CN109797033A - A kind of long-life magnesium alloy cutting fluid and preparation method thereof - Google Patents
A kind of long-life magnesium alloy cutting fluid and preparation method thereof Download PDFInfo
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- CN109797033A CN109797033A CN201910027520.4A CN201910027520A CN109797033A CN 109797033 A CN109797033 A CN 109797033A CN 201910027520 A CN201910027520 A CN 201910027520A CN 109797033 A CN109797033 A CN 109797033A
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Abstract
The invention discloses a kind of long-life magnesium alloy cutting fluids, component including following mass fraction: 6~10 parts of water-based antirust agent, 1~3 part of chelating agent, 5~8 parts of couplant, 15~20 parts of diluent, 3~5 parts of wetting agent, 1~3 part of extraordinary amine, 5~8 parts of emulsifier, hard water resistance dose 1~3 part, compound 1~2 part of the packet of corrosion inhibiter, compound 1~2 part of the packet of fungicide, 10~20 parts of base oil, 5~10 parts of water-based lubricant, 1~3 part of extreme-pressure lubricant, 20~25 parts of dispersing agent, 1~3 part of surfactant, compound 0.1~2 part of the packet of defoaming agent.A kind of long-life magnesium alloy cutting fluid provided by the invention can significantly improve the service life of magnesium alloy cutting fluid, and have inhibiting effect for the discoloration of magnesium alloy.The invention also discloses the preparation methods of above-mentioned long-life magnesium alloy cutting fluid.
Description
Technical field
The present invention relates to a kind of machining of metals liquid technical field, especially a kind of long-life magnesium alloy cutting fluid and
Preparation method.
Background technique
Cutting fluid is a kind of working solution for needing to meet various metals processing technology, such as needs to meet turnery processing, milling
Processing and spatter property, rust-preventing characteristic, lubricity, low bubble property and hard water resistance property in the processing technologys such as drilling processing etc.
It is required that furthermore in order to meet the requirement of environment protection health, usually also require without nitrite natrium, without chlorine, not sulfur-bearing in cutting fluid,
Ensure cutting fluid odorlessness, nontoxic, to plant personnel skin not allergy.
The most service life of magnesium alloy cutting fluid in the prior art is shorter, is just needed replacing later using a period of time
Working solution, to affect the working efficiency of magnesium alloy cutting;In addition, processed in conventional Cutting Process magnesium alloy when,
Magnesium alloy can have certain discoloration problem.
Summary of the invention
It for overcome the deficiencies in the prior art, can be significant the present invention provides a kind of long-life magnesium alloy cutting fluid
The service life of magnesium alloy cutting fluid is improved, and has inhibiting effect for the discoloration of magnesium alloy.
The technical solution adopted by the present invention to solve the technical problems is:
A kind of long-life magnesium alloy cutting fluid, the component including following mass fraction:
As above-mentioned technical proposal specific preferred, the water-based antirust agent is one in boric acid, neodecanoic acid and ternary acid
Kind or a variety of mixing, the ternary acid are the ternary polycarboxylic acids that Hangzhou Lv Pu chemical science and technology limited liability company provides
TAT730;The chelating agent is ETDA-2Na;The couplant is the mixed of one or both of monoethanolamine and triethanolamine
It closes;The diluent is deionized water;The wetting agent is glycerol.
As above-mentioned technical proposal specific preferred, the special type amine is one of dicyclohexyl amine and APM-95 special type amine
Or two kinds of mixing, the APM-95 special type amine are the AMP-95 multifunctional assistant that Dow Chemical Company provides, mainly at
It is divided into 2-amino-2-methyl-1-propanol, the water containing 5% mass ratio.
As above-mentioned technical proposal specific preferred, the emulsifier is the low bubble that Shang Qing Industrial Co., Ltd. in Shanghai provides
The mixing of one or both of efficient 2815 amide emulsifier of emulsifier Genifol SA6062 and Genimus;It is described anti-hard
Aqua is alcohol ether carboxylate;The base oil is naphthenic mineral oil.
As above-mentioned technical proposal specific preferred, the water-based lubricant is Nanjing Dan Yu new material Science and Technology Ltd.
The DY-70 synthetic ester of offer;The extreme-pressure lubricant is phosphoric acid ester oil grease.
It is as above-mentioned technical proposal it is specific preferably, the compound packet of corrosion inhibiter be aluminium corrosion inhibiter and copper inhibitor mixing and
At, and the aluminium corrosion inhibiter is the aluminium corrosion inhibiter NEUF815 that safe biotechnology (Hefei) Co. provides, the copper inhibition
Agent is water soluble copper corrosion inhibitor FUNTAG CU250.
As above-mentioned technical proposal specific preferred, the compound packet of fungicide is metal working fluid fungicide BK and metal
Working fluid fungicide MBM is mixed according to 2/1 mass ratio.
