CN104327933A - Environmental-protection lubricating water-based cutting fluid - Google Patents
Environmental-protection lubricating water-based cutting fluid Download PDFInfo
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- CN104327933A CN104327933A CN201410525346.3A CN201410525346A CN104327933A CN 104327933 A CN104327933 A CN 104327933A CN 201410525346 A CN201410525346 A CN 201410525346A CN 104327933 A CN104327933 A CN 104327933A
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Abstract
The present invention discloses an environmental-protection lubricating water-based cutting fluid, which comprises the following raw materials by weight: 8-20 parts of sodium abietate, 15-25 parts of a rosin amine glucose ester surfactant, 5-10 parts of rosin amine polyoxyethylene ether, 12-18 parts of a polyaniline aqueous anti-corrosion agent, 5-15 parts of triethanolamine oleate, 3-8 parts of triethanolamine, 3-10 parts of diisopropanolamine, 10-15 parts of sodium carbonate, 5-15 parts of hydrophilic alcohol, 3-6 parts of a sterilization agent, 2-5 parts of a foaming agent, 3-10 parts of a stabilizer, and 80-100 parts of water. The environmental-protection lubricating water-based cutting fluid has functions of excellent cleaning, excellent lubrication, excellent corrosion resistance and excellent cooling, and further has characteristics of environmental protection, long service life, good water solubility, low cost, and high stability.
Description
Technical field
The present invention relates to cutting fluid technical field, particularly relate to a kind of environmental protection lubrication water-base cutting fluid.
Background technology
Cutting fluid a kind of to be cut at metal, cut, grinds in the course of processing, is used for cooling, the industrial type fluid of lubrication cutter and workpiece, and formed through science compound compatibility by multiple super strong functional auxiliary agent, it is a kind of lubricant.The effect of cutting fluid has a lot; wherein lubricate, antirust, clean and be cooled to topmost effect; thus cutting-tool's used life can be extended; prevent metal parts corrosion; take away the heat produced in the course of processing; effectively remove chip and the powder ash end of part and tool surface, improve processing quality, enhance productivity.
By moiety, cutting fluid is divided into oil-base fluid and the large class of water base fluid two usually.Oil base cutting fluid cost is high and seriously polluted, and along with the development of advanced manufacturing technology, the reinforcement of people's environmental consciousness, water-base cutting fluid product occupies larger market in recent years.In prior art, water-base cutting fluid needs to be improved further in work-ing life, rust-preventing characteristic, oilness etc., and poor stability, the demand of society can not be met.
Summary of the invention
The present invention proposes a kind of environmental protection lubrication water-base cutting fluid, it has excellent cleaning, lubrication, anticorrosion, refrigerating function, and environmental protection, long service life, good water solubility, with low cost, stability is strong.
The present invention proposes a kind of environmental protection lubrication water-base cutting fluid, its raw materials by weight portion comprises: sodium abietate 8-20 part, rosin Amine D glucose ester tensio-active agent 15-25 part, Rosin Amine Polyoxyethylene Ether ether 5-10 part, polyaniline aqueous sanitas 12-18 part, triethanolamine oleate 5-15 part, trolamine 3-8 part, diisopropanolamine (DIPA) 3-10 part, sodium carbonate 10-15 part, hydrophilic polyol 5-15 part, sterilant 3-6 part, defoamer 2-5 part, stablizer 3-10 part, water 80-100 part.
Preferably, its raw material comprises by weight: sodium abietate 10-18 part, rosin Amine D glucose ester tensio-active agent 17-21 part, Rosin Amine Polyoxyethylene Ether ether 6-8 part, polyaniline aqueous sanitas 13-15 part, triethanolamine oleate 7-12 part, trolamine 4-6 part, diisopropanolamine (DIPA) 5-8 part, sodium carbonate 12-13 part, hydrophilic polyol 6-10 part, sterilant 4-5 part, defoamer 3-4 part, stablizer 4-7 part, water 85-95 part.
Preferably, described hydrophilic polyol is one or more combination in ethylene glycol, glycol ether, triglycol, dipropylene glycol, tripropylene glycol, polyoxyethylene glycol.
Preferably, described sterilant is benzotriazole series bactericidal agent.
Preferably, described defoamer is silicone antifoam agent.
Preferably, described stablizer is one or more the combination in carboxymethyl cellulose and salt thereof, carboxymethyl starch, natural gum.
