CN106244295A - A kind of extreme boundary lubrication metalworking fluid - Google Patents
A kind of extreme boundary lubrication metalworking fluid Download PDFInfo
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- CN106244295A CN106244295A CN201610550375.4A CN201610550375A CN106244295A CN 106244295 A CN106244295 A CN 106244295A CN 201610550375 A CN201610550375 A CN 201610550375A CN 106244295 A CN106244295 A CN 106244295A
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
- C10M169/048—Mixtures of base-materials and additives the additives being a mixture of compounds of unknown or incompletely defined constitution, non-macromolecular and macromolecular compounds
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M159/00—Lubricating compositions characterised by the additive being of unknown or incompletely defined constitution
- C10M159/12—Reaction products
- C10M159/123—Reaction products obtained by phosphorus or phosphorus-containing compounds, e.g. P x S x with organic compounds
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/087—Boron oxides, acids or salts
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/121—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms
- C10M2207/123—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms polycarboxylic
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
- C10M2207/126—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids monocarboxylic
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/14—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings
- C10M2207/141—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings monocarboxylic
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/108—Polyethers, i.e. containing di- or higher polyoxyalkylene groups etherified
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/223—Five-membered rings containing nitrogen and carbon only
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
- C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/12—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions obtained by phosphorisation of organic compounds, e.g. with PxSy, PxSyHal or PxOy
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2225/00—Organic macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2225/04—Organic macromolecular compounds containing phosphorus as ingredients in lubricant compositions obtained by phosphorisation of macromolecualr compounds not containing phosphorus in the monomers
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling
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Abstract
The invention discloses a kind of extreme boundary lubrication metalworking fluid, its raw material includes by weight: cycloalkyl silicone oil 20 50 parts, 5 15 parts of modified anion type surfactant, Borax 26 parts, diethanolamine 36 parts, boric acid 15 parts, enanthic acid 26 parts, oleic acid 36 parts, polyoxyethylene stearyl base phosphate ester 14 parts, polyoxyethylene phenyl phosphate ester 25 parts, br dilute anhydride 13 parts, ten DAADBSA amine 26 parts, sodium alkyl sulfonate 35 parts, fatty alcohol-polyoxyethylene ether 14 parts, sodium benzoate 26 parts, defoamer 35 parts, methyl benzotriazole 15 parts, rust-inhibiting additive 26 parts, anticorrosion and bactericidal agent 14 parts, 39 parts of water.The metalworking fluid extreme boundary lubrication excellent performance of the present invention, has lubrication, cooling, anticorrosion and the rustless property of excellence.
Description
Technical field
The present invention relates to a kind of cutting fluid, particularly relate to a kind of extreme boundary lubrication metalworking fluid.
Background technology
Metalworking fluid is a kind of important auxiliary material required for process of metal working, and it primarily serves antirust, profit
Effect sliding, that clean and cool down.Cutting fluid is broadly divided into oil base cutting fluid and water base two big kinds the most both at home and abroad, and
There is the oil type trend to water-base cutting fluid transition, the cutting oil that oil base cutting fluid is the most usually said, its greasy property is good, but
Cooling effect is poor, at a high speed and can produce smog under the conditions of heavy cut, and meeting serious environment pollution, and product uses process
In easily catch fire, cause use dangerous.Just because of disadvantage mentioned above, therefore, oil base cutting fluid can not meet advanced metal and added
The use requirement of work technology.And water-base cutting fluid has series of advantages, such as good cooling results, fire line is good, the dirt to environment
Dye problem is easily solved.Therefore, quickly, water-base cutting fluid includes emulsion, synthetic cutting fluid and microemulsion to development in recent years
Cutting fluid (the most semi-synthetic cutting fluid).The liquid form of synthetic cutting fluid approximates with semi-synthetic cutting fluid, and dilution property is transparent
Shape, is easy in the course of processing observe processing situation, and service life is longer 4～6 times than emulsion；Machine tool slide parts can be played good
Good lubricating and antirust effect.
The synthesis of cutting fluid of the prior art is mainly some lubricants, surfactant, antirust agent, coupling agent, has
Machine silicon type defoamer etc. form, and lubricant mainly applies machine oil, Polyethylene Glycol, fatty acid soaps etc., and antirust agent mainly should
With triethanolamine oleate, borate, nitrite, chromate etc..Surfactant is mainly applied NP series, TX series, is gathered
Ether series etc..
