CN106118834B - A kind of aluminum alloy cutting fluid with long service life and preparation method thereof - Google Patents

A kind of aluminum alloy cutting fluid with long service life and preparation method thereof Download PDF

Info

Publication number
CN106118834B
CN106118834B CN201610456793.7A CN201610456793A CN106118834B CN 106118834 B CN106118834 B CN 106118834B CN 201610456793 A CN201610456793 A CN 201610456793A CN 106118834 B CN106118834 B CN 106118834B
Authority
CN
China
Prior art keywords
cutting fluid
agent
weight
service life
extreme pressure
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201610456793.7A
Other languages
Chinese (zh)
Other versions
CN106118834A (en
Inventor
雷海
李清华
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dongguan Keze Lubricant Co
Original Assignee
Dongguan Keze Lubricant Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dongguan Keze Lubricant Co filed Critical Dongguan Keze Lubricant Co
Priority to CN201610456793.7A priority Critical patent/CN106118834B/en
Publication of CN106118834A publication Critical patent/CN106118834A/en
Application granted granted Critical
Publication of CN106118834B publication Critical patent/CN106118834B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M173/00—Lubricating compositions containing more than 10% water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/08—Inorganic acids or salts thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/106—Naphthenic fractions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/16—Paraffin waxes; Petrolatum, e.g. slack wax
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/04—Ethers; Acetals; Ortho-esters; Ortho-carbonates
    • C10M2207/046—Hydroxy ethers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/14—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/141—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings monocarboxylic
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/14—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/142—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings polycarboxylic
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/18—Tall oil acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/109—Polyethers, i.e. containing di- or higher polyoxyalkylene groups esterified
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/08—Amides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/10—Amides of carbonic or haloformic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/225—Heterocyclic nitrogen compounds the rings containing both nitrogen and oxygen
    • C10M2215/226—Morpholines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/06—Thio-acids; Thiocyanates; Derivatives thereof
    • C10M2219/062—Thio-acids; Thiocyanates; Derivatives thereof having carbon-to-sulfur double bonds
    • C10M2219/066—Thiocarbamic type compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/10—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
    • C10M2219/104—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring containing sulfur and carbon with nitrogen or oxygen in the ring
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/06—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having phosphorus-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
    • C10M2227/02—Esters of silicic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
    • C10M2227/06—Organic compounds derived from inorganic acids or metal salts
    • C10M2227/061—Esters derived from boron
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/02—Unspecified siloxanes; Silicones
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
    • C10N2020/01—Physico-chemical properties
    • C10N2020/085—Non-volatile compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/16—Antiseptic; (micro) biocidal or bactericidal
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/244—Metal working of specific metals
    • C10N2040/245—Soft metals, e.g. aluminum

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

The present invention relates to metalworking fluid fields, and in particular to a kind of aluminum alloy cutting fluid with long service life and preparation method thereof.The semi-synthetic cutting fluid of the present invention is made of 10%-30% mineral oil, 5%-15% hydramine, 5%-12% emulsifier, 3%-8% antirust agent, 3%-10% lubricant, 1%-4% corrosion inhibiter, 1%-4% extreme pressure agent, 0.5%-1% defoaming agent, 1%-3% fungicide, inventive formulation has abandoned traditional monoethanolamine, diethanol amine, triethanolamine as pH adjusting agent, and by distinguishingly compounding mode, make cutting fluid that there is better stability, while reducing cost.Secondly, the present invention is also adjusted by the dosage of each raw material, the dosage of extreme pressure agent is reduced, and the effect for the anti-corrosion lubrication for keeping cutting fluid excellent, it can be used for a long time, the period of the primary cutting fluid of the invention of replacement is 1 year or so, environmentally friendly, human body damage is minimum.

