CN106675751A - Glass cutting fluid - Google Patents

Glass cutting fluid Download PDF

Info

Publication number
CN106675751A
CN106675751A CN201611184701.0A CN201611184701A CN106675751A CN 106675751 A CN106675751 A CN 106675751A CN 201611184701 A CN201611184701 A CN 201611184701A CN 106675751 A CN106675751 A CN 106675751A
Authority
CN
China
Prior art keywords
glass cutting
cutting liquid
liquid according
agent
glass
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201611184701.0A
Other languages
Chinese (zh)
Other versions
CN106675751B (en
Inventor
董恩莲
严定龙
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
GUANGDONG WINDSCAPE ENVIRONMENTAL PROTECTION TECHNOLOGY Co Ltd
Original Assignee
GUANGDONG WINDSCAPE ENVIRONMENTAL PROTECTION TECHNOLOGY Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by GUANGDONG WINDSCAPE ENVIRONMENTAL PROTECTION TECHNOLOGY Co Ltd filed Critical GUANGDONG WINDSCAPE ENVIRONMENTAL PROTECTION TECHNOLOGY Co Ltd
Priority to CN201611184701.0A priority Critical patent/CN106675751B/en
Publication of CN106675751A publication Critical patent/CN106675751A/en
Application granted granted Critical
Publication of CN106675751B publication Critical patent/CN106675751B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M173/00Lubricating compositions containing more than 10% water
    • C10M173/02Lubricating compositions containing more than 10% water not containing mineral or fatty oils
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02Hydroxy compounds
    • C10M2207/021Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/022Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms containing at least two hydroxy groups
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/12Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • C10M2207/127Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids polycarboxylic
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/14Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/141Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings monocarboxylic
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/104Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/105Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing three carbon atoms only
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2215/042Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2227/00Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
    • C10M2227/04Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions having a silicon-to-carbon bond, e.g. organo-silanes
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2229/00Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/04Siloxanes with specific structure
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/12Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/16Antiseptic; (micro) biocidal or bactericidal
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/18Anti-foaming property
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/64Environmental friendly compositions

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

The invention discloses a glass cutting fluid which comprises the following components: polyhydric alcohols, soluble lubricants, carboxylate antirust agents, sinking agents and de-foaming agents, wherein the components by weight percent include: 5-30% of polyhydric alcohols, 4-20% of soluble lubricants, 2-5% of carboxylate antirust agents, 1-5% of sinking agents and 0.1-2% of de-foaming agents. The glass cutting fluid provided by the invention has excellent lubricating, cooling, permeating and settling properties, meets the environmental requirements and the occupational safety and health requirements, expands the application of the glass cutting fluid in the halogen-free and phosphor-free fields, and is environment-friendly.

