CN102618372A - High performance biodegradation type metal machining protection liquid - Google Patents
High performance biodegradation type metal machining protection liquid Download PDFInfo
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- CN102618372A CN102618372A CN201210046980XA CN201210046980A CN102618372A CN 102618372 A CN102618372 A CN 102618372A CN 201210046980X A CN201210046980X A CN 201210046980XA CN 201210046980 A CN201210046980 A CN 201210046980A CN 102618372 A CN102618372 A CN 102618372A
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- protection liquid
- type metal
- high performance
- metal machining
- shaped metal
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- 239000007788 liquid Substances 0.000 title claims abstract description 23
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 23
- 239000002184 metal Substances 0.000 title claims abstract description 23
- 238000006065 biodegradation reaction Methods 0.000 title abstract 8
- 238000003754 machining Methods 0.000 title abstract 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 15
- 150000002148 esters Chemical class 0.000 claims abstract description 14
- 150000001412 amines Chemical class 0.000 claims abstract description 7
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 7
- 239000001301 oxygen Substances 0.000 claims abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 6
- 230000015556 catabolic process Effects 0.000 claims description 13
- 238000006731 degradation reaction Methods 0.000 claims description 13
- 229920002545 silicone oil Polymers 0.000 claims description 13
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 11
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 10
- SJRJJKPEHAURKC-UHFFFAOYSA-N N-Methylmorpholine Chemical compound CN1CCOCC1 SJRJJKPEHAURKC-UHFFFAOYSA-N 0.000 claims description 9
- 239000002253 acid Substances 0.000 claims description 9
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims description 8
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims description 7
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims description 7
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 7
- 239000005642 Oleic acid Substances 0.000 claims description 7
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims description 7
- 239000013543 active substance Substances 0.000 claims description 7
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 7
- 229920000570 polyether Polymers 0.000 claims description 7
- -1 polyoxyethylene Polymers 0.000 claims description 7
- 235000013311 vegetables Nutrition 0.000 claims description 7
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims description 6
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 claims description 6
- 150000001298 alcohols Chemical class 0.000 claims description 6
- BKIMMITUMNQMOS-UHFFFAOYSA-N nonane Chemical compound CCCCCCCCC BKIMMITUMNQMOS-UHFFFAOYSA-N 0.000 claims description 6
- FBUKVWPVBMHYJY-UHFFFAOYSA-N nonanoic acid Chemical compound CCCCCCCCC(O)=O FBUKVWPVBMHYJY-UHFFFAOYSA-N 0.000 claims description 6
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- 229940058020 2-amino-2-methyl-1-propanol Drugs 0.000 claims description 4
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 4
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 4
- SLINHMUFWFWBMU-UHFFFAOYSA-N Triisopropanolamine Chemical compound CC(O)CN(CC(C)O)CC(C)O SLINHMUFWFWBMU-UHFFFAOYSA-N 0.000 claims description 4
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 claims description 4
- 239000012964 benzotriazole Substances 0.000 claims description 4
- LVTYICIALWPMFW-UHFFFAOYSA-N diisopropanolamine Chemical compound CC(O)CNCC(C)O LVTYICIALWPMFW-UHFFFAOYSA-N 0.000 claims description 4
- 229940049964 oleate Drugs 0.000 claims description 4
- 239000001294 propane Substances 0.000 claims description 4
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 4
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 4
- WIHIUTUAHOZVLE-UHFFFAOYSA-N 1,3-diethoxypropan-2-ol Chemical compound CCOCC(O)COCC WIHIUTUAHOZVLE-UHFFFAOYSA-N 0.000 claims description 3
- SNTWKPAKVQFCCF-UHFFFAOYSA-N 2,3-dihydro-1h-triazole Chemical compound N1NC=CN1 SNTWKPAKVQFCCF-UHFFFAOYSA-N 0.000 claims description 3
