CN102250673B - Environment-friendly emulsion cutting oil with high lubricity and high permeability for metal working - Google Patents
Environment-friendly emulsion cutting oil with high lubricity and high permeability for metal working Download PDFInfo
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- CN102250673B CN102250673B CN 201110160691 CN201110160691A CN102250673B CN 102250673 B CN102250673 B CN 102250673B CN 201110160691 CN201110160691 CN 201110160691 CN 201110160691 A CN201110160691 A CN 201110160691A CN 102250673 B CN102250673 B CN 102250673B
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- 239000010730 cutting oil Substances 0.000 title abstract description 6
- 230000035699 permeability Effects 0.000 title abstract description 5
- 239000000839 emulsion Substances 0.000 title abstract 4
- 238000005555 metalworking Methods 0.000 title abstract 2
- 238000003754 machining Methods 0.000 claims description 10
- 239000002184 metal Substances 0.000 claims description 9
- 229910052751 metal Inorganic materials 0.000 claims description 9
- 206010020852 Hypertonia Diseases 0.000 claims description 7
- 230000007613 environmental effect Effects 0.000 claims description 7
- 238000004519 manufacturing process Methods 0.000 claims description 7
- 235000013336 milk Nutrition 0.000 claims description 7
- 239000008267 milk Substances 0.000 claims description 7
- 210000004080 milk Anatomy 0.000 claims description 7
- 239000002480 mineral oil Substances 0.000 abstract description 8
- 235000010446 mineral oil Nutrition 0.000 abstract description 8
- 239000000314 lubricant Substances 0.000 abstract description 7
- 150000001412 amines Chemical class 0.000 abstract description 5
- 239000013530 defoamer Substances 0.000 abstract description 5
- 150000001732 carboxylic acid derivatives Chemical class 0.000 abstract 1
- 239000003518 caustics Substances 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 239000004094 surface-active agent Substances 0.000 abstract 1
- 239000003921 oil Substances 0.000 description 17
- 235000019198 oils Nutrition 0.000 description 17
- 229920002545 silicone oil Polymers 0.000 description 9
- 239000002199 base oil Substances 0.000 description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- SJRJJKPEHAURKC-UHFFFAOYSA-N N-Methylmorpholine Chemical compound CN1CCOCC1 SJRJJKPEHAURKC-UHFFFAOYSA-N 0.000 description 6
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 6
- 239000002253 acid Substances 0.000 description 6
- LVTYICIALWPMFW-UHFFFAOYSA-N diisopropanolamine Chemical compound CC(O)CNCC(C)O LVTYICIALWPMFW-UHFFFAOYSA-N 0.000 description 6
- 229940043276 diisopropanolamine Drugs 0.000 description 6
- FBUKVWPVBMHYJY-UHFFFAOYSA-N nonanoic acid Chemical compound CCCCCCCCC(O)=O FBUKVWPVBMHYJY-UHFFFAOYSA-N 0.000 description 6
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 6
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- -1 polyoxyethylene Polymers 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 4
- 239000013543 active substance Substances 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 150000002148 esters Chemical class 0.000 description 4
- MNWFXJYAOYHMED-UHFFFAOYSA-N heptanoic acid Chemical compound CCCCCCC(O)=O MNWFXJYAOYHMED-UHFFFAOYSA-N 0.000 description 4
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 4
- BKIMMITUMNQMOS-UHFFFAOYSA-N nonane Chemical compound CCCCCCCCC BKIMMITUMNQMOS-UHFFFAOYSA-N 0.000 description 4
- 229920000570 polyether Polymers 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 3
- 231100000111 LD50 Toxicity 0.000 description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 3
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 3
- 239000012964 benzotriazole Substances 0.000 description 3
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 238000004945 emulsification Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 229940049964 oleate Drugs 0.000 description 3
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 3
- 239000001294 propane Substances 0.000 description 3
- 229960004418 trolamine Drugs 0.000 description 3
- WIHIUTUAHOZVLE-UHFFFAOYSA-N 1,3-diethoxypropan-2-ol Chemical compound CCOCC(O)COCC WIHIUTUAHOZVLE-UHFFFAOYSA-N 0.000 description 2
- HXKKHQJGJAFBHI-UHFFFAOYSA-N 1-aminopropan-2-ol Chemical compound CC(O)CN HXKKHQJGJAFBHI-UHFFFAOYSA-N 0.000 description 2
- SNTWKPAKVQFCCF-UHFFFAOYSA-N 2,3-dihydro-1h-triazole Chemical compound N1NC=CN1 SNTWKPAKVQFCCF-UHFFFAOYSA-N 0.000 description 2
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- 229940058020 2-amino-2-methyl-1-propanol Drugs 0.000 description 2
- SFAAOBGYWOUHLU-UHFFFAOYSA-N 2-ethylhexyl hexadecanoate Chemical compound CCCCCCCCCCCCCCCC(=O)OCC(CC)CCCC SFAAOBGYWOUHLU-UHFFFAOYSA-N 0.000 description 2