Wear-resistant, the lubrication of cutting fluid of the prior art and rustless property cannot meet the demand in actual production process,
Therefore a kind of extreme boundary lubrication metalworking fluid of exploitation is needed badly to solve the problems of the prior art.
Summary of the invention
For solving technical problem present in background technology, the present invention proposes a kind of extreme boundary lubrication metalworking fluid, pole
Pressure lubricating excellent performance, has lubrication, cooling, anticorrosion and the rustless property of excellence.
A kind of extreme boundary lubrication metalworking fluid that the present invention proposes, its raw material includes by weight: cycloalkyl silicone oil 20-
50 parts, modified anion type surfactant 5-15 part, Borax 2-6 part, diethanolamine 3-6 part, boric acid 1-5 part, enanthic acid 2-6
Part, oleic acid 3-6 part, polyoxyethylene stearyl base phosphate ester 1-4 part, polyoxyethylene phenyl phosphate ester 2-5 part, br dilute anhydride
1-3 part, ten DAADBSA amine 2-6 parts, sodium alkyl sulfonate 3-5 part, fatty alcohol-polyoxyethylene ether 1-4 part, sodium benzoate 2-6 part,
Defoamer 3-5 part, methyl benzotriazole 1-5 part, rust-inhibiting additive 2-6 part, anticorrosion and bactericidal agent 1-4 part, water 3-9 part.
Preferably, modified anion type surfactant is prepared by following technique: Oleum Brassicae campestris and vulcanizing agent are mixed
Uniformly, it is warming up to 140-160 DEG C, is incubated 2-4h, is then cooled to 50-60 DEG C, add catalyst and ester exchange agent, then heat up
To 65-75 DEG C, it is incubated 1-3h, adds phosphorus pentoxide after being cooled to room temperature, be warming up to 65-75 DEG C, be incubated 2-4h, be cooled to room
Temperature obtains modified anion type surfactant.
Preferably, in the preparation technology of modified anion type surfactant, Oleum Brassicae campestris, vulcanizing agent, catalyst, ester exchange
Agent and phosphorus pentoxide are by weight 5-15:2-4:3-5:1-3:3-5.
Preferably, in the preparation technology of modified anion type surfactant, ester exchange agent is by methanol and polyhydroxy chemical combination
Thing 1:0.2-0.6 in molar ratio mixes.
Preferably, in the preparation technology of modified anion type surfactant, Oleum Brassicae campestris and the weight ratio of phosphorus pentoxide
For 8-12:3.5-4.5.
Preferably, its raw material includes by weight: cycloalkyl silicone oil 25-45 part, modified anion type surfactant 8-
12 parts, Borax 3-5 part, diethanolamine 4-5 part, boric acid 2-4 part, enanthic acid 3-5 part, oleic acid 4-5 part, polyoxyethylene stearyl base phosphorus
Acid esters 2-3 part, polyoxyethylene phenyl phosphate ester 3-4 part, br dilute anhydride 1.5-2.5 part, ten DAADBSA amine 3-5 parts, alkane
Base sodium sulfonate 3.5-4.5 part, fatty alcohol-polyoxyethylene ether 2-3 part, sodium benzoate 3-5 part, defoamer 3.5-4.5 part, methylbenzene
Triazole 2-4 part, rust-inhibiting additive 3-5 part, anticorrosion and bactericidal agent 2-3 part, water 4-8 part.
Preferably, its raw material includes by weight: cycloalkyl silicone oil 35 parts, 10 parts of modified anion type surfactant,
Borax 4 parts, diethanolamine 4.5 parts, boric acid 3 parts, enanthic acid 4 parts, oleic acid 4.5 parts, polyoxyethylene stearyl base phosphate ester 2.5 parts,
Polyoxyethylene phenyl phosphate ester 3.5 parts, br dilute anhydride 2 parts, ten DAADBSA amine 4 parts, sodium alkyl sulfonate 4 parts, fatty alcohol
Polyoxyethylene ether 2.5 parts, sodium benzoate 4 parts, defoamer 4 parts, methyl benzotriazole 3 parts, rust-inhibiting additive 4 parts, anticorrosion and bactericidal agent
2.5 parts, 6 parts of water.
