CN107739651A - A kind of magnesium alloy cutting fluid - Google Patents

A kind of magnesium alloy cutting fluid Download PDF

Info

Publication number
CN107739651A
CN107739651A CN201711210112.XA CN201711210112A CN107739651A CN 107739651 A CN107739651 A CN 107739651A CN 201711210112 A CN201711210112 A CN 201711210112A CN 107739651 A CN107739651 A CN 107739651A
Authority
CN
China
Prior art keywords
mass fraction
magnesium alloy
cutting fluid
agent
alloy cutting
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711210112.XA
Other languages
Chinese (zh)
Inventor
王为林
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Han Lin Chemical Technology (shanghai) Co Ltd
Original Assignee
Han Lin Chemical Technology (shanghai) Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Han Lin Chemical Technology (shanghai) Co Ltd filed Critical Han Lin Chemical Technology (shanghai) Co Ltd
Priority to CN201711210112.XA priority Critical patent/CN107739651A/en
Publication of CN107739651A publication Critical patent/CN107739651A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M173/00Lubricating compositions containing more than 10% water
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/12Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • C10M2207/126Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids monocarboxylic
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/12Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • C10M2207/127Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids polycarboxylic
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/18Tall oil acids
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/108Polyethers, i.e. containing di- or higher polyoxyalkylene groups etherified
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/109Polyethers, i.e. containing di- or higher polyoxyalkylene groups esterified
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2215/042Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22Heterocyclic nitrogen compounds
    • C10M2215/221Six-membered rings containing nitrogen and carbon only
    • C10M2215/222Triazines
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22Heterocyclic nitrogen compounds
    • C10M2215/223Five-membered rings containing nitrogen and carbon only
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/04Detergent property or dispersant property
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/08Resistance to extreme temperature
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/12Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/16Antiseptic; (micro) biocidal or bactericidal
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/26Waterproofing or water resistance
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/64Environmental friendly compositions
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/22Metal working with essential removal of material, e.g. cutting, grinding or drilling
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/244Metal working of specific metals
    • C10N2040/245Soft metals, e.g. aluminum

Abstract

The invention discloses a kind of magnesium alloy cutting fluid,Including deionized water,Monoisopropanolamine,Dodecyl benzyl dimethyl ammonium chloride,Diglycolamine,Triethanolamine oleate,SA,BTA,Refined tall oil,No. five white oils,White emulsifiable polyisocyanate,Hard water resistance dose,Tween 20,S-triazine,Magnesium alloy corrosion inhibiter,Glycerine and defoamer,The present invention has excellent lubrication abrasion resistance,Clean cooling performance,Anti-rust and anti-corrosion,Sterilization algae removal performance and hard water resistance performance,Avoid the generation of cut tumor,It is effectively protected cutter,Improve the quality of product,Reduce the temperature of machined surface,The phenomenon for avoiding workpiece from being deformed by high temperature,Improve the precision of processing,Avoid the corrosion of workpiece and get rusty,Save production cost,Simplify processing technology,Shorten the process-cycle,Improve production efficiency,Environmental protection will not be contaminated,Cost is cheap,Long acting antibiotic,Belong to environmentally friendly product.