Description

A kind of aluminum alloy cutting fluid with long service life and preparation method thereof
Technical field
The present invention relates to metalworking fluid fields, and in particular to a kind of aluminum alloy cutting fluid with long service life and its preparation Method.
Background technique
In the prior art, aluminium alloy density is low, but intensity is relatively high, and plasticity is good, can be processed into various profiles, has excellent Thermal conductivity and preferable corrosion resistance, purposes industrially is very extensive, usage amount is only second to steel, but aluminium alloy The problems such as chemical activity is relatively strong, quality is very soft, and viscosity is strong, and viscous knife, discoloration are easy to appear in processing, therefore processed for aluminium alloy The demand of dedicated cutting fluid is also growing.
Metalworking fluid service life always is emphasis concerned by people, needs that list is added in traditional metalworking fluid The hydramine such as ethanol amine, triethanolamine substance extends the service life of cutting fluid, but aluminium burn into can also be easy to cause to become simultaneously The bad phenomenons such as color, and those hydramine substances have volatility, have serious irritation to eyes and skin, seriously endanger production The health of worker.
The patent of invention that number of patent application is 201210444791.8 discloses a kind of semi-synthetic cutting fluid of aluminium alloy, this is specially Sharp product has certain cutting protective effect, however it still uses traditional monoethanolamine, diethanol amine, triethanolamine, Still there is very big limitation on service life.Secondly, additionally using a large amount of chlorinated paraffins, chlorinated paraffin is as extreme pressure agent Principle is that the fracture of C-Cl key occurs under high temperature, and wherein the Fe element in Cl and metal friction face reacts the FeCl3 of generation It is one layer of solid lubricant film that coefficient of friction is small, shear strength is low, resistance to extreme pressure can be high, to have the function that anti-corrosion lubricates. However its there are two big disadvantages: 1, its effect is limited to alfer；2, it is easy to produce free chloride ion, and chloride ion is to metal With stronger corrosiveness.Although chlorinated paraffin is quality-high and inexpensive, since processing chlorination waste liquid is related to environmental pollution and poison Property problem, therefore from the eighties in 19th century, Europe has gradually reduced use of the chlorinated paraffin in machining of metals liquid, It is especially German, it is being forbidden to use chlorinated paraffin or chloride containing wax additive 20th century.
Therefore, develop that a kind of Corrosion Protection is good and the aluminum alloy cutting fluid of function admirable with long service life has been worked as It is engaged in anxious.
Summary of the invention
The purpose of the present invention is be directed to above-mentioned deficiency in the prior art, provide a kind of Corrosion Protection it is good and use the longevity Order the long aluminum alloy cutting fluid of function admirable and preparation method thereof.
The purpose of the present invention is achieved through the following technical solutions:
A kind of aluminum alloy cutting fluid with long service life, comprises the following raw materials by weight percent:
Mineral oil 10%-30%
Hydramine 5%-15%
Emulsifier 5%-12%
Antirust agent 3%-8%
Lubricant 3%-10%
Corrosion inhibiter 1%-4%
Extreme pressure agent 1%-4%
Defoaming agent 0.5%-1%
Fungicide 1%-3%
Surplus is water；
Wherein the hydramine is diglycolamine, N methyldiethanol amine, 2-amino-2-methyl-1-propanol and diisopropanol At least one of amine.Preferably, the hydramine is by diglycolamine, N methyldiethanol amine, 2-amino-2-methyl-1-propanol At least one of compounded with diisopropanolamine (DIPA).Diglycolamine to cobalt metal dissolving well below other amine, to aluminum metal Stain corrosion is low, to extend cutting element service life；It is N methyldiethanol amine, 2-amino-2-methyl-1-propanol, two different Propanolamine can play inhibition, emulsification, adjust the effects of pH.Inventive formulation has abandoned traditional monoethanolamine, diethanol amine, three Ethanol amine makes cutting fluid have better stability as pH adjusting agent, and by distinguishingly compounding mode, at the same reduce at This.Secondly, the present invention is also adjusted by the dosage of each raw material, the dosage of extreme pressure agent is reduced, and keeps cutting fluid is excellent to prevent The effect of corruption lubrication.
Wherein, the mineral oil is naphthenic mineral oil or paraffin base mineral oil.
Wherein, the emulsifier is made of nonionic surfactant and anionic surfactant；The nonionic table Face activating agent is at least one of fatty alcohol polyoxyethylene ether, alkoxy alcohol ether, fatty acid amide, and the anionic surface is living Property agent be petroleum sodium sulfonate.Nonionic surfactant stability is high, does not influence vulnerable to strong electrolyte, also not vulnerable to acid-base property shadow It rings, it is good with anionic surfactant compatibility, and by using specific surfactant, be conducive to improve emulsifier point It dissipates, the effect of emulsification, wetting, solves the problems, such as that the semi-synthetic cutting fluid wetability of tradition is poor.
Wherein, the emulsifier is by nonionic surfactant and anionic surfactant by weight the ratio of 2:1 Mixing composition.Preferably, the emulsifier is mixed by fatty alcohol polyoxyethylene ether and petroleum sodium sulfonate by weight the ratio of 2:1 Composition, or be made of alkoxy alcohol ether and petroleum sodium sulfonate by weight the ratio mixing of 2:1.