Description

Glass cutting liquid
Technical field
The present invention relates to glass working arts field, is related to a kind of glass cutting liquid.
Background technology
Hand-set lid glass belongs to the high-end field of glass processing, particularly modern touch-screen with optical lens glass processing The development of Display Technique and imaging technique, define handset touch panel glass processing and optical lens processing " high manufacturing accuracy, The industry characteristic of high efficiency, high-quality yield ", processing conditionss are towards " the high speed of mainshaft, high feed speed, big hydrojet pressure The direction of power " is developed, therefore also to the processing characteristics of glass cutting liquid proposes requirements at the higher level.
Glass belongs to hard crisp nonmetallic materials, and generally studding with the cutter of diamond, bistrique using surface carries out glass Cutting, grinding.In the course of processing, a large amount of glass micro mists and heat can be formed in machining area, these are to machining accuracy All can have a negative impact with efficiency, so that absorbing heat by injection glass cutting liquid and taking away glass dust.But glass Often granule is tiny for glass powder, the not free settling in cutting fluid, and settling can produce not in time glass dust and circulate again with cutting fluid The problem of secondary damage is produced to machining area and to glass to be processed, this is to handset touch panel glass and optical lens glass Huge infringement.As can be seen here, the cutting fluid for using during such glass processing must have good settleability, and have concurrently Low bubble property and lubricity, and from from the aspect of the protection of machine tool and metal parts, glass cutting liquid is also required to certain Rustless property.Glass cutting liquid common on Vehicles Collected from Market under high rotating speed, the processing conditionss of high feed rate, machining accuracy, The processing technique that efficiency cannot simultaneously meet above-mentioned glass with yields is required.
On the other hand, with environmental protection of enterprise consciousness and the gradually enhancing of occupational health risk prevention consciousness, to glass cutting Liquid safety is further strict with environmental requirement.Existing glass cutting liquid is used mostly quaternary ammonium salt cationic additive to improve sedimentation Performance, such as application publication number are the patented product of CN102102008A and CN103275803 A, but most quaternary ammonium salts contain There are the halide ions such as chloride ion or bromide ion, it is impossible to be applied to require the occasion of Halogen.Additionally, quaternary ammonium salt cationic additive exists The biological cell surface in electronegativity is adsorbed under electrostatic force, cell membrane is destroyed, is made protein denaturation, bactericidal properties are presented Can, be also based on the same mechanism of action there is larger zest in it to human body skin and mucosa, due to operator one As free-hand operation, directly contact workpiece and cutting fluid, therefore add quaternary ammonium salt cationic additive glass cutting liquid cannot Meet the requirement of environmental protection and occupational safety and health.More there are some traditional glass cutting liquid to use suspected carcinogens nitrite, The harm to operator's health is more increased.Additive present in some cutting fluids can also be to environmental pollution, such as Authorization Notice No. is this to add as cleaning agent for phosphorous raw material inositol hexaphosphate used in the patent of CN103275803 A Plus agent easily causes body eutrophication, it is unfavorable for the improvement and protection of water environment.
The content of the invention
Based on this, present invention seek to address that above-mentioned technical problem, there is provided a kind of with good settleability, low bubble, profit The glass cutting liquid of slip, rust-preventing characteristic and Safety and Environmental Protection.
The invention provides a kind of glass cutting liquid, its component for including has:Polyhydric alcohol, soluble oil, carboxylate Antirust agent, sedimentation agent and defoamer, the component is calculated as according to mass percent:
Wherein in one embodiment, the polyhydric alcohol is at least one in 2~10 polyhydric alcohol selected from carbon number; The sedimentation agent is polypropylene glycol that number-average molecular weight is 200~1000;The defoamer is emulsified silicone oil or polyether-modified has Machine silicon defoaming agent.
Further, the polyhydric alcohol selected from ethylene glycol, diethylene glycol, 1,2-PD, 1,3-PD, dipropylene glycol, At least one in 1,4- butanediols, glycerol, trimethylolpropane, tetramethylolmethane, Bis(pentaerythritol) or Sorbitol.
