CN104762127A - Nano aqueous completely-synthetic environmental-friendly metal working fluid - Google Patents
Nano aqueous completely-synthetic environmental-friendly metal working fluid Download PDFInfo
- Publication number
- CN104762127A CN104762127A CN201510117306.XA CN201510117306A CN104762127A CN 104762127 A CN104762127 A CN 104762127A CN 201510117306 A CN201510117306 A CN 201510117306A CN 104762127 A CN104762127 A CN 104762127A
- Authority
- CN
- China
- Prior art keywords
- working fluid
- metal working
- nano
- environmentally friendly
- friendly metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
- 238000005555 metalworking Methods 0.000 title claims abstract description 22
- 239000012530 fluid Substances 0.000 title claims abstract description 21
- 150000001412 amines Chemical class 0.000 claims abstract description 7
- 239000000314 lubricant Substances 0.000 claims abstract description 7
- 239000002086 nanomaterial Substances 0.000 claims abstract description 7
- 150000007524 organic acids Chemical class 0.000 claims abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 5
- 230000015572 biosynthetic process Effects 0.000 claims description 13
- 238000003786 synthesis reaction Methods 0.000 claims description 13
- YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical compound C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 claims description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 6
- 239000013543 active substance Substances 0.000 claims description 6
- 239000013530 defoamer Substances 0.000 claims description 6
- -1 sulfamic acid compound Chemical class 0.000 claims description 6
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical group NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 4
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 4
- 239000012964 benzotriazole Substances 0.000 claims description 4
- 239000000839 emulsion Substances 0.000 claims description 4
- 229910021389 graphene Inorganic materials 0.000 claims description 4
- 229920001296 polysiloxane Polymers 0.000 claims description 4
- 229960004418 trolamine Drugs 0.000 claims description 4
- HXKKHQJGJAFBHI-UHFFFAOYSA-N 1-aminopropan-2-ol Chemical compound CC(O)CN HXKKHQJGJAFBHI-UHFFFAOYSA-N 0.000 claims description 3
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical group CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims description 3
- OTLNPYWUJOZPPA-UHFFFAOYSA-N 4-nitrobenzoic acid Chemical compound OC(=O)C1=CC=C([N+]([O-])=O)C=C1 OTLNPYWUJOZPPA-UHFFFAOYSA-N 0.000 claims description 3
- HJHKQTDOQPBKDB-UHFFFAOYSA-N C(=O)O.C(CCCCC)C1=CC=CC=C1 Chemical compound C(=O)O.C(CCCCC)C1=CC=CC=C1 HJHKQTDOQPBKDB-UHFFFAOYSA-N 0.000 claims description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 3
- 125000003354 benzotriazolyl group Chemical group N1N=NC2=C1C=CC=C2* 0.000 claims description 3
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 3
- 229910044991 metal oxide Inorganic materials 0.000 claims description 3
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 3
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 3
- 231100000111 LD50 Toxicity 0.000 abstract description 6
- 239000002994 raw material Substances 0.000 abstract description 3
- 238000009533 lab test Methods 0.000 abstract description 2
- 238000012360 testing method Methods 0.000 abstract description 2
- 230000001050 lubricating effect Effects 0.000 abstract 2
- 239000002518 antifoaming agent Substances 0.000 abstract 1
- 230000007797 corrosion Effects 0.000 abstract 1
- 238000005260 corrosion Methods 0.000 abstract 1
- 239000003112 inhibitor Substances 0.000 abstract 1
- 231100000636 lethal dose Toxicity 0.000 abstract 1
- 231100000017 mucous membrane irritation Toxicity 0.000 abstract 1
- 210000002345 respiratory system Anatomy 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 239000004094 surface-active agent Substances 0.000 abstract 1
- 230000002194 synthesizing effect Effects 0.000 abstract 1
- 239000007788 liquid Substances 0.000 description 4
- 230000007613 environmental effect Effects 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000006257 total synthesis reaction Methods 0.000 description 2
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 210000001533 respiratory mucosa Anatomy 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Landscapes
- Lubricants (AREA)
Abstract
The invention discloses a nano aqueous completely-synthetic environmental-friendly metal working fluid being composed of an organic acid, an organic amine, a corrosion inhibitor, a synthetic lubricant, a surfactant, water, a nano material and a defoaming agent. In the invention, a nano high-molecular lubricating raw material is employed for synthesizing the metal working fluid, so that the metal working fluid is greatly improved in lubricating performance (a laboratory test proves that a 5% diluted solution of the metal working fluid is not more than 0.03 in friction coefficient). The raw materials are free of harmful substances harming body health and environment safety so that the metal working fluid is greatly improved in safety and sanitation quality (a test proves that the metal working fluid is not less than 5000 g/kg in biological median lethal dose LD50, is not less than 5000 mg/m<3> in medial lethal concentration LC50 and is not higher than 1 grade in respiratory tract mucous membrane irritation).
Description
Technical field
The present invention relates to a kind of metal working fluid.