Wherein, the antirust agent includes borate, further includes lauric acid, eleven carbon diacids, in dodecanedicarboxylic acid It is at least one.Preferably, the antirust agent is by lauric acid: eleven carbon diacids: dodecanedicarboxylic acid: borate is by weight 2: The ratio of 1:2:3 mixes composition, or by dodecanedicarboxylic acid: borate is formed by weight the ratio mixing of 1:2, or by 11 Carbon dicarboxylic acid: dodecanedicarboxylic acid: borate mixes composition by weight the ratio of 1:1:3.The rust-preventing characteristic of single antirust agent Can be undesirable, good synergistic effect can reduce the dosage of additive, but not all antirust agent all have work of mutually promoting With, some even can produce reaction, this is because contain in cutting fluid there are many surfactant, antirust agent isopolarity molecule, Their polarity is different, also different to metal surface adsorption capacity, some Molecular Adsorption abilities are strong but non-film is not fine and close enough, has A little Molecular Adsorptions are indifferent but film forming is fine and close.Only the polar group of these polar molecules and nonpolar base are carried out appropriate flat Weighing apparatus can just make polar group securely be adsorbed on metal surface, and antirust agent can just show good rustless property.Laurel of the invention Acid, eleven carbon diacids, dodecanedicarboxylic acid are not only able to satisfy effect or outstanding lubricant, oiliness improver, the surface of antirust Activating agent, and it is environmentally friendly, mode is compounded with borate formation, can reduce concentration needed for antirust agent, reagent is reduced and uses It measures and improves antirust ability.And borate can metal friction surface formed adsorbed film, and by hydrolysis or and its It occurs friction chemical reaction with agent and forms deposition film, has the function of excellent extreme boundary lubrication, cooperates with the extreme pressure of this formula system Its dosage is effectively reduced in agent, promotes the preservative efficacy of cutting fluid.
Wherein, the lubricant is one or both of tall oil acid and self-emulsifying ester.Preferably, the lubricant by Tall oil acid and self-emulsifying ester are mixed by weight the ratio of 1:1 to be formed.Self-emulsifying ester, tall oil acid are in addition to excellent profit Slip energy also has good emulsibility, biological degradability and hypotoxicity, with petroleum sodium sulfonate of the invention, fatty alcohol polyoxy Vinethene, alkoxy alcohol ether, fatty acid amide are used in combination, and can be effectively reduced oil water interfacial tension, assign present invention cutting The good lubricity of liquid and excellent cooling.
Wherein, the corrosion inhibiter is that at least one of triazole derivative, molybdate, siloxanes specifically can be used wide The RC5820 of COINFAL A127 and the Rhein chemistry of Zhou meter Qi Chemical Co., Ltd., two kinds of corrosion inhibiter are without in industry at present The traditional phosphorus and silicate used, it is possible to provide emulsification and lubricating function can reduce the dosage of other surfaces activating agent in formula, And by forming one layer of form compact and stable film, the various aluminium alloys of effective protection in metal surface.
Wherein, the extreme pressure agent includes fat-based phosphate.Fat-based phosphate of the invention can be neutralized with hydramine Reaction generates fat-based phosphoric acid ester ammonium salt, which not only increases four ball extreme pressure properties of cutting fluid of the present invention, also It improves terraced nurse and agrees extreme pressure property, its excellent extreme pressure property can be shown at low levels, and do not have element sulphur, therefore Non-ferrous metal will not be caused to corrode.
Preferably, the extreme pressure agent is mixed by fat-based phosphate and dithiocarbamate by weight the ratio of 3:1 It is combined into, introduces sulfur-containing extreme-pressure additive, it is very few for Al-alloy metal side effect, but the metal sulfide film generated is more resistant to high temperature, The compounding of the two cooperates with, and can increase substantially the inoxidizability and wear resistence of cutting fluid.
Wherein, the defoaming agent is organic silicon defoamer.
Wherein, the fungicide is 2,6- thebaine, in benzoisothiazolinone and iodopropynyl formic acid At least one of butyl ester.Preferably, the fungicide is by one of 2,6- thebaine, benzoisothiazolinone and iodine It mixes and forms for propynylbutylcarbamate.Influencing one of main problem of cutting fluid service life is microbial growth, is made Cutting fluid goes bad smelly, and the present invention effectively inhibits the breeding of microorganism by the complex role of hydramine and fungicide.
The present invention also provides a kind of preparation methods of aluminum alloy cutting fluid with long service life: successively adding in mineral oil Enter hydramine, emulsifier, antirust agent, lubricant, corrosion inhibiter, extreme pressure agent, defoaming agent, fungicide and water, be mixed evenly to get To a kind of aluminum alloy cutting fluid with long service life.
Beneficial effects of the present invention: 1, the present invention selects specific emulsifier, with mineral oil, hydramine, antirust agent, lubrication Agent, corrosion inhibiter, extreme pressure agent, defoaming agent, fungicide carry out reasonable compatibility, and product of the present invention is made to have longer service life, and Realize its excellent Corrosion Protection；2, the hydramine and corrosion inhibiter that the present invention uses can effectively prevent corrosion of aluminium alloy to change colour, Simultaneously as having excellent pH stability and antibiotic property, the service life of cutting fluid is substantially prolonged；3, the present invention uses nothing Chlorine extreme pressure agent is generated in production process non-toxic gas, reduces the damage to human body, and the present invention is made by the compatibility of each composition With, the dosage of extreme pressure agent is reduced, it is environmentally friendly.