Wherein in one embodiment, the carboxylate antirust agent is selected from decanedioic acid, DC11,12 carbon binary In at least one or decanedioic acid, DC11, SL-AH or ternary polycarboxylic acids in acid or ternary polycarboxylic acids At least one neutralized reaction product with alkali.
Wherein in one embodiment, the soluble oil selected from water soluble polyether, number-average molecular weight be 200~ 2000 Polyethylene Glycol or number-average molecular weight are at least one in 500~3000 glycerin polyoxyethylene ether.
Further, the water soluble polyether is block copolymer of the Polyethylene oxide with polyoxypropylene and/or random copolymerization Thing, and the number-average molecular weight of the water soluble polyether is 2000~4000.
It is also steady including the pH value that mass percent is 4~20% in the glass cutting liquid wherein in one embodiment Determine agent;At least one of the pH stable agent in alkyl alcoholamine.
Further, the pH stable agent is selected from triethanolamine, triisopropanolamine, monoisopropanolamine, methyl diethanol At least one in amine, 2-amino-2-methyl-1-propanol, n-butyldiethanolamine, isobutyl group diethanolamine or diglycolamine.
Wherein in one embodiment, also help including the infiltration that mass percent is 2~8% in the glass cutting liquid Agent.
Further, the penetrant is 5~8% hexylene glycol.
Wherein in one embodiment, the glass cutting liquid is also including the antibacterial that mass percent is 0.5~4%.
Further, the antibacterial is 1~3% sodium benzoate.
Compared with prior art, the invention has the advantages that:
1st, the glass cutting liquid that the present invention is provided has good lubrication, cooling, infiltration and settling property, can effectively prevent Glass powder blocks the surface gaps of diamond abrasive tool, improves the cutting force of diamond abrasive tool and extends diamond abrasive tool and use the longevity Life, can significantly reduce the harmful effects such as grinding burn, chipping and scuffing, it is ensured that good machining accuracy and high working (machining) efficiency.
2nd, glass cutting liquid of the invention does not contain quaternary ammonium salt and cationic surfactant, reduces existing glass cutting Liquid meets environmental requirement and requires with occupational safety and health to human body skin and the zest of mucosa, and has expanded glass cutting liquid In the application for requiring Halogen with prohibit phosphorus field.
3rd, glass cutting liquid of the invention also has good rustless property, and antibacterial sodium benzoate can also be with carboxylate Antirust agent compounding produces unexpected effect:Collaboration antirust, and reduce the addition of carboxylate antirust agent, reduce cutting fluid into This.
Specific embodiment
Above-mentioned glass cutting liquid is further elaborated below by specific embodiment.
The present invention glass cutting liquid, including component have:Polyhydric alcohol, soluble oil, carboxylate antirust agent, sedimentation Agent, defoamer, solvent selects water.
In parts by weight, the formula of the glass cutting liquid is above each component:
Polyhydric alcohol is at least one in 2~10 polyhydric alcohol selected from carbon number, dissolving of the polyhydric alcohol to polar substancess Ability is stronger, and toxicity and volatility are then smaller, enables glass cutting liquid each component excellent dissolution to form solution, unlikely In the precipitation for causing some compositions but the performance of cutting fluid is unbalanced, while also complying with the requirement of environment protection health.Preferably, it is many First alcohol is selected from ethylene glycol, diethylene glycol, 1,2- Propylene Glycol, 1,3- Propylene Glycol, dipropylene glycol, 1,4- butanediols, glycerol, three hydroxyl first At least one in base propane, tetramethylolmethane, Bis(pentaerythritol) or Sorbitol.
Carboxylate antirust agent is selected from least in decanedioic acid, DC11, SL-AH, ternary polycarboxylic acids Kind, or the neutralization of at least one and alkali in decanedioic acid, DC11, SL-AH or ternary polycarboxylic acids Product.
Sedimentation agent is polypropylene glycol, and polypropylene glycol has the effect of the settling property for improving glass cutting liquid, by preferential Glass dust surface is diffused to, realizes that liquid-solid interface replaces rapidly gas-solid interface, the tiny air that glass dust surface is carried drives From the sedimentation resistance of reduction glass dust, so as to improve the settling property of glass cutting liquid.
