CN102660368A - Biodegradable hard water-resistant water-soluble metalworking liquid - Google Patents
Biodegradable hard water-resistant water-soluble metalworking liquid Download PDFInfo
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- CN102660368A CN102660368A CN2012101355365A CN201210135536A CN102660368A CN 102660368 A CN102660368 A CN 102660368A CN 2012101355365 A CN2012101355365 A CN 2012101355365A CN 201210135536 A CN201210135536 A CN 201210135536A CN 102660368 A CN102660368 A CN 102660368A
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- Prior art keywords
- water
- hard water
- acid
- soluble cutting
- type hard
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- 239000008233 hard water Substances 0.000 title claims abstract description 23
- 239000007788 liquid Substances 0.000 title abstract description 6
- 238000005555 metalworking Methods 0.000 title abstract description 6
- 150000001412 amines Chemical class 0.000 claims abstract description 7
- 239000000314 lubricant Substances 0.000 claims abstract description 7
- 150000007524 organic acids Chemical class 0.000 claims abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 24
- -1 sulfamic acid compound Chemical class 0.000 claims description 21
- 238000005520 cutting process Methods 0.000 claims description 14
- 238000006065 biodegradation reaction Methods 0.000 claims description 13
- SJRJJKPEHAURKC-UHFFFAOYSA-N N-Methylmorpholine Chemical compound CN1CCOCC1 SJRJJKPEHAURKC-UHFFFAOYSA-N 0.000 claims description 9
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical group C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims description 7
- YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical compound C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 claims description 6
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 claims description 6
- 229920002545 silicone oil Polymers 0.000 claims description 6
- 239000013543 active substance Substances 0.000 claims description 5
- 239000000839 emulsion Substances 0.000 claims description 5
- BFSVOASYOCHEOV-UHFFFAOYSA-N 2-diethylaminoethanol Chemical compound CCN(CC)CCO BFSVOASYOCHEOV-UHFFFAOYSA-N 0.000 claims description 4
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 4
- 229920005862 polyol Polymers 0.000 claims description 4
- 229920001296 polysiloxane Polymers 0.000 claims description 4
- 229960004418 trolamine Drugs 0.000 claims description 4
- AYRBHTOSHJHALD-UHFFFAOYSA-N 1-amino-2-methylpropan-1-ol Chemical compound CC(C)C(N)O AYRBHTOSHJHALD-UHFFFAOYSA-N 0.000 claims description 3
- MIJDSYMOBYNHOT-UHFFFAOYSA-N 2-(ethylamino)ethanol Chemical compound CCNCCO MIJDSYMOBYNHOT-UHFFFAOYSA-N 0.000 claims description 3
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical group NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 3
- OTLNPYWUJOZPPA-UHFFFAOYSA-N 4-nitrobenzoic acid Chemical compound OC(=O)C1=CC=C([N+]([O-])=O)C=C1 OTLNPYWUJOZPPA-UHFFFAOYSA-N 0.000 claims description 3
- KDVYCTOWXSLNNI-UHFFFAOYSA-N 4-t-Butylbenzoic acid Chemical compound CC(C)(C)C1=CC=C(C(O)=O)C=C1 KDVYCTOWXSLNNI-UHFFFAOYSA-N 0.000 claims description 3
- XBPCUCUWBYBCDP-UHFFFAOYSA-N Dicyclohexylamine Chemical compound C1CCCCC1NC1CCCCC1 XBPCUCUWBYBCDP-UHFFFAOYSA-N 0.000 claims description 3
- SLINHMUFWFWBMU-UHFFFAOYSA-N Triisopropanolamine Chemical compound CC(O)CN(CC(C)O)CC(C)O SLINHMUFWFWBMU-UHFFFAOYSA-N 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 3
- 235000011037 adipic acid Nutrition 0.000 claims description 3
- 239000001361 adipic acid Substances 0.000 claims description 3
- 150000001408 amides Chemical class 0.000 claims description 3
- JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 claims description 3
- 239000012964 benzotriazole Substances 0.000 claims description 3
- 125000003354 benzotriazolyl group Chemical group N1N=NC2=C1C=CC=C2* 0.000 claims description 3
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 3
- LVTYICIALWPMFW-UHFFFAOYSA-N diisopropanolamine Chemical compound CC(O)CNCC(C)O LVTYICIALWPMFW-UHFFFAOYSA-N 0.000 claims description 3
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims description 3
- 150000007520 diprotic acids Chemical class 0.000 claims description 3