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 3
- SFAAOBGYWOUHLU-UHFFFAOYSA-N 2-ethylhexyl hexadecanoate Chemical compound CCCCCCCCCCCCCCCC(=O)OCC(CC)CCCC SFAAOBGYWOUHLU-UHFFFAOYSA-N 0.000 claims description 3
- XBPCUCUWBYBCDP-UHFFFAOYSA-N Dicyclohexylamine Chemical compound C1CCCCC1NC1CCCCC1 XBPCUCUWBYBCDP-UHFFFAOYSA-N 0.000 claims description 3
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 3
- OYHQOLUKZRVURQ-HZJYTTRNSA-N Linoleic acid Chemical compound CCCCC\C=C/C\C=C/CCCCCCCC(O)=O OYHQOLUKZRVURQ-HZJYTTRNSA-N 0.000 claims description 3
- 239000005643 Pelargonic acid Substances 0.000 claims description 3
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 3
- 150000001408 amides Chemical class 0.000 claims description 3
- 229910021529 ammonia Inorganic materials 0.000 claims description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 3
- JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 claims description 3
- 125000003354 benzotriazolyl group Chemical group N1N=NC2=C1C=CC=C2* 0.000 claims description 3
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 3
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 3
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims description 3
- 229960004232 linoleic acid Drugs 0.000 claims description 3
- 150000002632 lipids Chemical class 0.000 claims description 3
- 239000000314 lubricant Substances 0.000 claims description 3
- 230000001050 lubricating effect Effects 0.000 claims description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 3
- 229920003216 poly(methylphenylsiloxane) Polymers 0.000 claims description 3
- 150000003918 triazines Chemical class 0.000 claims description 3
- 229960004418 trolamine Drugs 0.000 claims description 3
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims 1
- 231100000111 LD50 Toxicity 0.000 abstract description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract description 6
- 239000003085 diluting agent Substances 0.000 abstract description 5
- 238000010079 rubber tapping Methods 0.000 abstract description 3
- 239000000654 additive Substances 0.000 abstract description 2
- 239000000126 substance Substances 0.000 abstract description 2
- 238000005461 lubrication Methods 0.000 abstract 2
- 239000010773 plant oil Substances 0.000 abstract 2
- 239000002518 antifoaming agent Substances 0.000 abstract 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 abstract 1
- 239000004519 grease Substances 0.000 abstract 1
- 231100000636 lethal dose Toxicity 0.000 abstract 1
- 231100000017 mucous membrane irritation Toxicity 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 239000003755 preservative agent Substances 0.000 abstract 1
- 230000002335 preservative effect Effects 0.000 abstract 1
- 210000002345 respiratory system Anatomy 0.000 abstract 1
- 239000004094 surface-active agent Substances 0.000 abstract 1
- 239000003921 oil Substances 0.000 description 8
- 239000000047 product Substances 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- REIUXOLGHVXAEO-UHFFFAOYSA-N pentadecan-1-ol Chemical compound CCCCCCCCCCCCCCCO REIUXOLGHVXAEO-UHFFFAOYSA-N 0.000 description 2
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 2
- ASFAFOSQXBRFMV-LJQANCHMSA-N 3-n-(2-benzyl-1,3-dihydroxypropan-2-yl)-1-n-[(1r)-1-(4-fluorophenyl)ethyl]-5-[methyl(methylsulfonyl)amino]benzene-1,3-dicarboxamide Chemical compound N([C@H](C)C=1C=CC(F)=CC=1)C(=O)C(C=1)=CC(N(C)S(C)(=O)=O)=CC=1C(=O)NC(CO)(CO)CC1=CC=CC=C1 ASFAFOSQXBRFMV-LJQANCHMSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000002199 base oil Substances 0.000 description 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
- 239000002173 cutting fluid Substances 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000012263 liquid product Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 239000012169 petroleum derived wax Substances 0.000 description 1
- 235000019381 petroleum wax Nutrition 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 210000001533 respiratory mucosa Anatomy 0.000 description 1
- 235000010288 sodium nitrite Nutrition 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Abstract