Preferably, its raw material comprises by weight: sodium abietate 15 parts, 20 parts, rosin Amine D glucose ester tensio-active agent, 7 parts, Rosin Amine Polyoxyethylene Ether ether, polyaniline aqueous sanitas 14 parts, triethanolamine oleate 10 parts, trolamine 5 parts, diisopropanolamine (DIPA) 6 parts, 10 parts, sodium carbonate, polyoxyethylene glycol 3 parts, glycol ether 8 parts, benzotriazole 4.6 parts, silicone antifoam agent 3.5 parts, sodium cellulose glycolate 6 parts, 88 parts, water.
In the present invention, the hydrophilic group of anion surfactant sodium abietate is adsorbed on metallic surface, and oleophilic group forms layer protecting film in metallic surface, play the effect of starvation, prevent metal rusting, the protective membrane that oleophilic group is formed, play a part to isolate surface of friction, reduce the friction resistance between metal and cutter, play the effect of lubricant; Sodium abietate has excellent emulsion dispersion property in addition and excellent calcium soap disperses and anti-performance of hard water, can maintain the stability of the rustless property of cutting fluid; Existing hydrophilic radical in nonionogenic tenside rosin Amine D glucose ester tensio-active agent, again containing lipophilic group, join in cutting fluid, greasy dirt-the water of metallic surface and metal-water termination free energy are declined, the work of adhesion of greasy dirt and metal interface reduces, in conjunction with weakening, there is very strong wettability and cleaning; Nonionogenic tenside Rosin Amine Polyoxyethylene Ether ether forms layer protecting film in metallic surface, stops metal to be corroded further; By being undertaken composite by anion surfactant and nonionogenic tenside, improve the cleaning of cutting fluid, anticorrosion, lubricity; The polyaniline aqueous sanitas added can form the protective oxide film of one deck densification on the one hand in metallic surface, the electropotential of metal is made to be in passivation region, metal is prevented to be further corroded, play rot-resistant object, on the other hand, in polyaniline, the lone-pair electron of nitrogen-atoms can form coordinate bond with the metal containing d unoccupied orbital, be adsorbed on metallic surface and form absorption protective layer, prevent metallic corrosion further, triethanolamine oleate, trolamine, diisopropanolamine (DIPA), sodium carbonate coordinate the non-corrosibility enhancing cutting fluid; The hydrophilic polyol added coordinates with various tensio-active agent, improves the cleaning performance of cutting fluid; The stablizer added can prevent metal to be again deposited on metallic surface, has consolidated cleaning performance; Various raw material coordinates the effect making the cutting fluid obtained have antirust, cleaning, lubrication, cooling, and environmental protection, long service life, good water solubility, with low cost, stability is strong.
Embodiment
Below in conjunction with specific embodiment, the present invention is described in detail; should understand; embodiment is only for illustration of the present invention, instead of for limiting the present invention, any amendment, equivalent replacement etc. made on basis of the present invention is all in protection scope of the present invention.
In a particular embodiment, environmental protection lubrication water-base cutting fluid of the present invention, in its raw material, the weight part of sodium abietate can be 9, 10, 12, 13.5, 16, 17, 18, 19 parts, the weight part of rosin Amine D glucose ester tensio-active agent can be 16, 17, 18.5, 19, 21, 22, 23, 24 parts, the weight part of Rosin Amine Polyoxyethylene Ether ether can be 6, 8, 8.9 parts, the weight part of polyaniline aqueous sanitas can be 13, 15, 16, 17.3 parts, the weight part of triethanolamine oleate can be 6, 7, 8, 9, 11.5, 13, 14 parts, the weight part of trolamine can be 4, 5.6, 6, 7.5 parts, the parts by weight of diisopropanolamine (DIPA) can be 4, 5, 7, 8, 8.5 parts, the parts by weight of sodium carbonate can be 11, 12, 13, 14.5 parts, the weight part of hydrophilic polyol can be 6, 7, 8, 9, 10, 13, 13.8 parts, the weight part of sterilant can be 4, 5, 5.6 parts, the weight part of defoamer can be 2.6, 3, 4, 4.5 parts, the weight part of stablizer can be 4, 5, 7, 8, 8.9 parts, the weight part of water can be 83, 85, 88, 91.3, 93, 94, 96, 97, 98.6 parts.
