CN106190480A - A kind of anti-rust metal cutting fluid of high lubricating property - Google Patents

A kind of anti-rust metal cutting fluid of high lubricating property Download PDF

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Publication number
CN106190480A
CN106190480A CN201610550611.2A CN201610550611A CN106190480A CN 106190480 A CN106190480 A CN 106190480A CN 201610550611 A CN201610550611 A CN 201610550611A CN 106190480 A CN106190480 A CN 106190480A
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China
Prior art keywords
parts
oil
base
cutting fluid
lubricating property
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Withdrawn
Application number
CN201610550611.2A
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Chinese (zh)
Inventor
林伟
江海涛
江海波
江浩
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Tianchang Runda Metal Antirust Auxiliary Co Ltd
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Tianchang Runda Metal Antirust Auxiliary Co Ltd
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Priority to CN201610550611.2A priority Critical patent/CN106190480A/en
Publication of CN106190480A publication Critical patent/CN106190480A/en
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04—Mixtures of base-materials and additives
    • C10M169/044—Mixtures of base-materials and additives the additives being a mixture of non-macromolecular and macromolecular compounds
    • C—CHEMISTRY; METALLURGY
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    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/04—Elements
    • C10M2201/041—Carbon; Graphite; Carbon black
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    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/08—Inorganic acids or salts thereof
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    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/087—Boron oxides, acids or salts
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    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/106—Naphthenic fractions
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    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
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    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/16—Paraffin waxes; Petrolatum, e.g. slack wax
    • C10M2205/163—Paraffin waxes; Petrolatum, e.g. slack wax used as base material
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    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • C10M2207/126—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids monocarboxylic
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    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/14—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/141—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings monocarboxylic
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    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40—Fatty vegetable or animal oils
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    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
    • C10M2209/084—Acrylate; Methacrylate
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    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
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    • C10M2211/00—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2211/08—Halogenated waxes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
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    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/223—Five-membered rings containing nitrogen and carbon only
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    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/02—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
    • C10M2219/024—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of esters, e.g. fats
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    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
    • C—CHEMISTRY; METALLURGY
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    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
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    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/049—Phosphite
    • C—CHEMISTRY; METALLURGY
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    • C10M2225/00—Organic macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2225/04—Organic macromolecular compounds containing phosphorus as ingredients in lubricant compositions obtained by phosphorisation of macromolecualr compounds not containing phosphorus in the monomers
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    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/02—Groups 1 or 11
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    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
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    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
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    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

The invention discloses the anti-rust metal cutting fluid of a kind of high lubricating property, its raw material includes by weight: paraffine base crude oil 20 40 parts, polyalphaolefin artificial oil 28 parts, vegetable oil 15 parts, naphthene base crude oil 39 parts, chlorinated paraffin 5 15 parts, sulfide fat oil 39 parts, sulfur chlorination Oleum Gossypii semen 25 parts, modified water-base lubricant 14 parts, dibutyl phosphite 39 parts, triethyl phosphate 13 parts, thermally coupled distillation columns 25 parts, Nonyl pheno phosphate ester 14 parts, alkyl oxygen vinyl Ether 25 parts, Polyethylene Glycol 39 parts, BTA 14 parts, boric acid 25 parts, oleic acid 15 parts, triethanolamine 26 parts, sodium benzoate 39 parts, sodium molybdate 48 parts.The metalworking fluid of the present invention has the high lubricating property of excellence, and anti-rust and corrosionproperties is excellent.

Description

A kind of anti-rust metal cutting fluid of high lubricating property
Technical field
The present invention relates to a kind of cutting fluid, particularly relate to the anti-rust metal cutting fluid of a kind of high lubricating property.
