CN102250677B - High-performance environment-friendly magnetic material cutting fluid - Google Patents
High-performance environment-friendly magnetic material cutting fluid Download PDFInfo
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- CN102250677B CN102250677B CN 201110161285 CN201110161285A CN102250677B CN 102250677 B CN102250677 B CN 102250677B CN 201110161285 CN201110161285 CN 201110161285 CN 201110161285 A CN201110161285 A CN 201110161285A CN 102250677 B CN102250677 B CN 102250677B
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- magnetic material
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- material cutting
- cutting fluid
- agent
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- 239000002173 cutting fluid Substances 0.000 title claims abstract description 13
- 239000000696 magnetic material Substances 0.000 title claims abstract description 12
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 8
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000010949 copper Substances 0.000 claims abstract description 6
- 229910052802 copper Inorganic materials 0.000 claims abstract description 6
- 239000003112 inhibitor Substances 0.000 claims abstract description 6
- 239000000314 lubricant Substances 0.000 claims abstract description 6
- 239000000203 mixture Substances 0.000 claims description 16
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 14
- HXKKHQJGJAFBHI-UHFFFAOYSA-N 1-aminopropan-2-ol Chemical compound CC(O)CN HXKKHQJGJAFBHI-UHFFFAOYSA-N 0.000 claims description 6
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 6
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 6
- 230000015572 biosynthetic process Effects 0.000 claims description 6
- 229910052799 carbon Inorganic materials 0.000 claims description 6
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 6
- 150000007524 organic acids Chemical class 0.000 claims description 6
- 229960004418 trolamine Drugs 0.000 claims description 6
- 239000013543 active substance Substances 0.000 claims description 5
- OTLNPYWUJOZPPA-UHFFFAOYSA-N 4-nitrobenzoic acid Chemical compound OC(=O)C1=CC=C([N+]([O-])=O)C=C1 OTLNPYWUJOZPPA-UHFFFAOYSA-N 0.000 claims description 3
- KDVYCTOWXSLNNI-UHFFFAOYSA-N 4-t-Butylbenzoic acid Chemical compound CC(C)(C)C1=CC=C(C(O)=O)C=C1 KDVYCTOWXSLNNI-UHFFFAOYSA-N 0.000 claims description 3
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 claims description 3
- NSPMIYGKQJPBQR-CVMUNTFWSA-N 1h-1,2,4-triazole Chemical group [13CH]=1[15N]=[13CH][15NH][15N]=1 NSPMIYGKQJPBQR-CVMUNTFWSA-N 0.000 claims 1
- 239000007788 liquid Substances 0.000 abstract description 7
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 abstract description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract description 6
- 238000005520 cutting process Methods 0.000 abstract description 4
- 230000007797 corrosion Effects 0.000 abstract description 3
- 238000005260 corrosion Methods 0.000 abstract description 3
- 230000001070 adhesive effect Effects 0.000 abstract description 2
- 229920003169 water-soluble polymer Polymers 0.000 abstract description 2
- 239000004094 surface-active agent Substances 0.000 abstract 2
- 239000000853 adhesive Substances 0.000 abstract 1
- 239000003513 alkali Substances 0.000 abstract 1
- 238000004090 dissolution Methods 0.000 abstract 1
- 230000001050 lubricating effect Effects 0.000 abstract 1
- 150000002826 nitrites Chemical class 0.000 abstract 1
- 239000003755 preservative agent Substances 0.000 abstract 1
- 230000002335 preservative effect Effects 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
- 238000003754 machining Methods 0.000 description 8
- 239000011230 binding agent Substances 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 4
- 238000005555 metalworking Methods 0.000 description 4
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 4
- 231100000111 LD50 Toxicity 0.000 description 3
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical group C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 2
- CSNIZNHTOVFARY-UHFFFAOYSA-N 1,2-benzothiazole Chemical compound C1=CC=C2C=NSC2=C1 CSNIZNHTOVFARY-UHFFFAOYSA-N 0.000 description 2
- JIHQDMXYYFUGFV-UHFFFAOYSA-N 1,3,5-triazine Chemical compound C1=NC=NC=N1 JIHQDMXYYFUGFV-UHFFFAOYSA-N 0.000 description 2
- SNTWKPAKVQFCCF-UHFFFAOYSA-N 2,3-dihydro-1h-triazole Chemical compound N1NC=CN1 SNTWKPAKVQFCCF-UHFFFAOYSA-N 0.000 description 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 2
- CMGDVUCDZOBDNL-UHFFFAOYSA-N 4-methyl-2h-benzotriazole Chemical compound CC1=CC=CC2=NNN=C12 CMGDVUCDZOBDNL-UHFFFAOYSA-N 0.000 description 2