As above-mentioned technical proposal specific preferred, the dispersing agent is deionized water;The surfactant is sapn
80;The compound packet of defoaming agent is stirred evenly with long-life type defoaming agent according to 1/1 mass ratio for Quick-type defoaming agent to be made,
The Quick-type defoaming agent is the defoaming agent SE47 that German wacker chemicals provide, and the long-life type defoaming agent is that the bright icepro of Germany is public
The product type that department provides is the defoaming agent of Foam Ban MS-575.
The preparation method of above-mentioned long-life magnesium alloy cutting fluid, comprising the following steps:
S1: water-based antirust agent, chelating agent, couplant and diluent are weighed according to the ratio, is put into agitated kettle and stirs half an hour;
S2: wetting agent and extraordinary amine are weighed according to the ratio, is added in agitated kettle and stirs evenly;
S3: emulsifier and hard water resistance dose are weighed according to the ratio, is added in agitated kettle and stirs evenly;
S4: the compound packet of corrosion inhibiter and the compound packet of fungicide are weighed according to the ratio, is added in agitated kettle and stirs evenly;
S5: base oil, water-based lubricant, extreme-pressure lubricant and dispersing agent are weighed according to the ratio again, is added in agitated kettle
It stirs evenly;
S6: weighing surfactant according to the ratio, is added in agitated kettle and stirs evenly, and solution is yellow transparent liquid at this time
Body;
S7: finally weighing the compound packet of defoaming agent according to the ratio, is added in agitated kettle and stirs evenly acquisition finished product concentrate.
Further, further comprising the steps of:
S8: in use, finished product concentrate and water are made into the translucent working solution of micro emulsion according to 1/19 mass ratio.
A kind of long-life magnesium alloy cutting fluid provided by the present invention has beneficial below compared with prior art
Effect:
1, properties can meet or exceed chinese national standard GB/T7453-2013 and China Petroleum Ministry of Chemical Industry
Related index in ministerial standard SY 1374-77, can completely outside surrogate famous brand name similar product;
2, there is preferably lubricity, can be applied in the various processing equipments such as CNC, lathe for machining, milling machine, sawing machine, it can
Tool wear is effectively reduced, cutting-tool's used life is improved;
3, there is antirust cleaning function well, effective refractive power 46 ± 1% is keeping workpiece surface to clean bright antirust
At the same time it can also preferably cleaning workpiece;
5, by using a variety of special magnalium copper function corrosion inhibiter, it is suitable for the non-ferrous metals material workpiece such as magnalium copper
Processing, the especially processing of aluminum bronze part and part magnesium alloy member;
6, the compound packet of functional form formed by using various sterilization agent can effectively inhibit fungi, mould etc. to generate, constant
It is matter, not smelly, can single machine use, can also centralizedly supply use;
7, the achievable long-life uses and is recycled, and can be changed without new liquid for a long time, need to only carry out monitoring dimension family, in time
New liquid is supplemented, possessing certain concentration can be used for a long time;
8, there is preferable board rustless property, do not destroy paint, it is compatible with usually used lathe sealing element;
9, formula is free of chlorine, phenols and nitrite, also not poisonous and harmful substances such as sulfur-bearing, to no damage to human body, to ring
Border belongs to environmentally friendly machine without influence.
Specific embodiment
The present invention is further described combined with specific embodiments below.
Specific embodiment 1
A kind of long-life magnesium alloy cutting fluid provided by the present embodiment, the component including following mass fraction:
Specifically, the water-based antirust agent is one of boric acid, neodecanoic acid and ternary acid or a variety of mixing, described three
First acid is the ternary polycarboxylic acids TAT730 that Hangzhou Lv Pu chemical science and technology limited liability company provides;The chelating agent is ETDA-
2Na;The couplant is the mixing of one or both of monoethanolamine and triethanolamine;The diluent is deionized water;
The wetting agent is glycerol.The special type amine is the mixing of one or both of dicyclohexyl amine and APM-95 special type amine, described
APM-95 special type amine is the AMP-95 multifunctional assistant that Dow Chemical Company provides, and main component is 2- amino-2-methyl-
1- propyl alcohol, the water containing 5% mass ratio.The emulsifier is the efficient emulsifier of low bubble that Shang Qing Industrial Co., Ltd. in Shanghai provides
The mixing of one or both of 2815 amide emulsifier of Genifol SA6062 and Genimus;Described hard water resistance dose is alcohol ether
Carboxylic acid;The base oil is naphthenic mineral oil.The water-based lubricant provides for Nanjing Dan Yu new material Science and Technology Ltd.