The invention discloses high performance biodegradation type metal machining protection liquid, which is composed of high polymer carboxylic acid, organic amine, higher alcohol, a surfactant, plant oil or synthetic lubrication grease, pure water, an antifoaming agent and preservative or bacteriacide. The high performance biodegradation type metal machining protection liquid is good in biodegradable performance. A formula of the high performance biodegradation type metal machining protection liquid can be designed by choosing the plant oil or synthetic ester and other additives. Biochemical oxygen demand (BOD) / chemical oxygen demand (COD) of 3.3% of diluent is larger than or equal to 1.0, so that the high performance biodegradation type metal machining protection liquid is excellent in lubrication performance. The frictional factor mu of the 3.3% of diluent is smaller than or equal to 0.03, and tapping torque of the 3.3% of diluent is smaller than or equal to 400N*cm, so that the high performance biodegradation type metal machining protection liquid is safe, hygienic and reliable in quality. The biological median lethal dose LD50 of the high performance biodegradation type metal machining protection liquid is larger than or equal to 5,000mg/kg, the medical lethal concentration LC50 is larger than or equal to 5,000mg/m<3>, respiratory tract mucous membrane irritation is smaller than or equal to 1 level, and the high performance biodegradation type metal machining protection liquid is friendly to human and environment.
Description
Technical field
The present invention relates to a kind of metal processing protection liquid.
Background technology
Traditional metal processing protection liquid is generally all made base oil by lubricity good MO or synthetic hydrocarbon, and composite phosphorus is that extreme pressure agent, rust-preventive agent, tensio-active agent and the blending of other auxiliary agent form.Because MO and synthetic hydrocarbon biodegradability are relatively poor, the waste liquid of discharging is trapped in the water and soil ground serious environment pollution for a long time; Contain toxic substances such as oxidized petroleum wax, Sodium Nitrite in the composite auxiliary agent, the harm health of human body.Domestic in recent years many producers release Environmental Protection Cutting Fluid product (but not seeing the examining report that carries weight) one after another, but because lubricity is unsatisfactory, and frictional coefficient is big, the tapping torque value is high, and are not good by market.
Summary of the invention
The object of the present invention is to provide that a kind of biodegradability is good, the oilness permeate well, to the high-performance biological degradation shaped metal processing protection liquid of human and environment safety.
Technical solution of the present invention is:
A kind of high-performance biological degradation shaped metal processing protection liquid is characterized in that: be made up of following component in percentage by weight:
Polymeric carboxylic 5～20%
Organic amine 5～30%
Higher alcohols 1～10%
Tensio-active agent 1～20%
Vegetables oil or synthetic lubricating ester 10～30%
Pure water 15～45%
Skimmer 0～0.5%
Sanitas or sterilant 0～5%.
Polymeric carboxylic is sad, pelargonic acid, sebacic acid, hexanodioic acid, nonane diacid, bay diacid, C
8-C
18Among lipid acid, oleic acid, linolic acid, the triazines multi-carboxylic acid compounds one or more.
Organic amine is one or more in Monoethanolamine MEA BASF, diethylolamine, trolamine, a Yi Bingchunan, HSDB 338, tri-isopropanolamine, morpholine, dicyclohexyl amine, N-methylmorpholine, 2-amino-2-methyl-1-propanol, the diethylin ethanol.
Higher alcohols is C
8～C
16Straight-chain monohydric alcohol or isomery monohydroxy-alcohol.
Tensio-active agent is AEO (5～12), aliphatic alcohol polyethenoxy polyethenoxy ether, polyoxyethylene poly-oxygen propylene aether (5～12), alkylol amide, aliphatic alcohol polyethenoxy ester (5～12) or sulphonate.
Vegetables oil or synthetic lubricant are one or more in sirasimeyu, VT 18, plam oil, Oleum Cocois, suet, tricarboxymethyl propane oleate, pentaerythritol ester, the different monooctyl ester of oleic acid, hexanodioic acid dibutyl ester, the Wickenol 155.
