CN104357204A - Environment-friendly water-based metal working fluid and preparation method thereof - Google Patents

Environment-friendly water-based metal working fluid and preparation method thereof Download PDF

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Publication number
CN104357204A
CN104357204A CN201410498991.0A CN201410498991A CN104357204A CN 104357204 A CN104357204 A CN 104357204A CN 201410498991 A CN201410498991 A CN 201410498991A CN 104357204 A CN104357204 A CN 104357204A
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China
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environment
water
parts
working fluid
metal working
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CN201410498991.0A
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Chinese (zh)
Inventor
张明
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Qingdao Baizhong Chemical Technology Co Ltd
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Qingdao Baizhong Chemical Technology Co Ltd
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Priority to CN201410498991.0A priority Critical patent/CN104357204A/en
Publication of CN104357204A publication Critical patent/CN104357204A/en
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Abstract

The invention relates to an environment-friendly water-based metal working fluid and a preparation method thereof. The water-based metal working fluid comprises the following ingredients in parts by weight: 15-20 parts of fatty alcohol-polyoxyethylene ether, 15-20 parts of coconut oil fatty acid diethanolamide, 15-20 parts of coconut oil amine polyoxyethylene ether, 3-6 parts of a rosin alcohol solution, 2-5 parts of a synthetic antirusting agent, 0.1-0.2 part of a defoaming agent, 0.3-0.5 part of benzotriazole and the balance of water. The water-based metal working fluid is good in lubricity, high in anti-rust property, high in antibacterial ability, high in stability, and long in service life, does not pollute the environment, is harmless to the human body, and comprehensively satisfies the requirements of highly difficult machining for cutting.