- WNLRTRBMVRJNCN-UHFFFAOYSA-N hexanedioic acid Natural products OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 claims description 3
- 238000005260 corrosion Methods 0.000 abstract description 3
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 abstract description 2
- 239000004094 surface-active agent Substances 0.000 abstract description 2
- 230000007797 corrosion Effects 0.000 abstract 2
- 239000013530 defoamer Substances 0.000 abstract 1
- 239000003112 inhibitor Substances 0.000 abstract 1
- 230000002265 prevention Effects 0.000 abstract 1
- 239000000047 product Substances 0.000 description 12
- 231100000111 LD50 Toxicity 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000003085 diluting agent Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 238000010079 rubber tapping Methods 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 241000522254 Cassia Species 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 231100001261 hazardous Toxicity 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 239000012263 liquid product Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 230000001473 noxious effect Effects 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 210000001533 respiratory mucosa Anatomy 0.000 description 1
- WBHHMMIMDMUBKC-QJWNTBNXSA-N ricinoleic acid Chemical compound CCCCCC[C@@H](O)C\C=C/CCCCCCCC(O)=O WBHHMMIMDMUBKC-QJWNTBNXSA-N 0.000 description 1
- 229960003656 ricinoleic acid Drugs 0.000 description 1
- FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 235000010288 sodium nitrite Nutrition 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Landscapes
- Lubricants (AREA)
Abstract
The invention discloses biodegradable hard water-resistant water-soluble metalworking liquid. The biodegradable hard water-resistant water-soluble metalworking liquid consists of organic acid, organic amine, corrosion inhibitor, synthetic lubricant, surfactant, water and defoamer. The biodegradable hard water-resistant water-soluble metalworking liquid is high in biodegradability, hard water resistance, lubricity, rust prevention property and corrosion resistance and long in service life and is friendly to people and environment.
Description
Technical field
The present invention relates to a kind of biodegradation type hard water resistant water-soluble cutting solution.
Background technology
For adapting to the fast development of China's mechanical workout industry; Satisfy user's request for utilization better; Over past ten years, the water-soluble metalworking liquid product that the metal processing that domestic manufacturer produces is used, not only lubricity, anti-rust and anti-corrosion, recycle performance index such as life-span and obtained remarkable lifting; And the hard water resistant water-soluble cutting solution product that combines national conditions to research and develop; Under 7000mg/l hardness condition of water quality, use; There are not the oil of analysing, graining phenomenon yet; But owing to multiple reasons such as technology, technology, understanding, the hard water resistant water-soluble cutting solution product of domestic production at present also exists two big drawbacks to be badly in need of solving.The one, the biodegradable performance is poor, and through test, its BOD (biological oxygen demand)/COD (COD) generally about 0.2, causes waste liquid to be difficult for handling serious environment pollution; The 2nd, contain hazardous and noxious substances such as Sodium Nitrite in the prescription, jeopardize HUMAN HEALTH.
Summary of the invention
The object of the present invention is to provide a kind of biological degradability, stability in hard water, the biodegradation type stability in hard water water-soluble metalworking liquid friendly to human and environment.
Technical solution of the present invention is:
A kind of biodegradation type hard water resistant water-soluble cutting solution is characterized in that: be made up of following component in percentage by weight:
Organic acid 5-25%
Organic amine 10-25%
Inhibiter 1-5%
Synthetic lubricant 20-40%
Tensio-active agent 5-15%
Water 5-15%
Skimmer 0.1 ~ 0.8%.