A kind of extreme boundary lubrication metalworking fluid of the present invention, its raw material includes cycloalkyl silicone oil, modified anion type table
Face activating agent, Borax, diethanolamine, boric acid, enanthic acid, oleic acid, polyoxyethylene stearyl base phosphate ester, polyoxyethylene phosphenylic acid
Ester, br dilute anhydride, ten DAADBSA amine, sodium alkyl sulfonate, fatty alcohol-polyoxyethylene ether, sodium benzoate, defoamer, methyl
Benzotriazole, rust-inhibiting additive, anticorrosion and bactericidal agent and water.Wherein with cycloalkyl silicone oil for oil phase base material, auxiliary add modified cloudy from
Subtype surfactant, Borax, diethanolamine, boric acid, enanthic acid, oleic acid, polyoxyethylene stearyl base phosphate ester, polyoxyethylene benzene
Base phosphate ester, br dilute anhydride, ten DAADBSA amine, sodium alkyl sulfonate, fatty alcohol-polyoxyethylene ether, sodium benzoate, froth breaking
Agent, methyl benzotriazole, rust-inhibiting additive, anticorrosion and bactericidal agent and water, as auxiliary agent, give the pole that metalworking fluid of the present invention is excellent
Pressure lubricating performance.Wherein modified anion type surfactant is with Oleum Brassicae campestris, vulcanizing agent, catalyst, ester exchange agent and five oxidations
Two phosphorus are raw material, and Oleum Brassicae campestris generates the sulfuration Oleum Brassicae campestris with extreme pressure element S under vulcanizing agent effect, hand at catalyst and ester
Change under the effect of agent, obtained the mulit-hydroxy fatty acid ester containing S, P and N, be both to live in the modified anion type surface of the present invention
Property agent, it not only has a high extreme boundary lubrication, and itself is also a kind of emulsifying agent, and high rust resistance, anti-friction performance is good.
Wherein with the metalworking fluid extreme boundary lubrication excellent performance of the present invention, there is lubrication, cooling, anticorrosion and the rustless property of excellence.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described in detail, it should be appreciated that embodiment is served only for this is described
Bright rather than be used for limiting the invention, any made on the basis of the present invention amendment, equivalent etc. is all at this
In bright protection domain.
In detailed description of the invention, the weight portion of cycloalkyl silicone oil can be 20 parts, 25 parts, 30 parts, 35 parts, 40 parts, 45 parts,
50 parts；The weight portion of modified anion type surfactant can be 5 parts, 6 parts, 7 parts, 8 parts, 9 parts, 10 parts, 11 parts, 12 parts,
13 parts, 14 parts, 15 parts；The weight portion of Borax can be 2 parts, 3 parts, 4 parts, 5 parts, 6 parts；The weight portion of diethanolamine can be 3
Part, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts；The weight portion of boric acid can be 1 part, 2 parts, 3 parts, 4 parts, 5 parts；Enanthic acid
Weight portion can be 2 parts, 3 parts, 4 parts, 5 parts, 6 parts；The weight portion of oleic acid can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5
Part, 6 parts；The weight portion of polyoxyethylene stearyl base phosphate ester can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts；
The weight portion of polyoxyethylene phenyl phosphate ester can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；Butadiene dilute acid
The weight portion of acid anhydride can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts；The weight portion of ten DAADBSA amine can be 2 parts, 3 parts, 4
Part, 5 parts, 6 parts；The weight portion of sodium alkyl sulfonate can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；Fatty alcohol-polyoxyethylene ether
Weight portion can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts；The weight portion of sodium benzoate can be 2 parts, 3 parts, 4
Part, 5 parts, 6 parts；The weight portion of defoamer can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；The weight portion of methyl benzotriazole is permissible
It it is 1 part, 2 parts, 3 parts, 4 parts, 5 parts；The weight portion of rust-inhibiting additive can be 2 parts, 3 parts, 4 parts, 5 parts, 6 parts；Anticorrosion and bactericidal agent
Weight portion can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts；The weight portion of water can be 3 parts, 4 parts, 5 parts, 6
Part, 7 parts, 8 parts, 9 parts.
Embodiment 1
A kind of extreme boundary lubrication metalworking fluid that the present invention proposes, its raw material includes by weight: cycloalkyl silicone oil 35
Part, 10 parts of modified anion type surfactant, Borax 4 parts, diethanolamine 4.5 parts, boric acid 3 parts, enanthic acid 4 parts, oleic acid 4.5
Part, polyoxyethylene stearyl base phosphate ester 2.5 parts, polyoxyethylene phenyl phosphate ester 3.5 parts, br dilute anhydride 2 parts, ten hexichol
Sulfanilic acid 4 parts, sodium alkyl sulfonate 4 parts, fatty alcohol-polyoxyethylene ether 2.5 parts, sodium benzoate 4 parts, defoamer 4 parts, methylbenzene three
Azoles 3 parts, rust-inhibiting additive 4 parts, anticorrosion and bactericidal agent 2.5 parts, 6 parts of water.
Modified anion type surfactant is prepared by following technique: by weight by 10 portions of Oleum Brassicae campestriss and 3 parts of sulfur
Agent mix homogeneously, is warming up to 150 DEG C, is incubated 3h, is then cooled to 55 DEG C, adds 4 parts of catalyst and 2 parts of ester exchange agent, so
After be warming up to 70 DEG C, be incubated 2h, be cooled to after room temperature add 4 parts of phosphorus pentoxides, be warming up to 70 DEG C, be incubated 3h, be cooled to room
Temperature obtains modified anion type surfactant.
In the preparation technology of modified anion type surfactant, ester exchange agent by methanol and polyol by mole
Mix than 1:0.4.
Embodiment 2
A kind of extreme boundary lubrication metalworking fluid that the present invention proposes, its raw material includes by weight: cycloalkyl silicone oil 20
Part, 15 parts of modified anion type surfactant, Borax 2 parts, diethanolamine 6 parts, boric acid 1 part, enanthic acid 6 parts, oleic acid 3 parts, poly-
Oxygen ethylene octadecyl phosphate ester 4 parts, polyoxyethylene phenyl phosphate ester 2 parts, br dilute anhydride 3 parts, ten DAADBSA amine 2
Part, sodium alkyl sulfonate 5 parts, fatty alcohol-polyoxyethylene ether 1 part, sodium benzoate 6 parts, defoamer 3 parts, methyl benzotriazole 5 parts, antirust
Additive 2 parts, anticorrosion and bactericidal agent 4 parts, 3 parts of water.
Modified anion type surfactant is prepared by following technique: by weight by 5 portions of Oleum Brassicae campestriss and 4 parts of sulfurations
Agent mix homogeneously, is warming up to 140 DEG C, is incubated 4h, is then cooled to 50 DEG C, adds 5 parts of catalyst and 1 part of ester exchange agent, then
It is warming up to 75 DEG C, is incubated 1h, add 5 parts of phosphorus pentoxides after being cooled to room temperature, be warming up to 65 DEG C, be incubated 4h, be cooled to room temperature
Obtain modified anion type surfactant.
In the preparation technology of modified anion type surfactant, ester exchange agent by methanol and polyol by mole
Mix than 1:0.2.
Embodiment 3
A kind of extreme boundary lubrication metalworking fluid that the present invention proposes, its raw material includes by weight: cycloalkyl silicone oil 50
Part, 5 parts of modified anion type surfactant, Borax 6 parts, diethanolamine 3 parts, boric acid 5 parts, enanthic acid 2 parts, oleic acid 6 parts, polyoxy
Ethylene octadecyl phosphate ester 1 part, polyoxyethylene phenyl phosphate ester 5 parts, br dilute anhydride 1 part, ten DAADBSA amine 6 parts,
Sodium alkyl sulfonate 3 parts, fatty alcohol-polyoxyethylene ether 4 parts, sodium benzoate 2 parts, defoamer 5 parts, methyl benzotriazole 1 part, antirust add
Add agent 6 parts, anticorrosion and bactericidal agent 1 part, 9 parts of water.
Modified anion type surfactant is prepared by following technique: by weight by 15 portions of Oleum Brassicae campestriss and 2 parts of sulfur
Agent mix homogeneously, is warming up to 160 DEG C, is incubated 2h, is then cooled to 60 DEG C, adds 3 parts of catalyst and 3 parts of ester exchange agent, so
After be warming up to 65 DEG C, be incubated 3h, be cooled to after room temperature add 3 parts of phosphorus pentoxides, be warming up to 75 DEG C, be incubated 2h, be cooled to room
Temperature obtains modified anion type surfactant.
In the preparation technology of modified anion type surfactant, ester exchange agent by methanol and polyol by mole
Mix than 1:0.6.