Skimmer is dimethyl silicone oil, diethyl silicone oil, methyl phenyl silicone oil, ammonia alkyl silicone oil, polyether silicone oil or polyethers.
Anticorrosive agent is benzotriazole, methyl benzotriazazole, 1H-1 or 2, the 4-triazole.
Biodegradability of the present invention is good.Select good vegetables oil of biodegradability or synthetic ester and other additive deisgn product prescription for use.3.3% diluent BOD (BOD)/COD (chemical oxygen demand) >=1.0; Lubricity is good.During 3.3% diluent, its coefficientoffriction≤0.03, tapping torque value≤400N.cm; The safety and sanitation reliable in quality.The biological Lethal Dose 50 LD50>=5000mg/kg of product, toxic limit medium dose LC50>=5000mg/m
3, respiratory mucosa stimulates≤1 grade, and is friendly to human and environment.
Below in conjunction with embodiment the present invention is described further.
Embodiment
Embodiment 1:
Weight components is mixed stirring under certain condition, gets high-performance biological degradation shaped metal processing protection liquid product:
Bay diacid 10%
Oleic acid 5%
2-amino-2-methyl-1-propanol 11%
HSDB 338 6%
Tri-isopropanolamine 6%
Alkylol amide 4%
Polyoxyethylene poly-oxygen propylene aether (12) 5%
Pure water 25.4%
Pentadecanol 2%
Tricarboxymethyl propane oleate 15%
Plam oil 10%
Polyether silicone oil 0.5%
Benzotriazole 0.1%.
Embodiment 2:
A kind of high-performance biological degradation shaped metal processing protection liquid, form by following component in percentage by weight:
Polymeric carboxylic 5～20% (example 5%, 13%, 20%)
Organic amine 5～30% (example 5%, 20%, 30%)
Higher alcohols 1～10% (example 1%, 5%, 10%)
Tensio-active agent 1～20% (example 1%, 13%, 20%)
Vegetables oil or synthetic lubricating ester 10～30% (example 10%, 20%, 30%)
Pure water 15～45% (example 15%, 30%, 45%)
Skimmer 0～0.5% (example 0%, 0.3%, 0.5%)
Sanitas or sterilant 0～5% (example 0%, 0.3%, 0.5%).
Polymeric carboxylic is sad, pelargonic acid, sebacic acid, hexanodioic acid, nonane diacid, bay diacid, C
8-C
18Among lipid acid, oleic acid, linolic acid, the triazines multi-carboxylic acid compounds one or more.
Organic amine is one or more in Monoethanolamine MEA BASF, diethylolamine, trolamine, a Yi Bingchunan, HSDB 338, tri-isopropanolamine, morpholine, dicyclohexyl amine, N-methylmorpholine, 2-amino-2-methyl-1-propanol, the diethylin ethanol.
Higher alcohols is C
8～C
16Straight-chain monohydric alcohol or isomery monohydroxy-alcohol, like C
8～C
10Straight chain alcohol, C
12～C
13Straight chain alcohol or isomery alcohol, C
14～C
15Straight chain alcohol or isomery alcohol etc.
Tensio-active agent is AEO (5～12), aliphatic alcohol polyethenoxy polyethenoxy ether, polyoxyethylene poly-oxygen propylene aether (5～12), alkylol amide, aliphatic alcohol polyethenoxy ester (5～12) or sulphonate.
Vegetables oil or synthetic lubricant are one or more in sirasimeyu, VT 18, plam oil, Oleum Cocois, suet, tricarboxymethyl propane oleate, pentaerythritol ester, the different monooctyl ester of oleic acid, hexanodioic acid dibutyl ester, the Wickenol 155.
Skimmer is dimethyl silicone oil, diethyl silicone oil, methyl phenyl silicone oil, ammonia alkyl silicone oil, polyether silicone oil or polyethers.
Anticorrosive agent is benzotriazole, methyl benzotriazazole, 1H-1 or 2, the 4-triazole.