Specific embodiment
The invention will be further described with the following Examples.
Embodiment 1
A kind of aluminum alloy cutting fluid with long service life of the present embodiment, comprises the following raw materials by weight percent:
Mineral oil 10%
Hydramine 15%
Emulsifier 5%
Antirust agent 8%
Lubricant 10%
Corrosion inhibiter 4%
Extreme pressure agent 4%
Defoaming agent 0.5%
Fungicide 1%
Surplus is water；
The mineral oil is naphthenic mineral oil；
The hydramine is made of diglycolamine and diisopropanolamine (DIPA) by weight the ratio mixing of 1:2；
The emulsifier is made of fatty alcohol polyoxyethylene ether and petroleum sodium sulfonate by weight the ratio mixing of 2:1；
The antirust agent is by lauric acid: eleven carbon diacids: dodecanedicarboxylic acid: borate is by weight 2:1:2:3's Ratio mixing composition；
The lubricant is made of tall oil acid and self-emulsifying ester by weight the ratio mixing of 1:1；
The corrosion inhibiter is the COINFAL A127 of Guangzhou meter Qi Chemical Co., Ltd.；
The extreme pressure agent is fat-based phosphate；
The defoaming agent is organic silicon defoamer；
The fungicide is mixed by 2,6- thebaine and iodopropynyl butyl formate by weight the ratio of 1:1 It is combined into.
Embodiment 2
A kind of aluminum alloy cutting fluid with long service life of the present embodiment, comprises the following raw materials by weight percent:
Mineral oil 30%
Hydramine 5%
Emulsifier 12%
Antirust agent 3%
Lubricant 3%
Corrosion inhibiter 1%
Extreme pressure agent 1%
Defoaming agent 1%
Fungicide 3%
Surplus is water；
The hydramine mixes group by the ratio in 2-amino-2-methyl-1-propanol with diisopropanolamine (DIPA) by weight 2:3 At；
Wherein, the mineral oil is paraffin base mineral oil；
The emulsifier is made of alkoxy alcohol ether and petroleum sodium sulfonate by weight the ratio mixing of 2:1；
The antirust agent is made of dodecanedicarboxylic acid and borate by weight the ratio mixing of 1:2；
The lubricant is tall oil acid；
The corrosion inhibiter is the RC5820 of Rhein chemistry；
The extreme pressure agent is fat-based phosphate；
The defoaming agent is organic silicon defoamer
The fungicide by benzoisothiazolinone and iodopropynyl butyl formate in by weight 2:1 ratio Example mixing composition.
Embodiment 3
A kind of aluminum alloy cutting fluid with long service life of the present embodiment, comprises the following raw materials by weight percent:
Mineral oil 20%
Hydramine 10%
Emulsifier 9%
Antirust agent 5%
Lubricant 6%
Corrosion inhibiter 2%
Extreme pressure agent 2%
Defoaming agent 1%
Fungicide 2%
Surplus is water；
The hydramine is made of N methyldiethanol amine and diisopropanolamine (DIPA) by weight the ratio mixing of 1:1；
Wherein, the mineral oil is paraffin base mineral oil；
The emulsifier is made of fatty acid amide and petroleum sodium sulfonate by weight the ratio mixing of 2:1；
The antirust agent is by eleven carbon diacids: dodecanedicarboxylic acid: ratio mixing group of the borate by weight 1:1:3 At；
The lubricant is self-emulsifying ester；
The corrosion inhibiter is the COINFAL A127 of Guangzhou meter Qi Chemical Co., Ltd.；
The extreme pressure agent is by fat-based phosphate；
The defoaming agent is organic silicon defoamer
The fungicide is that 2,6- thebaine and iodopropynyl butyl formate are mixed by weight the ratio of 1:1 It is combined into.
Embodiment 4
A kind of aluminum alloy cutting fluid with long service life of the present embodiment, comprises the following raw materials by weight percent:
Mineral oil 25%
Hydramine 7%
Emulsifier 10%
Antirust agent 7%
Lubricant 4%
Corrosion inhibiter 3%
Extreme pressure agent 2.5%
Defoaming agent 0.8%
Fungicide 1.5%
Surplus is water；
Ratio of the hydramine by diglycolamine, N methyldiethanol amine and diisopropanolamine (DIPA) by weight 1:1:1 mixes Composition；
Wherein, the mineral oil is naphthenic mineral oil；
The emulsifier is by fatty alcohol polyoxyethylene ether, alkoxy alcohol ether and petroleum sodium sulfonate by weight the ratio of 1:2:1 Example mixing composition；
The antirust agent is made of lauric acid, eleven carbon diacids, borate by weight the ratio mixing of 2:1:3；
The lubricant is made of tall oil acid and self-emulsifying ester in the ratio mixing by weight 4:1；
The corrosion inhibiter is made of benzotriazole, sodium molybdate by weight the ratio mixing of 1:2；
The extreme pressure agent is made of fat-based phosphate and dithiocarbamate by weight the ratio mixing of 3:1；
The defoaming agent is organic silicon defoamer；
The fungicide in 2,6- thebaine, benzoisothiazolinone with iodopropynyl butyl formate by pressing The ratio of weight ratio 1:1:2 mixes composition.
Embodiment 5
A kind of aluminum alloy cutting fluid with long service life of the present embodiment, comprises the following raw materials by weight percent:
Mineral oil 15%
Hydramine 12%
Emulsifier 7%
Antirust agent 4%
Lubricant 4%
Corrosion inhibiter 2%
Extreme pressure agent 3%
Defoaming agent 0.6%
Fungicide 2.3%
Surplus is water；
The hydramine is pressed by diglycolamine, N methyldiethanol amine, 2-amino-2-methyl-1-propanol and diisopropanolamine (DIPA) The ratio of weight ratio 1:2:2:3 mixes composition；
Wherein, the mineral oil is paraffin base mineral oil；
The emulsifier is by fatty alcohol polyoxyethylene ether, fatty acid amide and petroleum sodium sulfonate by weight the ratio of 3:2:2 Example mixing composition；
Ratio of the antirust agent by eleven carbon diacids, dodecanedicarboxylic acid and borate by weight 1:2:1 mixes Composition；
The lubricant is self-emulsifying ester；
