CN108517251A - A kind of aqueous, environmental protective cutting fluid and preparation method - Google Patents
A kind of aqueous, environmental protective cutting fluid and preparation method Download PDFInfo
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- CN108517251A CN108517251A CN201810358690.6A CN201810358690A CN108517251A CN 108517251 A CN108517251 A CN 108517251A CN 201810358690 A CN201810358690 A CN 201810358690A CN 108517251 A CN108517251 A CN 108517251A
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- cutting fluid
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- protective cutting
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M173/00—Lubricating compositions containing more than 10% water
- C10M173/02—Lubricating compositions containing more than 10% water not containing mineral or fatty oils
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/06—Metal compounds
- C10M2201/062—Oxides; Hydroxides; Carbonates or bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/283—Esters of polyhydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/223—Five-membered rings containing nitrogen and carbon only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/06—Thio-acids; Thiocyanates; Derivatives thereof
- C10M2219/062—Thio-acids; Thiocyanates; Derivatives thereof having carbon-to-sulfur double bonds
- C10M2219/064—Thiourea type compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
- C10M2227/06—Organic compounds derived from inorganic acids or metal salts
- C10M2227/061—Esters derived from boron
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
- C10N2020/01—Physico-chemical properties
- C10N2020/055—Particles related characteristics
- C10N2020/06—Particles of special shape or size
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/18—Anti-foaming property
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Abstract
The present invention provides a kind of aqueous, environmental protective cutting fluids, raw material includes antirust agent, surfactant, extreme pressure agent, corrosion inhibiter, antifoaming agent and water, wherein antirust agent is made of organic alcohol amine and borate, surfactant is the mixture of polyethylene glycol synthetic emulsifier and compound polyhydric alcohol ester PE 25, extreme pressure agent is the mixture of ZDDP and nanoscale molybdenum oxide, corrosion inhibiter is the mixture of benzotriazole and thiocarbamide, antifoaming agent is at least one of B118, B103, B273 and B308, and the present invention also provides the preparation methods of above-mentioned aqueous, environmental protective cutting fluid.Inventive formulation raw material has water solubility, stability in water is good, oily precipitation is not had, and poisonous and harmful substance is free of, and it is environmental-friendly, it is machined using cutting fluid provided by the invention, the workpiece processed is highly polished, without additionally increasing cleaning step, reduces technological process, improve work efficiency.
Description
Technical field
The invention belongs to cutting fluid fields, and in particular to a kind of aqueous, environmental protective cutting fluid and preparation method.
Background technology
In processing manufacturing industry, metalworking fluid mainly plays cooling, lubrication, cleaning and antirust.Now in the art,
Cutting fluid lubricate, cool down, cleaning and whether antirust ability outstanding, selection with additive and using whether proper having closely
The performance that suitable additive can not only promote cutting fluid properties to act on is chosen in association, while being also ensured that cutting adds
The quality and efficiency of work.
CN103436343A discloses a kind of aqueous cutting fluid and preparation method thereof, main component include sorbic acid,
Decanedioic acid, diethanol amine, triethanolamine, sodium molybdate, boric acid, lubricant, benzotriazole, monoethanolamine, sodium nitrite and water,
The different processing operations such as grinding, cutting and wire cutting of the cutting fluid suitable for the processing of all kinds of precision machineries, have preferable
Antirust, cooling, lubrication and cleaning function, environmental pollution are small.CN104479826A is disclosed in a kind of superhard material process
Cutting fluid, which includes following several components：Molybdenum disulfide, tartaric acid, chlorinated paraffin, oleic acid, petroleum sodium sulfonate, with
And transformer oil and/or soya-bean oil, the cutting fluid being formulated using the inventive method can be in 600~1000 DEG C of hot conditions
Under still play lubrication and cooling effect, be particularly suitable for high hardness material machining, solve with general hard alloy cutter
The key technology of the Common Use Tools such as YG8, YT15, YW1 energy processing high-hardness material, this cutting fluid is relative to other cutting fluids
Advantage is that it can preferably be attached on the point of a knife of universal cutter, can be in the high temperature for cutting high hardness material, generating high heat
Under the conditions of normally cut high hardness material, greatly improve cutter life, regular turning tool when machining high hardness material,
The needs that production cost also solves actual production are reduced, it is convenient which prepares, and preparation cost is not high, however should
The service life of invention cutting fluid is unknown.CN103351932A discloses a kind of transparent water-soluble metalworking liquid, which includes：
Hydrophilic polyol, boric acid, sodium phosphate, aluminum alloy corrosion inhibitor, anion surfactant, nonionic surfactant and water,
Each substance is mixed by blender when preparation, you can obtain finely dispersed cutting fluid, which has good profit
Cunning, antirust, cooling, cleaning and environmental-protecting performance, overcome the big problem of existing cutting fluid exhaust emission, and performance is better than soap
Change dissolved oil, sulfurized oil and diesel oil, however the service life of the invention cutting fluid is unknown.