- SAUIGQBKPDQYHL-QXMHVHEDSA-N 6-methylheptyl (z)-octadec-9-enoate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCCCCCC(C)C SAUIGQBKPDQYHL-QXMHVHEDSA-N 0.000 description 2
- XBPCUCUWBYBCDP-UHFFFAOYSA-N Dicyclohexylamine Chemical compound C1CCCCC1NC1CCCCC1 XBPCUCUWBYBCDP-UHFFFAOYSA-N 0.000 description 2
- 239000004721 Polyphenylene oxide Substances 0.000 description 2
- SLINHMUFWFWBMU-UHFFFAOYSA-N Triisopropanolamine Chemical compound CC(O)CN(CC(C)O)CC(C)O SLINHMUFWFWBMU-UHFFFAOYSA-N 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 125000003354 benzotriazolyl group Chemical group N1N=NC2=C1C=CC=C2* 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 2
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 150000002632 lipids Chemical class 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 239000012188 paraffin wax Substances 0.000 description 2
- 229920003216 poly(methylphenylsiloxane) Polymers 0.000 description 2
- 229920000056 polyoxyethylene ether Polymers 0.000 description 2
- 229940051841 polyoxyethylene ether Drugs 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 238000010079 rubber tapping Methods 0.000 description 2
- 235000012424 soybean oil Nutrition 0.000 description 2
- 239000003549 soybean oil Substances 0.000 description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 2
- 230000003746 surface roughness Effects 0.000 description 2
- 150000003918 triazines Chemical class 0.000 description 2
- 206010009866 Cold sweat Diseases 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 208000008784 apnea Diseases 0.000 description 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000029087 digestion Effects 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 231100000017 mucous membrane irritation Toxicity 0.000 description 1
- 239000007764 o/w emulsion Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
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- Lubricants (AREA)
Abstract
The invention discloses an environment-friendly emulsion cutting oil with high lubricity and high permeability for metal working. The emulsion cutting oil is composed of a polymer carboxylic acid, an amine, a surfactant, mineral oil, a synthetic lubricant, a defoamer and an anti-corrosive agent. The emulsion cutting oil disclosed by the invention causes small pollution during processing, has excellent lubricity and permeability, and is safe to human and environment.
Description
Technical field
The present invention relates to the oil-in-water type machining oil of use in a kind of metal processing.
Background technology
For a long time, metal cutting, the widely used treated oil in ground finish field all are take mineral oil as the basis basically, are divided into water insoluble cutting oil and water-emulsifiable machining oil two large classes.Smolder, mist of oil, easily to catch fire and workpiece many drawbacks such as easy cleaning not because water insoluble cutting oil exists, thus at present just gradually processed excellent property, cooling performance and health, safety performance preferably water emulsifiable oils substitute.But at present commercially available water-emulsifiable machining oil oilness undesirable (during 5% concentration, all more than 2100 N ﹒ cm, fraising surface roughness Ra value is all more than 0.7 μ m for the tapping torque value); Perviousness relatively poor (when 5% concentration, 100 order iron particle size, the testing permeability time is all greater than 60s); The objectionable impurities that contains health risk in the prescription; In the course of processing, the spittle of diluent pollutes operating environment, and its non-volatile composition causes machinery to be clamminess after the spittle drying.For overcoming the problems referred to above, satisfy better the high-end user demand, we spend one-year age, on the basis of digestion, the external advanced technologies of absorption and technology, innovate again in conjunction with national conditions, successfully researched and developed " high lubricated, the hypertonicity environmental friendliness shaped metal manufacturing milk machining oil of FGE201 ".
Summary of the invention
The object of the present invention is to provide in a kind of course of processing pollute less, the oilness permeate well,, hypertonicity environmental friendliness shaped metal manufacturing milk machining oil lubricated to the height of human and environment safety.
Technical solution of the present invention is:
A kind of high lubricated, hypertonicity environmental friendliness shaped metal manufacturing milk machining oil, it is characterized in that: the one-tenth by following weight percent is grouped into:
Polymeric carboxylic 5～20%
Amine 5～30%
Tensio-active agent 1～20%
Mineral oil and synthetic lubricant 40～70%
Defoamer 0.05 ~ 2%
Anticorrosive agent 0～5%.
