CN108559592A - A kind of environmental protection cutting oil and its preparation method and application - Google Patents
A kind of environmental protection cutting oil and its preparation method and application Download PDFInfo
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- CN108559592A CN108559592A CN201810490976.XA CN201810490976A CN108559592A CN 108559592 A CN108559592 A CN 108559592A CN 201810490976 A CN201810490976 A CN 201810490976A CN 108559592 A CN108559592 A CN 108559592A
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
- C10M169/044—Mixtures of base-materials and additives the additives being a mixture of non-macromolecular and macromolecular compounds
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23Q—DETAILS, COMPONENTS, OR ACCESSORIES FOR MACHINE TOOLS, e.g. ARRANGEMENTS FOR COPYING OR CONTROLLING; MACHINE TOOLS IN GENERAL CHARACTERISED BY THE CONSTRUCTION OF PARTICULAR DETAILS OR COMPONENTS; COMBINATIONS OR ASSOCIATIONS OF METAL-WORKING MACHINES, NOT DIRECTED TO A PARTICULAR RESULT
- B23Q11/00—Accessories fitted to machine tools for keeping tools or parts of the machine in good working condition or for cooling work; Safety devices specially combined with or arranged in, or specially adapted for use in connection with, machine tools
- B23Q11/10—Arrangements for cooling or lubricating tools or work
- B23Q11/1038—Arrangements for cooling or lubricating tools or work using cutting liquids with special characteristics, e.g. flow rate, quality
- B23Q11/1061—Arrangements for cooling or lubricating tools or work using cutting liquids with special characteristics, e.g. flow rate, quality using cutting liquids with specially selected composition or state of aggregation
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
- C10M2205/028—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers containing aliphatic monomers having more than four carbon atoms
- C10M2205/0285—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers containing aliphatic monomers having more than four carbon atoms used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/0215—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms used as base material
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
- C10M2207/026—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings with tertiary alkyl groups
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/281—Esters of (cyclo)aliphatic monocarboxylic acids
- C10M2207/2815—Esters of (cyclo)aliphatic monocarboxylic acids used as base material
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/283—Esters of polyhydroxy compounds
- C10M2207/2835—Esters of polyhydroxy compounds used as base material
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/287—Partial esters
- C10M2207/289—Partial esters containing free hydroxy groups
- C10M2207/2895—Partial esters containing free hydroxy groups used as base material
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
- C10M2215/064—Di- and triaryl amines
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/223—Five-membered rings containing nitrogen and carbon only
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/10—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
- C10M2219/104—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring containing sulfur and carbon with nitrogen or oxygen in the ring
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/10—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
- C10M2219/104—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring containing sulfur and carbon with nitrogen or oxygen in the ring
- C10M2219/106—Thiadiazoles
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/10—Inhibition of oxidation, e.g. anti-oxidants
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/64—Environmental friendly compositions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Fluid Mechanics (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Lubricants (AREA)
Abstract
The invention discloses a kind of environmental protection cutting oil and its preparation method and application.This environmental protection cutting oil is made of the raw material of following mass parts：30~50 parts of synthetic ester；20~40 parts of fatty alcohol；20~40 parts of polyalphaolefin；1~2 part of antioxidant；1~2 part of antirust agent；1~2 part of metal deactivator.The preparation method of this environmental protection cutting oil is also disclosed that simultaneously.Also disclose a kind of method for cutting oil progress metal cutting process using the environmental protection.The cutting oil lubrication of the present invention is had excellent performance, and antioxygenic property is good, biodegradable, nontoxic to human body and ecological environment, meets relevant environment index request.
Description
Technical field
The present invention relates to a kind of environmental protection cutting oil and its preparation method and application.
Background technology
In the machining of metal, workpiece and cutter will produce between cutter and chip and largely rub and generate
Amount of heat improves stock-removing efficiency to reduce friction, improves the precision of workpiece and reduces the roughness of workpiece surface, extends
Cutter life is generally mated using cutting fluid or using cutting oil.
With workpiece material superhardization and diversified development, intermetallic composite coating difficulty is higher and higher, to cutting oiliness energy
It is required that also increasingly improving.
Traditional cutting oil biodegradability is poor, and Ecological Cost is high, with the continuous improvement of people's environmental consciousness, it is desirable that
Cutting oil is other than having good performance, it is necessary to and it is environmentally safe, it is harmless.
Invention content
The purpose of the present invention is to provide a kind of environmental protection cutting oil and its preparation method and application.