Claims (8)
1. liquid is protected in a high-performance biological degradation shaped metal processing, it is characterized in that: be made up of following component in percentage by weight:
Polymeric carboxylic 5～20%
Organic amine 5～30%
Higher alcohols 1～10%
Tensio-active agent 1～20%
Vegetables oil or synthetic lubricating ester 10～30%
Pure water 15～45%
Skimmer 0～0.5%
Sanitas or sterilant 0～5%.
2. high-performance biological degradation shaped metal according to claim 1 processing protection liquid is characterized in that: polymeric carboxylic is sad, pelargonic acid, sebacic acid, hexanodioic acid, nonane diacid, bay diacid, C
8-C
18Among lipid acid, oleic acid, linolic acid, the triazines multi-carboxylic acid compounds one or more.
3. high-performance biological degradation shaped metal processing protection liquid according to claim 1, it is characterized in that: organic amine is one or more in Monoethanolamine MEA BASF, diethylolamine, trolamine, a Yi Bingchunan, HSDB 338, tri-isopropanolamine, morpholine, dicyclohexyl amine, N-methylmorpholine, 2-amino-2-methyl-1-propanol, the diethylin ethanol.
4. high-performance biological degradation shaped metal processing protection liquid according to claim 1 and 2, it is characterized in that: higher alcohols is C
8～C
16Straight-chain monohydric alcohol or isomery monohydroxy-alcohol.
5. high-performance biological degradation shaped metal processing protection liquid according to claim 1 and 2, it is characterized in that: tensio-active agent is AEO (5～12), aliphatic alcohol polyethenoxy polyethenoxy ether, polyoxyethylene poly-oxygen propylene aether (5～12), alkylol amide, aliphatic alcohol polyethenoxy ester (5～12) or sulphonate.
6. high-performance biological degradation shaped metal processing protection liquid according to claim 1 and 2, it is characterized in that: vegetables oil or synthetic lubricant are one or more in sirasimeyu, VT 18, plam oil, Oleum Cocois, suet, tricarboxymethyl propane oleate, pentaerythritol ester, the different monooctyl ester of oleic acid, hexanodioic acid dibutyl ester, the Wickenol 155.
7. high-performance biological degradation shaped metal processing protection liquid according to claim 1 and 2, it is characterized in that: skimmer is dimethyl silicone oil, diethyl silicone oil, methyl phenyl silicone oil, ammonia alkyl silicone oil, polyether silicone oil or polyethers.
8. high-performance biological degradation shaped metal processing protection liquid according to claim 1 and 2, it is characterized in that: anticorrosive agent is benzotriazole, methyl benzotriazazole, 1H-1 or 2, the 4-triazole.
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|---|---|---|---|
| CN201210046980XA CN102618372A (en) | 2012-02-28 | 2012-02-28 | High performance biodegradation type metal machining protection liquid |
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|---|---|---|---|
| CN201210046980XA CN102618372A (en) | 2012-02-28 | 2012-02-28 | High performance biodegradation type metal machining protection liquid |
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Family
ID=46558586
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| CN106398819A (en) * | 2016-08-30 | 2017-02-15 | 宝捷润滑油镇江有限公司 | Biodegradable lubricating oil |
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| CN113549486A (en) * | 2021-07-26 | 2021-10-26 | 富兰克科技（深圳）股份有限公司 | Application and preparation method of composition |
| CN116751622A (en) * | 2023-06-15 | 2023-09-15 | 泰伦特生物工程股份有限公司 | Low-odor high-rust-resistance corrosion-inhibition cutting fluid and preparation method thereof |
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| CN113549486A (en) * | 2021-07-26 | 2021-10-26 | 富兰克科技（深圳）股份有限公司 | Application and preparation method of composition |
| CN116751622A (en) * | 2023-06-15 | 2023-09-15 | 泰伦特生物工程股份有限公司 | Low-odor high-rust-resistance corrosion-inhibition cutting fluid and preparation method thereof |
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