In conclusion being easy the problem that corruption is smelly, service life is very short in use in view of existing cutting fluid, have
A kind of environmental-friendly, service life length cutting fluid of necessity exploitation.
Invention content
To solve problems of the prior art, an object of the present invention is to provide a kind of aqueous, environmental protective cutting fluid.
The second object of the present invention is to provide the preparation method of above-mentioned line cutting fluid.
To achieve the above object, the present invention uses following technical scheme：
A kind of aqueous, environmental protective cutting fluid includes the component of following mass percent meter：
Antirust agent 15~20%,
Surfactant 4~8%,
Extreme pressure agent 3~6%,
Corrosion inhibiter 1~3%,
Antifoaming agent 0.5~2%,
Surplus is water.
Preferably, the antirust agent is made of organic alcohol amine and borate, and preparation method is：By organic alcohol amine and borate
It is stirred and heated to 60~80 DEG C.
It is further preferred that the weight ratio of the organic alcohol amine and borate is (4：1)~(3：2).
It is further preferred that the organic alcohol amine is triethanolamine.
Preferably, the surfactant is the mixture of polyethylene glycol synthetic emulsifier and compound polyhydric alcohol ester PE-25.
It is further preferred that the weight ratio of the polyethylene glycol synthetic emulsifier and compound polyhydric alcohol ester PE-25 are (3：1)
~(1：1).
Preferably, the extreme pressure agent is the mixture of ZDDP and nanoscale molybdenum oxide, the weight of the ZDDP and nanoscale molybdenum oxide
Amount is than being (5：1)~(3：1).
Preferably, the corrosion inhibiter is the mixture of benzotriazole and thiocarbamide, the weight of the benzotriazole and thiocarbamide
Amount is than being (1:10)~(1:15).
Preferably, the antifoaming agent is at least one of B118, B103, B273 and B308.
A kind of preparation method of aqueous, environmental protective cutting fluid, the preparation method is that：Each component is weighed according to the ratio, 60~80
DEG C antirust agent in sequentially add water, surfactant and extreme pressure agent stirring and dissolving after, sequentially add corrosion inhibiter and antifoaming agent
Stirring is complete to dissolving.
Beneficial effects of the present invention
1, inventive formulation raw material has water solubility, and stability in water is good, does not have oily precipitation, and have without toxic
Evil substance, it is environmental-friendly；
2, it is machined using cutting fluid provided by the invention, the workpiece processed is highly polished, increases without additional
Add cleaning step, reduce technological process, improves work efficiency；
3, be not in peculiar smell during cutting fluid service life length provided by the invention, use.
Specific implementation mode
Following embodiment is intended to further illustrate the content of present invention, rather than limits the protection model of the claims in the present invention
It encloses.
Each raw material is commercially available customary commercial as not having specified otherwise in being formulated in following embodiment.
Embodiment 1
The formula of four kinds of cutting fluids is present embodiments provided, that is, is formulated A~D, it is specific as shown in Table 1 and Table 2.
Table 1 is formulated the concrete component and content of A and B
Table 2 is formulated the concrete component and content of C and D
Embodiment 2
The preparation method of cutting fluid is present embodiments provided, specially：Each component is weighed according to the ratio, in 60~80 DEG C prevent
After sequentially adding water, surfactant and extreme pressure agent stirring and dissolving in rust agent, sequentially add corrosion inhibiter and antifoaming agent stir to
Dissolving is complete.
Embodiment 3
Four kinds of formulas of the preparation method and embodiment 1 that are provided using embodiment 2, are prepared for corresponding four kinds of line cutting fluids
Liquid A~D, performance are as shown in Table 3 and Table 4.
Table 3 is formulated the cutting fluid performance of A and B
Table 4 is formulated the cutting fluid performance of C and D
It is found that the cutting fluid stability of formula A and formula B are good, no layering, phase transformation and glue are tested for contrast table 3 and table 4
Resilient afterwards there are no oily precipitation, and rust-preventing characteristic, defoaming and corrosion resistance are good in addition.And it is formulated C and is formulated C's
Cutting fluid storage is unstable, and corrosion test is unqualified.
Embodiment 4
Carbide alloy YG 8 N is cut using formula two kinds of cutting fluids of A and C, the results are shown in Table 5.
The processing performance of 5 cutting fluid of table
As can be seen from Table 5, the cutting fluid prepared using inventive formulation, chip removal is smooth in process, makes for a long time
It is precipitated with floccule is not had, workpiece surface finish is high after processing, without additional cleaning.
Claims (10)
1. a kind of aqueous, environmental protective cutting fluid, which is characterized in that include the component of following mass percent meter：
Antirust agent 15~20%,
Surfactant 4~8%,
Extreme pressure agent 3~6%,
Corrosion inhibiter 1~3%,
Antifoaming agent 0.5~2%,
Surplus is water.