Background technology
When carrying out machining to metallic substance, because mature preparation process, lubricity are good, but there is the problems such as resource is serious, waste liquid is difficult that consume petroleum, thus substituted by total synthesis metal processing liquid gradually in the emulsion-type metalworking liquid that tradition uses.Although also there is total synthesis metal processing liquid in the market, also there is many defects: one is that lubricity is general; Two is add the material to human body and bad environmental such as nitrite.These drawbacks constrain the popularization of product in user especially in high-end user.
Summary of the invention
The object of the present invention is to provide the complete synthesis environmentally friendly metal working fluid of nano aqueous that a kind of lubricity is good, product safety hygienic quality is high.
Technical solution of the present invention is:
The complete synthesis environmentally friendly metal working fluid of a kind of nano aqueous, is characterized in that: be grouped into by the one-tenth of following weight percents:
Organic acid 2-8%
Organic amine 15-25%
Inhibiter 0.5-3%
Synthetic lubricant 15-40%
Tensio-active agent 1-5%
Water 20-50%
Nano material 1-5%
Defoamer 0-3%;
Above-mentioned each amounts of components sum is 100%.
Organic acid is bay diacid, p-nitrobenzoic acid, sulfamic acid compound or to hexyl benzene formic acid between the tertiary butyl.
Organic amine is Monoethanolamine MEA BASF, trolamine or α-amino isopropyl alcohol.
Inhibiter is benzotriazole or 2-mercaptobenzothiazole.
Synthetic lubricant is EO, PO multipolymer or polyoxyethylene glycol.
Tensio-active agent is ethylene glycol monobutyl ether, polyvinylamine or fatty alcohol-polyoxyethylene ether.
Nano material is Graphene, nano-metal-oxide.
Defoamer is silicone emulsion.
The present invention selects nano-high molecule to lubricate raw material participation group 5, and the lubricity of product is increased dramatically.(through laboratory test, 5% diluent frictional coefficient≤0.03).Product Raw does not use the objectionable impurities jeopardizing HUMAN HEALTH and environmental safety, and the safety and sanitation quality of product is increased dramatically (after testing, this product biological Lethal Dose 50 LD50>=5000mg/kg, toxic limit medium dose LC50>=5000mg/m
3, respiratory mucosa stimulates≤1 grade).
Below in conjunction with embodiment, the invention will be further described.
Embodiment
Embodiment 1:
By the component mix and blend of following weight percents, obtain the complete synthesis environmentally friendly metal working fluid of nano aqueous:
Bay diacid 3%
Monoethanolamine MEA BASF 8%
Trolamine 12%
EO, PO multipolymer 30%
Polyvinylamine 2.5%
Benzotriazole 0.5%
Graphene 2%
Alumina in Nano level 2%
Silicone emulsion 0.5%
Water 39.5%.
Embodiment 2:
The complete synthesis environmentally friendly metal working fluid of a kind of nano aqueous, is grouped into by the one-tenth of following weight percents:
Organic acid 2-8%(example 2%, 5%, 8%)
Organic amine 15-25%(example 15%, 20%, 25%)
Inhibiter 0.5-3%(example 0.5%, 2%, 3%)
Synthetic lubricant 15-40%(example 15%, 25%, 40%)
Tensio-active agent 1-5%(example 1%, 3%, 5%)
Water 20-50%(example 20%, 35%, 50%)
Nano material 1-5%(example 1%, 3%, 5%)
Defoamer 0-3%(example 1%, 2%, 3%);
Above-mentioned each amounts of components sum is 100%.
Organic acid is bay diacid, p-nitrobenzoic acid, sulfamic acid compound or to hexyl benzene formic acid between the tertiary butyl.
Organic amine is Monoethanolamine MEA BASF, trolamine or α-amino isopropyl alcohol.
Inhibiter is benzotriazole or 2-mercaptobenzothiazole.
Synthetic lubricant is EO, PO multipolymer or polyoxyethylene glycol.
Tensio-active agent is ethylene glycol monobutyl ether, polyvinylamine or fatty alcohol-polyoxyethylene ether.
Nano material is Graphene, nano-metal-oxide.
Defoamer is silicone emulsion.
Claims (8)
1. the complete synthesis environmentally friendly metal working fluid of nano aqueous, is characterized in that: be grouped into by the one-tenth of following weight percents:
Organic acid 2-8%
Organic amine 15-25%
Inhibiter 0.5-3%
Synthetic lubricant 15-40%
Tensio-active agent 1-5%
Water 20-50%
Nano material 1-5%
Defoamer 0-3%;
Above-mentioned each amounts of components sum is 100%.
2. the complete synthesis environmentally friendly metal working fluid of nano aqueous according to claim 1, is characterized in that: organic acid is bay diacid, p-nitrobenzoic acid, sulfamic acid compound or to hexyl benzene formic acid between the tertiary butyl.
3. the complete synthesis environmentally friendly metal working fluid of nano aqueous according to claim 1, is characterized in that: organic amine is Monoethanolamine MEA BASF, trolamine or α-amino isopropyl alcohol.