The corrosion inhibiter is sodium molybdate and siloxanes ketone in the ratio mixing composition by weight 1:1；
The extreme pressure agent is made of fat-based phosphate and dithiocarbamate by weight the ratio mixing of 2:1；
The defoaming agent is organic silicon defoamer；
The fungicide is 2,6- thebaine, benzoisothiazolinone and iodopropynyl butyl formate by weight It measures the ratio than 1:2:3 and mixes composition.
Embodiment 6
A kind of aluminum alloy cutting fluid with long service life of the present embodiment, comprises the following raw materials by weight percent:
Mineral oil 12%
Hydramine 14%
Emulsifier 7%
Antirust agent 7%
Lubricant 6%
Corrosion inhibiter 1.5%
Extreme pressure agent 3.5%
Defoaming agent 0.9%
Fungicide 1.8%
Surplus is water；
The hydramine is by diglycolamine, N methyldiethanol amine, 2-amino-2-methyl-1-propanol and diisopropanolamine (DIPA) Composition is mixed by weight the ratio of 1:1:3:2；
Wherein, the mineral oil is naphthenic mineral oil；
The emulsifier is by fatty alcohol polyoxyethylene ether, alkoxy alcohol ether, fatty acid amide and petroleum sodium sulfonate weight ratio The ratio of 2:1:1:2 mixes composition；
The antirust agent is by lauric acid, eleven carbon diacids, dodecanedicarboxylic acid and borate by weight 3:1:3:4's Ratio mixing composition；
The lubricant is made of tall oil acid and self-emulsifying ester by weight the ratio mixing of 1:3；
The corrosion inhibiter is made of benzotriazole, sodium molybdate, siloxanes ketone by weight the ratio mixing of 2:2:3；
The extreme pressure agent is made of fat-based phosphate and dithiocarbamate by weight the ratio mixing of 1:1；
The defoaming agent is organic silicon defoamer；
The fungicide in 2,6- thebaine, benzoisothiazolinone with iodopropynyl butyl formate by pressing The ratio of weight ratio 1:1:1 mixes composition.
Embodiment 7
A kind of aluminum alloy cutting fluid with long service life of the present embodiment, comprises the following raw materials by weight percent:
Mineral oil 28%
Hydramine 13%
Emulsifier 10%
Antirust agent 4.5%
Lubricant 8.5%
Corrosion inhibiter 3.2%
Extreme pressure agent 2.2%
Defoaming agent 0.75%
Fungicide 2.6%
Surplus is water；
The hydramine is pressed by diglycolamine, N methyldiethanol amine, 2-amino-2-methyl-1-propanol and diisopropanolamine (DIPA) The ratio of weight ratio 3:2:1:5 mixes composition；
Wherein, the mineral oil is paraffin base mineral oil；
The emulsifier by fatty alcohol polyoxyethylene ether, alkoxy alcohol ether, fatty acid amide and petroleum sodium sulfonate by weight Ratio than 1:1:2:2 mixes composition；
Ratio mixing of the antirust agent by lauric acid, dodecanedicarboxylic acid and borate by weight 1:1:2 forms；
The lubricant is made of tall oil acid and self-emulsifying ester by weight the ratio mixing of 3:2；
The corrosion inhibiter is made of benzotriazole, sodium molybdate, siloxanes ketone by weight the ratio mixing of 1:3:3；
The extreme pressure agent is made of fat-based phosphate and dithiocarbamate by weight the ratio mixing of 3:2；
The defoaming agent is organic silicon defoamer；
The fungicide in 2,6- thebaine, benzoisothiazolinone with iodopropynyl butyl formate by pressing The ratio of weight ratio 1:1:4 mixes composition.
Embodiment 8
A kind of aluminum alloy cutting fluid with long service life of the present embodiment, comprises the following raw materials by weight percent:
Mineral oil 17%
Hydramine 11%
Emulsifier 9%
Antirust agent 5%
Lubricant 5%
Corrosion inhibiter 3%
Extreme pressure agent 1%
Defoaming agent 0.9%
Fungicide 3%
Surplus is water；
The hydramine is pressed by diglycolamine, N methyldiethanol amine, 2-amino-2-methyl-1-propanol and diisopropanolamine (DIPA) The ratio of weight ratio 1:2:1:2 mixes composition；
Wherein, the mineral oil is naphthenic mineral oil；
The emulsifier is made of fatty alcohol polyoxyethylene ether and petroleum sodium sulfonate by weight the ratio mixing of 1:1；
The antirust agent is made of lauric acid and borate by weight the ratio mixing of 1:2；
The lubricant is made of the mixing of the ratio of tall oil acid and self-emulsifying ester 1:1 by weight；
The corrosion inhibiter is sodium molybdate；
The extreme pressure agent is made of fat-based phosphate and dithiocarbamate by weight the ratio mixing of 3:1；
The defoaming agent is organic silicon defoamer；
The fungicide in 2,6- thebaine, benzoisothiazolinone with iodopropynyl butyl formate by pressing The ratio of weight ratio 3:1:2 mixes composition.
Embodiment 1-8 respectively by sequentially added in mineral oil hydramine, emulsifier, antirust agent, lubricant, corrosion inhibiter, Extreme pressure agent, defoaming agent, fungicide and water are mixed evenly and cut to get to a kind of aluminium alloy with long service life Liquid.
GB/T6144 and GB/T7919 test is carried out to embodiment 1-8, obtains GB/T6144 test table (following table).
The cutting fluid of embodiment 1-8 is free of chlorine, nitrite, phenol, passes through the test of GB/T6144 " synthetic cutting fluid " With the toxicity test of GB/T7919, anti-rust and corrosionproperties are excellent, especially apply the anti-corrosion effect on aluminium alloy significant, can be long-term It uses, through client feedback, the period of the primary cutting fluid of the invention of replacement is 1 year or so, and environmentally friendly, human body damages pole It is small.
Finally it should be noted that the above embodiments are merely illustrative of the technical solutions of the present invention, rather than the present invention is protected The limitation of range is protected, although explaining in detail referring to preferred embodiment to the present invention, those skilled in the art are answered Work as understanding, it can be with modification or equivalent replacement of the technical solution of the present invention are made, without departing from the reality of technical solution of the present invention Matter and range.

