial knock damage of lasso etc.For obtain better working accuracy in manufacturing processed to bearing ultra essential oil agent have higher requirement.Ultra essential oil is mainly used in hyperfine grinding (post forming grinding) complete processing of bearing, plays cooling, lubricated, rust protection and cleanup action, so that bearing obtains higher precision and better smooth finish.At present commercially available ultra essential oil frictional coefficient is all more than 0.2; The oily water separation time is all more than 30min; The toxic substance that generally contains harm environmental safety such as clorafin and HUMAN HEALTH in the prescription; Also exist in the course of processing and smolder, mist of oil, be difficult for drawback such as cleanings, can not satisfy the high-end customer constantly request for utilization of the bearing processing of lifting and the environmental friendliness requirement of people's growing interest.
Summary of the invention
The object of the present invention is to provide that a kind of oilness is good, water separable performance is good,, high-moisture lubricated to the height of human and environment safety from the processing of property bearing grinding with ultra essential oil.
Technical solution of the present invention is:
A kind of high lubricated, high-moisture, is characterized in that: be made up of following component in percentage by weight with ultra essential oil from the processing of property bearing grinding:
MO 65~90%
Polymeric carboxylic 2~5%
Organic amine 2~5%
Tensio-active agent 1~5%
Synthetic lubricant 1~10%
Anticorrosive agent 0~5%
Extreme pressure agent 0~10%
Inhibitor 0~3%.
MO is one or more the mixture in paraffin base oil, naphthenic base oils, the intermediate base base oil.
Organic carboxyl acid is at least a long-chain carboxylic acid, this sour binary to hexa-atomic multipolymer or its mixture that contains 8~20 carbon atoms.
Organic amine is 1,2-dimethyl propylamine, trolamine, hexanediamine, tri-isopropanolamine, N, N-diethylethanolamine, 2-amino-2-methyl-1-propanol, hexanolactam or tallow base trimethylene diamines.
Tensio-active agent be AEO (5~12), aliphatic alcohol polyethenoxy polyethenoxy ether, Fatty Alcohol(C12-C14 and C12-C18) alcohol amide, aliphatic alcohol polyethenoxy ester (5~12), sulphonate, Lipid acidThe mixture of one or more in glyceryl ester, sapn, the tween.
Synthetic lubricant is one or more in sirasimeyu, VT 18, tung oil, plam oil, Oleum Cocois, Oleum Gossypii semen, tricarboxymethyl propane oleate, pentaerythritol ester, the different monooctyl ester of oleic acid, Witconol 2301, hexanodioic acid dibutyl ester, the Wickenol 155.
Anticorrosive agent is benzotriazole, methyl benzotriazazole, 1H-1 or 2, the 4-triazole.
Inhibitor is DBPC 2,6 ditertiary butyl p cresol or tertiarybutylhydroquinone.
Extreme pressure agent is olefine sulfide, sulfuration Witconol 2301, vulcanized vegetable oil or sulfuration lard.
The present invention has excellent oilness, uses the Bao testing machine test that pauses, crude oil friction co-efficient value≤0.1; Has excellent water separable performance, oily water separation time≤10min (add the 50ml sample in the 50ml water, overturn 10 times); Formula material does not use the hazardous and noxious substances that influences environmental safety and HUMAN HEALTH,, the biological Lethal Dose 50 LD50>=5000mg/kg of product, toxic limit medium dose LC50>=5000mg/m 3, respiratory mucosa stimulates≤1 grade, has reliable safety and sanitation quality.
Below in conjunction with embodiment the present invention is described further.
Embodiment
Embodiment 1:
Following components in weight percentage mixed stirs, high lubricated, high-moisture from the processing of property bearing grinding with ultra essential oil product:
5# paraffin base oil 70%
9# naphthenic base oils 10%
VT 18 5.0%
Oleic acid 3.0%
Tallow base trimethylene diamines 3.0%
Tween-80 2.0%
Tertiarybutylhydroquinone 0.2%
Sulfuration lard 5.8%
Methyl benzotriazazole 1.0%.
Embodiment 2:
A kind of high lubricated, high-moisture, is mixed by following component in percentage by weight with ultra essential oil from the processing of property bearing grinding:
MO 65~90% (example 65%, 75%, 90%)
Polymeric carboxylic 2~5% (example 2%, 3%, 5%)
Organic amine 2~5% (example 2%, 3%, 5%)
Tensio-active agent 1~5% (example 1%, 3%, 5%)
Synthetic lubricant 1~10% (example 1%, 5%, 10%)
Anticorrosive agent 0~5% (example 0%, 3%, 5%)
Extreme pressure agent 0~10% (example 0%, 5%, 10%)
Inhibitor 0~3%.(example 0%, 1%, 3%)
Above-mentioned each component sum is 100%.
MO is one or more the mixture in paraffin base oil, naphthenic base oils, the intermediate base base oil.
Organic carboxyl acid is at least a long-chain carboxylic acid, this sour binary to hexa-atomic multipolymer or its mixture that contains 8~20 carbon atoms.
Organic amine is 1,2-dimethyl propylamine, trolamine, hexanediamine, tri-isopropanolamine, N, N-diethylethanolamine, 2-amino-2-methyl-1-propanol, hexanolactam or tallow base trimethylene diamines.
Tensio-active agent be AEO (5~12), aliphatic alcohol polyethenoxy polyethenoxy ether, Fatty Alcohol(C12-C14 and C12-C18) alcohol amide, aliphatic alcohol polyethenoxy ester (5~12), sulphonate, Lipid acidThe mixture of one or more in glyceryl ester, sapn, the tween.
Synthetic lubricant is one or more in sirasimeyu, VT 18, tung oil, plam oil, Oleum Cocois, Oleum Gossypii semen, tricarboxymethyl propane oleate, pentaerythritol ester, the different monooctyl ester of oleic acid, Witconol 2301, hexanodioic acid dibutyl ester, the Wickenol 155.
Anticorrosive agent is benzotriazole, methyl benzotriazazole, 1H-1 or 2, the 4-triazole.
Inhibitor is DBPC 2,6 ditertiary butyl p cresol or tertiarybutylhydroquinone.
Extreme pressure agent is olefine sulfide, sulfuration Witconol 2301, vulcanized vegetable oil or sulfuration lard.