Polymeric carboxylic is caproic acid, enanthic acid, sad, n-nonanoic acid, sebacic acid, hexanodioic acid, nonane diacid, bay diacid, C
8-C
12Among lipid acid, the triazines multi-carboxylic acid compounds one or more.
Amine is one or more in Monoethanolamine MEA BASF, diethanolamine, trolamine, monoisopropanolamine, diisopropanolamine (DIPA), tri-isopropanolamine, morpholine, dicyclohexyl amine, N-methylmorpholine, 2-amino-2-methyl-1-propanol, the diethylin ethanol.
Tensio-active agent is one or more in fatty alcohol-polyoxyethylene ether (5-12), alkylphenol polyoxyethylene (5-12), aliphatic alcohol polyethenoxy polyethenoxy ether, alkylol amide, aliphatic alcohol polyethenoxy ester (5-12), the sulfonate.
Mineral oil is one or more in naphthenic base oils, paraffin base oil, the intermediate base base oil; Synthetic lubricant is one or more in sirasimeyu, soybean oil, plam oil, Oleum Cocois, suet, tricarboxymethyl propane oleate, pentaerythritol ester, isooctyl oleate, hexanodioic acid dibutyl ester, the Wickenol 155; The mass ratio of mineral oil and synthetic lubricant is 1:0.3 ~ 0.7.
Defoamer is one or more in dimethyl silicone oil, diethyl silicone oil, methyl phenyl silicone oil, ammonia alkyl silicone oil, polyether silicone oil, the polyethers; Anticorrosive agent is benzotriazole, methyl benzotriazazole, 1H-1, one or more in 2, the 4-triazole.
Mechanical contamination is few in the course of processing of the present invention, through testing the actual achievement that relatively reaches in-situ processing, greatly reduces than traditional oil in water emulsion mechanical contamination; Lubricity is good, tapping torque value during 5% concentration, and the present invention is 1700 N ﹒ cm, conventional emulsification oil is 2100 N ﹒ cm; Fraising surface roughness value (Ra) during 5% concentration, the present invention is 0.1 μ m, conventional emulsification oil is 0.7 μ m; Good penetrability, uses granularity to be 50-100 purpose iron powder at 5% concentration, and the testing permeability time of the present invention is 18s, and conventional emulsification oil is 60s; The safety and sanitation reliable in quality.Do not contain any sterilant, after testing, the biological Lethal Dose 50 LD50＞5000mg/kg of the present invention, biological toxic limit medium dose LC50＞5000mg/m3, apnea road mucous membrane irritation, friendly to human and environment.
The invention will be further described below in conjunction with embodiment.
Embodiment
Embodiment 1:
With the component mix and blend of following weight percent, get high lubricated, hypertonicity environmental friendliness shaped metal manufacturing milk machining oil product:
Sebacic acid 10%
N-nonanoic acid 5%
Trolamine 14.9%
Diisopropanolamine (DIPA) 8%
Alkylphenol polyoxyethylene (9) 6%
Aliphatic alcohol polyethenoxy polyethenoxy ether 5%
22# naphthenic base oils 35%
Tricarboxymethyl propane oleate 15%
Dimethyl silicone oil 1%
Benzotriazole 0.1%.
Embodiment 2:
With the component mix and blend of following weight percent, get high lubricated, hypertonicity environmental friendliness shaped metal manufacturing milk machining oil product:
Polymeric carboxylic 5～20%(example 5%, 12%, 20%)
Amine 5～30%(example 5%, 20%, 30%)
Tensio-active agent 1～20%(example 1%, 12%, 20%)
Mineral oil and synthetic lubricant 40～70%(example 40%, 55%, 70%)
Defoamer 0.05 ~ 2%(example 0.05%, 1%, 2%)
Anticorrosive agent 0～5%(example 0%, 3%, 5%).
Polymeric carboxylic is caproic acid, enanthic acid, sad, n-nonanoic acid, sebacic acid, hexanodioic acid, nonane diacid, bay diacid, C
8-C
12Among lipid acid, the triazines multi-carboxylic acid compounds one or more.
Amine is one or more in Monoethanolamine MEA BASF, diethanolamine, trolamine, monoisopropanolamine, diisopropanolamine (DIPA), tri-isopropanolamine, morpholine, dicyclohexyl amine, N-methylmorpholine, 2-amino-2-methyl-1-propanol, the diethylin ethanol.