Embodiment 1
Environmental protection lubrication water-base cutting fluid of the present invention, its raw materials by weight portion comprises: sodium abietate 8 parts, 25 parts, rosin Amine D glucose ester tensio-active agent, 10 parts, Rosin Amine Polyoxyethylene Ether ether, polyaniline aqueous sanitas 12 parts, triethanolamine oleate 15 parts, trolamine 3 parts, diisopropanolamine (DIPA) 10 parts, 10 parts, sodium carbonate, hydrophilic polyol 15 parts, 3 parts, sterilant, defoamer 5 parts, stablizer 3 parts, 100 parts, water.
Embodiment 2
Environmental protection lubrication water-base cutting fluid of the present invention, its raw materials by weight portion comprises: sodium abietate 20 parts, 15 parts, rosin Amine D glucose ester tensio-active agent, 5 parts, Rosin Amine Polyoxyethylene Ether ether, polyaniline aqueous sanitas 18 parts, triethanolamine oleate 5 parts, trolamine 8 parts, diisopropanolamine (DIPA) 3 parts, 15 parts, sodium carbonate, tripropylene glycol 1 part, ethylene glycol 2 parts, triglycol 2 parts, 6 parts, sterilant, defoamer 2 parts, Xylo-Mucine 10 parts, 80 parts, water.
Embodiment 3
Environmental protection lubrication water-base cutting fluid of the present invention, its raw materials by weight portion comprises: sodium abietate 16 parts, 21 parts, rosin Amine D glucose ester tensio-active agent, 8 parts, Rosin Amine Polyoxyethylene Ether ether, polyaniline aqueous sanitas 16 parts, triethanolamine oleate 11.5 parts, trolamine 6 parts, diisopropanolamine (DIPA) 7 parts, 13 parts, sodium carbonate, triglycol 13 parts, 5.6 parts, sterilant, defoamer 4 parts, carboxymethyl starch 3 parts, natural gum 4 parts, 96 parts, water.
Embodiment 4
Environmental protection lubrication water-base cutting fluid of the present invention, its raw materials by weight portion comprises: sodium abietate 15 parts, 20 parts, rosin Amine D glucose ester tensio-active agent, 7 parts, Rosin Amine Polyoxyethylene Ether ether, polyaniline aqueous sanitas 14 parts, triethanolamine oleate 10 parts, trolamine 5 parts, diisopropanolamine (DIPA) 6 parts, 10 parts, sodium carbonate, polyoxyethylene glycol 3 parts, glycol ether 8 parts, benzotriazole 4.6 parts, silicone antifoam agent 3.5 parts, sodium cellulose glycolate 6 parts, 88 parts, water.
In embodiment 1-4, the preparation method of described environmental protection lubrication water-base cutting fluid is: mixed by each raw material according to formula.
Carry out performance test to the lubrication of environmental protection described in embodiment 1-4 water-base cutting fluid, result is as shown in the table:
Claims (7)
1. an environmental protection lubrication water-base cutting fluid, it is characterized in that, its raw materials by weight portion comprises: sodium abietate 8-20 part, rosin Amine D glucose ester tensio-active agent 15-25 part, Rosin Amine Polyoxyethylene Ether ether 5-10 part, polyaniline aqueous sanitas 12-18 part, triethanolamine oleate 5-15 part, trolamine 3-8 part, diisopropanolamine (DIPA) 3-10 part, sodium carbonate 10-15 part, hydrophilic polyol 5-15 part, sterilant 3-6 part, defoamer 2-5 part, stablizer 3-10 part, water 80-100 part.
2. environmental protection lubrication water-base cutting fluid according to claim 1, it is characterized in that, its raw material comprises by weight: sodium abietate 10-18 part, rosin Amine D glucose ester tensio-active agent 17-21 part, Rosin Amine Polyoxyethylene Ether ether 6-8 part, polyaniline aqueous sanitas 13-15 part, triethanolamine oleate 7-12 part, trolamine 4-6 part, diisopropanolamine (DIPA) 5-8 part, sodium carbonate 12-13 part, hydrophilic polyol 6-10 part, sterilant 4-5 part, defoamer 3-4 part, stablizer 4-7 part, water 85-95 part.
3. environmental protection lubrication water-base cutting fluid according to claim 1 or 2, it is characterized in that, described hydrophilic polyol is one or more the combination in ethylene glycol, glycol ether, triglycol, dipropylene glycol, tripropylene glycol, polyoxyethylene glycol.