Embodiment 4
A kind of extreme boundary lubrication metalworking fluid that the present invention proposes, its raw material includes by weight: cycloalkyl silicone oil 25
Part, 12 parts of modified anion type surfactant, Borax 3 parts, diethanolamine 5 parts, boric acid 2 parts, enanthic acid 5 parts, oleic acid 4 parts, poly-
Oxygen ethylene octadecyl phosphate ester 3 parts, polyoxyethylene phenyl phosphate ester 3 parts, br dilute anhydride 2.5 parts, ten DAADBSA amine 3
Part, sodium alkyl sulfonate 4.5 parts, fatty alcohol-polyoxyethylene ether 2 parts, sodium benzoate 5 parts, defoamer 3.5 parts, methyl benzotriazole 4 parts,
Rust-inhibiting additive 3 parts, anticorrosion and bactericidal agent 3 parts, 4 parts of water.
Modified anion type surfactant is prepared by following technique: by weight by 8 portions of Oleum Brassicae campestriss and 3.5 parts of sulfur
Agent mix homogeneously, is warming up to 145 DEG C, is incubated 3.5h, is then cooled to 52 DEG C, adds 4.5 parts of catalyst and 1.5 parts of ester exchanges
Agent, then heats to 72 DEG C, is incubated 1.5h, adds 4.5 parts of phosphorus pentoxides, be warming up to 68 DEG C after being cooled to room temperature, insulation
3.5h, is cooled to room temperature and obtains modified anion type surfactant.
In the preparation technology of modified anion type surfactant, ester exchange agent by methanol and polyol by mole
Mix than 1:0.3.
Embodiment 5
A kind of extreme boundary lubrication metalworking fluid that the present invention proposes, its raw material includes by weight: cycloalkyl silicone oil 45
Part, 8 parts of modified anion type surfactant, Borax 5 parts, diethanolamine 4 parts, boric acid 4 parts, enanthic acid 3 parts, oleic acid 5 parts, polyoxy
Ethylene octadecyl phosphate ester 2 parts, polyoxyethylene phenyl phosphate ester 4 parts, br dilute anhydride 1.5 parts, ten DAADBSA amine 5
Part, sodium alkyl sulfonate 3.5 parts, fatty alcohol-polyoxyethylene ether 3 parts, sodium benzoate 3 parts, defoamer 4.5 parts, methyl benzotriazole 2 parts,
Rust-inhibiting additive 5 parts, anticorrosion and bactericidal agent 2 parts, 8 parts of water.
Modified anion type surfactant is prepared by following technique: by weight by 12 portions of Oleum Brassicae campestriss and 2.5 parts
Vulcanizing agent mix homogeneously, is warming up to 155 DEG C, is incubated 2.5h, is then cooled to 58 DEG C, adds 3.5 parts of catalyst and 2.5 parts of esters are handed over
Change agent, then heat to 68 DEG C, be incubated 2.5h, add 3.5 parts of phosphorus pentoxides after being cooled to room temperature, be warming up to 72 DEG C, insulation
2.5h, is cooled to room temperature and obtains modified anion type surfactant.
In the preparation technology of modified anion type surfactant, ester exchange agent by methanol and polyol by mole
Mix than 1:0.5.
The above, the only present invention preferably detailed description of the invention, but protection scope of the present invention is not limited thereto,
Any those familiar with the art in the technical scope that the invention discloses, according to technical scheme and
Inventive concept equivalent or change in addition, all should contain within protection scope of the present invention.
Claims (7)
1. an extreme boundary lubrication metalworking fluid, it is characterised in that its raw material includes by weight: cycloalkyl silicone oil 20-50
Part, modified anion type surfactant 5-15 part, Borax 2-6 part, diethanolamine 3-6 part, boric acid 1-5 part, enanthic acid 2-6 part,
Oleic acid 3-6 part, polyoxyethylene stearyl base phosphate ester 1-4 part, polyoxyethylene phenyl phosphate ester 2-5 part, br dilute anhydride 1-3
Part, ten DAADBSA amine 2-6 parts, sodium alkyl sulfonate 3-5 part, fatty alcohol-polyoxyethylene ether 1-4 part, sodium benzoate 2-6 part, froth breaking
Agent 3-5 part, methyl benzotriazole 1-5 part, rust-inhibiting additive 2-6 part, anticorrosion and bactericidal agent 1-4 part, water 3-9 part.