Description

A kind of environment-friendly type water metalworking fluid and preparation method thereof
technical field
The present invention relates to a kind of environment-friendly type water metalworking fluid and preparation method thereof, belong to metal processing sectors.
technical background
Current domestic traditional intermetallic composite coating enterprise great majority use Sodium Nitrite and oil in water emulsion to allocate making metal working fluid voluntarily for main raw material, some enterprises are also had to use common finish and emulsifying agent to be made as metal working fluid, there is contaminate environment in above-mentioned metal working fluid, perishable smelly, harmful to the person, lathe, cutter and work material, harm worker is healthy, also there is working fluid corrosion processing material, knife sharpener consumption is large, the shortcomings such as unstable product quality.
Modern mechanical processing also makes machining difficulty day by day increase to the development of the difficult-to-machine material such as high speed, brute force, accurate future development, superhard, super-strength.The reason of these two aspects causes the frictional force in cutting process, heat of friction increases substantially, and this just requires that metal working fluid has better lubrication, cooling, cleaning, rustless property, to obtain desirable finished surface.The lubrication of mineral lubricating oils, rustless property is superior, but cooling, cleaning performance is poor; Cooling, the cleaning performance of emulsion are excellent, but lubrication, rustless property are poor.
Summary of the invention
The object of this invention is to provide and a kind ofly improve grinding speed, grinding temperature is cut in reduction, biodegradable, environmental pollution is little, cost is low metal working fluid.
For realizing above object, a kind of environment-friendly type water metalworking fluid of the present invention, its component and weight proportion are: fatty alcohol-polyoxyethylene ether 15-20 part; Cocoanut fatty acid diethanolamide 15-20 part; Coco amine Soxylat A 25-7 15-20 part; Rosin spirituous solution 3-6 part; Synthesis rust-preventive agent 2-5 part; Defoamer 0.1-0.2 part; Benzotriazole 0.3-0.5 part; The water of surplus.
Further, described synthesis rust-preventive agent comprises Sodium hexametaphosphate 99, triethanolamine oleate ester and water.
Further, in described synthesis rust-preventive agent, the mass ratio of Sodium hexametaphosphate 99, triethanolamine oleate ester and water is 1-2:4-5:10.
A preparation method for environment-friendly type water metalworking fluid, comprises the steps:
Fatty alcohol-polyoxyethylene ether, cocoanut fatty acid diethanolamide, coco amine Soxylat A 25-7, rosin spirituous solution, synthesis rust-preventive agent, defoamer, benzotriazole and water are mixed in proportion, and stir, through after the assay was approved, obtained environment-friendly type water metalworking fluid.
The beneficial effect that the present invention produces is:
(1) cooling performance is given prominence to: greatly can take away heat in metal cutting and fully cool cutter, it is made to keep hardness, intensity, working fluid in use can infiltrate in the superfine microfracture of workpiece cutting surface, make surface metal lattice brittle, machining is easily carried out, thus improves working efficiency.
(2) oilness superior performance: form oil-bound film in cutting zone, the last non seizure load PB value of cutting fluid can reach more than 716N, reduce frictional coefficient, reduce heat generation, reduce cutting force, reduce the consumption of cutter and emery wheel, significant prolongation cutter life, surface processing accuracy significantly improves, and solves lubrication and antirust contradiction between the two well.
(3) excellent stability: the physical and chemical stability that complete synthesis structural rigidity regulates automatically and anti-waste oil ability ensures under high pressure, under correct maintenance, can life-time service.When storing and use, not stratified, can not throw out be separated out, not easily corrupt, do not produce the gas hindering workers ' health.Simultaneously also not containing carcinogenic substances such as nitrite, Working environment is totally tasteless, and adding man-hour can clear observation workpiece surface.Work waste liquid is few, greatly reduces environmental pollution.
Embodiment
Embodiment 1
A kind of environment-friendly type water metalworking fluid, its component and weight proportion are: fatty alcohol-polyoxyethylene ether 15 parts; Cocoanut fatty acid diethanolamide 15 parts; Coco amine Soxylat A 25-7 20 parts; Rosin spirituous solution 3 parts; Synthesis rust-preventive agent 2 parts; Defoamer 0.1 part; Benzotriazole 0.5 part; 44.4 parts, water.In described synthesis rust-preventive agent, the mass ratio of Sodium hexametaphosphate 99, triethanolamine oleate ester and water is 1:4:10.
Embodiment 2
A kind of environment-friendly type water metalworking fluid, its component and weight proportion are: fatty alcohol-polyoxyethylene ether 15 parts; Cocoanut fatty acid diethanolamide 20 parts; Coco amine Soxylat A 25-7 15 parts; Rosin spirituous solution 5 parts; Synthesis rust-preventive agent 5 parts; Defoamer 0.15 part; Benzotriazole 0.4 part; 39.45 parts, water.In described synthesis rust-preventive agent, the mass ratio of Sodium hexametaphosphate 99, triethanolamine oleate ester and water is 1:5:10.
Embodiment 3
A kind of environment-friendly type water metalworking fluid, its component and weight proportion are: fatty alcohol-polyoxyethylene ether 20 parts; Cocoanut fatty acid diethanolamide 15 parts; Coco amine Soxylat A 25-7 15 parts; Rosin spirituous solution 6 parts; Synthesis rust-preventive agent 3 parts; Defoamer 0.1 part; Benzotriazole 0.5 part; 40.4 parts, water.In described synthesis rust-preventive agent, the mass ratio of Sodium hexametaphosphate 99, triethanolamine oleate ester and water is 2:5:10.
Embodiment 4
The preparation method of a kind of environment-friendly type water metalworking fluid of the present invention is, fatty alcohol-polyoxyethylene ether, cocoanut fatty acid diethanolamide, coco amine Soxylat A 25-7, rosin spirituous solution, synthesis rust-preventive agent, defoamer, benzotriazole and water are mixed in proportion, and stir, through after the assay was approved, obtained environment-friendly type water metalworking fluid.
 
Product performance detect: carry out performance measurement according to the method for GB GB6144-2010 to the emulsion in above-described embodiment, result is as following table 1.
Table 1 is the performance index of metal working fluid of the present invention
Project Embodiment 1 Embodiment 2 Embodiment 3
Outward appearance Transparent incarnadine Transparent incarnadine Transparent incarnadine
Storage stability Qualified Qualified Qualified
PH value 8-9 8-9 8-9
Defoaming (mL/10min) ≤1 ≤1 ≤1
Corrodibility (grey cast iron) A level A level A level
Corrodibility (red copper) A level A level A level
Corrodibility (aluminium alloy) A level A level A level
Rust-preventing characteristic (monolithic) A level A level A level
Rust-preventing characteristic (monolithic) A level A level A level

Claims (4)