Claims (2)

1. a kind of aluminum alloy cutting fluid with long service life, it is characterised in that: comprise the following raw materials by weight percent:
Wherein the hydramine by least one of diglycolamine, N methyldiethanol amine, 2-amino-2-methyl-1-propanol with Diisopropanolamine (DIPA) compounds, and the emulsifier is by nonionic surfactant and anionic surfactant by weight 2:1 Ratio mix composition；The nonionic surfactant is fatty alcohol polyoxyethylene ether, in alkoxy alcohol ether, fatty acid amide At least one, the anionic surfactant be petroleum sodium sulfonate, it further includes laurel that the antirust agent, which includes borate, At least one of acid, eleven carbon diacids, dodecanedicarboxylic acid, the lubricant are one in tall oil acid and self-emulsifying ester Kind or two kinds, the extreme pressure agent includes fat-based phosphate；
Wherein, the mineral oil is naphthenic mineral oil or paraffin base mineral oil；
Wherein, the defoaming agent is organic silicon defoamer；
Wherein, the fungicide is 2,6- thebaine, in benzoisothiazolinone and iodopropynyl butyl formate At least one of.
2. a kind of preparation method of aluminum alloy cutting fluid with long service life described in claim 1, it is characterised in that: in mineral Hydramine, emulsifier, antirust agent, lubricant, corrosion inhibiter, extreme pressure agent, defoaming agent, fungicide and water are sequentially added in oil, mixing is stirred It mixes uniformly to get to a kind of aluminum alloy cutting fluid with long service life.
CN201610456793.7A 2016-06-22 2016-06-22 A kind of aluminum alloy cutting fluid with long service life and preparation method thereof Active CN106118834B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610456793.7A CN106118834B (en) 2016-06-22 2016-06-22 A kind of aluminum alloy cutting fluid with long service life and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610456793.7A CN106118834B (en) 2016-06-22 2016-06-22 A kind of aluminum alloy cutting fluid with long service life and preparation method thereof