Description

A kind of magnesium alloy cutting fluid
Technical field
The present invention relates to a kind of cutting fluid, and in particular to a kind of magnesium alloy cutting fluid.
Background technology
Most domestic enterprise is in magnesium alloy molded processing technology still using oil base cutting fluid or emulsion as lubrication Cooling agent.The main component of general oil base cutting fluid is kerosene or diesel oil, and this cutting fluid lubrication and rust-preventing characteristic are good, but easily wave Hair, smell are big, can thermally decompose in use, and substantial amounts of oil vapour and greasy filth not only pollute environment, and easily Generation fire.For emulsion between oil base cutting fluid and water-base cutting fluid, its lubrication, antirust, cooling are preferable, but stably Property it is poor, it is affected by environment in use demulsification layering easily occurs to cause cutting speed is slack-off, corrosion aggravates, fouls etc.. More than 80% composition is mineral oil in other emulsion, and as the rising of oil price is as oil base cutting fluid, emulsion adds Work cost also more and more higher, meanwhile, the waste emulsified mixture periodically discharged can not be biodegradable, and the pollution to bad border is also very serious.
The content of the invention
The purpose of the present invention is that to solve the above problems and provides a kind of magnesium alloy cutting fluid, so as to solve above-mentioned ask Topic.
In order to solve the above-mentioned technical problem, the invention provides following technical scheme:
The invention provides a kind of magnesium alloy cutting fluid, including deionized water, monoisopropanolamine, dodecyl dimethyl benzyl chloride Change ammonium, diglycolamine, triethanolamine oleate, SA, BTA, refined tall oil, No. five white oils, white emulsifiable polyisocyanate, anti- Hard water agent, tween 20, s-triazine, magnesium alloy corrosion inhibiter, glycerine and defoamer, the mass fraction of the deionized water are 10%-13%, the mass fraction of the monoisopropanolamine are 1.5%-3%, the quality of the dodecyl benzyl dimethyl ammonium chloride Fraction is 2%-5%, the mass fraction of the diglycolamine is 2%-4%, the mass fraction of the triethanolamine oleate be 1%-3%, The mass fraction of the SA is 0.5%-1.3%, the mass fraction of the BTA is 0.1%-0.5%, described refined The mass fraction of tall oil is 8%-12%, the mass fraction of No. five white oils is 20%-33%, the quality point of the white emulsifiable polyisocyanate Number is 5%-8%, described hard water resistance dose of mass fraction is 2%-4%, the mass fraction of the tween 20 is 1%-3%, described equal The mass fraction of triazine is 0.5%-1%, the mass fraction of the magnesium alloy corrosion inhibiter is 1%-2%, the quality of the glycerine point Number is 10%-12%, the mass fraction of the defoamer is 0.1%-0.2%.
As a preferred technical solution of the present invention, the defoamer is silicone emulsion, higher alcohols are fatty acid ester compounded Thing, polyoxyethylene polyoxypropylene pentaerythrite ether, polyoxyethylene polyoxy propyl alcohol amidogen ether, polypropylene glycerol aether and polyoxypropylene gather One or more of mixtures of oxygen Ethylene Glycol ether and dimethyl silicone polymer.
As a preferred technical solution of the present invention, the magnesium alloy corrosion inhibiter is phosphate, tall oil and 2- ammonia One or more of mixtures of base -2- methyl isophthalic acids-propyl alcohol, sodium metasilicate and modified phosphate.
As a preferred technical solution of the present invention, described hard water resistance dose is ethylenediamine tetra-acetic acid, hydroxyl ethylenediamine tetrem One or more of mixtures in acid, edetate or hydroxyl edetate.
As a preferred technical solution of the present invention, the monoisopropanolamine is excellent solvent;It is important washing Agent and cosmetic material, are also used for soap;In alkalescence, the absorbent of sour gas is also served as;The SA lubricates for synthesis Oil or lube oil additive;The BTA is water treatment agent, metal antirusting agent and corrosion inhibiter.
As a preferred technical solution of the present invention, the diglycolamine is mainly used as the absorbent of sour gas;Institute Dodecyl benzyl dimethyl ammonium chloride is stated as acrylic fibers levelling agent, printed fabrics retarding agents, oilfield bactericide, cooling water System Biocidal algae-killing agent, medical apparatus sterilizing agent etc.;The triethanolamine oleate has excellent emulsification and dispersive property;Foaming Ability is strong, and foam is fine and smooth;Stability is strong in acid and alkaline medium;There are good washing and antirust ability.
As a preferred technical solution of the present invention, the refined tall oil is emulsion auxiliary agent, has antirust, lubrication And clean-up performance, the surface smoothness of workpiece can be improved, reduces the adhesion of chip, so as to improve cutting-tool's used life;It is described No. five white oils can be used as the purposes such as the tasteless lubricating oil of advanced sewing machine.