Background technology
Metalworking fluid is a kind of important auxiliary material required for process of metal working, and it primarily serves antirust, profit Effect sliding, that clean and cool down.Cutting fluid is broadly divided into oil base cutting fluid and water base two big kinds the most both at home and abroad, and There is the oil type trend to water-base cutting fluid transition, the cutting oil that oil base cutting fluid is the most usually said, its greasy property is good, but Cooling effect is poor, at a high speed and can produce smog under the conditions of heavy cut, and meeting serious environment pollution, and product uses process In easily catch fire, cause use dangerous.Just because of disadvantage mentioned above, therefore, oil base cutting fluid can not meet advanced metal and added The use requirement of work technology.And water-base cutting fluid has series of advantages, such as good cooling results, fire line is good, the dirt to environment Dye problem is easily solved.Therefore, quickly, water-base cutting fluid includes emulsion, synthetic cutting fluid and microemulsion to development in recent years Cutting fluid (the most semi-synthetic cutting fluid).The liquid form of synthetic cutting fluid approximates with semi-synthetic cutting fluid, and dilution property is transparent Shape, is easy in the course of processing observe processing situation, and service life is longer 4～6 times than emulsion；Machine tool slide parts can be played good Good lubricating and antirust effect.
The synthesis of cutting fluid of the prior art is mainly some lubricants, surfactant, antirust agent, coupling agent, has Machine silicon type defoamer etc. form, and lubricant mainly applies machine oil, Polyethylene Glycol, fatty acid soaps etc., and antirust agent mainly should With triethanolamine oleate, borate, nitrite, chromate etc..Surfactant is mainly applied NP series, TX series, is gathered Ether series etc..
The lubrication of cutting fluid of the prior art and rustless property cannot meet the demand in actual production process, the most urgently The anti-rust metal cutting fluid of a kind of high lubricating property need to be developed to solve the problems of the prior art.
Summary of the invention
For solving technical problem present in background technology, the present invention proposes the anti-rust metal cutting of a kind of high lubricating property Liquid.
The anti-rust metal cutting fluid of a kind of high lubricating property that the present invention proposes, its raw material includes by weight: paraffinic base Oil 20-40 part, poly alpha olefine synthetic oil 2-8 part, vegetable oil 1-5 part, naphthene base crude oil 3-9 part, chlorinated paraffin 5-15 part, sulfurized fat Fat oil 3-9 part, sulfur chlorination Oleum Gossypii semen 2-5 part, modified water-base lubricant 1-4 part, dibutyl phosphite 3-9 part, triethyl phosphate 1-3 part, thermally coupled distillation columns 2-5 part, Nonyl pheno phosphate ester 1-4 part, alkyl oxygen vinyl Ether 2-5 Part, Polyethylene Glycol 3-9 part, BTA 1-4 part, boric acid 2-5 part, oleic acid 1-5 part, triethanolamine 2-6 part, sodium benzoate 3- 9 parts, sodium molybdate 4-8 part.
Preferably, modified water-base lubricant is prepared by following technique: by graphite powder, dodecyl sodium sulfate and OP- 10 mixing, are subsequently adding distilled water, ultrasonic disperse 10-14h, are subsequently adding Butyl Acrylate Monomer, mechanical agitation 20-40min, It is subsequently added into initiator K2S2O8, it is warming up to 70-90 DEG C, magnetic agitation 5-7h, it is cooled to room temperature and obtains modified water-base lubricant.
Preferably, in the preparation technology of modified water-base lubricant, graphite powder, dodecyl sodium sulfate, OP-10, distilled water, Butyl Acrylate Monomer and initiator K2S2O8Weight ratio be 2-5:1-4:3-6:1-7:2-5:1-3.
Preferably, paraffine base crude oil, poly alpha olefine synthetic oil, vegetable oil, naphthene base crude oil, chlorinated paraffin, sulfide fat oil and The weight ratio of sulfur chlorination Oleum Gossypii semen is 25-35:3-7:2-4:4-8:8-12:4-8:3-4.
Preferably, modified water-base lubricant, dibutyl phosphite, triethyl phosphate, thermally coupled distillation columns, The weight ratio of Nonyl pheno phosphate ester, alkyl oxygen vinyl Ether, Polyethylene Glycol, BTA, boric acid and oleic acid is 2- 3:4-8:1.5-2.5:3-4:2-3:3-4:4-8:2-3:3-4:2-4.
Preferably, its raw material includes by weight: paraffine base crude oil 25-35 part, poly alpha olefine synthetic oil 3-7 part, vegetable oil 2-4 part, naphthene base crude oil 4-8 part, chlorinated paraffin 8-12 part, sulfide fat oil 4-8 part, sulfur chlorination Oleum Gossypii semen 3-4 part, modified water-base Lubricant 2-3 part, dibutyl phosphite 4-8 part, triethyl phosphate 1.5-2.5 part, thermally coupled distillation columns 3-4 Part, Nonyl pheno phosphate ester 2-3 part, alkyl oxygen vinyl Ether 3-4 part, Polyethylene Glycol 4-8 part, BTA 2-3 part, Boric acid 3-4 part, oleic acid 2-4 part, triethanolamine 3-5 part, sodium benzoate 4-8 part, sodium molybdate 5-7 part.