2. aqueous, environmental protective cutting fluid according to claim 1, which is characterized in that the antirust agent is by organic alcohol amine and boric acid
Ester is made, and preparation method is：Organic alcohol amine and borate are stirred and heated to 60~80 DEG C.
3. aqueous, environmental protective cutting fluid according to claim 2, which is characterized in that the weight of the organic alcohol amine and borate
Than being (4：1)~(3：2).
4. aqueous, environmental protective cutting fluid according to claim 3, which is characterized in that the organic alcohol amine is triethanolamine.
5. aqueous, environmental protective cutting fluid according to claim 1, which is characterized in that the surfactant closes for polyethylene glycol
At the mixture of emulsifier and compound polyhydric alcohol ester PE-25.
6. aqueous, environmental protective cutting fluid according to claim 5, which is characterized in that the polyethylene glycol synthetic emulsifier with it is multiple
The weight ratio for closing polyol ester PE-25 is (3：1)~(1：1).
7. aqueous, environmental protective cutting fluid according to claim 1, which is characterized in that the extreme pressure agent be ZDDP with it is nano oxidized
The weight ratio of the mixture of molybdenum, the ZDDP and nanoscale molybdenum oxide is (5：1)~(3：1).
8. aqueous, environmental protective cutting fluid according to claim 1, which is characterized in that the corrosion inhibiter is benzotriazole and sulphur
The weight ratio of the mixture of urea, the benzotriazole and thiocarbamide is (1:10)~(1:15).
9. aqueous, environmental protective cutting fluid according to claim 1, which is characterized in that the antifoaming agent is B118, B103, B273
At least one of with B308.
10. according to the preparation method of any one of the claim 1~9 aqueous, environmental protective cutting fluid, which is characterized in that the preparation
Method is：Each component is weighed according to the ratio, and water, surfactant and extreme pressure agent stirring are sequentially added in 60~80 DEG C of antirust agent
After dissolving, sequentially adds corrosion inhibiter and antifoaming agent is stirred to dissolving completely.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810358690.6A CN108517251A (en) | 2018-04-20 | 2018-04-20 | A kind of aqueous, environmental protective cutting fluid and preparation method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810358690.6A CN108517251A (en) | 2018-04-20 | 2018-04-20 | A kind of aqueous, environmental protective cutting fluid and preparation method |
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| Publication Number | Publication Date |
|---|---|
| CN108517251A true CN108517251A (en) | 2018-09-11 |
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ID=63429889
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810358690.6A Pending CN108517251A (en) | 2018-04-20 | 2018-04-20 | A kind of aqueous, environmental protective cutting fluid and preparation method |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111234909A (en) * | 2020-03-03 | 2020-06-05 | 诺而曼环保科技（江苏）有限公司 | Water-based oil-free energy-saving environment-friendly efficient synthetic cutting fluid for machining |
| CN112048362A (en) * | 2020-09-16 | 2020-12-08 | 江苏赢新润滑科技有限公司 | Environment-friendly superhard alloy processing liquid |
| CN114292690A (en) * | 2022-01-04 | 2022-04-08 | 南京工程学院 | Water-based metal processing lubricating fluid containing nano calcium tungstate, preparation method and preparation device |
| CN114874834A (en) * | 2022-05-27 | 2022-08-09 | 广东红日星实业有限公司 | Cutting fluid and preparation method and application thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102899146A (en) * | 2012-10-17 | 2013-01-30 | 沈阳创达技术交易市场有限公司 | Metal cutting lubricant |
-
2018
- 2018-04-20 CN CN201810358690.6A patent/CN108517251A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102899146A (en) * | 2012-10-17 | 2013-01-30 | 沈阳创达技术交易市场有限公司 | Metal cutting lubricant |
Non-Patent Citations (1)
| Title |
|---|
| 张欲凌: "水性环保纳米切削液的研究与应用", 《中国优秀硕士学位论文全文数据库》 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111234909A (en) * | 2020-03-03 | 2020-06-05 | 诺而曼环保科技（江苏）有限公司 | Water-based oil-free energy-saving environment-friendly efficient synthetic cutting fluid for machining |
| CN112048362A (en) * | 2020-09-16 | 2020-12-08 | 江苏赢新润滑科技有限公司 | Environment-friendly superhard alloy processing liquid |
| CN114292690A (en) * | 2022-01-04 | 2022-04-08 | 南京工程学院 | Water-based metal processing lubricating fluid containing nano calcium tungstate, preparation method and preparation device |
| CN114874834A (en) * | 2022-05-27 | 2022-08-09 | 广东红日星实业有限公司 | Cutting fluid and preparation method and application thereof |
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Application publication date: 20180911 |