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 2
- 239000005642 Oleic acid Substances 0.000 description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 2
- 239000012964 benzotriazole Substances 0.000 description 2
- 125000003354 benzotriazolyl group Chemical group N1N=NC2=C1C=CC=C2* 0.000 description 2
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 2
- 239000004327 boric acid Substances 0.000 description 2
- 239000003085 diluting agent Substances 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 2
- 235000010288 sodium nitrite Nutrition 0.000 description 2
- 229910052779 Neodymium Inorganic materials 0.000 description 1
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 description 1
- 229910052772 Samarium Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 208000008784 apnea Diseases 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 231100000017 mucous membrane irritation Toxicity 0.000 description 1
- QEFYFXOXNSNQGX-UHFFFAOYSA-N neodymium atom Chemical compound [Nd] QEFYFXOXNSNQGX-UHFFFAOYSA-N 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- KZUNJOHGWZRPMI-UHFFFAOYSA-N samarium atom Chemical compound [Sm] KZUNJOHGWZRPMI-UHFFFAOYSA-N 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
Landscapes
- Lubricants (AREA)
Abstract
The invention discloses high-performance environment-friendly magnetic material cutting fluid, which consists of an antirusting agent, surfactants, a lubricating agent, a preservative, a copper corrosion inhibitor and water. In the invention, a special water soluble polymer serving as a lubricating agent is combined with various surfactants, the antirusting agent and the copper corrosion inhibitor, so the cutting liquid has high lubricating performance and antirusting performance, the yield of processed magnetic materials is high and the processing precision is high. Because the use of strong alkali such as sodium hydroxide and potassium hydroxide is avoided, the dissolution of adhesive can be prevented. Meanwhile, the cutting liquid does not contain nitrites and therefore is an environment-friendly magnetic material cutting liquid.
Description
Technical field
The present invention relates to the cutting fluid used in a kind of magneticsubstance course of processing.
Background technology:
To the machining manufacturing of magneticsubstance (alloys such as samarium, cobalt, neodymium), tradition is used mostly is the oiliness cutting fluid.Although oiliness cutting fluid lubricity is good, in use there are many drawbacks such as mist of oil, inflammable, contaminate environment.Therefore present many enterprises have used water-soluble metalworking liquid instead magneticsubstance have been carried out machining manufacturing.
Be machining quality (i.e. smooth finish and the planeness of section), the prolongation cutting-tool's used life (reducing production costs) of guaranteeing magneticsubstance, this just requires the lubricity of used water-soluble metalworking liquid will get well (being that frictional coefficient is little), rustless property will be got well (can not produce corrosion to workpiece and machining tool in the course of processing).
Be convenient processing, during the magneticsubstance machining, usually all be to be that binding agent is fixed on the anchor clamps with the magneticsubstance workpiece with wax, then carry out machining by outer round-bladed knife sheet, interior round-bladed knife sheet and wire cutting machine, this just requires used water-soluble metalworking liquid on the impact of binding agent little (do not make its very fast dissolving, cause workpiece to come off).
But the performance quality of the at present commercially available water-soluble metalworking liquid that is used for the magneticsubstance machining is unsatisfactory, main drawback: the one, lubricity relatively poor (frictional coefficient is large), workpiece planeness and smooth finish after causing processing are difficult to reach processing requirement, cutter life is short, affects production cost; The 2nd, the rust-preventive agent that adds in the cutting fluid affects the adhesive property (binding agent is soluble after soaking, and causes workpiece easily to come off) of binding agent; The 3rd, contain the objectionable impuritiess such as Sodium Nitrite in the prescription, jeopardize environmental safety and HUMAN HEALTH.
Summary of the invention
The high-performance environment-friendly type magnetic material cutting fluid that the object of the present invention is to provide a kind of high lubricity, anti-workpiece to come off.