Preferably, its raw material includes by weight: paraffine base crude oil 30 parts, poly alpha olefine synthetic oil 5 parts, vegetable oil 3 parts, ring Alkyl oil 6 parts, chlorinated paraffin 10 parts, sulfide fat oil 6 parts, sulfur chlorination Oleum Gossypii semen 3.5 parts, modified water-base lubricant 2.5 parts, Asia Dibutylphosphoric acid ester 6 parts, triethyl phosphate 2 parts, thermally coupled distillation columns 3.5 parts, Nonyl pheno phosphate ester 2.5 parts, alkyl oxygen vinyl Ether 3.5 parts, Polyethylene Glycol 6 parts, BTA 2.5 parts, boric acid 3.5 parts, oleic acid 3 parts, three ethanol Amine 4 parts, sodium benzoate 6 parts, sodium molybdate 6 parts.
The anti-rust metal cutting fluid of a kind of high lubricating property of the present invention, its raw material includes that paraffine base crude oil, poly alpha olefin close Become oil, vegetable oil, naphthene base crude oil, chlorinated paraffin, sulfide fat oil, sulfur chlorination Oleum Gossypii semen, modified water-base lubricant, phosphorous acid two Butyl ester, triethyl phosphate, thermally coupled distillation columns, Nonyl pheno phosphate ester, alkyl oxygen vinyl Ether, poly-second Glycol, BTA, boric acid, oleic acid, triethanolamine, sodium benzoate and sodium molybdate.Wherein paraffine base crude oil, poly alpha olefin synthesis Oil, vegetable oil, naphthene base crude oil, chlorinated paraffin, sulfide fat oil and sulfur chlorination Oleum Gossypii semen are oil phase base material, and by adding modification Water base lubricant, as the lubrication reinforcing agent of oil phase base material, gives the greasy property that metalworking fluid of the present invention is excellent, Qi Zhonggai Property water base lubricant is with graphite powder, dodecyl sodium sulfate, OP-10, distilled water, Butyl Acrylate Monomer and initiator K2S2O8 For raw material, membrane wrapping modified by graphite powder so that create active force between graphite powder and Butyl Acrylate Monomer, effectively Improve the anti-friction anti-attrition greasy property of graphite powder, and then be effectively increased the anti-friction anti-attrition lubricity of metalworking fluid of the present invention Energy.The metalworking fluid of the present invention has the high lubricating property of excellence, and anti-rust and corrosionproperties is excellent.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described in detail, it should be appreciated that embodiment is served only for this is described Bright rather than be used for limiting the invention, any made on the basis of the present invention amendment, equivalent etc. is all at this In bright protection domain.
In detailed description of the invention, the weight portion of paraffine base crude oil can be 20 parts, 25 parts, 30 parts, 35 parts, 40 parts；Poly-α-alkene The weight portion of hydrocarbon artificial oil can be 2 parts, 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts；The weight portion of vegetable oil can be 1 part, 2 Part, 3 parts, 4 parts, 5 parts；The weight portion of naphthene base crude oil can be 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts, 9 parts；The weight of chlorinated paraffin Amount part can be 5 parts, 6 parts, 7 parts, 8 parts, 9 parts, 10 parts, 11 parts, 12 parts, 13 parts, 14 parts, 15 parts；The weight of sulfide fat oil Part can be 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts, 9 parts；The weight portion of sulfur chlorination Oleum Gossypii semen can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；The weight portion of modified water-base lubricant can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 Part, 4 parts；The weight portion of dibutyl phosphite can be 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts, 9 parts；The weight of triethyl phosphate Part can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts；The weight portion of thermally coupled distillation columns can be 2 parts, 2.5 Part, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；The weight portion of Nonyl pheno phosphate ester can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts；The weight portion of alkyl oxygen vinyl Ether can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 Part；The weight portion of Polyethylene Glycol can be 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts, 9 parts；The weight portion of BTA can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts；The weight portion of boric acid can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；The weight portion of oleic acid can be 1 part, 2 parts, 3 parts, 4 parts, 5 parts；The weight portion of triethanolamine can be 2 parts, 3 Part, 4 parts, 5 parts, 6 parts；The weight portion of sodium benzoate can be 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts, 9 parts；The weight of sodium molybdate Part can be 4 parts, 5 parts, 6 parts, 7 parts, 8 parts.
