CN107353995A - A kind of environment-friendly type fully synthetic cutting fluid and preparation method thereof - Google Patents
A kind of environment-friendly type fully synthetic cutting fluid and preparation method thereof Download PDFInfo
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- CN107353995A CN107353995A CN201710603450.3A CN201710603450A CN107353995A CN 107353995 A CN107353995 A CN 107353995A CN 201710603450 A CN201710603450 A CN 201710603450A CN 107353995 A CN107353995 A CN 107353995A
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M173/00—Lubricating compositions containing more than 10% water
- C10M173/02—Lubricating compositions containing more than 10% water not containing mineral or fatty oils
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M141/00—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential
- C10M141/12—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential at least one of them being an organic compound containing atoms of elements not provided for in groups C10M141/02 - C10M141/10
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/08—Inorganic acids or salts thereof
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/087—Boron oxides, acids or salts
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
- C10M2207/127—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids polycarboxylic
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/14—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings
- C10M2207/141—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings monocarboxylic
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/109—Polyethers, i.e. containing di- or higher polyoxyalkylene groups esterified
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/223—Five-membered rings containing nitrogen and carbon only
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
- C10M2227/06—Organic compounds derived from inorganic acids or metal salts
- C10M2227/061—Esters derived from boron
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
- C10M2229/02—Unspecified siloxanes; Silicones
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling
Abstract
A kind of environment-friendly type fully synthetic cutting fluid and preparation method thereof, the cutting fluid include following components by mass percentage:Composite lubricated antirust agent 10 30%, surfactant 1 3%, defoamer 0.1 1%, bactericide 0.1 2%, PH regulators 1 5%, corrosion inhibiter 1 2%, remaining is deionized water, and the cutting fluid compensate for deficiency of the existing water-base cutting fluid in rust-preventing characteristic, lubricity, high/low temperature good stability is non-discolouring, human body skin is had no stimulation, biological stability is good, and safety and environmental protection is non-stimulated.
Description
Technical field
The present invention designs a kind of cutting fluid, especially designs a kind of environment-friendly type fully synthetic cutting fluid and preparation method thereof, belongs to
Cutting fluid technical field.
Background technology
Cutting fluid is a kind of in metal cutting, mill process, for cooling down and lubricating the work of cutter and workpiece
Industry liquid, its from multiple functions auxiliary agent it is compound through science with form.Its main function includes cooling, lubrication, antirust and clear
Wash four aspects.The cutting fluid typically used is mainly oil base and water base two class, and in recent years, water-base cutting fluid is in cooling, clear
Washing property, rust-preventing characteristic, lubricity etc. have distinguishing feature and are used widely.Aqueous cutting fluid can be divided into micro emulsion
Type, emulsifying and fully synthetic type, compared with micro-emulsion type and emulsified cutting fluid, fully synthetic cutting fluid is free of mineral oil, its each group
Point such as antirust agent, extreme-pressure anti-friction additive, surfactant and defoamer multiple additives are soluble in water, and dilution is in
Translucent or transparent shape.Fully synthetic cutting fluid has following major advantage:(1)Excellent cooling and cleaning performance, therefore be adapted to
High-speed cutting processing;(2)Solution is transparent, has good observability, is particularly suitable for the modern processing such as Digit Control Machine Tool, machining center
Equipment uses;(3)Without mineral oil, then it is difficult to using process putrid and deteriorated, therefore service life is grown.
Fully synthetic cutting fluid is made up of a variety of chemical compositions, without mineral oil, therefore the greasy property of fully synthetic cutting fluid
Poor with extreme pressure property, in fundamentally cannot be used, heavy load machining, in order to reach rust-proof effect, in the market is much closed entirely
Contain cheap antirust agent nitrite into cutting liquid product, nitrite is potential carcinogenic substance, and Long Term Contact can influence to grasp
Make the health of personnel.In addition, synthetic cutting fluid of the prior art also has poor lubricity, extreme pressure value is low, rustless property
The shortcomings of weak and compatible insufficient.