Soluble oil is 500~3000 selected from the Polyethylene Glycol, number-average molecular weight that number-average molecular weight is 200~2000 Glycerin polyoxyethylene ether or water soluble polyether at least one.Soluble oil can make lubricant fully be dissolved into water In solvent, and ensure that glass cutting liquid has good greasy property, it is to avoid damage of the cutter to glass during glass cutting The damage of wound and glass chip, glass dust to glass.Preferably, water soluble polyether is the block of Polyethylene oxide and polyoxypropylene Copolymer and/or random copolymer, and the number-average molecular weight of the water soluble polyether is 2000~4000.
Defoamer is emulsified silicone oil or Polyether Modified Polysiloxanes Defoaming Agent, and emulsified silicone oil defoamer has excellent chemistry steady Qualitative, heat-resisting tolerance to cold, weather resisteant, lubricity, hydrophobicity and low surface tension, it is nontoxic to human body, it is a kind of nonpolar Compound, the material with water or with polarity gene is not had an effect, therefore froth breaking effect is strong, and consumption is extremely low.It is polyether-modified organic The characteristics of silicon defoaming agent is that surface tension is little, and surface activity is high, and froth breaking power is strong, nontoxic, and addition is few, low cost.
The glass cutting liquid that above-mentioned substance is grouped together into is a kind of compositionss for possessing combination property, this comprehensive The result that performance is each material coordinated is closed, each compositionss form a complete entirety so that glass cutting liquid has good Sedimentation well, cooling, infiltration, antirust and greasy property, while stimulating little and environmentally friendly to human body skin.
Preferably, the glass cutting liquid that the present invention is provided is also including the pH stable agent that mass percent is 4~20%, pH At least one of the value stabilization agent in alkyl alcoholamine.It is further preferred that these alkyl alcoholamines include triethanolamine, three isopropyls Hydramine, monoisopropanolamine, methyl diethanolamine, 2-amino-2-methyl-1-propanol, n-butyldiethanolamine, isobutyl group diethanol At least one in amine or diglycolamine.
Preferably, the glass cutting liquid that the present invention is provided is also including the penetrant that mass percent is 2~8%.Enter one Step is preferred, and the penetrant selects hexylene glycol, this kind of penetrant to have good permeability, can promote glass cutting Liquid rapid osmotic is to cutting, grinding area, improves cooling, the cleaning performance of glass cutting liquid, and can to a certain extent enter one Step improves the settling property of glass cutting liquid.
Preferably, the glass cutting liquid that the present invention is provided is also including the antibacterial of mass percent 0.5~4%.Antibacterial One kind in sodium benzoate or potassium sorbate, both antibacterial are the preservative commonly used in food industry, and human body is pacified It is complete gentle, health risk caused by regular industrial antibacterial can be avoided, wherein being preferably selected sodium benzoate, and cut in glass It is 1~3% to cut the mass percent in liquid.Surprisingly, sodium benzoate can be produced with carboxylate antirust agent compounding Collaboration rust inhibition, so as to reduce the addition of carboxylate antirust agent, reduces the production cost of cutting fluid.
Used as a preferred scheme, said components are according to the formula of mass fraction meter:
It is below specific embodiment.
Embodiment one
A kind of glass cutting liquid, raw material composition by mass percentage is as follows:
Embodiment two
A kind of glass cutting liquid, raw material composition by mass percentage is as follows:
Embodiment three
A kind of glass cutting liquid, raw material composition by mass percentage is as follows:
Example IV
A kind of glass cutting liquid, raw material composition by mass percentage is as follows:
Embodiment five
A kind of glass cutting liquid, raw material composition by mass percentage is as follows:
Embodiment six
Embodiment seven
Comparative example
This example provides a kind of glass cutting liquid, essentially identical in its basis and embodiment five, by mass percentage The raw material composition of meter is as follows:
By embodiment five and comparative example respectively gained glass cutting liquid deionized water be respectively configured to 5% diluent, enter Row glass dust settling property is contrasted, and it is that the diluent of comparative example is still muddy opaque to stand result after 10min, and embodiment five Middle diluent recovers transparent substantially, glass dust is settled completely substantially, and settling property is significantly increased than comparative example.
Although having been illustrated with some exemplary embodiments of the present invention above, those skilled in the art will manage Solution, in the case of the principle or spirit without departing from the present invention, can make a change to these exemplary embodiments, of the invention Scope is limited by claim and its equivalent.