Embodiment 1
The anti-rust metal cutting fluid of a kind of high lubricating property that the present invention proposes, its raw material includes by weight: paraffinic base Oil 30 parts, poly alpha olefine synthetic oil 5 parts, vegetable oil 3 parts, naphthene base crude oil 6 parts, chlorinated paraffin 10 parts, sulfide fat oil 6 parts, sulfur Chlorination Oleum Gossypii semen 3.5 parts, modified water-base lubricant 2.5 parts, dibutyl phosphite 6 parts, triethyl phosphate 2 parts, polyoxyethylene nonyl phenyl Vinyl Ether phosphate ester 3.5 parts, Nonyl pheno phosphate ester 2.5 parts, alkyl oxygen vinyl Ether 3.5 parts, Polyethylene Glycol 6 parts, benzene And triazole 2.5 parts, boric acid 3.5 parts, oleic acid 3 parts, triethanolamine 4 parts, sodium benzoate 6 parts, sodium molybdate 6 parts.
Modified water-base lubricant is prepared by following technique: by weight by 3.5 parts of graphite powders, 2.5 parts of dodecyls Sodium sulfonate and 4.5 parts of OP-10 mixing, be subsequently adding 4 parts of distilled water, ultrasonic disperse 12h, be subsequently adding 3.5 parts of butyl acrylate Monomer, mechanical agitation 30min, it is subsequently added into 2 parts of initiator K2S2O8, it is warming up to 80 DEG C, magnetic agitation 6h, it is cooled to room temperature and obtains To modified water-base lubricant.
Embodiment 2
The anti-rust metal cutting fluid of a kind of high lubricating property that the present invention proposes, its raw material includes by weight: paraffinic base Oil 20 parts, poly alpha olefine synthetic oil 8 parts, vegetable oil 1 part, naphthene base crude oil 9 parts, chlorinated paraffin 5 parts, sulfide fat oil 9 parts, sulfur chlorine Change Oleum Gossypii semen 2 parts, modified water-base lubricant 4 parts, dibutyl phosphite 3 parts, triethyl phosphate 3 parts, NPE Phosphate ester 2 parts, Nonyl pheno phosphate ester 4 parts, alkyl oxygen vinyl Ether 2 parts, Polyethylene Glycol 9 parts, BTA 1 part, Boric acid 5 parts, oleic acid 1 part, triethanolamine 6 parts, sodium benzoate 3 parts, sodium molybdate 8 parts.
Modified water-base lubricant is prepared by following technique: by weight by 2 parts of graphite powders, 4 parts of dodecyl sodium sulfonates Sodium and 3 parts of OP-10 mixing, be subsequently adding 7 parts of distilled water, ultrasonic disperse 10h, be subsequently adding 5 parts of Butyl Acrylate Monomers, machinery Stirring 20min, is subsequently added into 3 parts of initiator K2S2O8, it is warming up to 70 DEG C, magnetic agitation 7h, it is cooled to room temperature and obtains modified water-base Lubricant.
Embodiment 3
The anti-rust metal cutting fluid of a kind of high lubricating property that the present invention proposes, its raw material includes by weight: paraffinic base Oil 40 parts, poly alpha olefine synthetic oil 2 parts, vegetable oil 5 parts, naphthene base crude oil 3 parts, chlorinated paraffin 15 parts, sulfide fat oil 3 parts, sulfur Chlorination Oleum Gossypii semen 5 parts, modified water-base lubricant 1 part, dibutyl phosphite 9 parts, triethyl phosphate 1 part, Nonyl pheno Ether phosphate 5 parts, Nonyl pheno phosphate ester 1 part, alkyl oxygen vinyl Ether 5 parts, Polyethylene Glycol 3 parts, BTA 4 Part, boric acid 2 parts, oleic acid 5 parts, triethanolamine 2 parts, sodium benzoate 9 parts, sodium molybdate 4 parts.