Extreme boundary lubrication metalworking fluid the most according to claim 1, it is characterised in that modified anion type surface activity
Agent is prepared by following technique: by Oleum Brassicae campestris and vulcanizing agent mix homogeneously, be warming up to 140-160 DEG C, is incubated 2-4h, then drops
Temperature, to 50-60 DEG C, adds catalyst and ester exchange agent, then heats to 65-75 DEG C, is incubated 1-3h, adds after being cooled to room temperature
Phosphorus pentoxide, is warming up to 65-75 DEG C, is incubated 2-4h, is cooled to room temperature and obtains modified anion type surfactant.
Extreme boundary lubrication metalworking fluid the most according to claim 1 and 2, it is characterised in that modified anion type surface
In the preparation technology of activating agent, Oleum Brassicae campestris, vulcanizing agent, catalyst, ester exchange agent and phosphorus pentoxide are by weight 5-15:2-4:
3-5:1-3:3-5.
4. according to the extreme boundary lubrication metalworking fluid described in any one of claim 1-3, it is characterised in that modified anion type
In the preparation technology of surfactant, ester exchange agent is mixed by methanol and polyol 1:0.2-0.6 in molar ratio.
5. according to the extreme boundary lubrication metalworking fluid described in any one of claim 1-4, it is characterised in that modified anion type
In the preparation technology of surfactant, the weight ratio of Oleum Brassicae campestris and phosphorus pentoxide is 8-12:3.5-4.5.
6. according to the extreme boundary lubrication metalworking fluid described in any one of claim 1-5, it is characterised in that its raw material is by weight
Part includes: cycloalkyl silicone oil 25-45 part, modified anion type surfactant 8-12 part, Borax 3-5 part, diethanolamine 4-5
Part, boric acid 2-4 part, enanthic acid 3-5 part, oleic acid 4-5 part, polyoxyethylene stearyl base phosphate ester 2-3 part, polyoxyethylene phosphenylic acid
Ester 3-4 part, br dilute anhydride 1.5-2.5 part, ten DAADBSA amine 3-5 parts, sodium alkyl sulfonate 3.5-4.5 part, poly alkyl alcohol
Oxygen vinyl Ether 2-3 part, sodium benzoate 3-5 part, defoamer 3.5-4.5 part, methyl benzotriazole 2-4 part, rust-inhibiting additive 3-5 part,
Anticorrosion and bactericidal agent 2-3 part, water 4-8 part.
7. according to the extreme boundary lubrication metalworking fluid described in any one of claim 1-6, it is characterised in that its raw material is by weight
Part includes: cycloalkyl silicone oil 35 parts, 10 parts of modified anion type surfactant, Borax 4 parts, diethanolamine 4.5 parts, boric acid 3
Part, enanthic acid 4 parts, oleic acid 4.5 parts, polyoxyethylene stearyl base phosphate ester 2.5 parts, polyoxyethylene phenyl phosphate ester 3.5 parts, suitable fourth
Dilute dicarboxylic anhydride 2 parts, ten DAADBSA amine 4 parts, sodium alkyl sulfonate 4 parts, fatty alcohol-polyoxyethylene ether 2.5 parts, sodium benzoate 4 parts,
Defoamer 4 parts, methyl benzotriazole 3 parts, rust-inhibiting additive 4 parts, anticorrosion and bactericidal agent 2.5 parts, 6 parts of water.
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| CN106967473A (en) * | 2017-04-06 | 2017-07-21 | 天长市润达金属防锈助剂有限公司 | A kind of modified metal cutting fluid with excellent rustless property |
| CN107057808A (en) * | 2017-04-06 | 2017-08-18 | 天长市润达金属防锈助剂有限公司 | A kind of metalworking fluid with excellent lubricity |
| CN107142134A (en) * | 2017-04-06 | 2017-09-08 | 天长市润达金属防锈助剂有限公司 | A kind of metalworking fluid with excellent extreme pressure property |
| CN107164030A (en) * | 2017-04-06 | 2017-09-15 | 天长市润达金属防锈助剂有限公司 | A kind of modified metal cutting fluid with excellent antiseptic property |
| CN107760433A (en) * | 2017-12-05 | 2018-03-06 | 苏州市宽道模具机械有限公司 | A kind of water-base metal cutting fluid and preparation method thereof |
| CN108342525A (en) * | 2018-03-13 | 2018-07-31 | 齐河力厚化工有限公司 | A kind of modified silicon oil leather fat |
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| CN108342525A (en) * | 2018-03-13 | 2018-07-31 | 齐河力厚化工有限公司 | A kind of modified silicon oil leather fat |
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