4. the complete synthesis environmentally friendly metal working fluid of nano aqueous according to claim 1, is characterized in that: inhibiter is benzotriazole or 2-mercaptobenzothiazole.
5. the complete synthesis environmentally friendly metal working fluid of nano aqueous according to claim 1, is characterized in that: synthetic lubricant is EO, PO multipolymer or polyoxyethylene glycol.
6. the complete synthesis environmentally friendly metal working fluid of nano aqueous according to claim 1, is characterized in that: tensio-active agent is ethylene glycol monobutyl ether, polyvinylamine or fatty alcohol-polyoxyethylene ether.
7. the complete synthesis environmentally friendly metal working fluid of nano aqueous according to claim 1, is characterized in that: nano material is Graphene, nano-metal-oxide.
8. the complete synthesis environmentally friendly metal working fluid of nano aqueous according to claim 1, is characterized in that: defoamer is silicone emulsion.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510117306.XA CN104762127A (en) | 2015-03-18 | 2015-03-18 | Nano aqueous completely-synthetic environmental-friendly metal working fluid |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510117306.XA CN104762127A (en) | 2015-03-18 | 2015-03-18 | Nano aqueous completely-synthetic environmental-friendly metal working fluid |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104762127A true CN104762127A (en) | 2015-07-08 |
Family
ID=53644226
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510117306.XA Pending CN104762127A (en) | 2015-03-18 | 2015-03-18 | Nano aqueous completely-synthetic environmental-friendly metal working fluid |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104762127A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105349226A (en) * | 2015-11-19 | 2016-02-24 | 苏州捷德瑞精密机械有限公司 | Emulsified cutting fluid for aluminium alloy and preparation method thereof |
| CN105925341A (en) * | 2016-04-26 | 2016-09-07 | 江苏大学 | Liquid-like graphene water-based lubricant, and preparation method and use thereof |
| CN106635354A (en) * | 2016-12-12 | 2017-05-10 | 深圳市广仁达实业有限公司 | Nano cutting fluid |
| CN107418683A (en) * | 2017-08-09 | 2017-12-01 | 广东尔航实业有限公司 | Screw lubricating wax and preparation method thereof, application |
| CN107858194A (en) * | 2017-11-08 | 2018-03-30 | 上海尤希路化学工业有限公司 | Resist miscellaneous oily, resistance to metal erosion, the water-based fully synthetic working fluid of Biostatic type |
| CN109504522A (en) * | 2017-09-15 | 2019-03-22 | 南京美克斯精密机械有限公司 | A kind of water soluble metal working fluids |
| CN110157537A (en) * | 2019-05-21 | 2019-08-23 | 南京工程学院 | A kind of nano-graphene compounds metal working fluid and preparation method thereof with chambersite |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102029551A (en) * | 2010-11-18 | 2011-04-27 | 长沙理工大学 | Lubricating and cooling method for cutting process and device thereof |
| CN102660368A (en) * | 2012-05-04 | 2012-09-12 | 启东尤希路化学工业有限公司 | Biodegradable hard water-resistant water-soluble metalworking liquid |
-
2015
- 2015-03-18 CN CN201510117306.XA patent/CN104762127A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102029551A (en) * | 2010-11-18 | 2011-04-27 | 长沙理工大学 | Lubricating and cooling method for cutting process and device thereof |
| CN102660368A (en) * | 2012-05-04 | 2012-09-12 | 启东尤希路化学工业有限公司 | Biodegradable hard water-resistant water-soluble metalworking liquid |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105349226A (en) * | 2015-11-19 | 2016-02-24 | 苏州捷德瑞精密机械有限公司 | Emulsified cutting fluid for aluminium alloy and preparation method thereof |
| CN105925341A (en) * | 2016-04-26 | 2016-09-07 | 江苏大学 | Liquid-like graphene water-based lubricant, and preparation method and use thereof |
| CN105925341B (en) * | 2016-04-26 | 2019-06-28 | 江苏大学 | A kind of class I liquid I graphene water base lubricant, Preparation method and use |
| CN106635354A (en) * | 2016-12-12 | 2017-05-10 | 深圳市广仁达实业有限公司 | Nano cutting fluid |
| CN107418683A (en) * | 2017-08-09 | 2017-12-01 | 广东尔航实业有限公司 | Screw lubricating wax and preparation method thereof, application |
| CN109504522A (en) * | 2017-09-15 | 2019-03-22 | 南京美克斯精密机械有限公司 | A kind of water soluble metal working fluids |
| CN107858194A (en) * | 2017-11-08 | 2018-03-30 | 上海尤希路化学工业有限公司 | Resist miscellaneous oily, resistance to metal erosion, the water-based fully synthetic working fluid of Biostatic type |
| CN110157537A (en) * | 2019-05-21 | 2019-08-23 | 南京工程学院 | A kind of nano-graphene compounds metal working fluid and preparation method thereof with chambersite |
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| C06 | Publication | ||
| PB01 | Publication | ||
| EXSB | Decision made by sipo to initiate substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20150708 |