As a preferred technical solution of the present invention, the white emulsifiable polyisocyanate can be used in metal working fluid using, and be to work as One of preceding best product for solving metal working fluid lubricity, alternative part sulphur, phosphorus extreme pressure agent, meanwhile, chlorine can be substituted completely It is product, reduces the harm of chlorine base lubricant;The tween 20 is used as the solubilizer of insoluble medicine in some water;Described equal three Piperazine is used for circulating water sterilizing algicide.
As a preferred technical solution of the present invention, comprise the following steps:Step 1:Gone according to the amount of formula by described Ionized water, which is put into reactor, is warming up to 40-50 degrees Celsius, be then sequentially placed into the monoisopropanolamine, the triethanolamine, The dodecyl benzyl dimethyl ammonium chloride, the diglycolamine, the triethanolamine oleate, the SA and the benzene And triazole fully stir half after 20 minutes, was warming up to 70-80 degrees Celsius;Step 2:After reacting 2 hours, temperature is dropped To 40-50 degrees Celsius, the refined tall oil, No. five white oils and the white emulsifiable polyisocyanate are sequentially added, is stirred 10 minutes Afterwards, it is warming up to 70-80 degrees Celsius;Step 3:After reaction 30 minutes, temperature is dropped to 40-50 degrees Celsius, sequentially added described anti- Hard water agent, the tween 20, the s-triazine, the magnesium alloy corrosion inhibiter, the glycerine and the defoamer, stirring 30 It is finished product after minute.
The beneficial effect that is reached of the present invention is:The device is a kind of magnesium alloy cutting fluid, and the present invention is cut magnesium alloy Processing plays an important role, and there is excellent lubrication abrasion resistance, cleaning cooling performance, anti-rust and anti-corrosion, sterilization to go out Algae performance and hard water resistance performance, avoid the generation of cut tumor, are effectively protected cutter, improve the quality of product, reduce The temperature of machined surface, the phenomenon for avoiding workpiece from being deformed by high temperature, the precision of processing is improved, avoids the corrosion and life of workpiece Rust, production cost to be saved, simplify processing technology, shorten the process-cycle, improve production efficiency, environmental protection will not be contaminated, into This cheap, long acting antibiotic, belongs to environmentally friendly product.
Embodiment
The preferred embodiments of the present invention are illustrated below, it will be appreciated that preferred embodiment described herein is only used In the description and interpretation present invention, it is not intended to limit the present invention.
Embodiment 1
The present invention provides a kind of magnesium alloy cutting fluid, including deionized water, monoisopropanolamine, dodecyl dimethyl Benzylmagnesium chloride It is ammonium, diglycolamine, triethanolamine oleate, SA, BTA, refined tall oil, No. five white oils, white emulsifiable polyisocyanate, anti-hard Aqua, tween 20, s-triazine, magnesium alloy corrosion inhibiter, glycerine and defoamer, the mass fraction of deionized water is 10%-13%, The mass fraction of monoisopropanolamine is 1.5%-3%, the mass fraction of dodecyl benzyl dimethyl ammonium chloride is 2%-5%, two sweet The mass fraction of hydramine is 2%-4%, the mass fraction of triethanolamine oleate is 1%-3%, the mass fraction of SA is 0.5%- 1.3%th, the mass fraction of BTA is 0.1%-0.5%, the mass fraction of refined tall oil is 8%-12%, No. five white oils Mass fraction is 20%-33%, the mass fraction of white emulsifiable polyisocyanate is 5%-8%, hard water resistance dose of mass fraction is 2%-4%, tween two Ten mass fraction is 1%-3%, the mass fraction of s-triazine is 0.5%-1%, the mass fraction of magnesium alloy corrosion inhibiter is 1%- 2%th, the mass fraction of glycerine be 10%-12%, the mass fraction of defoamer be 0.1%-0.2%.
Defoamer is silicone emulsion, the fatty acid ester compounded thing of higher alcohols, polyoxyethylene polyoxypropylene pentaerythrite ether, polyoxy Ethene polyoxy propyl alcohol amidogen ether, polypropylene glycerol aether and one kind of polyoxyethylene polyoxypropylene glycerin ether and dimethyl silicone polymer Or several mixture.
Magnesium alloy corrosion inhibiter is phosphate, tall oil and 2-amino-2-methyl-1-propanol, sodium metasilicate and modified phosphorus One or more of mixtures of acid esters.
Hard water resistance dose is ethylenediamine tetra-acetic acid, hydroxyl ethylenediamine tetra-acetic acid, edetate or hydroxyl ethylenediamine tetra-acetic acid One or more of mixtures in salt.