DY-70 synthetic ester;The extreme-pressure lubricant is phosphoric acid ester oil grease.The compound packet of corrosion inhibiter is aluminium corrosion inhibiter and copper inhibition
Agent mixes, and the aluminium corrosion inhibiter is the aluminium corrosion inhibiter NEUF815 that safe biotechnology (Hefei) Co. provides, institute
Stating copper inhibitor is water soluble copper corrosion inhibitor FUNTAG CU250.The compound packet of the fungicide be metal working fluid fungicide BK and
Metal working fluid fungicide MBM is mixed according to 2/1 mass ratio.The dispersing agent is deionized water;The surface-active
Agent is sorbester p17;The compound packet of defoaming agent is that Quick-type defoaming agent and long-life type defoaming agent are stirred according to 1/1 mass ratio
It is uniformly made, the Quick-type defoaming agent is the defoaming agent SE47 that German wacker chemicals provide, and the long-life type defoaming agent is
The product type that German Ming Ling company provides is the defoaming agent of Foam Ban MS-575.
A kind of preparation method of long-life magnesium alloy cutting fluid provided by the present embodiment, comprising the following steps:
S1: water-based antirust agent, chelating agent, couplant and diluent are weighed according to the ratio, is put into agitated kettle and stirs half an hour.
S2: wetting agent and extraordinary amine are weighed according to the ratio, is added in agitated kettle and stirs evenly.
S3: emulsifier and hard water resistance dose are weighed according to the ratio, is added in agitated kettle and stirs evenly.
S4: the compound packet of corrosion inhibiter and the compound packet of fungicide are weighed according to the ratio, is added in agitated kettle and stirs evenly.
S5: base oil, water-based lubricant, extreme-pressure lubricant and dispersing agent are weighed according to the ratio again, is added in agitated kettle
It stirs evenly.
S6: weighing surfactant according to the ratio, is added in agitated kettle and stirs evenly, and solution is yellow transparent liquid at this time
Body.
S7: finally weighing the compound packet of defoaming agent according to the ratio, is added in agitated kettle and stirs evenly acquisition finished product concentrate.
S8: in use, finished product concentrate and water are made into the translucent working solution of micro emulsion according to 1/19 mass ratio.
Specific embodiment 2
A kind of long-life magnesium alloy cutting fluid provided by the present embodiment, the component including following mass fraction:
The specific raw material type of above-mentioned each component is identical as specific embodiment 1.
A kind of preparation method of long-life magnesium alloy cutting fluid, identical as specific embodiment 1 provided by the present embodiment.
Specific embodiment 3
A kind of long-life magnesium alloy cutting fluid provided by the present embodiment, the component including following mass fraction:
The specific raw material type of above-mentioned each component is identical as specific embodiment 1.
A kind of preparation method of long-life magnesium alloy cutting fluid, identical as specific embodiment 1 provided by the present embodiment.
Better embodiment of the invention is specifically described above, certainly, the present invention can also using with it is upper
The different form of embodiment is stated, those skilled in the art are made equivalent on the premise of without prejudice to spirit of the invention
Transformation or corresponding change, all should belong in protection scope of the present invention.
Claims (10)
1. a kind of long-life magnesium alloy cutting fluid, which is characterized in that the component including following mass fraction:
2. a kind of long-life magnesium alloy cutting fluid according to claim 1, it is characterised in that: the water-based antirust agent is
One of boric acid, neodecanoic acid and ternary acid or a variety of mixing, the ternary acid are that the green general chemical science and technology share in Hangzhou is limited
The ternary polycarboxylic acids TAT730 that company provides;The chelating agent is ETDA-2Na;The couplant is monoethanolamine and three ethyl alcohol
The mixing of one or both of amine;The diluent is deionized water;The wetting agent is glycerol.
3. a kind of long-life magnesium alloy cutting fluid according to claim 1, it is characterised in that: the special type amine is two rings
The mixing of one or both of hexylamine and APM-95 special type amine, the APM-95 special type amine provide for Dow Chemical Company
AMP-95 multifunctional assistant, main component is 2-amino-2-methyl-1-propanol, the water containing 5% mass ratio.
4. a kind of long-life magnesium alloy cutting fluid according to claim 1, it is characterised in that: the emulsifier is Shanghai
In the efficient 2815 amide emulsifier of emulsifier Genifol SA6062 and Genimus of low bubble that Shang Qing Industrial Co., Ltd. provides
One or two kinds of mixing;Described hard water resistance dose is alcohol ether carboxylate;The base oil is naphthenic mineral oil.
5. a kind of long-life magnesium alloy cutting fluid according to claim 1, it is characterised in that: the water-based lubricant is
The DY-70 synthetic ester that Nanjing Dan Yu new material Science and Technology Ltd. provides;The extreme-pressure lubricant is phosphoric acid ester oil grease.