4. environmental protection lubrication water-base cutting fluid according to any one of claim 1-3, it is characterized in that, described sterilant is benzotriazole series bactericidal agent.
5. environmental protection lubrication water-base cutting fluid according to any one of claim 1-4, it is characterized in that, described defoamer is silicone antifoam agent.
6. environmental protection lubrication water-base cutting fluid according to any one of claim 1-5, it is characterized in that, described stablizer is one or more the combination in carboxymethyl cellulose and salt thereof, carboxymethyl starch, natural gum.
7. environmental protection lubrication water-base cutting fluid according to any one of claim 1-6, it is characterized in that, its raw material comprises by weight: sodium abietate 15 parts, 20 parts, rosin Amine D glucose ester tensio-active agent, 7 parts, Rosin Amine Polyoxyethylene Ether ether, polyaniline aqueous sanitas 14 parts, triethanolamine oleate 10 parts, trolamine 5 parts, diisopropanolamine (DIPA) 6 parts, 10 parts, sodium carbonate, polyoxyethylene glycol 3 parts, glycol ether 8 parts, benzotriazole 4.6 parts, silicone antifoam agent 3.5 parts, sodium cellulose glycolate 6 parts, 88 parts, water.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410525346.3A CN104327933A (en) | 2014-09-30 | 2014-09-30 | Environmental-protection lubricating water-based cutting fluid |
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| CN201410525346.3A CN104327933A (en) | 2014-09-30 | 2014-09-30 | Environmental-protection lubricating water-based cutting fluid |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104830506A (en) * | 2015-04-10 | 2015-08-12 | 合肥环照高分子材料厂 | Raw silk blend membrane cutting fluid |
| CN105154206A (en) * | 2015-10-20 | 2015-12-16 | 湖南金化科技集团有限公司 | Aqueous high-temperature lubricant and preparation method thereof |
| CN105670761A (en) * | 2016-03-09 | 2016-06-15 | 周紫阳 | Corrosion-resistant cutting fluid and preparation method thereof |
| WO2016176792A1 (en) * | 2015-05-03 | 2016-11-10 | 南通启秀门窗有限公司 | Metal door cleaning agent |
| CN111704955A (en) * | 2020-07-03 | 2020-09-25 | 江苏东之创半导体科技有限公司 | Anti-freezing water-based cutting fluid and preparation method thereof |
| CN114369495A (en) * | 2021-12-30 | 2022-04-19 | 广东红日星实业有限公司 | Cutting fluid and preparation method and application thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101323813A (en) * | 2007-06-29 | 2008-12-17 | 大连弘瑞化工有限公司 | Multiple-effect type water-based synthesized cutting solution and preparation thereof |
| CN103351932A (en) * | 2013-06-19 | 2013-10-16 | 天长市润达金属防锈助剂有限公司 | Transparent water-based cutting fluid and preparation method therefor |
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2014
- 2014-09-30 CN CN201410525346.3A patent/CN104327933A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101323813A (en) * | 2007-06-29 | 2008-12-17 | 大连弘瑞化工有限公司 | Multiple-effect type water-based synthesized cutting solution and preparation thereof |
| CN103351932A (en) * | 2013-06-19 | 2013-10-16 | 天长市润达金属防锈助剂有限公司 | Transparent water-based cutting fluid and preparation method therefor |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104830506A (en) * | 2015-04-10 | 2015-08-12 | 合肥环照高分子材料厂 | Raw silk blend membrane cutting fluid |
| WO2016176792A1 (en) * | 2015-05-03 | 2016-11-10 | 南通启秀门窗有限公司 | Metal door cleaning agent |
| CN105154206A (en) * | 2015-10-20 | 2015-12-16 | 湖南金化科技集团有限公司 | Aqueous high-temperature lubricant and preparation method thereof |
| CN105154206B (en) * | 2015-10-20 | 2018-03-16 | 湖南金化科技集团有限公司 | A kind of water-based high-temperature lubricant and preparation method thereof |
| CN105670761A (en) * | 2016-03-09 | 2016-06-15 | 周紫阳 | Corrosion-resistant cutting fluid and preparation method thereof |
| CN111704955A (en) * | 2020-07-03 | 2020-09-25 | 江苏东之创半导体科技有限公司 | Anti-freezing water-based cutting fluid and preparation method thereof |
| CN114369495A (en) * | 2021-12-30 | 2022-04-19 | 广东红日星实业有限公司 | Cutting fluid and preparation method and application thereof |
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