The content of the invention
For defect present in prior art, it is an object of the invention to provide a kind of environment-friendly type fully synthetic cutting fluid and
Its preparation method, the cutting fluid compensate for deficiency of the existing water-base cutting fluid in rust-preventing characteristic, lubricity, high/low temperature good stability
It is non-discolouring, human body skin is had no stimulation, biological stability is good, and safety and environmental protection is non-stimulated.
To achieve the above object, the technical solution adopted by the present invention is:A kind of environment-friendly type fully synthetic cutting fluid, its feature exist
In:It is made up of the percentage by weight of following component:Composite lubricated antirust agent 10-30%, surfactant 1-3%, defoamer 0.1-
1%, bactericide 0.1-2%, PH regulator 1-5%, corrosion inhibiter 1-2%, remaining is deionized water.
Described composite lubricated antirust agent is according to mass ratio 2 by triethanolamine borate ester and decanedioic acid triethanolamine salt:1
Compounding forms.
Described surfactant is Tween-80.
Described defoamer is water-soluble organic silicon defoamer.
Described bactericide is sodium benzoate.
Described PH regulators are one or both of sodium tetraborate or salicylic acid mixture.
Described corrosion inhibiter is the mixture of borax, ammonium molybdate, one or more of arbitrary proportions in BTA.
The preparation method of described environment-friendly type fully synthetic cutting fluid, is comprised the following steps that:
(1)The PH regulators that proportional quantity is added in 30% proportional quantity deionized water stir, and sequentially add defoamer, kill
Microbial inoculum, corrosion inhibiter are stirred to being completely dissolved;
(2)After the composite lubricated antirust agent of proportional quantity is mixed evenly, adds proportional quantity surfactant and stir;
(3)By step(2)In semi-finished product pour into step(1)Reaction system in, stir;
(4)Remaining 70% proportional quantity deionized water repeats rinsing step(2)The container of making, and washing lotion is all returned into step(1)
Reaction system in, continue stirring until solution homogeneous transparent, that is, finished product be made.
The environment-friendly type fully synthetic cutting fluid that the present invention improves, compounded, obtained composite lubricated anti-using borate and carboxylate
Rust agent, is solved in fully synthetic cutting fluid component in the prior art if its general greasy property is relatively poor without mineral oil
Problem.Environment-friendly type fully synthetic cutting fluid provided by the invention employs the additive combination of easily biological-degradable, solves in the market
The problem of lubricity and rust-preventing characteristic difference of like product generally existing, in can be used for, in heavy load machining, suitable for numerical control
The automated production equipments such as lathe, machining center, and be easily handled in being formulated without nitrite, aldehydes matter, waste liquid, will not
Environment is damaged, there is good environment friendly.
Specific implementation method
With reference to example, the present invention will be described in detail, so that advantages and features of the invention can be easier to by this area skill
Art personnel understand, apparent are clearly defined so as to be made to protection scope of the present invention.
Embodiment 1
A kind of environment-friendly type fully synthetic cutting fluid, is made up of the percentage by weight of following component:Composite lubricated antirust agent 25%, surface
Activating agent 2%, defoamer 0.5%, bactericide 1%, PH regulators 3%, corrosion inhibiter 1%, remaining is deionized water.
Wherein composite lubricated antirust agent is triethanolamine borate ester and decanedioic acid triethanolamine salt according to mass ratio 2:1 compounding
Form, surfactant is Tween-80, and defoamer is water-soluble organic silicon defoamer, and bactericide is sodium benzoate, PH regulators
For sodium tetraborate, corrosion inhibiter is borax.
The preparation method of above-mentioned environment-friendly type fully synthetic cutting fluid, comprises the following steps:
(1)The sodium tetraborate that proportional quantity is added in 30% proportional quantity deionized water stirs, and sequentially adds water-soluble organic
Silicon defoaming agent, sodium benzoate, borax are stirred to being completely dissolved;
(2)After the composite lubricated antirust agent of proportional quantity is mixed evenly, adds proportional quantity Tween-80 and stir;
(3)By step(2)In semi-finished product pour into step(1)Reaction system in, stir;
(4)Remaining 70% proportional quantity deionized water repeats rinsing step(2)The container of making, and washing lotion is all returned into step(1)
Reaction system in, continue stirring until solution homogeneous transparent, that is, finished product be made.
Embodiment 2
A kind of environment-friendly type fully synthetic cutting fluid, is made up of the percentage by weight of following component:Composite lubricated antirust agent 30%, surface
Activating agent 3%, defoamer 1%, bactericide 0.5%, PH regulators 1%, corrosion inhibiter 1%, remaining is deionized water.
Wherein composite lubricated antirust agent is triethanolamine borate ester and decanedioic acid triethanolamine salt according to mass ratio 2:1 compounding
Form, surfactant is Tween-80, and defoamer is water-soluble organic silicon defoamer, and bactericide is sodium benzoate, PH regulators
For salicylic acid, corrosion inhibiter is BTA.
The preparation method of above-mentioned environment-friendly type fully synthetic cutting fluid, comprises the following steps:
(1)The salicylic acid that proportional quantity is added in 30% proportional quantity deionized water stirs, and sequentially adds water-soluble organic silicon
Defoamer, sodium benzoate, BTA are stirred to being completely dissolved;
(2)After the composite lubricated antirust agent of proportional quantity is mixed evenly, adds proportional quantity Tween-80 and stir;
(3)By step(2)In semi-finished product pour into step(1)Reaction system in, stir;
(4)Remaining 70% proportional quantity deionized water repeats rinsing step(2)The container of making, and washing lotion is all returned into step(1)
Reaction system in, continue stirring until solution homogeneous transparent, that is, finished product be made.
Embodiment 3
A kind of environment-friendly type fully synthetic cutting fluid, is made up of the percentage by weight of following component:Composite lubricated antirust agent 20%, surface
Activating agent 2%, defoamer 0.5%, bactericide 1%, PH regulators 2%, corrosion inhibiter 2%, remaining is deionized water.
Wherein composite lubricated antirust agent is triethanolamine borate ester and decanedioic acid triethanolamine salt according to mass ratio 2:1 compounding
Form, surfactant is Tween-80, and defoamer is water-soluble organic silicon defoamer, and bactericide is sodium benzoate, PH regulators
For salicylic acid, corrosion inhibiter is ammonium molybdate.
The preparation method of above-mentioned environment-friendly type fully synthetic cutting fluid, comprises the following steps:
(1)The salicylic acid that proportional quantity is added in 30% proportional quantity deionized water stirs, and sequentially adds water-soluble organic silicon
Defoamer, sodium benzoate, ammonium molybdate are stirred to being completely dissolved;
(2)After the composite lubricated antirust agent of proportional quantity is mixed evenly, adds proportional quantity Tween-80 and stir;
(3)By step(2)In semi-finished product pour into step(1)Reaction system in, stir;
(4)Remaining 70% proportional quantity deionized water repeats rinsing step(2)The container of making, and washing lotion is all returned into step(1)
Reaction system in, continue stirring until solution homogeneous transparent, that is, finished product be made.
According to GB/T6144-2010 respectively to the outward appearance of embodiment 1,2,3, storage stability, transparency, pH value, foam
Property, surface tension, corrosion test, rust prevention test, maximum nonseizure load PBTested etc. project, test result is shown in Table 1.
Table 1.
After testing, embodiment 1,2,3 show excellent rust-preventing characteristic, extreme pressure anti-wear, compensate for water-base cutting fluid
Deficiency, indices are satisfied by meeting the requirements.
It is described above, it is only the specific implementation method of the present invention, but protection scope of the present invention is not limited thereto, and it is any
Those skilled in the art disclosed herein technical scope in, can without the change that creative work is expected or
Replace, should all be included within the scope of the present invention.Therefore, protection scope of the present invention should be limited with claims
Fixed protection domain is defined.
Claims (8)
- A kind of 1. environment-friendly type fully synthetic cutting fluid, it is characterised in that:It is made up of the percentage by weight of following component:It is composite lubricated anti- Become rusty agent 10-30%, surfactant 1-3%, defoamer 0.1-1%, bactericide 0.1-2%, PH regulator 1-5%, corrosion inhibiter 1-2%, Remaining is deionized water.
- 2. environment-friendly type fully synthetic cutting fluid according to claim 1, it is characterised in that:Described composite lubricated antirust agent is By triethanolamine borate ester and decanedioic acid triethanolamine salt according to mass ratio 2:1 compounding forms.
- 3. environment-friendly type fully synthetic cutting fluid according to claim 1, it is characterised in that:Described surfactant is to tell Temperature -80.
- 4. environment-friendly type fully synthetic cutting fluid according to claim 1, it is characterised in that:Described defoamer has for water solubility Machine silicon defoaming agent.
- 5. environment-friendly type fully synthetic cutting fluid according to claim 1, it is characterised in that:Described bactericide is benzoic acid Sodium.
- 6. environment-friendly type fully synthetic cutting fluid according to claim 1, it is characterised in that:Described PH regulators are tetraboric acid One or both of sodium or salicylic acid mixture.
- 7. environment-friendly type fully synthetic cutting fluid according to claim 1, it is characterised in that:Described corrosion inhibiter is borax, molybdenum The mixture of one or more of arbitrary proportions in sour ammonium, BTA.
- 8. the preparation method of environment-friendly type fully synthetic cutting fluid according to claim 1, it is characterised in that:Specific steps are such as Under:(1)The PH regulators that proportional quantity is added in 30% proportional quantity deionized water stir, and sequentially add defoamer, kill Microbial inoculum, corrosion inhibiter are stirred to being completely dissolved;(2)After the composite lubricated antirust agent of proportional quantity is mixed evenly, adds proportional quantity surfactant and stir;(3)By step(2)In semi-finished product pour into step(1)Reaction system in, stir;(4)Remaining 70% proportional quantity deionized water repeats rinsing step(2)The container of making, and washing lotion is all returned into step(1) Reaction system in, continue stirring until solution homogeneous transparent, that is, finished product be made.
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Cited By (4)
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CN107384561A (en) * | 2017-08-01 | 2017-11-24 | 屏南县康迈精选科技有限公司 | A kind of fully synthetic cutting fluid |
CN109054976A (en) * | 2018-08-16 | 2018-12-21 | 中国石油大学(华东) | A kind of fully synthetic cutting liquid of environment-friendly type suitable for plasma cutting slit screen pipes |
CN112899061A (en) * | 2021-01-26 | 2021-06-04 | 自贡硬质合金有限责任公司 | Special water-based grinding fluid for hard alloy and preparation method thereof |
CN114437862A (en) * | 2022-02-25 | 2022-05-06 | 广东孚延盛科技有限公司 | Water-based environment-friendly antirust aluminum foil punching and shearing liquid and preparation method thereof |
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CN104479833A (en) * | 2014-12-17 | 2015-04-01 | 江苏鑫露新材料股份有限公司 | High-efficiency safe environment-friendly all-synthetic cutting fluid and preparation method thereof |
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CN109054976A (en) * | 2018-08-16 | 2018-12-21 | 中国石油大学(华东) | A kind of fully synthetic cutting liquid of environment-friendly type suitable for plasma cutting slit screen pipes |
CN112899061A (en) * | 2021-01-26 | 2021-06-04 | 自贡硬质合金有限责任公司 | Special water-based grinding fluid for hard alloy and preparation method thereof |
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Application publication date: 20171117 |