Monoisopropanolamine is excellent solvent;It is important detergent and cosmetic material, is also used for soap;In alkalescence, Also serve as the absorbent of sour gas;SA is synthetic lubricant fluid or lube oil additive;BTA be water treatment agent, Metal antirusting agent and corrosion inhibiter.
Diglycolamine is mainly used as the absorbent of sour gas;Dodecyl benzyl dimethyl ammonium chloride is used as acrylic fibers level dyeing Agent, printed fabrics retarding agents, oilfield bactericide, cooling water system Biocidal algae-killing agent, medical apparatus sterilizing agent etc.;Oleic acid three Monoethanolamine has excellent emulsification and dispersive property;Foaming capacity is strong, and foam is fine and smooth;The stability in acid and alkaline medium By force;There are good washing and antirust ability.
Refined tall oil is emulsion auxiliary agent, has antirust, lubrication and clean-up performance, can improve any surface finish of workpiece Degree, reduces the adhesion of chip, so as to improve cutting-tool's used life;No. five white oils can be used as tasteless lubricating oil of advanced sewing machine etc. Purposes.
White emulsifiable polyisocyanate can be used in metal working fluid using, be the current best product for solving metal working fluid lubricity it One, alternative part sulphur, phosphorus extreme pressure agent, meanwhile, chlorine system product can be substituted completely, reduce the harm of chlorine base lubricant;Tween two Ten are used as the solubilizer of insoluble medicine in some water;S-triazine is used for circulating water sterilizing algicide.
Comprise the following steps:Step 1:Deionized water is put into reactor to be warming up to 40-50 Celsius according to the amount of formula Degree, is then sequentially placed into monoisopropanolamine, triethanolamine, dodecyl benzyl dimethyl ammonium chloride, diglycolamine, oily triethylenetetraminehexaacetic acid Hydramine, SA and BTA fully stir half after 20 minutes, were warming up to 70-80 degrees Celsius;Step 2:Reaction 2 After hour, temperature is dropped to 40-50 degrees Celsius, sequentially adds refined tall oil, No. five white oils and white emulsifiable polyisocyanate, stirs 10 points Zhong Hou, it is warming up to 70-80 degrees Celsius;Step 3:After reaction 30 minutes, temperature is dropped to 40-50 degrees Celsius, sequentially added anti-hard Aqua, tween 20, s-triazine, magnesium alloy corrosion inhibiter, glycerine and defoamer, stirring were finished product after 30 minutes.
Composition and ratio
The mass fraction of deionized water is 12%, the mass fraction of monoisopropanolamine is 2.5%, dodecyl dimethyl Benzylmagnesium chloride The mass fraction of ammonium is 4%, the mass fraction of diglycolamine is 3%, the mass fraction of triethanolamine oleate is 2%, the matter of SA Amount fraction is 1.2%, the mass fraction of BTA is 0.4%, the mass fraction of refined tall oil is 10%, No. five white oil Mass fraction is 30%, the mass fraction of white emulsifiable polyisocyanate is 7%, hard water resistance dose of mass fraction is 3%, the quality of tween 20 point Number is 3%, the mass fraction of s-triazine is 1%, the mass fraction of magnesium alloy corrosion inhibiter is 2%, the mass fraction of glycerine is 12%, The mass fraction of defoamer is 0.2%.
Performance test:
Sequence number Product Hard water resistance value Lubricity Rust-preventing characteristic Surface smoothness Service life Workpiece quality
1 Magnesium alloy cutting fluid 10000ppm 700 Nothing is got rusty within 30 days It is qualified More than 10 months It is qualified
2 Magnalium cutting fluid 10100ppm 720 Nothing is got rusty within 31 days It is qualified More than 9 months It is qualified
3 Magnalium cutting fluid 9800ppm 680 Nothing is got rusty within 29 days It is qualified More than 9 months It is qualified
4 In the market magnalium cutting fluid 5000ppm 510 Nothing is got rusty within 7 days It is qualified 1 month It is unqualified
5 In the market magnalium cutting fluid 4300ppm 480 Nothing is got rusty within 6 days It is unqualified 40 days It is qualified
6 In the market magnalium cutting fluid 4900ppm 500 Nothing is got rusty within 10 days It is qualified 29 days It is qualified
The invention is a kind of magnesium alloy cutting fluid, including deionized water, monoisopropanolamine, dodecyl dimethyl Benzylmagnesium chloride It is ammonium, diglycolamine, triethanolamine oleate, SA, BTA, refined tall oil, No. five white oils, white emulsifiable polyisocyanate, anti-hard Aqua, tween 20, s-triazine, magnesium alloy corrosion inhibiter, glycerine and defoamer, defoamer are silicone emulsion, higher alcohols fat Acid esters compound, polyoxyethylene polyoxypropylene pentaerythrite ether, polyoxyethylene polyoxy propyl alcohol amidogen ether, polypropylene glycerol aether and poly- One or more of mixtures of oxypropylene polyoxyethylene glycerol ether and dimethyl silicone polymer.Magnesium alloy corrosion inhibiter is phosphoric acid One or more of mixtures of ester, tall oil and 