CN104277902A - Heavy-load metal machining total synthesis cutting fluid as well as preparation method and application thereof - Google Patents
Heavy-load metal machining total synthesis cutting fluid as well as preparation method and application thereof Download PDFInfo
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Abstract
The invention belongs to the field of metal machining fluids, and discloses a heavy-load metal machining total synthesis cutting fluid as well as a preparation method and an application thereof. The total synthesis cutting fluid comprises the following components in percentage by weight: 20%-30% of mixed alcohol amine, 6%-9% of anti-rust agents, 4%-6% of special amine, 6%-10% of lubricating agents, 15%-25% of extreme pressure agents, 6%-10% of cosolvents, 1%-2% of water-softening agents, 1%-3% of corrosion inhibitors and the balance of water. The total synthesis cutting fluid disclosed by the invention has excellent lubricating extreme pressure property, can meet the requirement for heavy-load machining, namely reaming, drilling, tapping, threading, broaching, thread machining and the like, of difficult-to-machine materials, namely high-temperature alloy steel, a titanium alloy and the like; a product is green and environment-friendly without containing boron, sodium nitrite, secondary amine, chlorine, phenol, formaldehyde, heavy metals and the like; in addition, the total synthesis cutting fluid disclosed by the invention has excellent anti-rust property, biological stability and machining property, and can enhance the surface quality of a machined part, prolong the service life of a cutter and reduce the rejection rate, thus improving the production efficiency.
Description
Technical field
The invention belongs to metal working fluid field, be specifically related to a kind of heavy loading intermetallic composite coating fully synthetic cutting fluid and preparation method thereof and application.
Background technology
Continually developing and applying along with new metallic material and complete processing, the heavy loading processing application in metal-processing industry of some difficult-to-machine materials as metallic substance such as extraordinary die steel, stainless steel, high-temperature alloy steel, titanium alloy, nickelalloys gets more and more.The heavy loading processing of difficult-to-machine material, as fraising, boring, tapping, tapping, broaching and screw thread process etc. in the course of processing due to features such as material hardness are high, yield strength is large, thermohardening is obvious, difficulty of processing is large, cause producing between cutter and workpiece in working angles very large friction and heat (temperature can up to 1000 DEG C), also can cause damage to cutter and equipment.Therefore, add man-hour in the heavy loading of difficult-to-machine material, select a cutting fluid having better oilness, cooling, rust-preventing characteristic and cleaning concurrently, to the precision of converted products and cutter life, there is important effect.
Cutting fluid is divided into water-insoluble (oil base) cutting fluid and the large class of water-soluble (water base) cutting fluid two according to composition and medium state, and water-soluble metalworking liquid is divided into again emulsion, microemulsion and synthesis liquid.Oil base cutting fluid has oilness and the good advantage of rust-preventing characteristic, but cooling and cleaning poor, the mist of oil produced in use procedure is larger, big for environment pollution, and have the danger of potential fire, in recent years along with the shortage of petroleum resources and constantly rising violently of oil price, its use is subject to certain restrictions; Emulsion and microemulsion form primarily of mineral oil, water and emulsifying agent, be characterized in oilness and rust-preventing characteristic better, but poor in cooling, perviousness, stability in storage and biologically stable, easy to be smelly rotten, work-ing life is shorter, and there is environmental issue during discharge; Fully synthetic cutting fluid is primarily of water and various water-soluble additive (as soluble oil, extreme pressure agent, rust-preventive agent, tensio-active agent etc.) composition, there is excellent cooling, cleaning and stability in storage, owing to not containing mineral oil, having positive meaning from aspects such as environmental protection, saving petroleum resources, is the direction of cutting fluid development.But, in domestic prior art, fully synthetic cutting fluid is not at oilness, rust-preventing characteristic, also have ideal result of use in work-ing life, be mainly used in the light load processing occasions such as grinding, during the heavy loading of metal-working industry difficult-to-machine material is processed at home, the application of fully synthetic cutting fluid does not also have larger breakthrough.
In addition, in domestic prior art, fully synthetic cutting fluid uses boric acid, Sodium Nitrite and secondary amine as antirust, anticorrosive agent in a large number.Europe has forced have the material of potential hazard to carry out label to some, and boric acid is wherein a kind of material.Boric acid likely makes the mankind sterile and has harm to unborn child; Boric acid, once be dissolved in water, is difficult in the treatment of waste water remove thus affect environment, works the mischief to the mankind.Sodium Nitrite and secondary amine reaction generate the nitrosamine having carcinogenic danger, and Europe has forbidden using Sodium Nitrite and secondary amine in cutting fluid.
Summary of the invention
In order to solve the shortcoming and defect part of prior art, primary and foremost purpose of the present invention is to provide a kind of heavy loading intermetallic composite coating fully synthetic cutting fluid that can be used for the difficult-to-machine materials such as extraordinary die steel, stainless steel, high-temperature alloy steel, titanium alloy, nickelalloy.
Another object of the present invention is to the preparation method that a kind of above-mentioned heavy loading intermetallic composite coating fully synthetic cutting fluid is provided.
Another object of the present invention is the application providing above-mentioned heavy loading intermetallic composite coating fully synthetic cutting fluid.
The object of the invention is achieved through the following technical solutions:
A kind of heavy loading intermetallic composite coating fully synthetic cutting fluid, this fully synthetic cutting fluid is made up of following component by mass percentage: 20 ~ 30% mixing hydramine, 6 ~ 9% rust-preventive agent, 4 ~ 6% special amine, 6 ~ 10% lubricants, 15 ~ 25% extreme pressure agents, 6 ~ 10% solubility promoters, 1 ~ 2% anti-hard water agent, 1 ~ 3% inhibiter and excess water;
Described rust-preventive agent is monocarboxylic acid, diprotic acid and triprotic acid; Described monocarboxylic acid is tolysulfonyl hexosamine; Described diprotic acid is more than one in ten carbon dicarboxylic acids, DC11 and SL-AH; Described triprotic acid is triazine triamino caproic acid (i.e. 2,4,6-tri-(amino caproyl)-1,3,5-triazines);
Described lubricant is more than one in dimeracid, trimer acid, ricinolic acid polyester and self-emulsifying polyester; Described extreme pressure agent is molecular-weight average 2000 ~ 4000g/mol, the trans block polyether of cloud point 20 ~ 50 DEG C.
Described mixing hydramine is two or more in monoethanolamine, trolamine, monoisopropanolamine and di-alcohol monoisopropanolamine.
Described special amine is more than one in 2-amino-2-methyl-1-propanol, 3-amino-4-octanol, 2-amino-n-butyl alcohol, diglycolamine, polyetheramine and oxyethane hexahydroaniline.
Described solubility promoter is more than one in n-caprylic acid, isocaprylic acid, pelargonic acid, different n-nonanoic acid and neodecanoic acid; Described anti-hard water agent is more than one in disodium EDTA, tetrasodium salt of EDTA, fatty alcohol-ether carboxylic acid, aralkyl alcohol ether carboxylate and alkylethoxy yl carboxylic acid; Described inhibiter is two or more in benzotriazole, Benzotriazole Derivative, methyl benzotriazazole derivative, ethoxy phosphate ester, fatty alcohol modified phosphoric acid ester and phosphonic acid ester.
The preparation method of above-mentioned heavy loading intermetallic composite coating fully synthetic cutting fluid, comprises following operation steps:
Mixing hydramine and lubricant are joined in reactor, stirring at normal temperature 30 ~ 60 minutes is to homogeneous transparent, then water, rust-preventive agent, anti-hard water agent, inhibiter is added, stirring at normal temperature 90 ~ 120 minutes is to homogeneous transparent, then special amine, extreme pressure agent, solubility promoter is added successively, stirring at normal temperature obtains heavy loading intermetallic composite coating fully synthetic cutting fluid to homogeneous transparent in 60 ~ 90 minutes.
The speed of described stirring is 80 ~ 100rpm.
Described heavy loading intermetallic composite coating fully synthetic cutting fluid is applied to the heavy loading machining of various metallic substance.
Compared with prior art, tool of the present invention has the following advantages and beneficial effect:
(1) fully synthetic cutting fluid of the present invention adopts novel lubricant and extreme-pressure additive compounded technology, product has excellent oilness, extreme pressure property and biologically stable, the oil in water emulsion containing mineral oil and semi-synthetic cutting fluid can be substituted, heavy loading for difficult-to-machine materials such as extraordinary die steel, stainless steel, high-temperature alloy steel, titanium alloy, nickelalloys is processed, and comprises fraising, boring, tapping, tapping, broaching and screw thread process etc.; Particularly adopt molecular-weight average 2000 ~ 4000g/mol, the trans block polyether of cloud point 20 ~ 50 DEG C, as extreme-pressure additive, carries out composite with self-emulsifying polyester, can reach better lubrication extreme pressure effect.
(2) fully synthetic cutting fluid of the present invention adopts novel monocarboxylic acid, diprotic acid and triprotic acid composite antirust technology simultaneously, and product has excellent rustless property; Product is boracic not, avoids boric acid to reproductive system harm, water pollutions and the water-base cutting fluid at present containing the boric acid easy problem leaving adhesivity residue and non-easy cleaning at workpiece and board surface after processing; Product, not containing Sodium Nitrite and secondary amine, avoids Sodium Nitrite and secondary amine and reacts and form nitrosamine and have carcinogenic danger.
(3) fully synthetic cutting fluid of the present invention introduces special amine component, improves biologically stable and the processing characteristics of working fluid, extends the work-ing life of working fluid, avoids the use in the product of poisonous sterilant.
(4) fully synthetic cutting fluid of the present invention not boracic, Sodium Nitrite, secondary amine, chlorine, phenol, formaldehyde, heavy metal etc., Product Green environmental protection, meets machinery manufacturing industry, electronic apparatus industry, aerospace to the high request of machining of metals liquid environmental protection.
Embodiment
Below in conjunction with embodiment, the present invention is described in further detail, but embodiments of the present invention are not limited thereto.
Embodiment 1
A kind of heavy loading intermetallic composite coating fully synthetic cutting fluid, be made up of following component by mass percentage: monoethanolamine 5%, trolamine 15%, tolysulfonyl hexosamine 2%, ten carbon dicarboxylic acids 2%, triazine triamino caproic acid 2%, 2-amino-2-methyl-1-propanol 4%, dimeracid 6%, polyethers (molecular-weight average 2000g/mol, the trans block polyether of cloud point 20 DEG C) 15%, n-caprylic acid 6%, disodium EDTA 1%, benzotriazole 0.2%, ethoxy phosphate ester 0.8%, water surplus.
Preparation method: first monoethanolamine, trolamine and dimeracid are joined in reactor, stirring at normal temperature 60 minutes is to homogeneous transparent, then water, tolysulfonyl hexosamine is added, ten carbon dicarboxylic acids, triazine triamino caproic acid, disodium EDTA, benzotriazole, ethoxy phosphate ester, stirring at normal temperature 90 minutes is to homogeneous transparent, then 2-amino-2-methyl-1-propanol, polyethers, n-caprylic acid is added successively, stirring at normal temperature obtains heavy loading intermetallic composite coating fully synthetic cutting fluid to homogeneous transparent in 60 minutes.
The fully synthetic cutting fluid deionized water prepared is diluted to the solution that mass fraction is 5%, screw thread process is carried out for the petroleum steel pipe of high-temperature alloy steel material and box cupling part, the requirement of Material Processing and technique can be met, work piece surface is highly polished, successful in raising petroleum steel pipe and box cupling part surface quality, tool life and rate of reducing the number of rejects and seconds.
Embodiment 2
A kind of heavy loading intermetallic composite coating fully synthetic cutting fluid, be made up of following component by mass percentage: di-alcohol monoisopropanolamine 8%, trolamine 17%, tolysulfonyl hexosamine 2.5%, DC11 2.5%, triazine triamino caproic acid 2%, 3-amino-4-octanol 5%, trimer acid 8%, polyethers (molecular-weight average 2600g/mol, the trans block polyether of cloud point 30 DEG C) 18%, isocaprylic acid 7%, tetrasodium salt of EDTA 1.5%, Benzotriazole Derivative 0.3%, fatty alcohol modified phosphoric acid ester 1.2%, water surplus.
Preparation method: first di-alcohol monoisopropanolamine, trolamine and trimer acid are joined in reactor, stirring at normal temperature 30 minutes is to homogeneous transparent, then water, tolysulfonyl hexosamine, DC11, triazine triamino caproic acid, tetrasodium salt of EDTA, Benzotriazole Derivative, fatty alcohol modified phosphoric acid ester is added, stirring at normal temperature 120 minutes is to homogeneous transparent, then 3-amino-4-octanol, polyethers, isocaprylic acid is added successively, stirring at normal temperature obtains heavy loading intermetallic composite coating fully synthetic cutting fluid to homogeneous transparent in 90 minutes.
The fully synthetic cutting fluid deionized water prepared is diluted to the solution that mass fraction is 5%, screw thread process is carried out for the petroleum steel pipe of high-temperature alloy steel material and box cupling part, the requirement of Material Processing and technique can be met, work piece surface is highly polished, successful in raising petroleum steel pipe and box cupling part surface quality, tool life and rate of reducing the number of rejects and seconds.
Embodiment 3
A kind of heavy loading intermetallic composite coating fully synthetic cutting fluid, be made up of following component by mass percentage: monoisopropanolamine 15%, trolamine 10%, tolysulfonyl hexosamine 2.5%, SL-AH 3%, triazine triamino caproic acid 2.5%, diglycolamine 5%, ricinolic acid polyester 8%, polyethers (molecular-weight average 3200g/mol, the trans block polyether of cloud point 40 DEG C) 22%, different n-nonanoic acid 8%, fatty alcohol-ether carboxylic acid 1.8%, methyl benzotriazazole derivative 0.5%, fatty alcohol modified phosphoric acid ester 1.5%, water surplus.
Preparation method: first monoisopropanolamine, trolamine and ricinolic acid polyester are joined in reactor, stirring at normal temperature 50 minutes is to homogeneous transparent, then water, tolysulfonyl hexosamine, SL-AH, triazine triamino caproic acid, fatty alcohol-ether carboxylic acid, methyl benzotriazazole derivative, fatty alcohol modified phosphoric acid ester is added, stirring at normal temperature 100 minutes is to homogeneous transparent, then diglycolamine, polyethers, different n-nonanoic acid is added successively, stirring at normal temperature obtains heavy loading intermetallic composite coating fully synthetic cutting fluid to homogeneous transparent in 80 minutes.
The fully synthetic cutting fluid deionized water prepared is diluted to the solution that mass fraction is 5%, screw thread process is carried out for the petroleum steel pipe of high-temperature alloy steel material and box cupling part, the requirement of Material Processing and technique can be met, work piece surface is highly polished, successful in raising petroleum steel pipe and box cupling part surface quality, tool life and rate of reducing the number of rejects and seconds.
Embodiment 4
A kind of heavy loading intermetallic composite coating fully synthetic cutting fluid, be made up of following component by mass percentage: monoethanolamine 10%, trolamine 20%, tolysulfonyl hexosamine 3%, SL-AH 3%, triazine triamino caproic acid 3%, oxyethane hexahydroaniline 6%, self-emulsifying polyester 10%, polyethers (molecular-weight average 4000g/mol, the trans block polyether of cloud point 50 DEG C) 25%, neodecanoic acid 10%, alkylethoxy yl carboxylic acid 2%, benzotriazole 0.5%, phosphonic acid ester 2.5%, water surplus.
Preparation method: first monoethanolamine, trolamine and self-emulsifying polyester are joined in reactor, stirring at normal temperature 40 minutes is to homogeneous transparent, then water, tolysulfonyl hexosamine, SL-AH, triazine triamino caproic acid, alkylethoxy yl carboxylic acid, benzotriazole, phosphonic acid ester is added, stirring at normal temperature 110 minutes is to homogeneous transparent, then oxyethane hexahydroaniline, polyethers, neodecanoic acid is added successively, stirring at normal temperature obtains heavy loading intermetallic composite coating fully synthetic cutting fluid to homogeneous transparent in 70 minutes.
The fully synthetic cutting fluid deionized water prepared is diluted to the solution that mass fraction is 5%, screw thread process is carried out for the petroleum steel pipe of high-temperature alloy steel material and box cupling part, the requirement of Material Processing and technique can be met, work piece surface is highly polished, successful in raising petroleum steel pipe and box cupling part surface quality, tool life and rate of reducing the number of rejects and seconds.
Comparative example 1
Monoethanolamine 10%, trolamine 20%, SL-AH 9%, oxyethane hexahydroaniline 6%, self-emulsifying polyester 10%, polyethers (molecular-weight average 4000g/mol, the trans block polyether of cloud point 50 DEG C) 25%, neodecanoic acid 10%, alkylethoxy yl carboxylic acid 2%, benzotriazole 0.5%, phosphonic acid ester 2.5%, water surplus.
Preparation method: first monoethanolamine, trolamine and self-emulsifying polyester are joined in reactor, stirring at normal temperature 40 minutes is to homogeneous transparent, then water, SL-AH, alkylethoxy yl carboxylic acid, benzotriazole, phosphonic acid ester is added, stirring at normal temperature 110 minutes is to homogeneous transparent, then oxyethane hexahydroaniline, polyethers, neodecanoic acid is added successively, stirring at normal temperature obtains comparative example 1 fully synthetic cutting fluid to homogeneous transparent in 70 minutes.
Comparative example 2
Monoethanolamine 10%, trolamine 20%, tolysulfonyl hexosamine 4.5%, triazine triamino caproic acid 4.5%, oxyethane hexahydroaniline 6%, polyethers (molecular-weight average 4000g/mol, the trans block polyether of cloud point 50 DEG C) 25%, neodecanoic acid 10%, alkylethoxy yl carboxylic acid 2%, benzotriazole 0.5%, phosphonic acid ester 2.5%, water surplus.
Preparation method: first monoethanolamine, trolamine are joined in reactor, stirring at normal temperature 40 minutes is to homogeneous transparent, then water, tolysulfonyl hexosamine, triazine triamino caproic acid, alkylethoxy yl carboxylic acid, benzotriazole, phosphonic acid ester is added, stirring at normal temperature 110 minutes is to homogeneous transparent, then oxyethane hexahydroaniline, polyethers, neodecanoic acid is added successively, stirring at normal temperature obtains comparative example 2 fully synthetic cutting fluid to homogeneous transparent in 70 minutes.
According to standard and test methods such as GB/T 6144, GB/T3142, IP287, LAPTAB G II 8, carry out Performance Detection to the fully synthetic cutting fluid that embodiment 1 ~ 4 and comparative example 1 ~ 2 prepare, detected result is as shown in table 1.
The Performance Detection of the fully synthetic cutting fluid that table 1 embodiment 1 ~ 4 and comparative example 1 ~ 2 prepare.
In data as can be seen from table 1, heavy loading intermetallic composite coating fully synthetic cutting fluid prepared by the embodiment of the present invention 1 ~ 4 has excellent lubrication extreme pressure property, rust-preventing characteristic, non-corrosibility and stability.The fully synthetic cutting fluid of comparative example 1, comparative example 2 is not owing to adopting monocarboxylic acid, diprotic acid and triprotic acid composite antirust technology simultaneously, the rust-preventing characteristic of this synthetic cutting fluid is poor, the cast iron in Performance Detection is antirust, iron corrosion and cast iron filing rust prevention test effect all poor; The fully synthetic cutting fluid of comparative example 2 is not owing to adopting self-emulsifying polyester lubricant and polyethers extreme pressure agent compounded technology, the oilness of this synthetic cutting fluid is poor, sintering load in Performance Detection is starkly lower than heavy loading intermetallic composite coating fully synthetic cutting fluid prepared by embodiment 1 ~ 4, and average torque is then higher than heavy loading intermetallic composite coating fully synthetic cutting fluid prepared by embodiment 1 ~ 4.
Above-described embodiment is the present invention's preferably embodiment; but embodiments of the present invention are not restricted to the described embodiments; change, the modification done under other any does not deviate from spirit of the present invention and principle, substitute, combine, simplify; all should be the substitute mode of equivalence, be included within protection scope of the present invention.
Claims (7)
1. a heavy loading intermetallic composite coating fully synthetic cutting fluid, is characterized in that; This fully synthetic cutting fluid is made up of following component by mass percentage: 20 ~ 30% mixing hydramine, 6 ~ 9% rust-preventive agent, 4 ~ 6% special amine, 6 ~ 10% lubricants, 15 ~ 25% extreme pressure agents, 6 ~ 10% solubility promoters, 1 ~ 2% anti-hard water agent, 1 ~ 3% inhibiter and excess water;
Described rust-preventive agent is monocarboxylic acid, diprotic acid and triprotic acid; Described monocarboxylic acid is tolysulfonyl hexosamine; Described diprotic acid is more than one in ten carbon dicarboxylic acids, DC11 and SL-AH; Described triprotic acid is triazine triamino caproic acid;
Described lubricant is more than one in dimeracid, trimer acid, ricinolic acid polyester and self-emulsifying polyester; Described extreme pressure agent is molecular-weight average 2000 ~ 4000g/mol, the trans block polyether of cloud point 20 ~ 50 DEG C.
2. heavy loading intermetallic composite coating fully synthetic cutting fluid according to claim 1, is characterized in that: described mixing hydramine is two or more in monoethanolamine, trolamine, monoisopropanolamine and di-alcohol monoisopropanolamine.
3. heavy loading intermetallic composite coating fully synthetic cutting fluid according to claim 1, is characterized in that: described special amine is more than one in 2-amino-2-methyl-1-propanol, 3-amino-4-octanol, 2-amino-n-butyl alcohol, diglycolamine, polyetheramine and oxyethane hexahydroaniline.
4. heavy loading intermetallic composite coating fully synthetic cutting fluid according to claim 1, is characterized in that: described solubility promoter is more than one in n-caprylic acid, isocaprylic acid, pelargonic acid, different n-nonanoic acid and neodecanoic acid; Described anti-hard water agent is more than one in disodium EDTA, tetrasodium salt of EDTA, fatty alcohol-ether carboxylic acid, aralkyl alcohol ether carboxylate and alkylethoxy yl carboxylic acid; Described inhibiter is two or more in benzotriazole, Benzotriazole Derivative, methyl benzotriazazole derivative, ethoxy phosphate ester, fatty alcohol modified phosphoric acid ester and phosphonic acid ester.
5. the preparation method of the heavy loading intermetallic composite coating fully synthetic cutting fluid according to any one of Claims 1 to 4, is characterized in that comprising following operation steps:
Mixing hydramine and lubricant are joined in reactor, stirring at normal temperature 30 ~ 60 minutes is to homogeneous transparent, then water, rust-preventive agent, anti-hard water agent, inhibiter is added, stirring at normal temperature 90 ~ 120 minutes is to homogeneous transparent, then special amine, extreme pressure agent, solubility promoter is added successively, stirring at normal temperature obtains heavy loading intermetallic composite coating fully synthetic cutting fluid to homogeneous transparent in 60 ~ 90 minutes.
6. preparation method according to claim 5, is characterized in that: the speed of described stirring is 80 ~ 100rpm.
7. the application of heavy loading intermetallic composite coating fully synthetic cutting fluid in the heavy loading machining of various metallic substance according to any one of claim 1 ~ 6.
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Address after: 510700 Maogang Road 828 Courtyard, Huangpu District, Guangzhou City, Guangdong Province, No. 22 401, 402 Patentee after: Guangzhou Guoji Lubrication Technology Co.,Ltd. Address before: 510700 Maogang Road 828 Courtyard, Huangpu District, Guangzhou City, Guangdong Province, No. 22 401, 402 Patentee before: GUANGZHOU JETSUN Co.,Ltd. |
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