The technical solution used in the present invention is：
A kind of environmental protection cutting oil, is made of the raw material of following mass parts：
In environmental protection cutting oil, synthetic ester is four oleate of pentaerythrite, tricarboxymethyl propane oleate, neopentyl glycol oleic acid
At least one of ester, Ethylhexyl stearate, isooctyl oleate.
In environmental protection cutting oil, fatty alcohol is the fatty alcohol of carbon atom number 6~24.
In environmental protection cutting oil, polyalphaolefin PAO4.
In environmental protection cutting oil, antioxidant is at least one of phenolic antioxidant, alkyl benzene amine kind antioxidant.
In environmental protection cutting oil, antirust agent is at least one of benzotriazole, 2-mercaptobenzothiazole.
In environmental protection cutting oil, metal deactivator is at least one of thiadiazoles derivative, triazole derivative.
The preparation method of this environmental protection cutting oil, includes the following steps：
1) raw material is weighed by above-mentioned composition, by synthetic ester, fatty alcohol and polyalphaolefin, is mixed, obtains base oil；
2) by base oil heating stirring, antioxidant, antirust agent and metal deactivator is added, is mixed, obtains crude oil product；
3) crude oil product are filtered, obtains environmental protection cutting oil.
The step 2) of preparation method is specially：Base oil is heated to 60 DEG C~100 DEG C stirrings, antioxidant, antirust is added
Agent and metal deactivator, are mixed evenly, and are then cooled to 50 DEG C hereinafter, stopping stirring, obtains crude oil product.
A kind of cutting working method of metal is to carry out fog lubrication processing using this environmental protection cutting oil.
The beneficial effects of the invention are as follows：
The cutting oil lubrication of the present invention is had excellent performance, and antioxygenic property is good, biodegradable, to human body and ecological environment without
Poison is harmless, meets relevant environment index request.
The cutting oil product of the present invention is nontoxic to human body and ecological environment, meets relevant environment index request, lubricates
Property and excellent oxidation stability, it is versatile, be suitable for the metal cutting process of most of material, especially suitable for half dry type and
Minimal quantity of lubrication oil is mainly used for fog lubrication.The mist of oil of gas-liquid two-phase can play lubricating action and take away a large amount of heat
Amount, moreover it is possible to which the usage amount for reducing cutting fluid reduces cost, reduces discharging of waste liquid, is conducive to environmental protection.
Specific implementation mode
Cutting oil is made of base oil and additive two parts, and base oil is the main component of cutting oil, plays main profit
Sliding effect；Additive can then improve the performance of cutting oil.
A kind of environmental protection cutting oil, is made of the raw material of following mass parts：
Preferably, in environmental protection cutting oil, synthetic ester is four oleate of pentaerythrite, tricarboxymethyl propane oleate, new penta
At least one of glycol oleate, Ethylhexyl stearate, isooctyl oleate；It is further preferred that in environmental protection cutting oil, synthesis
Ester is four oleate of pentaerythrite, tricarboxymethyl propane oleate, Ethylhexyl stearate, isooctyl oleate with mass ratio 4:3:1:
The mixture of 1 composition.
Preferably, in environmental protection cutting oil, fatty alcohol is the fatty alcohol of carbon atom number 6~24；It is further preferred that environmental protection is cut
It cuts in oil, fatty alcohol is at least one of isooctanol, Decanol, laruyl alcohol；Still further preferably, in environmental protection cutting oil,
Fatty alcohol is isooctanol, Decanol, laruyl alcohol with mass ratio 4:3:The mixture of 3 compositions.
Preferably, in environmental protection cutting oil, polyalphaolefin (PAO) is PAO4.
Preferably, in environmental protection cutting oil, antioxidant is at least one of phenolic antioxidant, alkyl benzene amine kind antioxidant；
It is further preferred that in environmental protection cutting oil, antioxidant is 2,6-di-tert-butyl p-cresol, liquid octyl butyl diphenylamines, high score
At least one of son amount phenolic antioxidant.
Preferably, in environmental protection cutting oil, antirust agent is at least one of benzotriazole, 2-mercaptobenzothiazole；Into
One step is preferred, and in environmental protection cutting oil, antirust agent is benzotriazole and 2-mercaptobenzothiazole with mass ratio 1:1 composition mixes
Close object.