2-amino-2-methyl-1-propanol, sodium metasilicate and modified phosphate.It is anti- Hard water agent is one kind in ethylenediamine tetra-acetic acid, hydroxyl ethylenediamine tetra-acetic acid, edetate or hydroxyl edetate Or several mixture.Monoisopropanolamine is excellent solvent;It is important detergent and cosmetic material, is also used for soap; In alkalescence, the absorbent of sour gas is also served as;SA is synthetic lubricant fluid or lube oil additive;BTA is water Inorganic agent, metal antirusting agent and corrosion inhibiter.Diglycolamine is mainly used as the absorbent of sour gas;Dodecyl dimethyl benzyl Ammonium chloride is used as acrylic fibers levelling agent, printed fabrics retarding agents, oilfield bactericide, cooling water system Biocidal algae-killing agent, medical treatment Sterilization of instruments agent etc.;Triethanolamine oleate has excellent emulsification and dispersive property;Foaming capacity is strong, and foam is fine and smooth;In acidity It is strong with stability in alkaline medium;There are good washing and antirust ability.Refined tall oil is emulsion auxiliary agent, have antirust, Lubrication and clean-up performance, can improve the surface smoothness of workpiece, reduce the adhesion of chip, so as to improve cutting-tool's used life; No. five white oils can be used as the purposes such as the tasteless lubricating oil of advanced sewing machine.White emulsifiable polyisocyanate can be used in metal working fluid using, and be to work as One of preceding best product for solving metal working fluid lubricity, alternative part sulphur, phosphorus extreme pressure agent, meanwhile, chlorine can be substituted completely It is product, reduces the harm of chlorine base lubricant;Tween 20 is used as the solubilizer of insoluble medicine in some water;S-triazine is used to follow Ring water sterilizing disinfectant.
Preparation method:
Step 1:The deionized water that mass fraction is 12% is put into reactor to be warming up to 40-50 Celsius according to the amount of formula Degree, then it is sequentially placed into the dodecyl dimethyl benzyl chloride that monoisopropanolamine, mass fraction that mass fraction is 2.5% are 4% Change diglycolamine, the SA that mass fraction is 2% triethanolamine oleate, mass fraction is 1.2% that ammonium, mass fraction are 3% and The BTA that mass fraction is 0.4% fully stir half after 20 minutes, was warming up to 70-80 degrees Celsius;Step 2:Reaction 2 After individual hour, temperature is dropped to 40-50 degrees Celsius, sequentially adding refined tall oil, mass fraction that mass fraction is 10% is 30% No. five white oils and mass fraction are 7% white emulsifiable polyisocyanate, after stirring 10 minutes, are warming up to 70-80 degrees Celsius;Step 3: After reaction 30 minutes, temperature is dropped to 40-50 degrees Celsius, sequentially adding hard water resistance dose, mass fraction that mass fraction is 3% is Magnesium alloy corrosion inhibiter that s-triazine that 3% tween 20, mass fraction are 1%, mass fraction are 2%, mass fraction 12% Glycerine and mass fraction be 0.2% defoamer, stirring 30 minutes after be finished product, then carry out barreled.
Practicable ways
The cutting fluid in finished product cutting fluid storage box is pipelined to by circulating pump the position of cutter tip, to workpiece It can be played a very good protection with cutter head.
The beneficial effect that is reached of the present invention is:The device is a kind of magnesium alloy cutting fluid, and the present invention is cut magnesium alloy Processing plays an important role, and there is excellent lubrication abrasion resistance, cleaning cooling performance, anti-rust and anti-corrosion, sterilization to go out Algae performance and hard water resistance performance, avoid the generation of cut tumor, are effectively protected cutter, improve the quality of product, reduce The temperature of machined surface, the phenomenon for avoiding workpiece from being deformed by high temperature, the precision of processing is improved, avoids the corrosion and life of workpiece Rust, production cost to be saved, simplify processing technology, shorten the process-cycle, improve production efficiency, environmental protection will not be contaminated, into This cheap, long acting antibiotic, belongs to environmentally friendly product.
Finally it should be noted that:The preferred embodiments of the present invention are the foregoing is only, are not intended to limit the invention, Although the present invention is described in detail with reference to the foregoing embodiments, for those skilled in the art, it still may be used To be modified to the technical scheme described in foregoing embodiments, or equivalent substitution is carried out to which part technical characteristic. Within the spirit and principles of the invention, any modification, equivalent substitution and improvements made etc., it should be included in the present invention's Within protection domain.

Claims (9)

1. a kind of magnesium alloy cutting fluid, including it is deionized water, monoisopropanolamine, dodecyl benzyl dimethyl ammonium chloride, two sweet Hydramine, triethanolamine oleate, SA, BTA, refined tall oil, No. five white oils, white emulsifiable polyisocyanate, hard water resistance dose, tell Wen Ershi, s-triazine, magnesium alloy corrosion inhibiter, glycerine and defoamer, it is characterised in that the mass fraction of the deionized water is 10%-13%, the mass fraction of the monoisopropanolamine are 1.5%-3%, the quality of the dodecyl benzyl dimethyl ammonium chloride Fraction is 2%-5%, the mass fraction of the diglycolamine is 2%-4%, the mass fraction of the triethanolamine oleate be 1%-3%, The mass fraction of the SA is 0.5%-1.3%, the mass fraction of the BTA is 0.1%-0.5%, described refined The mass fraction of tall oil is 8%-12%, the mass fraction of No. five white oils is 20%-33%, the quality point of the white emulsifiable polyisocyanate Number is 5%-8%, described hard water resistance dose of mass fraction is 2%-4%, the mass fraction of the tween 20 is 1%-3%, described equal The mass fraction of triazine is 0.5%-1%, the mass fraction of the magnesium alloy corrosion inhibiter is 1%-2%, the quality of the glycerine point Number is 10%-12%, the mass fraction of the defoamer is 0.1%-0.2%.
2. a kind of magnesium alloy cutting fluid according to claim 1, it is characterised in that the defoamer is silicone emulsion, height Carbon polyol fatty acid ester complexes, polyoxyethylene polyoxypropylene pentaerythrite ether, polyoxyethylene polyoxy propyl alcohol amidogen ether, polyoxypropylene are sweet One or more of mixtures of oily ether and polyoxyethylene polyoxypropylene glycerin ether and dimethyl silicone polymer.
3. a kind of magnesium alloy cutting fluid according to claim 1, it is characterised in that the magnesium alloy corrosion inhibiter is phosphoric acid One or more of mixtures of ester, tall oil and 2-amino-2-methyl-1-propanol, sodium metasilicate and modified phosphate.
4. a kind of magnesium alloy cutting fluid according to claim 1, it is characterised in that described hard water resistance dose is ethylenediamine tetrem One or more of mixtures in acid, hydroxyl ethylenediamine tetra-acetic acid, edetate or hydroxyl edetate.
5. a kind of magnesium alloy cutting fluid according to claim 1, it is characterised in that the monoisopropanolamine is excellent molten Agent;It is important detergent and cosmetic material, is also used for soap;In alkalescence, the absorbent of sour gas is also served as;The certain herbaceous plants with big flowers Diacid is synthetic lubricant fluid or lube oil additive;The BTA is water treatment agent, metal antirusting agent and corrosion inhibiter.
6. a kind of magnesium alloy cutting fluid according to claim 1, it is characterised in that the diglycolamine is mainly used as acidity The absorbent of gas;The dodecyl benzyl dimethyl ammonium chloride is used as acrylic fibers levelling agent, printed fabrics retarding agents, oil field oil Well bactericide, cooling water system Biocidal algae-killing agent, medical apparatus sterilizing agent etc.;The triethanolamine oleate has excellent emulsification And dispersive property;Foaming capacity is strong, and foam is fine and smooth;Stability is strong in acid and alkaline medium;There are good washing and antirust Ability.
7. a kind of magnesium alloy cutting fluid according to claim 1, it is characterised in that the refined tall oil helps for emulsion Agent, there is antirust, lubrication and clean-up performance, the surface smoothness of workpiece can be improved, reduce the adhesion of chip, so as to improve cutter Service life;No. five white oils can be used as the purposes such as the tasteless lubricating oil of advanced sewing machine.
8. a kind of magnesium alloy cutting fluid according to claim 1, it is characterised in that the white emulsifiable polyisocyanate adds available for metal Used in work liquid, be currently to solve one of best product of metal working fluid lubricity, alternative part sulphur, phosphorus extreme pressure agent, together When, chlorine system product can be substituted completely, reduce the harm of chlorine base lubricant;The tween 20 is used as insoluble medicine in some water Solubilizer;The s-triazine is used for circulating water sterilizing algicide.
9. a kind of magnesium alloy cutting fluid according to claim 1, it is characterised in that comprise the following steps:Step 1:According to The deionized water is put into reactor and is warming up to 40-50 degrees Celsius by the amount of formula, is then sequentially placed into an isopropanol Amine, the triethanolamine, the dodecyl benzyl dimethyl ammonium chloride, the diglycolamine, the triethanolamine oleate, institute State SA and the BTA fully stir half after 20 minutes, be warming up to 70-80 degrees Celsius;Step 2:Reaction 2 After hour, temperature is dropped to 40-50 degrees Celsius, sequentially adds the refined tall oil, No. five white oils and the Virgin's milk Change ester, after stirring 10 minutes, be warming up to 70-80 degrees Celsius;Step 3:After reaction 30 minutes, it is Celsius that temperature is dropped to 40-50 Degree, sequentially add described hard water resistance dose, the tween 20, the s-triazine, the magnesium alloy corrosion inhibiter, the glycerine and The defoamer, stirring were finished product after 30 minutes.
CN201711210112.XA 2017-11-28 2017-11-28 A kind of magnesium alloy cutting fluid Pending CN107739651A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711210112.XA CN107739651A (en) 2017-11-28 2017-11-28 A kind of magnesium alloy cutting fluid