Claims (9)

1. one kind high lubricated, high-moisture, is characterized in that: be made up of following component in percentage by weight with ultra essential oil from the processing of property bearing grinding:
MO 65~90%
Polymeric carboxylic 2~5%
Organic amine 2~5%
Tensio-active agent 1~5%
Synthetic lubricant 1~10%
Anticorrosive agent 0~5%
Extreme pressure agent 0~10%
Inhibitor 0~3%.
2. height according to claim 1 is lubricated, high-moisture, is characterized in that with ultra essential oil from the processing of property bearing grinding: MO is one or more the mixture in paraffin base oil, naphthenic base oils, the intermediate base base oil.
3. height according to claim 1 is lubricated, high-moisture, is characterized in that with ultra essential oil from the processing of property bearing grinding: organic carboxyl acid is at least a long-chain carboxylic acid, this sour binary to hexa-atomic multipolymer or its mixture that contains 8~20 carbon atoms.
4., high-moisture lubricated according to claim 1,2 or 3 described height from the processing of property bearing grinding with ultra essential oil; It is characterized in that: organic amine is 1; 2-dimethyl propylamine, trolamine, hexanediamine, tri-isopropanolamine, N, N-diethylethanolamine, 2-amino-2-methyl-1-propanol, hexanolactam or tallow base trimethylene diamines.
5., high-moisture lubricated according to claim 1,2 or 3 described height, is characterized in that with ultra essential oil from the processing of property bearing grinding: tensio-active agent be AEO (5~12), aliphatic alcohol polyethenoxy polyethenoxy ether, Fatty Alcohol(C12-C14 and C12-C18) alcohol amide, aliphatic alcohol polyethenoxy ester (5~12), sulphonate, Lipid acidThe mixture of one or more in glyceryl ester, sapn, the tween.
6. lubricated according to claim 1,2 or 3 described height, with ultra essential oil, it is characterized in that: synthetic lubricant is one or more in sirasimeyu, VT 18, tung oil, plam oil, Oleum Cocois, Oleum Gossypii semen, tricarboxymethyl propane oleate, pentaerythritol ester, the different monooctyl ester of oleic acid, Witconol 2301, hexanodioic acid dibutyl ester, the Wickenol 155 to high-moisture from the processing of property bearing grinding.
7. lubricated according to claim 1,2 or 3 described height, with ultra essential oil, it is characterized in that: anticorrosive agent is benzotriazole, methyl benzotriazazole, 1H-1 or 2 to high-moisture, the 4-triazole from the processing of property bearing grinding.
8. lubricated according to claim 1,2 or 3 described height, with ultra essential oil, it is characterized in that: inhibitor is DBPC 2,6 ditertiary butyl p cresol or tertiarybutylhydroquinone to high-moisture from the processing of property bearing grinding.
9., high-moisture lubricated according to claim 1,2 or 3 described height, is characterized in that with ultra essential oil from the processing of property bearing grinding: extreme pressure agent is olefine sulfide, sulfuration Witconol 2301, vulcanized vegetable oil or vulcanizes lard.
CN 201210135535 2012-05-04 2012-05-04 Superfine oil for abrasive machining of high-lubrication and high-water-separability bearing Active CN102660360B (en)