Organic acid is C
6-C
14Straight chain diprotic acid, C
8-C
18Lipid acid, p-tert-butyl benzoic acid, p-Nitrobenzenecarboxylic acid or sulfamic acid compound.
Organic amine is Monoethanolamine MEA BASF, diethylolamine, trolamine, a Yi Bingchunan, HSDB 338, tri-isopropanolamine, morpholine, dicyclohexyl amine, N-methylmorpholine, the amino 2-methylpropanol of 2-or diethylaminoethanol.
Inhibiter is benzotriazole, methyl benzotriazazole or 2-mercaptobenzothiazole.
Synthetic lubricant is trihydroxymethylpropanyl ester, pentaerythritol ester, neopentyl polyol ester or adipic acid ester.
Tensio-active agent is aliphatic alcohol polyethenoxy (5-12) ether, alkylphenol-polyethenoxy (5-12) ether, aliphatic alcohol polyethenoxy polyethenoxy ether, alkylol amide, alcohol ether carboxylate or sulphonate.
Skimmer is silicone emulsion, methyl-silicone oil or dimethyl silicone oil.
This product of the present invention has excellent biodegradability.Select the good formula material preparation of biological degradability for use; The biological degradability of product is greatly improved; 3.3% diluent BOD (biological oxygen demand)/COD (COD) >=1.2, and the general emulsion of the lubricity of the product of processing (tapping moment of torsion 5% 470 Ncm) (tapping moment of torsion 5% 510 Ncm) has also had large increase.This product has superpower stability in hard water ability.Select for use stability in hard water to prepare with the strong formula material of lime soap dispersing power, product 3.3% diluent uses under 9000mg/l hardness condition of water quality, no layering, analyses oil, graining.Product recycle life-span >=3 year.This product has reliable safety and sanitation performance.The formula for a product raw material does not use and jeopardizes HUMAN HEALTH and environmental safety objectionable impurities.The biological Lethal Dose 50 LD50 (mg/kg)>=5000 of product, toxic limit medium dose LC50 (mg/m
3)>=5000, respiratory mucosa stimulates≤1 grade.
Below in conjunction with embodiment the present invention is described further.
Embodiment
Embodiment 1:
The component of certainweight per-cent is mixed stirring, gets biodegradation type hard water resistant water-soluble cutting solution product:
Chinese cassia tree diacid 3%
Sebacic acid 3%
Oleic acid 4%
Ricinolic acid 5%
Trolamine 10%
One Yi Bingchunan 6%
Diethylaminoethanol 5%
Trihydroxymethylpropanyl ester 30%
Neopentyl polyol ester 10%
Aliphatic alcohol polyethenoxy (9) ether 8%
Alcohol ether carboxylate 3%
Methyl benzotriazazole 0.5%
Silicone emulsion 0.5%
Water 12%.
Embodiment 2:
A kind of biodegradation type hard water resistant water-soluble cutting solution is mixed by following component in percentage by weight:
Organic acid 5-25% (example 5%, 15%, 25%)
Organic amine 10-25% (example 10%, 15%, 25%)
Inhibiter 1-5% (example 1%, 3%, 5%)
Synthetic lubricant 20-40% (example 20%, 30%, 40%)
Novel surfactant 5-15% (example 5%, 10%, 15%)
Water 5-15% (example 5%, 10%, 15%)
Skimmer 0.1 ~ 0.8% (example 0.1%, 0.5%, 0.8%).
Above-mentioned each amounts of components sum is 100%.
Organic acid is C
6-C
14Straight chain diprotic acid, C
8-C
18Lipid acid, p-tert-butyl benzoic acid, p-Nitrobenzenecarboxylic acid or sulfamic acid compound.
Organic amine is Monoethanolamine MEA BASF, diethylolamine, trolamine, a Yi Bingchunan, HSDB 338, tri-isopropanolamine, morpholine, dicyclohexyl amine, N-methylmorpholine, the amino 2-methylpropanol of 2-or diethylaminoethanol.
Inhibiter is benzotriazole, methyl benzotriazazole or 2-mercaptobenzothiazole.
Synthetic lubricant is trihydroxymethylpropanyl ester, pentaerythritol ester, neopentyl polyol ester or adipic acid ester.
Tensio-active agent is aliphatic alcohol polyethenoxy (5-12) ether, alkylphenol-polyethenoxy (5-12) ether, aliphatic alcohol polyethenoxy polyethenoxy ether, alkylol amide, alcohol ether carboxylate or sulphonate.
Skimmer is silicone emulsion, methyl-silicone oil or dimethyl silicone oil.
Claims (7)
1. biodegradation type hard water resistant water-soluble cutting solution is characterized in that: be made up of following component in percentage by weight:
Organic acid 5-25%
Organic amine 10-25%
Inhibiter 1-5%
Synthetic lubricant 20-40%
Tensio-active agent 5-15%
Water 5-15%
Skimmer 0.1 ~ 0.8%.
2. biodegradation type hard water resistant water-soluble cutting solution according to claim 1 is characterized in that: organic acid is C
6-C
14Straight chain diprotic acid, C
8-C
18Lipid acid, p-tert-butyl benzoic acid, p-Nitrobenzenecarboxylic acid or sulfamic acid compound.
3. biodegradation type hard water resistant water-soluble cutting solution according to claim 1 is characterized in that: organic amine is Monoethanolamine MEA BASF, diethylolamine, trolamine, a Yi Bingchunan, HSDB 338, tri-isopropanolamine, morpholine, dicyclohexyl amine, N-methylmorpholine, the amino 2-methylpropanol of 2-or diethylaminoethanol.
4. according to claim 1,2 or 3 described biodegradation type hard water resistant water-soluble cutting solutions, it is characterized in that: inhibiter is benzotriazole, methyl benzotriazazole or 2-mercaptobenzothiazole.
5. according to claim 1,2 or 3 described biodegradation type hard water resistant water-soluble cutting solutions, it is characterized in that: synthetic lubricant is trihydroxymethylpropanyl ester, pentaerythritol ester, neopentyl polyol ester or adipic acid ester.
6. according to claim 1,2 or 3 described biodegradation type hard water resistant water-soluble cutting solutions, it is characterized in that: tensio-active agent is aliphatic alcohol polyethenoxy (5-12) ether, alkylphenol-polyethenoxy (5-12) ether, aliphatic alcohol polyethenoxy polyethenoxy ether, alkylol amide, alcohol ether carboxylate or sulphonate.
7. according to claim 1,2 or 3 described biodegradation type hard water resistant water-soluble cutting solutions, it is characterized in that: skimmer is silicone emulsion, methyl-silicone oil or dimethyl silicone oil.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012101355365A CN102660368A (en) | 2012-05-04 | 2012-05-04 | Biodegradable hard water-resistant water-soluble metalworking liquid |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012101355365A CN102660368A (en) | 2012-05-04 | 2012-05-04 | Biodegradable hard water-resistant water-soluble metalworking liquid |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102660368A true CN102660368A (en) | 2012-09-12 |
Family
ID=46769952
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2012101355365A Pending CN102660368A (en) | 2012-05-04 | 2012-05-04 | Biodegradable hard water-resistant water-soluble metalworking liquid |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102660368A (en) |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104293465A (en) * | 2014-09-26 | 2015-01-21 | 青岛佰众化工技术有限公司 | Environment-friendly metal cutting fluid and preparation method thereof |
| CN104312709A (en) * | 2014-09-25 | 2015-01-28 | 青岛佰众化工技术有限公司 | Environmentally-friendly metal processing solution and preparation method thereof |
| CN104673465A (en) * | 2013-11-28 | 2015-06-03 | 深圳市富兰克科技有限公司 | Water-soluble cutting fluid replacing stainless steel cutting oil |
| CN104762127A (en) * | 2015-03-18 | 2015-07-08 | 启东尤希路化学工业有限公司 | Nano aqueous completely-synthetic environmental-friendly metal working fluid |
| CN105296126A (en) * | 2015-12-02 | 2016-02-03 | 苏州捷德瑞精密机械有限公司 | Environment-friendly water-based antirust cutting fluid and preparation method thereof |
| CN105647633A (en) * | 2015-12-28 | 2016-06-08 | 上海应用技术学院 | Diester-type semisynthetic cutting fluid with high lubrication and high hard water resistance and preparation method thereof |
| CN107011977A (en) * | 2017-04-18 | 2017-08-04 | 济南大学 | A kind of cutting fluid and preparation method thereof |
| CN107418660A (en) * | 2017-09-07 | 2017-12-01 | 苏州浩焱精密模具有限公司 | A kind of emulsion cutting fluid and preparation method thereof |
| CN107629855A (en) * | 2016-07-18 | 2018-01-26 | 天津市澳路浦润滑科技股份有限公司 | A kind of water-soluble metalworking liquid |
| CN109321327A (en) * | 2018-09-19 | 2019-02-12 | 煤炭科学技术研究院有限公司 | A kind of high-efficiency lubricating additive for water-soluble hydraulic support assembly rouge |
| CN114369495A (en) * | 2021-12-30 | 2022-04-19 | 广东红日星实业有限公司 | Cutting fluid and preparation method and application thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102250676A (en) * | 2011-06-15 | 2011-11-23 | 启东尤希路化学工业有限公司 | High-performance environmentally-friendly semisynthetic water-soluble metal working fluid |
-
2012
- 2012-05-04 CN CN2012101355365A patent/CN102660368A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102250676A (en) * | 2011-06-15 | 2011-11-23 | 启东尤希路化学工业有限公司 | High-performance environmentally-friendly semisynthetic water-soluble metal working fluid |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104673465A (en) * | 2013-11-28 | 2015-06-03 | 深圳市富兰克科技有限公司 | Water-soluble cutting fluid replacing stainless steel cutting oil |
| CN104312709A (en) * | 2014-09-25 | 2015-01-28 | 青岛佰众化工技术有限公司 | Environmentally-friendly metal processing solution and preparation method thereof |
| CN104293465A (en) * | 2014-09-26 | 2015-01-21 | 青岛佰众化工技术有限公司 | Environment-friendly metal cutting fluid and preparation method thereof |
| CN104762127A (en) * | 2015-03-18 | 2015-07-08 | 启东尤希路化学工业有限公司 | Nano aqueous completely-synthetic environmental-friendly metal working fluid |
| CN105296126A (en) * | 2015-12-02 | 2016-02-03 | 苏州捷德瑞精密机械有限公司 | Environment-friendly water-based antirust cutting fluid and preparation method thereof |
| CN105647633A (en) * | 2015-12-28 | 2016-06-08 | 上海应用技术学院 | Diester-type semisynthetic cutting fluid with high lubrication and high hard water resistance and preparation method thereof |
| CN107629855A (en) * | 2016-07-18 | 2018-01-26 | 天津市澳路浦润滑科技股份有限公司 | A kind of water-soluble metalworking liquid |
| CN107011977A (en) * | 2017-04-18 | 2017-08-04 | 济南大学 | A kind of cutting fluid and preparation method thereof |
| CN107418660A (en) * | 2017-09-07 | 2017-12-01 | 苏州浩焱精密模具有限公司 | A kind of emulsion cutting fluid and preparation method thereof |
| CN109321327A (en) * | 2018-09-19 | 2019-02-12 | 煤炭科学技术研究院有限公司 | A kind of high-efficiency lubricating additive for water-soluble hydraulic support assembly rouge |
| CN114369495A (en) * | 2021-12-30 | 2022-04-19 | 广东红日星实业有限公司 | Cutting fluid and preparation method and application thereof |
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Application publication date: 20120912 |