1. an environment-friendly type water metalworking fluid, is characterized in that: its component and weight proportion are:
Fatty alcohol-polyoxyethylene ether 15-20 part;
Coco amine Soxylat A 25-7 15-20 part;
Cocoanut fatty acid diethanolamide 15-20 part;
Rosin spirituous solution 3-6 part;
Synthesis rust-preventive agent 2-5 part;
Defoamer 0.1-0.2 part;
Benzotriazole 0.3-0.5 part;
The water of surplus.
2. a kind of environment-friendly type water metalworking fluid as claimed in claim 1, is characterized in that: described synthesis rust-preventive agent comprises Sodium hexametaphosphate 99, triethanolamine oleate ester and water.
3. a kind of environment-friendly type water metalworking fluid as claimed in claim 2, is characterized in that: in described synthesis rust-preventive agent, the mass ratio of Sodium hexametaphosphate 99, triethanolamine oleate ester and water is 1-2:4-5:10.
4. the preparation method of a kind of environment-friendly type water metalworking fluid as claimed in claim 1, is characterized in that:
Fatty alcohol-polyoxyethylene ether, cocoanut fatty acid diethanolamide, coco amine Soxylat A 25-7, rosin spirituous solution, synthesis rust-preventive agent, defoamer, benzotriazole and water are mixed in proportion, and stir, through after the assay was approved, obtained environment-friendly type water metalworking fluid.
CN201410498991.0A 2014-09-26 2014-09-26 Environment-friendly water-based metal working fluid and preparation method thereof Pending CN104357204A (en)

Priority Applications (1)

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CN201410498991.0A CN104357204A (en) 2014-09-26 2014-09-26 Environment-friendly water-based metal working fluid and preparation method thereof

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Application Number Priority Date Filing Date Title
CN201410498991.0A CN104357204A (en) 2014-09-26 2014-09-26 Environment-friendly water-based metal working fluid and preparation method thereof

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CN104357204A true CN104357204A (en) 2015-02-18

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104694242A (en) * 2015-03-26 2015-06-10 南通市明建生物科技有限公司 Water-based metal cutting fluid with rust preventing function and preparing method thereof
CN105778863A (en) * 2016-04-20 2016-07-20 廊坊市北方天宇机电技术有限公司 Grinding fluid for aluminum wheel barreling-fishing machining and preparation method thereof
CN112029564A (en) * 2020-09-09 2020-12-04 南京科润工业介质股份有限公司 Neutral water-based antirust agent

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102618374A (en) * 2012-03-07 2012-08-01 东莞市安美润滑科技有限公司 Water-based cutting fluid used in slice machining of hard brittle crystal material and preparation method of water-based cutting fluid
CN102807912A (en) * 2012-09-13 2012-12-05 济南库伦特科技有限公司 Micro-emulsified cutting fluid production additive package and preparation method and application thereof
CN103666720A (en) * 2013-12-05 2014-03-26 马鞍山市恒毅机械制造有限公司 Stable semi-synthetic cutting fluid and preparation method thereof
CN104004580A (en) * 2014-05-27 2014-08-27 安徽蓝德集团股份有限公司 Method for processing total synthesis cutting fluid
CN104017636A (en) * 2014-06-06 2014-09-03 清华大学 Water soluble full-alloy metal grinding fluid

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102618374A (en) * 2012-03-07 2012-08-01 东莞市安美润滑科技有限公司 Water-based cutting fluid used in slice machining of hard brittle crystal material and preparation method of water-based cutting fluid
CN102807912A (en) * 2012-09-13 2012-12-05 济南库伦特科技有限公司 Micro-emulsified cutting fluid production additive package and preparation method and application thereof
CN103666720A (en) * 2013-12-05 2014-03-26 马鞍山市恒毅机械制造有限公司 Stable semi-synthetic cutting fluid and preparation method thereof
CN104004580A (en) * 2014-05-27 2014-08-27 安徽蓝德集团股份有限公司 Method for processing total synthesis cutting fluid
CN104017636A (en) * 2014-06-06 2014-09-03 清华大学 Water soluble full-alloy metal grinding fluid

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104694242A (en) * 2015-03-26 2015-06-10 南通市明建生物科技有限公司 Water-based metal cutting fluid with rust preventing function and preparing method thereof
CN105778863A (en) * 2016-04-20 2016-07-20 廊坊市北方天宇机电技术有限公司 Grinding fluid for aluminum wheel barreling-fishing machining and preparation method thereof
CN105778863B (en) * 2016-04-20 2018-06-29 廊坊市北方天宇机电技术有限公司 A kind of aluminium wheel centrifugal barrel finishing grinding fluid and preparation method thereof
CN112029564A (en) * 2020-09-09 2020-12-04 南京科润工业介质股份有限公司 Neutral water-based antirust agent

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Application publication date: 20150218

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