Modified water-base lubricant is prepared by following technique: by weight by 5 parts of graphite powders, 1 part of dodecyl sodium sulfonate Sodium and 6 parts of OP-10 mixing, be subsequently adding 1 part of distilled water, ultrasonic disperse 14h, be subsequently adding 2 parts of Butyl Acrylate Monomers, machinery Stirring 40min, is subsequently added into 1 part of initiator K2S2O8, it is warming up to 90 DEG C, magnetic agitation 5h, it is cooled to room temperature and obtains modified water-base Lubricant.
Embodiment 4
The anti-rust metal cutting fluid of a kind of high lubricating property that the present invention proposes, its raw material includes by weight: paraffinic base Oil 25 parts, poly alpha olefine synthetic oil 7 parts, vegetable oil 2 parts, naphthene base crude oil 8 parts, chlorinated paraffin 8 parts, sulfide fat oil 8 parts, sulfur chlorine Change Oleum Gossypii semen 3 parts, modified water-base lubricant 3 parts, dibutyl phosphite 4 parts, triethyl phosphate 2.5 parts, Nonyl pheno Ether phosphate 3 parts, Nonyl pheno phosphate ester 3 parts, alkyl oxygen vinyl Ether 3 parts, Polyethylene Glycol 8 parts, BTA 2 Part, boric acid 4 parts, oleic acid 2 parts, triethanolamine 5 parts, sodium benzoate 4 parts, sodium molybdate 7 parts.
Modified water-base lubricant is prepared by following technique: by weight by 3 parts of graphite powders, 3 parts of dodecyl sodium sulfonates Sodium and 4 parts of OP-10 mixing, be subsequently adding 6 parts of distilled water, ultrasonic disperse 11h, be subsequently adding 4 parts of Butyl Acrylate Monomers, machinery Stirring 25min, is subsequently added into 2.5 parts of initiator K2S2O8, it is warming up to 75 DEG C, magnetic agitation 6.5h, it is cooled to room temperature and obtains modification Water base lubricant.
Embodiment 5
The anti-rust metal cutting fluid of a kind of high lubricating property that the present invention proposes, its raw material includes by weight: paraffinic base Oil 35 parts, poly alpha olefine synthetic oil 3 parts, vegetable oil 4 parts, naphthene base crude oil 4 parts, chlorinated paraffin 12 parts, sulfide fat oil 4 parts, sulfur Chlorination Oleum Gossypii semen 4 parts, modified water-base lubricant 2 parts, dibutyl phosphite 8 parts, triethyl phosphate 1.5 parts, polyoxyethylene nonyl phenyl second Alkene ether phosphate 4 parts, Nonyl pheno phosphate ester 2 parts, alkyl oxygen vinyl Ether 4 parts, Polyethylene Glycol 4 parts, BTA 3 Part, boric acid 3 parts, oleic acid 4 parts, triethanolamine 3 parts, sodium benzoate 8 parts, sodium molybdate 5 parts.
Modified water-base lubricant is prepared by following technique: by weight by 4 parts of graphite powders, 2 parts of dodecyl sodium sulfonates Sodium and 5 parts of OP-10 mixing, be subsequently adding 2 parts of distilled water, ultrasonic disperse 13h, be subsequently adding 3 parts of Butyl Acrylate Monomers, machinery Stirring 35min, is subsequently added into 1.5 parts of initiator K2S2O8, it is warming up to 85 DEG C, magnetic agitation 5.5h, it is cooled to room temperature and obtains modification Water base lubricant.
The above, the only present invention preferably detailed description of the invention, but protection scope of the present invention is not limited thereto, Any those familiar with the art in the technical scope that the invention discloses, according to technical scheme and Inventive concept equivalent or change in addition, all should contain within protection scope of the present invention.

Claims (7)

1. the anti-rust metal cutting fluid of a high lubricating property, it is characterised in that its raw material includes by weight: paraffine base crude oil 20-40 part, poly alpha olefine synthetic oil 2-8 part, vegetable oil 1-5 part, naphthene base crude oil 3-9 part, chlorinated paraffin 5-15 part, sulfurized fatty Oil 3-9 part, sulfur chlorination Oleum Gossypii semen 2-5 part, modified water-base lubricant 1-4 part, dibutyl phosphite 3-9 part, triethyl phosphate 1-3 Part, thermally coupled distillation columns 2-5 part, Nonyl pheno phosphate ester 1-4 part, alkyl oxygen vinyl Ether 2-5 part, poly- Ethylene glycol 3-9 part, BTA 1-4 part, boric acid 2-5 part, oleic acid 1-5 part, triethanolamine 2-6 part, sodium benzoate 3-9 part, Sodium molybdate 4-8 part.