Claims (12)

1. a kind of glass cutting liquid, its component for including has:Polyhydric alcohol, soluble oil, carboxylate antirust agent, sedimentation agent and Defoamer, the component is calculated as according to mass percent:Polyhydric alcohol 5~30%, soluble oil 4~20%, carboxylate is prevented Rust agent 2~5%, sedimentation agent 1~5%, defoamer 0.1~2%.
2. glass cutting liquid according to claim 1, it is characterised in that the polyhydric alcohol is 2~10 selected from carbon number Polyhydric alcohol at least one;The sedimentation agent is polypropylene glycol that number-average molecular weight is 200~1000;The defoamer is Emulsified silicone oil or Polyether Modified Polysiloxanes Defoaming Agent.
3. glass cutting liquid according to claim 2, it is characterised in that the polyhydric alcohol selected from ethylene glycol, diethylene glycol, 1, 2- Propylene Glycol, 1,3- Propylene Glycol, dipropylene glycol, 1,4- butanediols, glycerol, trimethylolpropane, tetramethylolmethane, double Ji Wusi At least one in alcohol or Sorbitol.
4. glass cutting liquid according to claim 1, it is characterised in that the carboxylate antirust agent selected from decanedioic acid, ten At least one or decanedioic acid, DC11,12 carbon two in one carbon dicarboxylic acid, SL-AH or ternary polycarboxylic acids At least one neutralized reaction product with alkali in first acid or ternary polycarboxylic acids.
5. glass cutting liquid according to claim 1, it is characterised in that the soluble oil is selected from water-soluble poly In the glycerin polyoxyethylene ether that ether, number-average molecular weight are 200~2000 Polyethylene Glycol or number-average molecular weight is 500~3000 It is at least one.
6. glass cutting liquid according to claim 5, it is characterised in that the water soluble polyether is Polyethylene oxide and polyoxy The block copolymer and/or random copolymer of propylene, and the number-average molecular weight of the water soluble polyether is 2000~4000.
7. glass cutting liquid according to claim 1, it is characterised in that also include quality percentage in the glass cutting liquid Than for 4~20% pH stable agent;At least one of the pH stable agent in alkyl alcoholamine.
8. glass cutting liquid according to claim 7, it is characterised in that the pH stable agent selected from triethanolamine, three Isopropanolamine, monoisopropanolamine, methyl diethanolamine, 2-amino-2-methyl-1-propanol, n-butyldiethanolamine, isobutyl group two At least one in ethanolamine or diglycolamine.
9. glass cutting liquid according to claim 1, it is characterised in that also include quality percentage in the glass cutting liquid Than for 2~8% penetrant.
10. glass cutting liquid according to claim 9, it is characterised in that the penetrant is 5~8% dissident two Alcohol.
11. glass cutting liquid according to claim 1, it is characterised in that the glass cutting liquid also includes quality percentage Than for 0.5~4% antibacterial.
12. glass cutting liquid according to claim 11, it is characterised in that the antibacterial is 1~3% benzoic acid Sodium.
CN201611184701.0A 2016-12-20 2016-12-20 Glass cutting fluid Active CN106675751B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611184701.0A CN106675751B (en) 2016-12-20 2016-12-20 Glass cutting fluid

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611184701.0A CN106675751B (en) 2016-12-20 2016-12-20 Glass cutting fluid

Publications (2)

Publication Number Publication Date
CN106675751A true CN106675751A (en) 2017-05-17
CN106675751B CN106675751B (en) 2020-04-10

Family

ID=58869854

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201611184701.0A Active CN106675751B (en) 2016-12-20 2016-12-20 Glass cutting fluid

Country Status (1)

Country Link
CN (1) CN106675751B (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107384566A (en) * 2017-08-04 2017-11-24 安徽宽居电器有限公司 A kind of glass processing coolant and preparation method thereof
CN107384565A (en) * 2017-08-04 2017-11-24 安徽宽居电器有限公司 A kind of glass processing cutting fluid
CN108003977A (en) * 2018-01-04 2018-05-08 云南汇都科技有限公司 One kind is without oil type spray lubricants
CN111518603A (en) * 2020-04-07 2020-08-11 广东剑鑫科技股份有限公司 Water-based fully-synthetic sapphire glass cutting fluid and preparation method thereof
CN111560287A (en) * 2020-05-18 2020-08-21 广东欧派斯润滑科技有限公司 Stone processing liquid