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711210112.XA CN107739651A (en) 2017-11-28 2017-11-28 A kind of magnesium alloy cutting fluid

Publications (1)

Publication Number Publication Date
CN107739651A true CN107739651A (en) 2018-02-27

Family

ID=61239372

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201711210112.XA Pending CN107739651A (en) 2017-11-28 2017-11-28 A kind of magnesium alloy cutting fluid

Country Status (1)

Country Link
CN (1) CN107739651A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109694770A (en) * 2018-11-27 2019-04-30 上海樱花化研化工科技有限公司 One Albatra metal cutting fluid composite and preparation method thereof
CN114231346A (en) * 2021-12-20 2022-03-25 安美科技股份有限公司 Fully synthetic magnesium alloy cutting fluid

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005132882A (en) * 2003-10-28 2005-05-26 Neos Co Ltd Water-soluble metal working oil composition
US20060172897A1 (en) * 2005-02-02 2006-08-03 Osamu Yamamoto Process for machining metal and high performance aqueous lubricant therefor
CN104312710A (en) * 2014-09-30 2015-01-28 苏州长盛机电有限公司 Fully synthesized magnesium alloy cutting fluid and preparation method thereof
CN105754690A (en) * 2016-03-30 2016-07-13 安徽华灿润滑技术有限公司 Magnesium alloy cutting liquid and preparation method thereof
CN106118834A (en) * 2016-06-22 2016-11-16 东莞市科泽润滑油有限公司 A kind of service life length aluminum alloy cutting fluid and preparation method thereof
CN106479654A (en) * 2016-09-06 2017-03-08 深圳市宏达威表面处理技术有限公司 Aqueous cutting fluid
CN106833854A (en) * 2017-03-17 2017-06-13 希玛石油制品(镇江)有限公司 A kind of environment-friendly type high-magnesium aluminum alloy cutting fluid and its preparation and application