Technical solution of the present invention is:
A kind of high-performance environment-friendly type magnetic material cutting fluid, it is characterized in that: the one-tenth by following weight percent is grouped into:
Rust-preventive agent is one or more and Monoethanolamine MEA BASF, diethanolamine, the trolamine in the organic acid, p-tert-butyl benzoic acid, p-nitrobenzoic acid of boric acid, carbon number 8～18, the mixture of one or more formation in the α-amino isopropyl alcohol, and the pH value of mixture is 8～9.
Tensio-active agent is the mixture of one or more formation in the organic acid of carbon number 8～18 and Monoethanolamine MEA BASF, diethanolamine, trolamine, the α-amino isopropyl alcohol, and the pH value of mixture is 8～9; Or tensio-active agent is aliphatic alcohol polyethenoxy (5～12) ether or alkylphenol-polyethenoxy (5～12) ether.
Lubricant is polyoxyethylene polyoxypropylene block ether; Sanitas is one or more in 1,2 benzothiazole-3-ketone, 1,2 benzisothiazole, the s-triazine; Copper inhibitor is benzotriazole, tolyltriazole, 1H-1, one or more in 2,4-triazole, the alpha-mercapto benzothiazole.
The present invention adopts special water-soluble polymers as lubricant, composite kinds of surface promoting agent, rust-preventive agent and copper inhibitor, so that this product has excellent oilness and rust-preventing characteristic, processing magnetic material yield rate and working accuracy are high.Because the present invention does not use the highly basic such as sodium hydroxide, potassium hydroxide, therefore can prevent the dissolving of binding agent.Product does not contain nitrite simultaneously, and environmental protection is a kind of eco-friendly magnetic material cutting fluid.
1, this product has good lubricity.This Project Product 5% diluent frictional coefficient is compared with commercially available product less than 0.201, reduces on year-on-year basis 20%; Use this Project Product machining, compared with use commercially available prod greater than 7 days cutter life, improves on year-on-year basis 40%.
| Sample | This product | Commercially available product |
| Coefficientoffrictionμ | 0.201 | 0.261 |
| Cutter life | 7 days | 5 days |
2, this product can guarantee that wax is that binding agent soaks 3 hours non-whitenings, do not dissolve in this product 5% diluent, and workpiece does not come off.
3, this product safety health, reliable in quality.Prescription does not use the objectionable impuritiess such as Sodium Nitrite, the biological Lethal Dose 50 LD50＞5000mg/kg of product, biological toxic limit medium dose LC50＞5000mg/m
3, apnea road mucous membrane irritation, friendly to human and environment.
The invention will be further described below in conjunction with embodiment.
Embodiment
Embodiment 1:
With each component mix and blend of following weight percent, make high-performance environment-friendly type magnetic material cutting fluid product:
Embodiment 2:
With each component mix and blend of following weight percent, make high-performance environment-friendly type magnetic material cutting fluid product:
Rust-preventive agent is one or more and Monoethanolamine MEA BASF, diethanolamine, the trolamine in the organic acid (sad, the oleic acid of example, bay diacid), p-tert-butyl benzoic acid, p-nitrobenzoic acid of boric acid, carbon number 8～18, the mixture of one or more formation in the α-amino isopropyl alcohol, and the ratio of mixing is that to make the pH value of mixture be 8～9.
Tensio-active agent is the mixture of one or more formation in organic acid (sad, the oleic acid of example, bay diacid) and Monoethanolamine MEA BASF, diethanolamine, trolamine, the α-amino isopropyl alcohol of carbon number 8～18, and the ratio of mixing is that to make the pH value of mixture be 8～9; Or tensio-active agent is aliphatic alcohol polyethenoxy (5～12) ether or alkylphenol-polyethenoxy (5～12) ether.
Lubricant is polyoxyethylene polyoxypropylene block ether; Sanitas is one or more in 1,2 benzothiazole-3-ketone, 1,2 benzisothiazole, the s-triazine; Copper inhibitor is benzotriazole, tolyltriazole, 1H-1, one or more in 2,4-triazole, the alpha-mercapto benzothiazole.