Tensio-active agent is one or more in fatty alcohol-polyoxyethylene ether (5-12), alkylphenol polyoxyethylene (5-12), aliphatic alcohol polyethenoxy polyethenoxy ether, alkylol amide, aliphatic alcohol polyethenoxy ester (5-12), the sulfonate.
Mineral oil is one or more in naphthenic base oils, paraffin base oil, the intermediate base base oil; Synthetic lubricant is one or more in sirasimeyu, soybean oil, plam oil, Oleum Cocois, suet, tricarboxymethyl propane oleate, pentaerythritol ester, isooctyl oleate, hexanodioic acid dibutyl ester, the Wickenol 155; The mass ratio of mineral oil and synthetic lubricant is 1:0.3 ~ 0.7(example 1:0.3,1:0.5,1:0.7).
Defoamer is one or more in dimethyl silicone oil, diethyl silicone oil, methyl phenyl silicone oil, ammonia alkyl silicone oil, polyether silicone oil, the polyethers; Anticorrosive agent is benzotriazole, methyl benzotriazazole, 1H-1, one or more in 2, the 4-triazole.
Claims (1)
1. one kind high lubricated, hypertonicity environmental friendliness shaped metal manufacturing milk machining oil, it is characterized in that: the one-tenth by following weight percent is grouped into:
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110160691 CN102250673B (en) | 2011-06-15 | 2011-06-15 | Environment-friendly emulsion cutting oil with high lubricity and high permeability for metal working |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110160691 CN102250673B (en) | 2011-06-15 | 2011-06-15 | Environment-friendly emulsion cutting oil with high lubricity and high permeability for metal working |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102250673A CN102250673A (en) | 2011-11-23 |
| CN102250673B true CN102250673B (en) | 2013-04-10 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201110160691 Active CN102250673B (en) | 2011-06-15 | 2011-06-15 | Environment-friendly emulsion cutting oil with high lubricity and high permeability for metal working |
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| CN (1) | CN102250673B (en) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102618352A (en) * | 2012-02-27 | 2012-08-01 | 上海尤希路化学工业有限公司 | Work procedure rust preventive oil for processing high-quality metal |
| CN102660360B (en) * | 2012-05-04 | 2013-07-24 | 启东尤希路化学工业有限公司 | Superfine oil for abrasive machining of high-lubrication and high-water-separability bearing |
| CN102733260B (en) * | 2012-06-29 | 2014-11-26 | 上海东升新材料有限公司 | Aqueous lubricant used in papermaking, and preparation method thereof |
| CN103506567B (en) * | 2013-10-15 | 2015-07-01 | 上海尤希路化学工业有限公司 | Atomizing spraying oily aluminium alloy mould release agent |
| CN104711099B (en) * | 2013-12-15 | 2018-08-21 | 烟台道平化工材料有限公司 | A kind of aluminium alloy micro emulsion cutting fluid and preparation method thereof |
| CN104212539A (en) * | 2014-08-13 | 2014-12-17 | 铜陵日科电子有限责任公司 | Anticorrosive antirust transformer oil containing various nanoparticles, and preparation method thereof |
| CN104371800A (en) * | 2014-10-22 | 2015-02-25 | 安徽荣达阀门有限公司 | Special hard-water-resistant emulsified cutting oil for alloys and preparation method thereof |
| CN105296245B (en) * | 2015-11-18 | 2018-07-27 | 南京科润工业介质股份有限公司 | A kind of emulsion for without cleaning after nut tapping processing and use |
| CN106244295A (en) * | 2016-07-13 | 2016-12-21 | 天长市润达金属防锈助剂有限公司 | A kind of extreme boundary lubrication metalworking fluid |
| CN108611170B (en) * | 2018-05-07 | 2021-05-21 | 苏州捷德瑞精密机械有限公司 | Novel metal cutting fluid and preparation method thereof |
| CN108559592A (en) * | 2018-05-21 | 2018-09-21 | 广州汇专工具有限公司 | A kind of environmental protection cutting oil and its preparation method and application |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100465254C (en) * | 2005-08-09 | 2009-03-04 | 启东尤希路化学工业有限公司 | Hard water resistant water-soluble cutting solution |
| CN100482773C (en) * | 2006-12-08 | 2009-04-29 | 中国石油化工股份有限公司 | Cutting liquor composition for metal processing |
| CN101560433B (en) * | 2009-05-11 | 2012-03-07 | 启东尤希路化学工业有限公司 | Anti-magnesium hard water anti-magnesium corrosion environmentally-friendly water soluble cutting solution |
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2011
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