Publications (2)

Publication Number Publication Date
CN106118834A CN106118834A (en) 2016-11-16
CN106118834B true CN106118834B (en) 2019-04-12

Family

ID=57267890

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610456793.7A Active CN106118834B (en) 2016-06-22 2016-06-22 A kind of aluminum alloy cutting fluid with long service life and preparation method thereof

Country Status (1)

Country Link
CN (1) CN106118834B (en)

Families Citing this family (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106590882A (en) * 2016-12-20 2017-04-26 武汉航天航科石油化学有限公司 Emulsion cutting fluid
CN106675744A (en) * 2016-12-27 2017-05-17 长沙艾森设备维护技术有限公司 Water-based metal rust inhibitor
CN106694969B (en) * 2017-03-03 2019-02-19 潘勇 Headlight for vehicles lampshade mould light method for processing surface
CN107099367A (en) * 2017-06-08 2017-08-29 广州市联诺化工科技有限公司 A kind of floorboard with high oil content, environment-friendly water-based semi-synthetic cutting fluid of high anti-friction performance and preparation method thereof
CN107034471B (en) * 2017-06-16 2019-01-01 哈尔滨哈船新材料科技有限公司 A kind of photochemical treatment fluid of aluminum or aluminum alloy surface preparation and the method for chemical cleaning
CN107868693A (en) * 2017-11-24 2018-04-03 重庆信人科技发展有限公司 A kind of strong inhibition micro-emulsion cutting fluid
CN107739651A (en) * 2017-11-28 2018-02-27 涵麟化学科技（上海）有限公司 A kind of magnesium alloy cutting fluid
CN108034485A (en) * 2017-12-28 2018-05-15 南京科润新材料技术有限公司 A kind of semi-synthetic cutting fluid of low-phosphorous no chlorine non-formaldehyde aluminium alloy machining
CN108441310B (en) * 2018-04-25 2021-02-19 上海柯赛德斯加美石油集团有限公司 Semisynthesis cutting fluid for metal processing and preparation method thereof
CN108517255A (en) * 2018-05-19 2018-09-11 武汉诺通润滑科技有限公司 A kind of almag cutting fluid
CN108774568B (en) * 2018-05-25 2021-05-14 清华大学天津高端装备研究院 Semisynthetic aluminum alloy processing liquid and preparation method thereof
CN108843973B (en) * 2018-05-31 2021-01-29 中国石油天然气集团有限公司 Resistance reducing agent for coiled tubing, preparation method and application
CN109233949A (en) * 2018-09-05 2019-01-18 佛山市铂索润滑材料有限公司 A kind of water soluble magnesium aluminum alloy mould release agent and preparation method thereof
CN111004676B (en) * 2018-10-08 2022-07-05 中国石油天然气股份有限公司 Emulsified cutting fluid and preparation method thereof
CN110951533B (en) * 2019-12-05 2022-04-26 金雪驰科技（马鞍山）有限公司 Long-acting micro-emulsified cutting fluid for metal processing and preparation method thereof
CN113174287B (en) * 2021-03-23 2022-09-20 富联裕展科技(深圳)有限公司 Cutting fluid for metal
CN113801724A (en) * 2021-09-30 2021-12-17 安美科技股份有限公司 Metal processing cutting fluid and preparation method thereof
CN113845965A (en) * 2021-09-30 2021-12-28 安美科技股份有限公司 Aluminum alloy cutting fluid and preparation method thereof
CN114350432A (en) * 2021-12-13 2022-04-15 富兰克润滑科技（太仓）有限公司 Easy-to-clean environment-friendly cutting fluid for machining aluminum wheel hub and preparation method thereof
CN115058283A (en) * 2022-06-27 2022-09-16 重庆信人科技发展有限公司 High-performance cutting fluid for aviation mixed processing
CN115058282A (en) * 2022-06-27 2022-09-16 重庆信人科技发展有限公司 Long-acting anticorrosive cutting fluid for aviation aluminum alloy and preparation method thereof
CN115558538B (en) * 2022-09-22 2023-08-22 广州市联诺化工科技有限公司 Environment-friendly stamping drawing liquid and application thereof
CN115926874A (en) * 2022-12-30 2023-04-07 广东红日星实业有限公司 Cutting fluid without phosphorus and chlorine and preparation method and application thereof