Preferably, in environmental protection cutting oil, metal deactivator is at least one of thiadiazoles derivative, triazole derivative；
It is further preferred that in environmental protection cutting oil, metal deactivator is thiadiazoles derivative and triazole derivative with mass ratio 1:1 composition
Mixture.
The preparation method of this environmental protection cutting oil, includes the following steps：
1) raw material is weighed by above-mentioned composition, by synthetic ester, fatty alcohol and polyalphaolefin, is mixed, obtains base oil；
2) by base oil heating stirring, antioxidant, antirust agent and metal deactivator is added, is mixed, obtains crude oil product；
3) crude oil product are filtered, obtains environmental protection cutting oil.
The step 2) of preparation method is specially：Base oil is heated to 60 DEG C~100 DEG C stirrings, antioxidant, antirust is added
Agent and metal deactivator, are mixed evenly, and are then cooled to 50 DEG C hereinafter, stopping stirring, obtains crude oil product.
A kind of cutting working method of metal is to carry out fog lubrication processing using this environmental protection cutting oil.
Further, fog lubrication processing refers to that environmental protection cutting oil is carried out cooling for cut with mist of oil gas procedure.
Fog lubrication processing method refers to micro-lubricating cutting technology, this is a kind of typical near dry cutting method, is
Refer to and vaporize compressed gas (air, nitrogen, carbon dioxide etc.) and the mix lubricant of denier, forms micron-sized drop,
It is ejected into a kind of cutting working method that processing district carries out effectively lubricating.
Present disclosure is described in further detail below by way of specific embodiment.It is former used in embodiment
Material unless otherwise specified, can be obtained from routine business approach.
In Examples 1 to 5, synthetic ester used is that four oleate of pentaerythrite, tricarboxymethyl propane oleate, stearic acid are different
Monooctyl ester, isooctyl oleate are with mass ratio 4:3:1:The mixture of 1 composition；Fatty alcohol is isooctanol, Decanol, laruyl alcohol with quality
Than 4:3:The mixture of 3 compositions；Polyalphaolefin is PAO4；Antioxidant is DBPC 2,6 ditertiary butyl p cresol；Antirust agent is three nitrogen of benzo
Azoles and 2-mercaptobenzothiazole are with mass ratio 1:The mixture of 1 composition；Metal deactivator is that thiadiazoles derivative derives with triazole
Object is with mass ratio 1:The mixture of 1 composition.
Embodiment 1：
The environmental protection cutting oil of embodiment 1 includes the raw material of following mass fraction：40 parts of synthetic ester, 22 parts of fatty alcohol, poly- α alkene
35 parts of hydrocarbon, 1 part of antioxidant, 1 part of antirust agent, 1 part of metal deactivator.
The preparation method of 1 environmental protection cutting oil of embodiment, steps are as follows：
1) raw material is weighed according to mass fraction, first synthetic ester, fatty alcohol and polyalphaolefin is put into compounding kettle and mixed, is stirred
It mixes, obtains base oil；
2) base oil for obtaining step 1), which heats up, stirs, and is warming up to 60 DEG C~100 DEG C, antioxidant, antirust agent, gold is added
Belong to passivator stirring, is then cooled to 50 DEG C hereinafter, stopping stirring；
3) oil product that step 2) obtains is filtered, obtains cutting oily finished product.
Embodiment 2：
The environmental protection cutting oil of embodiment 2 includes the raw material of following mass fraction：35 parts of synthetic ester, 32 parts of fatty alcohol, poly- α alkene
30 parts of hydrocarbon, 1 part of antioxidant, 1 part of antirust agent, 1 part of metal deactivator.
The preparation method of 2 environmental protection cutting oil of embodiment is identical as embodiment 1.
Embodiment 3：
The environmental protection cutting oil of embodiment 3 includes the raw material of following mass fraction：30 parts of synthetic ester, 35 parts of fatty alcohol, poly- α alkene
30 parts of hydrocarbon, 1 part of antioxidant, 1 part of antirust agent, 1 part of metal deactivator.
The preparation method of 3 environmental protection cutting oil of embodiment is identical as embodiment 1.
Embodiment 4：
The environmental protection cutting oil of embodiment 4 includes the raw material of following mass fraction：37 parts of synthetic ester, 30 parts of fatty alcohol, poly- α alkene
30 parts of hydrocarbon, 1 part of antioxidant, 1 part of antirust agent, 1 part of metal deactivator.
The preparation method of 4 environmental protection cutting oil of embodiment is identical as embodiment 1.
Embodiment 5：
The environmental protection cutting oil of embodiment 5 includes the raw material of following mass fraction：35 parts of synthetic ester, 21 parts of fatty alcohol, poly- α alkene
40 parts of hydrocarbon, 1 part of antioxidant, 1 part of antirust agent, 2 parts of metal deactivator.
The preparation method of 5 environmental protection cutting oil of embodiment is identical as embodiment 1.
Using：
Fog lubrication processing test is carried out to metal using cutting oil.The machine tool of processing is FANUC robodrill
The method of clamping of α-D21MiA, material are vice clamping.Process the model BT30-SKA183-90HF of handle of a knife, the cutter of processing
For wolfram steel end mill(ing) cutter, a diameter of 6mm, sword number is 4.Cutting material used is vitallium, is processed using thick form is opened,
Milling mode includes vertical milling, climb cutting and upmilling, and the requirement of cutting is processing skeleton, each dimensional tolerance control 0.01mm with
It is interior.Specifically testing procedure is：First processing 29mm diameter circulars face, then processing 1mm is deep on this basis, 20mm diameter cavities,
Dress knife length is 25mm.Test A uses the environmental protection cutting oil of embodiment 1 to carry out external spraying.Test b uses outsourcing
Conventional cutting oil carry out external spraying, test C uses common emulsion to carry out liquid cooling.Table 1 be test parameter and
Test result.
1 test parameter of table and result
| Test A | Test b | Test C | |
| The type of cooling | Outside spraying | Outside spraying | Liquid cools down |
| Speed of mainshaft S | 3000r/min | 3000r/min | 2150r/min |
| Cutting speed V | 56.52m/min | 56.52m/min | 56.52m/min |
| Amount of feeding F | 195mm/min | 195mm/min | 120mm/min |
| Milling width | 3mm | 3mm | 3mm |
| Back engagement of the cutting edge | 0.05mm | 0.05mm | 0.05mm |
| Surface smoothness | Ra0.131μm | Ra0.211μm | Ra0.241μm |
It can be seen that from the test data of table 1 and carry out external spraying, the table of product using the environmental protection cutting oil of embodiment 1
Face finish will be substantially better than the product processed using conventional cutting oil and conventional emulsification liquid.
Using embodiment 1 environmental protection cutting oil fog lubrication processing by way of process respectively AL6063, SUS316L and
Ceramic (high intensity zirconium oxide combined aluminum oxide), cutter life test data is as shown in table 2.
2 embodiment 1 of table handles a variety of materials cutter life data
| Material | AL6063 | SUS316L | Ceramics |
| Cutting depth (mm) | 12 | 15 | 5 |
| Cutter diameter (mm) | 6 | 10 | 6 |
| Refine cutting output (mm) | 0.1 | 0.1 | 0.015 |
| Rotating speed (r/min) | 10000 | 7000 | 12000 |
| Finishing feed amount (mm/min) | 3000 | 5000 | 500 |
| Cutter life (rice) | 835 | 980 | 180 |
AL6063, SUS316L and ceramics (high intensity oxygen are processed respectively by way of liquid cooling using common emulsion
Change zirconium combined aluminum oxide), cutter life test data is as shown in table 3.
3 common liquid of table handles a variety of materials cutter life data
From the above test result it is found that cutting oiliness prepared by the present invention can have compared with traditional aqua type emulsion
There is good lubricity, is greatly improved processing efficiency, and tool life.
Compared with prior art, cutting oil of the invention has the following advantages that：(1) excellent lubricating properties；(2) anti-oxidant
It has good stability；(3) biodegradable, it is nontoxic to human body and environment.
Claims (10)
1. a kind of environmental protection cutting oil, it is characterised in that：It is made of the raw material of following mass parts：
2. a kind of environmental protection cutting oil according to claim 1, it is characterised in that：Synthetic ester be four oleate of pentaerythrite,
At least one of tricarboxymethyl propane oleate, neopentyl glycol oleate, Ethylhexyl stearate, isooctyl oleate.
3. a kind of environmental protection cutting oil according to claim 1, it is characterised in that：Fatty alcohol is the fat of carbon atom number 6~24
Fat alcohol.
4. a kind of environmental protection cutting oil according to claim 1, it is characterised in that：Polyalphaolefin is PAO4.
5. a kind of environmental protection cutting oil according to claim 1, it is characterised in that：Antioxidant is phenolic antioxidant, alkylbenzene
At least one of amine antioxidants.
6. a kind of environmental protection cutting oil according to claim 1, it is characterised in that：Antirust agent is benzotriazole, 2- sulfydryls
At least one of benzothiazole.
7. a kind of environmental protection cutting oil according to claim 1, it is characterised in that：Metal deactivator be thiadiazoles derivative,
At least one of triazole derivative.
8. a kind of preparation method of environmental protection cutting oil, it is characterised in that：Include the following steps：
1) raw material is weighed by claim 1~7 any one of them composition, by synthetic ester, fatty alcohol and polyalphaolefin, mixing is stirred
It mixes, obtains base oil；
2) by base oil heating stirring, antioxidant, antirust agent and metal deactivator is added, is mixed, obtains crude oil product；
3) crude oil product are filtered, obtains environmental protection cutting oil.
9. a kind of preparation method of environmental protection cutting oil according to claim 8, it is characterised in that：Step 2) is specially：It will
Base oil is heated to 60 DEG C~100 DEG C stirrings, and antioxidant, antirust agent and metal deactivator is added, is mixed evenly, then drops
Temperature is to 50 DEG C hereinafter, stopping stirring, obtains crude oil product.
10. a kind of cutting working method of metal, it is characterised in that：It is cut using claim 1~7 any one of them environmental protection
Oil carries out fog lubrication processing.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810490976.XA CN108559592A (en) | 2018-05-21 | 2018-05-21 | A kind of environmental protection cutting oil and its preparation method and application |
| CN201910136672.8A CN109852457B (en) | 2018-05-21 | 2019-02-25 | Environment-friendly cutting oil and preparation method and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810490976.XA CN108559592A (en) | 2018-05-21 | 2018-05-21 | A kind of environmental protection cutting oil and its preparation method and application |
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| CN108559592A true CN108559592A (en) | 2018-09-21 |
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| CN201810490976.XA Withdrawn CN108559592A (en) | 2018-05-21 | 2018-05-21 | A kind of environmental protection cutting oil and its preparation method and application |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111088103A (en) * | 2019-12-24 | 2020-05-01 | 南京科润工业介质股份有限公司 | Environment-friendly cutter grinding oil |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN110628493B (en) * | 2019-10-01 | 2021-09-21 | 中科孚迪科技发展有限公司 | High-oxidation-resistance trace lubricating cutting oil and preparation method and application thereof |
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| ES2172412B1 (en) * | 2000-07-21 | 2003-10-01 | Nueva Fl Iberica S A | PROCEDURE FOR THE PREPARATION OF LUBRICATING CUTTING FLUIDS. |
| CN1197942C (en) * | 2002-03-29 | 2005-04-20 | 中国石油化工股份有限公司 | EP antiwear recombiner concentrate and its using method |
| US20090298729A1 (en) * | 2006-04-24 | 2009-12-03 | The Lubrizol Corporation | Star Polymer Lubricating Composition |
| CN101654636A (en) * | 2009-09-14 | 2010-02-24 | 上海金兆节能科技有限公司 | Biological type micro lubricating oil and preparation method and application thereof |
| CN102031190A (en) * | 2010-12-28 | 2011-04-27 | 东莞太平洋博高润滑油有限公司 | Cutting oil and preparation method thereof |
| CN102250673B (en) * | 2011-06-15 | 2013-04-10 | 启东尤希路化学工业有限公司 | Environment-friendly emulsion cutting oil with high lubricity and high permeability for metal working |
| CN104911004A (en) * | 2015-06-19 | 2015-09-16 | 司徒建辉 | High-performance extreme-pressure abrasion-resistant emulsion cutting oil |
| CN106544077B (en) * | 2016-11-04 | 2017-12-12 | 青岛冠军石油化学有限公司 | A kind of ester composition and its application in lubricating oil |
| CN107629831A (en) * | 2017-09-22 | 2018-01-26 | 东莞安默琳机械制造技术有限公司 | A kind of cutting oil for low-temperature trace lubrication |
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2018
- 2018-05-21 CN CN201810490976.XA patent/CN108559592A/en not_active Withdrawn
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111088103A (en) * | 2019-12-24 | 2020-05-01 | 南京科润工业介质股份有限公司 | Environment-friendly cutter grinding oil |
| CN111088103B (en) * | 2019-12-24 | 2021-12-03 | 南京科润工业介质股份有限公司 | Environment-friendly cutter grinding oil |
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| CN109852457B (en) | 2022-05-17 |
| CN109852457A (en) | 2019-06-07 |
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