Claims (1)
1. high-performance environment-friendly type magnetic material cutting fluid, it is characterized in that: the one-tenth by following weight percent is grouped into:
Tensio-active agent is the mixture of one or more formation in the organic acid of carbon number 8～18 and Monoethanolamine MEA BASF, diethanolamine, trolamine, the α-amino isopropyl alcohol, and the pH value of mixture is 8 ~ 9; Rust-preventive agent is one or more and Monoethanolamine MEA BASF, diethanolamine, the trolamine in the organic acid, p-tert-butyl benzoic acid, p-nitrobenzoic acid of carbon number 8～18, the mixture of one or more formation in the α-amino isopropyl alcohol, and the pH value of mixture is 8 ~ 9; Lubricant is polyoxyethylene polyoxypropylene block ether; Sanitas is 1,2-[4-morpholinodithio-3-ketone; Copper inhibitor is 1H-1,2,4-triazole.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110161285 CN102250677B (en) | 2011-06-15 | 2011-06-15 | High-performance environment-friendly magnetic material cutting fluid |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110161285 CN102250677B (en) | 2011-06-15 | 2011-06-15 | High-performance environment-friendly magnetic material cutting fluid |
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| Publication Number | Publication Date |
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| CN102250677A CN102250677A (en) | 2011-11-23 |
| CN102250677B true CN102250677B (en) | 2013-04-03 |
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Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102660367B (en) * | 2012-04-24 | 2013-08-21 | 长春工业大学 | Producing method of water-soluble drawing oil for stamping carbon steel sheets |
| CN102876441B (en) * | 2012-09-24 | 2013-10-30 | 广西大学 | Environment-friendly titanium alloy microemulsion cutting liquid |
| CN103881798A (en) * | 2012-12-19 | 2014-06-25 | 上海工程技术大学 | Water-soluble silicon cutting fluid and its application thereof |
| CN104342279B (en) * | 2014-09-30 | 2016-08-24 | 上海尤希路化学工业有限公司 | Environmentally friendly polymolecularity permanent magnet wire cutting liquid |
| CN104947098A (en) * | 2015-05-29 | 2015-09-30 | 焦占付 | Hot galvanizing chromium-free passivation agent and preparation method thereof |
| CN106590907A (en) * | 2016-12-07 | 2017-04-26 | 上海应用技术大学 | Graphene-containing metal cutting fluid and preparation method thereof |
| CN107446685A (en) * | 2017-07-27 | 2017-12-08 | 江苏捷达油品有限公司 | High-lubricity cutting fluid |
| CN107603721A (en) * | 2017-07-27 | 2018-01-19 | 江苏捷达油品有限公司 | high cooling cutting fluid |
| CN111876228A (en) * | 2020-08-11 | 2020-11-03 | 广州洛德化工科贸有限公司 | Environment-friendly long-life cutting fluid and preparation method and application thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100999691A (en) * | 2006-12-27 | 2007-07-18 | 江苏科技大学 | Rust-proof cutting fluid |
| CN101240221A (en) * | 2008-02-29 | 2008-08-13 | 益田润石（北京）化工有限公司 | Water-soluble total synthesis metal processing liquid composition |
| CN101560433A (en) * | 2009-05-11 | 2009-10-21 | 启东尤希路化学工业有限公司 | Anti-magnesium hard water anti-magnesium corrosion environmentally-friendly water soluble cutting solution |
| CN101591584A (en) * | 2009-06-30 | 2009-12-02 | 山东卡松石化有限公司 | Water-base lubricant and preparation method thereof |
-
2011
- 2011-06-15 CN CN 201110161285 patent/CN102250677B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100999691A (en) * | 2006-12-27 | 2007-07-18 | 江苏科技大学 | Rust-proof cutting fluid |
| CN101240221A (en) * | 2008-02-29 | 2008-08-13 | 益田润石（北京）化工有限公司 | Water-soluble total synthesis metal processing liquid composition |
| CN101560433A (en) * | 2009-05-11 | 2009-10-21 | 启东尤希路化学工业有限公司 | Anti-magnesium hard water anti-magnesium corrosion environmentally-friendly water soluble cutting solution |
| CN101591584A (en) * | 2009-06-30 | 2009-12-02 | 山东卡松石化有限公司 | Water-base lubricant and preparation method thereof |
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| CN102250677A (en) | 2011-11-23 |
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