6. a kind of long-life magnesium alloy cutting fluid according to claim 1, it is characterised in that: the compound packet of corrosion inhibiter
It is mixed for aluminium corrosion inhibiter and copper inhibitor, and the aluminium corrosion inhibiter is what safe biotechnology (Hefei) Co. provided
Aluminium corrosion inhibiter NEUF815, the copper inhibitor are water soluble copper corrosion inhibitor FUNTAG CU250.
7. a kind of long-life magnesium alloy cutting fluid according to claim 1, it is characterised in that: the compound packet of fungicide
It is mixed for metal working fluid fungicide BK and metal working fluid fungicide MBM according to 2/1 mass ratio.
8. a kind of long-life magnesium alloy cutting fluid according to claim 1, it is characterised in that: the dispersing agent be go from
Sub- water;The surfactant is sorbester p17;The compound packet of defoaming agent is that Quick-type defoaming agent is pressed with long-life type defoaming agent
It stirs evenly and is made according to 1/1 mass ratio, the Quick-type defoaming agent is the defoaming agent SE47 that German wacker chemicals provide, described
Long-life type defoaming agent is the defoaming agent that the product type that German Ming Ling company provides is Foam Ban MS-575.
9. according to claim 1 in -8 a kind of any long-life magnesium alloy cutting fluid preparation method, feature exists
In, comprising the following steps:
S1: water-based antirust agent, chelating agent, couplant and diluent are weighed according to the ratio, is put into agitated kettle and stirs half an hour;
S2: wetting agent and extraordinary amine are weighed according to the ratio, is added in agitated kettle and stirs evenly;
S3: emulsifier and hard water resistance dose are weighed according to the ratio, is added in agitated kettle and stirs evenly;
S4: the compound packet of corrosion inhibiter and the compound packet of fungicide are weighed according to the ratio, is added in agitated kettle and stirs evenly;
S5: base oil, water-based lubricant, extreme-pressure lubricant and dispersing agent are weighed according to the ratio again, is added in agitated kettle and stirs
Uniformly;
S6: weighing surfactant according to the ratio, is added in agitated kettle and stirs evenly, and solution is yellow transparent liquid at this time;
S7: finally weighing the compound packet of defoaming agent according to the ratio, is added in agitated kettle and stirs evenly acquisition finished product concentrate.
10. a kind of preparation method of long-life magnesium alloy cutting fluid according to claim 9, which is characterized in that also wrap
Include following steps:
S8: in use, finished product concentrate and water are made into the translucent working solution of micro emulsion according to 1/19 mass ratio.
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113897239A (en) * | 2021-10-15 | 2022-01-07 | 深圳市油博士润滑科技有限公司 | High-lubrication universal type total-synthesis cutting fluid |
CN114854482A (en) * | 2021-02-04 | 2022-08-05 | 广东铂索新材料科技有限公司 | High-performance copper cutting fluid |
CN114854480A (en) * | 2021-02-04 | 2022-08-05 | 广东铂索新材料科技有限公司 | Semisynthetic cutting fluid |
CN114854483A (en) * | 2021-02-04 | 2022-08-05 | 广东铂索新材料科技有限公司 | Water-soluble tungsten-molybdenum grinding fluid |
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CN104212620A (en) * | 2014-09-03 | 2014-12-17 | 句容金猴机械研究所有限公司 | Magnesium alloy cutting fluid and preparation method thereof |
CN106318586A (en) * | 2016-07-25 | 2017-01-11 | 广州亦盛环保科技有限公司 | Multifunctional semi-synthetic metal processing liquid and preparation method thereof |
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JPH01201400A (en) * | 1988-02-05 | 1989-08-14 | Kyodo Yushi Kk | Water-soluble metal working oil |
CN104212620A (en) * | 2014-09-03 | 2014-12-17 | 句容金猴机械研究所有限公司 | Magnesium alloy cutting fluid and preparation method thereof |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN114854482A (en) * | 2021-02-04 | 2022-08-05 | 广东铂索新材料科技有限公司 | High-performance copper cutting fluid |
CN114854480A (en) * | 2021-02-04 | 2022-08-05 | 广东铂索新材料科技有限公司 | Semisynthetic cutting fluid |
CN114854483A (en) * | 2021-02-04 | 2022-08-05 | 广东铂索新材料科技有限公司 | Water-soluble tungsten-molybdenum grinding fluid |
CN113897239A (en) * | 2021-10-15 | 2022-01-07 | 深圳市油博士润滑科技有限公司 | High-lubrication universal type total-synthesis cutting fluid |
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Address after: No.18, 4th Road, Nanhua Qijiao Industrial Zone, Xingtan town, Shunde District, Foshan City, Guangdong Province Applicant after: Guangdong platinum cable new material technology Co.,Ltd. Address before: No.18, 4th Road, Nanhua Qijiao Industrial Zone, Xingtan town, Shunde District, Foshan City, Guangdong Province Applicant before: FOSHAN BOOST LUBRICATING MATERIAL Co.,Ltd. |
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