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103981003A (en) * 2014-05-23 2014-08-13 启东尤希路化学工业有限公司 Dual-purpose oil for environmental electromagnetic flaw detection and working procedure rust prevention
CN104342278A (en) * 2014-09-30 2015-02-11 宁波保润石化有限公司 Synthetic grinding fluid and preparation method thereof
CN104560345A (en) * 2014-10-09 2015-04-29 金寨县宏拓机电有限责任公司 Cooling fluid for mechanical cutting
CN104560343A (en) * 2014-10-09 2015-04-29 金寨县宏拓机电有限责任公司 Preparation method of coolant for mechanical cutting
CN106544135A (en) * 2016-11-04 2017-03-29 广西大学 A kind of 400 alloy grinding technique lubricant compositions of Monel
CN107267267A (en) * 2017-07-10 2017-10-20 上海尤希路化学工业有限公司 Anti- double exposure, peace and quiet, environment-friendly type bearing grinding special oil
CN109926874A (en) * 2019-01-25 2019-06-25 芜湖人本轴承有限公司 A kind of processing technology of the plating four-point contact ball Internal and external cycle of surface covering
CN109943404A (en) * 2019-04-24 2019-06-28 上海尤希路化学工业有限公司 High-grade environment-friendly type mirror finish grinding oil

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1548507A (en) * 2003-05-24 2004-11-24 启东尤希路化学工业有限公司 Water insoluble cutting oil
CN102250673A (en) * 2011-06-15 2011-11-23 启东尤希路化学工业有限公司 Environment-friendly emulsion cutting oil with high lubricity and high permeability for metal working

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1548507A (en) * 2003-05-24 2004-11-24 启东尤希路化学工业有限公司 Water insoluble cutting oil
CN102250673A (en) * 2011-06-15 2011-11-23 启东尤希路化学工业有限公司 Environment-friendly emulsion cutting oil with high lubricity and high permeability for metal working

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103981003A (en) * 2014-05-23 2014-08-13 启东尤希路化学工业有限公司 Dual-purpose oil for environmental electromagnetic flaw detection and working procedure rust prevention
CN104342278A (en) * 2014-09-30 2015-02-11 宁波保润石化有限公司 Synthetic grinding fluid and preparation method thereof
CN104560345A (en) * 2014-10-09 2015-04-29 金寨县宏拓机电有限责任公司 Cooling fluid for mechanical cutting
CN104560343A (en) * 2014-10-09 2015-04-29 金寨县宏拓机电有限责任公司 Preparation method of coolant for mechanical cutting
CN106544135A (en) * 2016-11-04 2017-03-29 广西大学 A kind of 400 alloy grinding technique lubricant compositions of Monel
CN107267267A (en) * 2017-07-10 2017-10-20 上海尤希路化学工业有限公司 Anti- double exposure, peace and quiet, environment-friendly type bearing grinding special oil
CN109926874A (en) * 2019-01-25 2019-06-25 芜湖人本轴承有限公司 A kind of processing technology of the plating four-point contact ball Internal and external cycle of surface covering
CN109943404A (en) * 2019-04-24 2019-06-28 上海尤希路化学工业有限公司 High-grade environment-friendly type mirror finish grinding oil

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