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101240218A (en) * 2008-02-29 2008-08-13 益田润石（北京）化工有限公司 Emulsification type metal cutting liquor composition
CN101240217A (en) * 2008-02-29 2008-08-13 益田润石（北京）化工有限公司 Micro-emulsion type metal cutting liquor composition
CN102492533A (en) * 2011-11-28 2012-06-13 上海应用技术学院 Hard water-resistant semi-synthetic metal cutting fluid and preparation method thereof
CN102618358A (en) * 2012-03-06 2012-08-01 上海应用技术学院 Green micro-emulsification metal machining liquid and preparation method thereof
CN102643708A (en) * 2012-04-13 2012-08-22 广州市联诺化工科技有限公司 High-oil-content environment-friendly aqueous cutting fluid and preparing method thereof
CN102660364A (en) * 2012-04-17 2012-09-12 广州市联诺化工科技有限公司 Non-phosphorus non-silicon aluminum alloy cutting fluid and preparation method thereof
CN102925269A (en) * 2012-11-09 2013-02-13 上海应用技术学院 Aluminum alloy semisynthesis cutting liquid and preparation method thereof
CN103468382A (en) * 2013-08-30 2013-12-25 广州机械科学研究院有限公司 Boron-free chlorine-free formaldehyde-free microemulsified cutting fluid and application thereof
CN104087404A (en) * 2014-07-29 2014-10-08 马思特（上海）化学有限公司 High-cleanliness economical microemulsion metal cutting fluid

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101240218A (en) * 2008-02-29 2008-08-13 益田润石（北京）化工有限公司 Emulsification type metal cutting liquor composition
CN101240217A (en) * 2008-02-29 2008-08-13 益田润石（北京）化工有限公司 Micro-emulsion type metal cutting liquor composition
CN102492533A (en) * 2011-11-28 2012-06-13 上海应用技术学院 Hard water-resistant semi-synthetic metal cutting fluid and preparation method thereof
CN102618358A (en) * 2012-03-06 2012-08-01 上海应用技术学院 Green micro-emulsification metal machining liquid and preparation method thereof
CN102643708A (en) * 2012-04-13 2012-08-22 广州市联诺化工科技有限公司 High-oil-content environment-friendly aqueous cutting fluid and preparing method thereof
CN102660364A (en) * 2012-04-17 2012-09-12 广州市联诺化工科技有限公司 Non-phosphorus non-silicon aluminum alloy cutting fluid and preparation method thereof
CN102925269A (en) * 2012-11-09 2013-02-13 上海应用技术学院 Aluminum alloy semisynthesis cutting liquid and preparation method thereof
CN103468382A (en) * 2013-08-30 2013-12-25 广州机械科学研究院有限公司 Boron-free chlorine-free formaldehyde-free microemulsified cutting fluid and application thereof
CN104087404A (en) * 2014-07-29 2014-10-08 马思特（上海）化学有限公司 High-cleanliness economical microemulsion metal cutting fluid

Also Published As

Publication number Publication date
CN106118834A (en) 2016-11-16

Similar Documents

Publication Publication Date Title
CN106118834B (en) A kind of aluminum alloy cutting fluid with long service life and preparation method thereof
CN105001964A (en) Microemulsified cutting fluid
CN104073333B (en) Water-ethylene glycol nonflame hydraulic fluid and preparation method thereof
CN105861135B (en) Green metal cutting fluid and preparation method thereof
CN102925269A (en) Aluminum alloy semisynthesis cutting liquid and preparation method thereof
CN106800963B (en) A kind of water soluble oil metalworking fluid raw material and metalworking fluid
CN104073321A (en) Microemulsion cutting fluid, cutting diluent and preparation and application methods of microemulsion cutting fluid
CN104073328A (en) Microemulsion cutting fluid, cutting diluent and preparation and application methods of microemulsion cutting fluid
CN104531323A (en) Nitrite-free concentrated solution for rapidly biodegrading mine prop and preparation method
CN107446681A (en) A kind of emulsifying type water-soluble metal cutting fluid and preparation method thereof
CN103555392A (en) Ionic liquid-containing micro-emulsified metal cutting fluid, and preparation method and application thereof
CN108865388A (en) A kind of synthesis type cutting fluid of the molybdenum sulfide containing nano particle and preparation method thereof
AU741967B2 (en) Surfactant mixture
CN108359522A (en) A kind of Biostatic type metal working fluid and preparation method thereof
CN104004578A (en) Special cutting fluid for aluminum alloys
CN104877736A (en) Boron-free and phosphorus-free aluminum alloy piston micro-emulsification processing liquid, dilution liquid and preparation method thereof
CN103820197B (en) A kind of complete synthesis metal working fluid
CN106566625B (en) One vegetable oil base titanium alloy emulsifies working fluid
CN104312705A (en) Environment-friendly cutting fluid and preparation method thereof
CN110684585B (en) Micro-emulsion type cutting fluid and preparation method thereof
CN104073322A (en) Metal processing liquid and preparation method thereof
CN105542929A (en) Low-VOCs environment-friendly micro-emulsified cutting fluid and preparation method thereof
CN107418693A (en) Aluminum alloy cutting fluid and preparation method thereof
KR102611347B1 (en) Oil-less aqueous cutting fluid
JPH08302379A (en) Bacteristat and water-base or emulsion-base metal processing composition containing same

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant