CN111234909A - Water-based oil-free energy-saving environment-friendly efficient synthetic cutting fluid for machining - Google Patents

Water-based oil-free energy-saving environment-friendly efficient synthetic cutting fluid for machining Download PDF

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Publication number
CN111234909A
CN111234909A CN202010138428.8A CN202010138428A CN111234909A CN 111234909 A CN111234909 A CN 111234909A CN 202010138428 A CN202010138428 A CN 202010138428A CN 111234909 A CN111234909 A CN 111234909A
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water
cutting fluid
weight
percentage
free energy
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吴爱平
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Rema Environmental Protection Technology Jiangsu Co ltd
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Rema Environmental Protection Technology Jiangsu Co ltd
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M173/00Lubricating compositions containing more than 10% water
    • C10M173/02Lubricating compositions containing more than 10% water not containing mineral or fatty oils
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/08Inorganic acids or salts thereof
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/104Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/109Polyethers, i.e. containing di- or higher polyoxyalkylene groups esterified
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2215/042Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/06Macromolecular compounds obtained by functionalisation op polymers with a nitrogen containing compound
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2227/00Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
    • C10M2227/06Organic compounds derived from inorganic acids or metal salts
    • C10M2227/061Esters derived from boron

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

The invention discloses a water-based oil-free energy-saving environment-friendly efficient synthetic cutting fluid for machining, which is compounded by the following components in percentage by weight: 4-8% of diethanolamine; 9-13% of polyester amide ester; 1-5% of polycarboxylic acid; 1-5% of triethanolamine; 0.3 to 1 percent of bactericide; 20-40% of antirust compound liquid; the balance of water; the antirust compound liquid is prepared by compounding the following components in percentage by weight: 9-14% of monoethanolamine; 6-10% of sodium molybdate; 8-12% of borate, 10-15% of polyethylene glycol ester and 40-70% of water; the formula does not contain any mineral oil and animal and vegetable oil, does not contain sodium nitrite, has excellent extreme pressure lubrication effect and ultra-long rust-proof effect of ferrous metal, and has the effects of low cost, simple preparation, low pollution, no color, no odor and long service life, thereby being suitable for the work of various machine tools.

Description

Water-based oil-free energy-saving environment-friendly efficient synthetic cutting fluid for machining
Technical Field
The invention relates to the field of cutting fluid, in particular to water-based oil-free energy-saving environment-friendly efficient synthetic cutting fluid for machining.
Background
The cutting fluid is generally a working fluid used for taking away heat generated in a cutting area in time to reduce cutting temperature, prolong the service life of a cutter and improve the processing precision of a workpiece in the mechanical processing process of the material. The cutting fluid generally has the functions of lubrication, cooling, cleaning, rust prevention and the like, but the existing cutting fluid basically contains mineral oil, animal and vegetable oil, sodium nitrite and other components in order to have the functions, the animal and vegetable oil is easy to decay and deteriorate, the influence of high and low temperature is large, the sodium nitrite is toxic and has certain harm to human and environment, and the mineral oil has the tendency of decay; and the energy is consumed, the sewage treatment cost of the product after use is high, and mineral oil is selected by most manufacturers in the market, so that the cutting fluid which does not contain the three components and has excellent anti-skid and anti-rust components is urgently needed to be produced based on the problems.
Disclosure of Invention
The invention aims to provide a water-based oil-free energy-saving environment-friendly efficient synthetic cutting fluid for machining, which has an excellent extreme pressure lubrication effect and an ultra-long rust prevention effect on ferrous metals.
The technical scheme adopted by the invention for solving the technical problems is as follows: the water-based oil-free energy-saving environment-friendly efficient synthetic cutting fluid for machining is compounded from the following components in percentage by weight:
Figure BDA0002398148870000011
further, the method comprises the following steps: the antirust compound liquid is compounded by the following components in percentage by weight:
Figure BDA0002398148870000012
further, the method comprises the following steps: the antirust compound liquid is prepared by mixing and compounding the components at the temperature of 32 ℃.
Further, the method comprises the following steps: the weight percentage of each component is as follows:
Figure BDA0002398148870000021
the antirust compound liquid comprises the following components in percentage by weight:
Figure BDA0002398148870000022
the invention has the beneficial effects that: the formula does not contain any mineral oil and animal and vegetable oil, does not contain sodium nitrite, has excellent extreme pressure lubrication effect and ultra-long rust-proof effect of ferrous metal, and has the effects of low cost, simple preparation, low pollution, no color, no odor and long service life, thereby being suitable for the work of various machine tools.
Detailed Description
The present invention is further illustrated by the following specific embodiments.
The invention discloses a water-based oil-free energy-saving environment-friendly efficient synthetic cutting fluid for machining, which is compounded by the following components in percentage by weight:
Figure BDA0002398148870000023
the antirust compound liquid is prepared by compounding the following components in percentage by weight:
Figure BDA0002398148870000024
Figure BDA0002398148870000031
the antirust compound liquid is prepared by mixing and compounding the components at the temperature of 32 ℃;
the diethanolamine has the functions of: the alkali content is kept, and the ferrous metal is rust-proof and corrosion-resistant;
the polyester amide ester has the following functions: lubricating;
the function of the polycarboxylic acid is as follows: rust prevention of ferrous metal;
the triethanolamine has the following functions: the alkali content is kept, and the ferrous metal is rust-proof and corrosion-resistant;
the bactericide has the functions of: corrosion prevention;
the water has the functions of: a carrier;
the antirust compound liquid has the following functions: ferrous metal is rust-proof, lubricating and non-ferrous metal is corrosion-proof;
the formula does not contain any mineral oil and animal and vegetable oil, does not contain sodium nitrite, has excellent extreme pressure lubrication effect and ultra-long rust-proof effect of ferrous metal, and has the effects of low cost, simple preparation, low pollution, no color, no odor and long service life, thereby being suitable for the work of various machine tools.
The first embodiment is as follows:
the weight percentage of each component is as follows:
Figure BDA0002398148870000032
the antirust compound liquid comprises the following components in percentage by weight:
Figure BDA0002398148870000033
the antirust compound liquid is prepared by mixing and compounding the components at the temperature of 32 ℃.
Example two:
the weight percentage of each component is as follows:
Figure BDA0002398148870000041
the antirust compound liquid comprises the following components in percentage by weight:
Figure BDA0002398148870000042
the antirust compound liquid is prepared by mixing and compounding the components at the temperature of 32 ℃.
Example three:
the weight percentage of each component is as follows:
Figure BDA0002398148870000043
the antirust compound liquid comprises the following components in percentage by weight:
Figure BDA0002398148870000044
Figure BDA0002398148870000051
the antirust compound liquid is prepared by mixing and compounding the components at the temperature of 32 ℃.
The following are experimental data for cutting fluids using the above composition:
test items Test structure
Appearance of the product Green fluorescence (colorless and transparent)
Density at normal temperature (15 deg.C), kg/L 1.10
In the form of an emulsion Transparent aqueous solution
PH value (3% concentration) 8.7
Refractive index 2.2
Corrosion test (IP287) 2% strength working solution produces pitting corrosion
The above-mentioned embodiments are intended to illustrate the objects, technical solutions and advantages of the present invention in further detail, and it should be understood that the above-mentioned embodiments are only exemplary embodiments of the present invention, and are not intended to limit the present invention, and any modifications, equivalents, improvements and the like made within the spirit and principle of the present invention should be included in the protection scope of the present invention.

Claims (4)

1. The water-based oil-free energy-saving environment-friendly efficient synthetic cutting fluid for machining is characterized by comprising the following components in parts by weight: the composite material is prepared by compounding the following components in percentage by weight:
Figure FDA0002398148860000011
2. the water-based oil-free energy-saving environment-friendly efficient synthetic cutting fluid for machining according to claim 1, characterized in that: the antirust compound liquid is compounded by the following components in percentage by weight:
Figure FDA0002398148860000012
3. the water-based oil-free energy-saving environment-friendly efficient synthetic cutting fluid for machining according to claim 2, characterized in that: the antirust compound liquid is prepared by mixing and compounding the components at the temperature of 32 ℃.
4. The water-based oil-free energy-saving environment-friendly efficient synthetic cutting fluid for machining according to claim 2, characterized in that: the weight percentage of each component is as follows:
Figure FDA0002398148860000013
the antirust compound liquid comprises the following components in percentage by weight:
Figure FDA0002398148860000014
Figure FDA0002398148860000021
CN202010138428.8A 2020-03-03 2020-03-03 Water-based oil-free energy-saving environment-friendly efficient synthetic cutting fluid for machining Pending CN111234909A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111647891A (en) * 2020-07-03 2020-09-11 苏州德韬科技有限公司 Water-based oil-free energy-saving environment-friendly efficient anti-rust water
CN111662772A (en) * 2020-06-28 2020-09-15 苏州德韬科技有限公司 Semisynthetic water-soluble cutting fluid for machining

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2632142A1 (en) * 1975-08-05 1977-02-10 Alusuisse OIL-IN-WATER EMULSION FOR COLD ROLLING LIGHT METALS
CN102888272A (en) * 2011-08-29 2013-01-23 孝感市江雁化工有限公司 Environment-friendly and high-cleanliness cutting solution and preparation method thereof
CN105482888A (en) * 2015-12-23 2016-04-13 南京科润工业介质股份有限公司 Complete synthesis cutting fluid capable of meeting machining requirements of multiple materials
CN108517251A (en) * 2018-04-20 2018-09-11 广东红日星实业有限公司 A kind of aqueous, environmental protective cutting fluid and preparation method
CN108774574A (en) * 2018-04-08 2018-11-09 清华大学天津高端装备研究院 A kind of total synthesis water-base antirust complexing agent and its evaluation method and application

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2632142A1 (en) * 1975-08-05 1977-02-10 Alusuisse OIL-IN-WATER EMULSION FOR COLD ROLLING LIGHT METALS
CN102888272A (en) * 2011-08-29 2013-01-23 孝感市江雁化工有限公司 Environment-friendly and high-cleanliness cutting solution and preparation method thereof
CN105482888A (en) * 2015-12-23 2016-04-13 南京科润工业介质股份有限公司 Complete synthesis cutting fluid capable of meeting machining requirements of multiple materials
CN108774574A (en) * 2018-04-08 2018-11-09 清华大学天津高端装备研究院 A kind of total synthesis water-base antirust complexing agent and its evaluation method and application
CN108517251A (en) * 2018-04-20 2018-09-11 广东红日星实业有限公司 A kind of aqueous, environmental protective cutting fluid and preparation method

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111662772A (en) * 2020-06-28 2020-09-15 苏州德韬科技有限公司 Semisynthetic water-soluble cutting fluid for machining
CN111647891A (en) * 2020-07-03 2020-09-11 苏州德韬科技有限公司 Water-based oil-free energy-saving environment-friendly efficient anti-rust water

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Application publication date: 20200605