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005132882A (en) * 2003-10-28 2005-05-26 Neos Co Ltd Water-soluble metal working oil composition
US20060172897A1 (en) * 2005-02-02 2006-08-03 Osamu Yamamoto Process for machining metal and high performance aqueous lubricant therefor
CN104312710A (en) * 2014-09-30 2015-01-28 苏州长盛机电有限公司 Fully synthesized magnesium alloy cutting fluid and preparation method thereof
CN105754690A (en) * 2016-03-30 2016-07-13 安徽华灿润滑技术有限公司 Magnesium alloy cutting liquid and preparation method thereof
CN106118834A (en) * 2016-06-22 2016-11-16 东莞市科泽润滑油有限公司 A kind of service life length aluminum alloy cutting fluid and preparation method thereof
CN106479654A (en) * 2016-09-06 2017-03-08 深圳市宏达威表面处理技术有限公司 Aqueous cutting fluid
CN106833854A (en) * 2017-03-17 2017-06-13 希玛石油制品(镇江)有限公司 A kind of environment-friendly type high-magnesium aluminum alloy cutting fluid and its preparation and application

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
李东光等: "《精细化工产品配方与工艺(一)》", 30 June 2000, 化学工业出版社 *
王家序等: "水基切削液的研制及应用", 《润滑与密封》 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109694770A (en) * 2018-11-27 2019-04-30 上海樱花化研化工科技有限公司 One Albatra metal cutting fluid composite and preparation method thereof
CN114231346A (en) * 2021-12-20 2022-03-25 安美科技股份有限公司 Fully synthetic magnesium alloy cutting fluid

Similar Documents

Publication Publication Date Title
JP5204390B2 (en) Water-soluble metal processing agent, coolant and preparation method thereof, method for preventing microbial degradation of water-soluble metal processing agent, and metal processing
JP5465004B2 (en) Lubricant composition
JP7030713B2 (en) Metalworking liquid
CN105001964A (en) Microemulsified cutting fluid
CN101104831A (en) Micro-emulsification stainless steel cutting liquid
CN109054973B (en) Micro-emulsified cutting fluid, preparation method and application
CN102295977A (en) Novel lubricant for sewing machine and preparation method thereof
CN104479833A (en) High-efficiency safe environment-friendly all-synthetic cutting fluid and preparation method thereof
CN107502437B (en) Semi-synthetic water-soluble cutting fluid for stainless steel and preparation method thereof
JP2008169371A (en) Composition of water-soluble metalworking fluid utilizing distillation residue generated during production of biodiesel
CN111909770A (en) Fully-synthetic high-lubrication metal working fluid, and preparation method and application thereof
CA1180321A (en) Water-based low foam hydraulic fluid
CN107739651A (en) A kind of magnesium alloy cutting fluid
JP4916462B2 (en) Metalworking fluid
JPH03229631A (en) Novel biodegradation resisting surfactant and cutting oil compound using same
JP2009161585A (en) Water-soluble metal working fluid composition
CN106675736A (en) Multifunctional cutting solution composition
JP6084534B2 (en) Hydrous hydraulic fluid
JP4812360B2 (en) Hydrous hydraulic fluid composition and kinematic viscosity stabilizer used therefor
CN104312710A (en) Fully synthesized magnesium alloy cutting fluid and preparation method thereof
KR100611735B1 (en) Composition of water soluble cutting oil
CN104357201A (en) Microemulsified cutting fluid applicable to magnesium alloy material machining and preparation method thereof
CN109504513A (en) A kind of water solubility stainless-steel seamless pipe cold rolling liquid and preparation method thereof
JP2014105244A (en) Water soluble metal processing oil agent composition
KR20150121612A (en) Environmental friendly water soluble metal working fluid composition

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20180227