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003082334A (en) * 2001-09-06 2003-03-19 Yushiro Chem Ind Co Ltd Water-soluble work liquid composition for abrasive train fixed wire saw
CN103391992A (en) * 2011-02-23 2013-11-13 尤希路化学工业有限公司 Water-soluble working fluid for fixed abrasive grain wire saw
CN103981008A (en) * 2014-05-23 2014-08-13 启东尤希路化学工业有限公司 High-performance environment-friendly water-based honing working fluid
CN105296106A (en) * 2015-10-26 2016-02-03 深圳市辛骏翔科技有限公司 Glass cutting fluid

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003082334A (en) * 2001-09-06 2003-03-19 Yushiro Chem Ind Co Ltd Water-soluble work liquid composition for abrasive train fixed wire saw
CN103391992A (en) * 2011-02-23 2013-11-13 尤希路化学工业有限公司 Water-soluble working fluid for fixed abrasive grain wire saw
CN103981008A (en) * 2014-05-23 2014-08-13 启东尤希路化学工业有限公司 High-performance environment-friendly water-based honing working fluid
CN105296106A (en) * 2015-10-26 2016-02-03 深圳市辛骏翔科技有限公司 Glass cutting fluid

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107384566A (en) * 2017-08-04 2017-11-24 安徽宽居电器有限公司 A kind of glass processing coolant and preparation method thereof
CN107384565A (en) * 2017-08-04 2017-11-24 安徽宽居电器有限公司 A kind of glass processing cutting fluid
CN108003977A (en) * 2018-01-04 2018-05-08 云南汇都科技有限公司 One kind is without oil type spray lubricants
CN111518603A (en) * 2020-04-07 2020-08-11 广东剑鑫科技股份有限公司 Water-based fully-synthetic sapphire glass cutting fluid and preparation method thereof
CN111518603B (en) * 2020-04-07 2023-02-10 广东剑鑫科技股份有限公司 Water-based fully-synthetic sapphire glass cutting fluid and preparation method thereof
CN111560287A (en) * 2020-05-18 2020-08-21 广东欧派斯润滑科技有限公司 Stone processing liquid

Also Published As

Publication number Publication date
CN106675751B (en) 2020-04-10

Similar Documents

Publication Publication Date Title
CN106675751A (en) Glass cutting fluid
CN103013638B (en) Water-soluble cooling liquid for fixed abrasive material line cutting, and preparation method thereof
CN101104831B (en) Micro-emulsification stainless steel cutting liquid
CN104087404A (en) High-cleanliness economical microemulsion metal cutting fluid
CN103525533B (en) Full-synthetic glass grinding fluid
KR101993485B1 (en) Amine-free voc-free metal working fluid
CN101240221A (en) Water-soluble total synthesis metal processing liquid composition
EP2904074B1 (en) A concentrated metalworking fluid and metalworking process
CN103333735A (en) Cooling liquid for optical processing and preparation method of cooling liquid
CN103981008A (en) High-performance environment-friendly water-based honing working fluid
TWI793193B (en) Fabrication fluids
JP2019509391A (en) Metal working fluid
CN104327933A (en) Environmental-protection lubricating water-based cutting fluid
CN113462458A (en) Efficient diamond wire silicon wafer cutting fluid
CN106350189A (en) Special synthesized cutting fluid with ultra-high lubricating property for black metal and preparation method of special synthesized cutting fluid
KR100187648B1 (en) Neat composition for soluble-type cutting fluid
JP4531882B2 (en) Water-soluble metalworking fluid
JP2011256377A (en) Water-soluble machining oil composition for fixed-abrasive wire saw
CN110029006B (en) Special grinding fluid for ELID grinding composite material and preparation method thereof
CN111117754A (en) High-lubrication stable cutting fluid and preparation method thereof
US7674754B2 (en) Water-based metalworking fluid incorporating polymeric boron materials
CN110951533B (en) Long-acting micro-emulsified cutting fluid for metal processing and preparation method thereof
CN106675754A (en) Water-based cutting fluid fog inhibitor and water-based cutting fluid
CN104357205A (en) Lubricating and rust-proof metal cutting fluid
EP3405543B1 (en) High molecular weight polyoxyalkylene glycol coolant for grinding glass

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant