CN108034485A - A kind of semi-synthetic cutting fluid of low-phosphorous no chlorine non-formaldehyde aluminium alloy machining - Google Patents

A kind of semi-synthetic cutting fluid of low-phosphorous no chlorine non-formaldehyde aluminium alloy machining Download PDF

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Publication number
CN108034485A
CN108034485A CN201711459367.XA CN201711459367A CN108034485A CN 108034485 A CN108034485 A CN 108034485A CN 201711459367 A CN201711459367 A CN 201711459367A CN 108034485 A CN108034485 A CN 108034485A
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China
Prior art keywords
cutting fluid
formaldehyde
phosphorous
semi
aluminium alloy
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靳永昌
张洪灿
赵凯利
聂晓霖
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Nanjing Kerun New Material Technology Co Ltd
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Nanjing Kerun New Material Technology Co Ltd
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Priority to CN201711459367.XA priority Critical patent/CN108034485A/en
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    • C10M173/00—Lubricating compositions containing more than 10% water
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    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
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    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/04—Well-defined cycloaliphatic compounds
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    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
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    • C10M2207/046—Hydroxy ethers
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    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • C10M2207/127—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids polycarboxylic
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    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
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    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/04—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an alcohol or ester thereof; bound to an aldehyde, ketonic, ether, ketal or acetal radical
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    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/102—Polyesters
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    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
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    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/108—Polyethers, i.e. containing di- or higher polyoxyalkylene groups etherified
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    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
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    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
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    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/08—Amides
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    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/223—Five-membered rings containing nitrogen and carbon only
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    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
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    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/10—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
    • C10M2219/104—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring containing sulfur and carbon with nitrogen or oxygen in the ring
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    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
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    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
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    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
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    • C10N2040/20—Metal working
    • C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling

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Abstract

The invention discloses a kind of semi-synthetic cutting fluid of low-phosphorous no chlorine non-formaldehyde aluminium alloy machining, belong to intermetallic composite coating media technology field, be formulated by the component of following percentage by weight：Naphthene base crude oil, extreme-pressure lubricant, oily lubricant, emulsifying agent, organic alcohol amine combination, siliceous class aluminium corrosion inhibiter, antirust agent, copper inhibitor, fungicide, coupling agent, water and defoamer.The present invention is combined using extreme-pressure lubricant and oily lubricant, improves the lubricating ability of cutting fluid and the surface smoothness of workpiece；Alkali holding capacity, pH stability and the microbial stability for improving cutting fluid are combined using hydramine；The aluminium corrosion inhibition of aluminum alloy cutting fluid is realized using siliceous aluminium corrosion inhibiter；Introduced using antibacterial system reduction phosphorus and increase the antibacterial component of alcohol ethers, extend cutting fluid service life；Harmful effect of the cutting fluid to human body and environment is reduced using non-formaldehyde release type fungicide.

Description

A kind of semi-synthetic cutting fluid of low-phosphorous no chlorine non-formaldehyde aluminium alloy machining
Technical field
The present invention relates to a kind of semi-synthetic cutting fluid, more particularly to a kind of low-phosphorous no chlorine non-formaldehyde aluminium alloy machining With semi-synthetic cutting fluid, belong to intermetallic composite coating media technology field.
Background technology
Aluminum alloy materials become most widely used a kind of non-ferrous metal in industry at present with excellent performance because of it Structural material, but easily there is workpiece corrosion, discoloration in aluminium alloy cutting process, cutter life is short, machined surface is bright and clean Degree is not up to standard, workpiece surface residual is big, easily the problems such as built-up edge occurs, particularly the siliceous cupric of pack alloy, non-processing EDS maps have substantial amounts of micropore, organize more loose, poor corrosion resistance, easily occur changing colour or producing electrochemical corrosion.
Phosphate, chlorinated paraffin and formaldehyde release-type fungicide are largely made always in traditional aluminum alloy cutting fluid With short chain chlorinated paraffin (SCCP) was put into first high attention rate material in EU REACH Legislation and in 2010 October 28 announced, and European Union and its member state have forbidden short chain chlorinated paraffin (SCCP) to produce and sell and use, and phosphate is made Cutting can be brought while providing excellent lubricating ability or corrosion inhibiting ability for a kind of EP agent and aluminium corrosion inhibiter for cutting fluid Liquid service life is short, easy corruption, the intractable problem of phosphorus-containing wastewater, and formaldehyde release-type fungicide is potential to environment and human body Harm is also gradually concerned.
The content of the invention
The main object of the present invention is to provide for a kind of low-phosphorous no chlorine non-formaldehyde aluminium alloy machining and is cut with semi-synthetic Liquid is cut, stabilizing it property is good, and resistance to hard water is strong, is not easy graining, and alkali holding capacity is strong, has biological stability, long lifespan, aluminium Corrosion inhibition is good, low-phosphorous, without chlorinated paraffin and formaldehydeless release.
The purpose of the present invention can reach by using following technical solution：
The semi-synthetic cutting fluid of a kind of low-phosphorous no chlorine non-formaldehyde aluminium alloy machining, by the component of following percentage by weight It is formulated：Naphthene base crude oil 10%-30%；Extreme-pressure lubricant 0.5%-1%；Oily lubricant 5%-15%；Emulsifying agent 10%- 20%；Organic alcohol amine combines 9%-20%；Siliceous class aluminium corrosion inhibiter 0.2%-3%；Antirust agent 5%-10%；Copper inhibitor 0.1%-1%；Fungicide 1%-4%；Coupling agent 0-5%；Water 20%-40%；Defoamer 0-1%.
Further, the flash-point of the naphthene base crude oil is 180~200 DEG C, cycloalkyl percentage Cn%>50%, at 40 DEG C Lower viscosity is 25-35mm2/ s, viscosity-gravity constant 0.85-0.88.
Further, the extreme-pressure lubricant is in phosphoric acid isooctanol ester, phosphate amine salt and fatty alcohol ether phosphate It is one or more.
Further, the oily lubricant is polyvinyl alcohol dibasic acid esters, neopentyl glycol fatty acid ester, four oleic acid of pentaerythrite Ester, fatty acid methyl ester, fatty acid isooctyl, aliphatic acid isopropyl alcohol ester, castor oil polyester, modified vegetable oil and saturated fatty acid three One kind or any two or more mixing in any proportion in hydroxymethyl-propane ester.
Further, the emulsifying agent for petroleum sodium sulfonate, fatty acid amide, fatty alcohol polyoxyethylene ether (5EO/2EO), Two or more in castor oil polyoxyethylene ether, polyisobutylene succinic acid acid amides and ready denier oil acid.
Further, the organic alcohol amine is combined as 2-amino-2-methyl-1-propanol, N methyldiethanol amine, N- methyl The mixing of at least two hydramine in monoethanolamine, 3- amino -4- octanols, diglycolamine and monoisopropanolamine and triisopropanolamine Thing.
Further, the siliceous class aluminium corrosion inhibiter is the one or more in different silicon-containing class aluminium corrosion inhibiter.
Further, the antirust agent is the one or more in organic dibasic acid, boric acid monoethanolamine ester and boric acid.
Further, the copper inhibitor is one or both of benzotriazole and its derivative.
Further, the fungicide is isothiazolinone derivatives, iodopropynyl formate butyl, pyrithione One or more in sodium, triclocarban and triclosan.
Further, the coupling agent is diethylene glycol monobutyl ether, Phenoxyethanol, benzene oxygen propyl alcohol, Dipropylene glycol mono-n-butyl Ether With the one or more in dipropylene glycol methyl ether.
Further, the water is tap water or pure water.
Further, the defoamer is modified siloxane class defoamer and one kind in polyethers defoamer or two Kind.
The advantageous effects of the present invention：Low-phosphorous no chlorine non-formaldehyde aluminium alloy machining according to the invention is with semi-synthetic Cutting fluid, the semi-synthetic cutting fluid of low-phosphorous no chlorine non-formaldehyde aluminium alloy machining provided by the invention, using extreme-pressure lubricant Combined with oily lubricant, improve the lubricating ability of cutting fluid and the surface smoothness of workpiece；Using the special hydramine of optimization Combination, improves the alkali holding capacity, pH stability and microbial stability of cutting fluid；Using the high silicon-aluminum containing of preferable stability Corrosion inhibiter, realizes the aluminium corrosion inhibition of aluminum alloy cutting fluid；Using antibacterial system, reduce phosphorus and introduce and increase antibacterial group of alcohol ethers Point, extend cutting fluid service life；Using non-formaldehyde release type fungicide, bad shadow of the cutting fluid to human body and environment is reduced Ring.
Embodiment
To make those skilled in the art more clear and clear and definite technical scheme, with reference to embodiment to this hair It is bright to be described in further detail, but the implementation of the present invention is not limited to this.
Embodiment 1：
The semi-synthetic cutting fluid of a kind of low-phosphorous no chlorine non-formaldehyde aluminium alloy machining that the present embodiment 1 provides, including：2- Amino-2-methyl -1- propyl alcohol 1.5%, three isopropanol hydramine 8%, boric acid 5%, organic dibasic acid 1%, fatty alcohol ether phosphate 0.5%th, tap water 20%, naphthene base crude oil 25%, siliceous aluminium corrosion inhibiter 2%, polyvinyl alcohol dibasic acid esters 5%, castor oil polyester 2%, Saturated fatty acid trihydroxymethylpropanyl ester 5%, ready denier oil acid 5%, fatty alcohol polyoxyethylene ether (5EO/2EO) 3%, oil Sodium sulfonate 3%, polyisobutylene succinic acid acid amides 4%, castor oil polyoxyethylene ether 3%, benzotriazole 0.2%, iodopropynyl Aminocarbamic acid butyl ester 0.5%, benzoisothiazolinone 2%, Dipropylene glycol mono-n-butyl Ether 4% and modified siloxane defoamer 0.3%.
A kind of preparation bag for low-phosphorous no semi-synthetic cutting fluid of chlorine non-formaldehyde aluminium alloy machining that the present embodiment 1 provides Include：Add 2-amino-2-methyl-1-propanol 1.5%, three isopropanol hydramine 8% while stirring under room temperature, boric acid 5%, have Machine binary acid 1%, fatty alcohol ether phosphoesterase 30 .5%, tap water 20%, naphthene base crude oil 25%, silicon-aluminum containing are added after stirring 20min Corrosion inhibiter 2%, polyvinyl alcohol dibasic acid esters 5%, castor oil polyester 2%, saturated fatty acid trihydroxymethylpropanyl ester 5%, tall oil grease Fat acid 5%, fatty alcohol polyoxyethylene ether (5EO/2EO) 3%, petroleum sodium sulfonate 3%, polyisobutylene succinic acid acid amides 4%, castor-oil plant Oily polyoxyethylene ether 3%, benzotriazole 0.2%, iodopropynyl butyl formate 0.5%, benzoisothiazolinone 2%th, Dipropylene glycol mono-n-butyl Ether 4%, stirring add modified siloxane defoamer 0.3% after twenty minutes, and stirring obtains after 30 minutes Finished product.
Semi-synthetic cutting fluid made from the present embodiment 1 meets JB/T7453 standards, and this product has excellent greasy property, Tapping torque numerical value is better than similar competing product under equal concentration, and this product can be used for requiring high, inter process to deposit aluminium inhibition The die casting aluminium processing that the time is long, storage environment humidity is big is put, can effectively prevent the discoloration or long white that the non-processing face of die casting aluminium occurs Spot, rustless property is strong, can meet that the mixed material of ferrous metal and aluminium alloy is processed, service life length, has excellent restraining and sterilizing bacteria Performance, resistance to hard water is strong, and graining is not produced during use, and cutting fluid is in stable condition.
Embodiment 2：Constituent：
The semi-synthetic cutting fluid of a kind of low-phosphorous no chlorine non-formaldehyde aluminium alloy machining that the present embodiment 2 provides, including：2- Amino-2-methyl -1- propyl alcohol 1%, monoisopropanolamine 1%, three isopropanol hydramine 8%, boric acid 2%, boric acid monoethanolamine ester 5%th, organic dibasic acid 1%, fatty alcohol ether phosphate 1%, tap water 25.2%, naphthene base crude oil 20%, siliceous aluminium corrosion inhibiter 1.5%th, polyvinyl alcohol dibasic acid esters 12%, ready denier oil acid 4%, fatty alcohol polyoxyethylene ether (5EO/2EO) 3%, mahogany acid Sodium 3%, fatty acid amide 3%, castor oil polyoxyethylene ether 2%, benzotriazole 0.2%, iodopropynyl formic acid fourth Ester 0.3%, benzoisothiazolinone 2%, triclocarban 0.5%, Dipropylene glycol mono-n-butyl Ether 2%, benzene oxygen propyl alcohol 2% and modified silicon Oxygen alkane defoamer 0.3%.
A kind of preparation bag for low-phosphorous no semi-synthetic cutting fluid of chlorine non-formaldehyde aluminium alloy machining that the present embodiment 2 provides Include：Add 2-amino-2-methyl-1-propanol 1%, monoisopropanolamine 1%, three isopropanol hydramine while stirring under room temperature 8%th, boric acid 2%, boric acid monoethanolamine ester 5%, organic dibasic acid 1%, fatty alcohol ether phosphate 1%, tap water 25.2%, are stirred Mix add after 20min naphthene base crude oil 20%, siliceous aluminium corrosion inhibiter 1.5%, polyvinyl alcohol dibasic acid esters 12%, ready denier oil acid 4%, Fatty alcohol polyoxyethylene ether (5EO/2EO) 3%, petroleum sodium sulfonate 3%, fatty acid amide 3%, castor oil polyoxyethylene ether 2%, Benzotriazole 0.2%, iodopropynyl butyl formate 0.3%, benzoisothiazolinone 2%, triclocarban 0.5%, Dipropylene glycol mono-n-butyl Ether 2%, benzene oxygen propyl alcohol 2%, stirring add modified siloxane defoamer 0.3% after twenty minutes, stir 30 points Finished product is obtained after clock.
Semi-synthetic cutting fluid made from the present embodiment 2 meets JB/T7453 standards, and this product has excellent greasy property, Tapping torque numerical value is better than similar competing product under equal concentration, is gently processed suitable for aluminium alloy to heavy load, emulsified particles It is small, do not produce graining during use, workpiece visibility is high during processing, and easy cleaning, lathe inner wall is clean, cutting fluid dilution liquid State is stablized, and has excellent restraining and sterilizing bacteria performance, service life length.
To sum up, semi-synthetic cutting fluid made from embodiment 1 and embodiment 2 meets JB/T7453 standards, it is with excellent Greasy property, tapping torque numerical value is better than similar competing product under equal concentration, cannot be only used for it is high to aluminium inhibition requirement, The die casting aluminium processing that the inter process resting period is long, storage environment humidity is big, the change that can effectively prevent the non-processing face of die casting aluminium from occurring Color or long hickie, rustless property is strong, can meet that the mixed material of ferrous metal and aluminium alloy is processed, service life length, has excellent Restraining and sterilizing bacteria performance, resistance to hard water is strong, and graining is not produced during use, and cutting fluid is in stable condition；It could be applicable to aluminium conjunction Gold is gently processed to heavy load, and emulsified particles is small, does not produce graining during use, and workpiece visibility is high during processing, easy cleaning, machine Bed inner wall is clean, and cutting fluid dilution is in stable condition, has excellent restraining and sterilizing bacteria performance, service life length.Embodiment 1 and reality Apply example 2 cutting fluid performance comparison summarize the results are shown in Table 1：
1 embodiment 1 of table and the cutting fluid performance comparison of embodiment 2 summarize result
In conclusion in the present embodiment, according to the low-phosphorous no chlorine non-formaldehyde aluminium alloy machining of the present embodiment with partly Synthetic cutting fluid, the semi-synthetic cutting fluid of low-phosphorous no chlorine non-formaldehyde aluminium alloy machining provided in this embodiment, using extreme pressure Lubricant and oily lubricant combination, improve the lubricating ability of cutting fluid and the surface smoothness of workpiece；Using the spy of optimization Different hydramine combination, improves the alkali holding capacity, pH stability and microbial stability of cutting fluid；It is high using preferable stability Siliceous aluminium corrosion inhibiter, realizes the aluminium corrosion inhibition of aluminum alloy cutting fluid；Using antibacterial system, reduce phosphorus and introduce and increase alcohol ethers Antibacterial component, extends cutting fluid service life；Using non-formaldehyde release type fungicide, cutting fluid is reduced to human body and environment not Good influence.
The above, is only further embodiment of the present invention, but protection scope of the present invention is not limited thereto, any In scope disclosed in this invention, technique according to the invention scheme and its design add those familiar with the art With equivalent substitution or change, protection scope of the present invention is belonged to.

Claims (13)

1. the semi-synthetic cutting fluid of a kind of low-phosphorous no chlorine non-formaldehyde aluminium alloy machining, it is characterised in that by following weight hundred The component of ratio is divided to be formulated：
Naphthene base crude oil 10%-30%；
Extreme-pressure lubricant 0.5%-1%；
Oily lubricant 5%-15%；
Emulsifying agent 10%-20%；
Organic alcohol amine combines 9%-20%；
Siliceous class aluminium corrosion inhibiter 0.2%-3%；
Antirust agent 5%-10%；
Copper inhibitor 0.1%-1%；
Fungicide 1%-4%；
Coupling agent 0-5%；
Water 20%-40%；
Defoamer 0-1%.
2. the semi-synthetic cutting fluid of the low-phosphorous no chlorine non-formaldehyde aluminium alloy machining of one kind according to claim 1, it is special Sign is that the flash-point of the naphthene base crude oil is 180~200 DEG C, cycloalkyl percentage Cn%>50%, viscosity is 25- at 40 DEG C 35mm2/ s, viscosity-gravity constant 0.85-0.88.
3. the semi-synthetic cutting fluid of the low-phosphorous no chlorine non-formaldehyde aluminium alloy machining of one kind according to claim 1, it is special Sign is that the extreme-pressure lubricant is the one or more in phosphoric acid isooctanol ester, phosphate amine salt and fatty alcohol ether phosphate.
4. the semi-synthetic cutting fluid of the low-phosphorous no chlorine non-formaldehyde aluminium alloy machining of one kind according to claim 1, it is special Sign is that the oily lubricant is polyvinyl alcohol dibasic acid esters, neopentyl glycol fatty acid ester, four oleate of pentaerythrite, aliphatic acid Methyl esters, fatty acid isooctyl, aliphatic acid isopropyl alcohol ester, castor oil polyester, modified vegetable oil and saturated fatty acid trihydroxy methyl third One kind or any two or more mixing in any proportion in alkyl ester.
5. the semi-synthetic cutting fluid of the low-phosphorous no chlorine non-formaldehyde aluminium alloy machining of one kind according to claim 1, it is special Sign is that the emulsifying agent is petroleum sodium sulfonate, fatty acid amide, fatty alcohol polyoxyethylene ether (5EO/2EO), castor oil polyoxy Two or more in vinethene, polyisobutylene succinic acid acid amides and ready denier oil acid.
6. the semi-synthetic cutting fluid of the low-phosphorous no chlorine non-formaldehyde aluminium alloy machining of one kind according to claim 1, it is special Sign is, the organic alcohol amine be combined as 2-amino-2-methyl-1-propanol, N methyldiethanol amine, (2-hydroxyethyl)methylamine), The mixture of at least two hydramine in 3- amino -4- octanols, diglycolamine and monoisopropanolamine and triisopropanolamine.
7. the semi-synthetic cutting fluid of the low-phosphorous no chlorine non-formaldehyde aluminium alloy machining of one kind according to claim 1, it is special Sign is that the siliceous class aluminium corrosion inhibiter is the one or more in different silicon-containing class aluminium corrosion inhibiter.
8. the semi-synthetic cutting fluid of the low-phosphorous no chlorine non-formaldehyde aluminium alloy machining of one kind according to claim 1, it is special Sign is that the antirust agent is the one or more in organic dibasic acid, boric acid monoethanolamine ester and boric acid.
9. the semi-synthetic cutting fluid of the low-phosphorous no chlorine non-formaldehyde aluminium alloy machining of one kind according to claim 1, it is special Sign is that the copper inhibitor is one or both of benzotriazole and its derivative.
10. the semi-synthetic cutting fluid of the low-phosphorous no chlorine non-formaldehyde aluminium alloy machining of one kind according to claim 1, it is special Sign is that the fungicide is isothiazolinone derivatives, iodopropynyl formate butyl, sodium pyrithione, trichlorine card One or more in class and triclosan.
11. the semi-synthetic cutting fluid of the low-phosphorous no chlorine non-formaldehyde aluminium alloy machining of one kind according to claim 1, it is special Sign is that the coupling agent is diethylene glycol monobutyl ether, Phenoxyethanol, benzene oxygen propyl alcohol, Dipropylene glycol mono-n-butyl Ether and dipropylene glycol One or more in methyl ether.
12. the semi-synthetic cutting fluid of the low-phosphorous no chlorine non-formaldehyde aluminium alloy machining of one kind according to claim 1, it is special Sign is that the water is tap water or pure water.
13. the semi-synthetic cutting fluid of the low-phosphorous no chlorine non-formaldehyde aluminium alloy machining of one kind according to claim 1, it is special Sign is that the defoamer is one or two kinds of in modified siloxane class defoamer and polyethers defoamer.
CN201711459367.XA 2017-12-28 2017-12-28 A kind of semi-synthetic cutting fluid of low-phosphorous no chlorine non-formaldehyde aluminium alloy machining Pending CN108034485A (en)

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CN108774568A (en) * 2018-05-25 2018-11-09 清华大学天津高端装备研究院 A kind of semi-synthetic aluminium alloy working fluid and preparation method thereof
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CN108774568B (en) * 2018-05-25 2021-05-14 清华大学天津高端装备研究院 Semisynthetic aluminum alloy processing liquid and preparation method thereof
CN108659941A (en) * 2018-07-21 2018-10-16 南阳斯全格尔润滑科技有限公司 A kind of cutting fluid and preparation method thereof
CN109097175A (en) * 2018-08-27 2018-12-28 烟台恒邦化工有限公司 Water base fully synthetic quartz glass cutting liquid of one kind and preparation method thereof
CN109652196A (en) * 2018-11-19 2019-04-19 富兰克润滑科技（太仓）有限公司 A kind of resource utilization method of oil-containing emulsified waste liquid and its cutting fluid of preparation
CN112239699A (en) * 2019-07-17 2021-01-19 中国石油化工股份有限公司 Cutting fluid composition and use thereof
CN110452762A (en) * 2019-07-31 2019-11-15 南宁珀源能源材料有限公司 Polytenization sheet silicon wafer cutting fluid and preparation method thereof
CN112300859A (en) * 2019-08-01 2021-02-02 东莞市绿博化工科技有限公司 Aluminum profile extrusion separating agent and preparation method thereof
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WO2023071898A1 (en) * 2021-10-29 2023-05-04 南京科润工业介质股份有限公司 Long-acting corrosion-inhibition aluminum alloy cutting fluid
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Application publication date: 20180515