The anti-rust metal cutting fluid of high lubricating property the most according to claim 1, it is characterised in that modified water-base lubricant It is prepared by following technique: graphite powder, dodecyl sodium sulfate are mixed with OP-10, is subsequently adding distilled water, ultrasonic disperse 10-14h, is subsequently adding Butyl Acrylate Monomer, mechanical agitation 20-40min, is subsequently added into initiator K2S2O8, it is warming up to 70- 90 DEG C, magnetic agitation 5-7h, it is cooled to room temperature and obtains modified water-base lubricant.
The anti-rust metal cutting fluid of high lubricating property the most according to claim 1 and 2, it is characterised in that modified water-base moistens In the preparation technology of lubrication prescription, graphite powder, dodecyl sodium sulfate, OP-10, distilled water, Butyl Acrylate Monomer and initiator K2S2O8Weight ratio be 2-5:1-4:3-6:1-7:2-5:1-3.
4. according to the anti-rust metal cutting fluid of the high lubricating property described in any one of claim 1-3, it is characterised in that paraffinic base The weight ratio of oil, poly alpha olefine synthetic oil, vegetable oil, naphthene base crude oil, chlorinated paraffin, sulfide fat oil and sulfur chlorination Oleum Gossypii semen is 25-35:3-7:2-4:4-8:8-12:4-8:3-4.
5. according to the anti-rust metal cutting fluid of the high lubricating property described in any one of claim 1-4, it is characterised in that modified water Base lubricating agent, dibutyl phosphite, triethyl phosphate, thermally coupled distillation columns, Nonyl pheno phosphate ester, The weight ratio of alkyl oxygen vinyl Ether, Polyethylene Glycol, BTA, boric acid and oleic acid is 2-3:4-8:1.5-2.5:3-4:2-3: 3-4:4-8:2-3:3-4:2-4.
6. according to the anti-rust metal cutting fluid of the high lubricating property described in any one of claim 1-5, it is characterised in that its raw material Include by weight: paraffine base crude oil 25-35 part, poly alpha olefine synthetic oil 3-7 part, vegetable oil 2-4 part, naphthene base crude oil 4-8 part, chlorine Fossil waxes 8-12 part, sulfide fat oil 4-8 part, sulfur chlorination Oleum Gossypii semen 3-4 part, modified water-base lubricant 2-3 part, phosphorous acid two fourth Ester 4-8 part, triethyl phosphate 1.5-2.5 part, thermally coupled distillation columns 3-4 part, Nonyl pheno phosphate ester 2-3 part, alkyl oxygen vinyl Ether 3-4 part, Polyethylene Glycol 4-8 part, BTA 2-3 part, boric acid 3-4 part, oleic acid 2-4 part, three Ethanolamine 3-5 part, sodium benzoate 4-8 part, sodium molybdate 5-7 part.
7. according to the anti-rust metal cutting fluid of the high lubricating property described in any one of claim 1-6, it is characterised in that its raw material Include by weight: paraffine base crude oil 30 parts, poly alpha olefine synthetic oil 5 parts, vegetable oil 3 parts, naphthene base crude oil 6 parts, chlorinated paraffin 10 Part, sulfide fat oil 6 parts, sulfur chlorination Oleum Gossypii semen 3.5 parts, modified water-base lubricant 2.5 parts, dibutyl phosphite 6 parts, tricresyl phosphate Ethyl ester 2 parts, thermally coupled distillation columns 3.5 parts, Nonyl pheno phosphate ester 2.5 parts, alkyl oxygen vinyl Ether 3.5 Part, Polyethylene Glycol 6 parts, BTA 2.5 parts, boric acid 3.5 parts, oleic acid 3 parts, triethanolamine 4 parts, sodium benzoate 6 parts, molybdic acid 6 parts of sodium.
CN201610550611.2A 2016-07-13 2016-07-13 A kind of anti-rust metal cutting fluid of high lubricating property Withdrawn CN106190480A (en)

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Application publication date: 20161207