CN106244296A - A kind of metalworking fluid with excellent rustless property - Google Patents
A kind of metalworking fluid with excellent rustless property Download PDFInfo
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- CN106244296A CN106244296A CN201610550487.XA CN201610550487A CN106244296A CN 106244296 A CN106244296 A CN 106244296A CN 201610550487 A CN201610550487 A CN 201610550487A CN 106244296 A CN106244296 A CN 106244296A
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- antirust agent
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M167/00—Lubricating compositions characterised by the additive being a mixture of a macromolecular compound, a non-macromolecular compound and a compound of unknown or incompletely defined constitution, each of these compounds being essential
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M159/00—Lubricating compositions characterised by the additive being of unknown or incompletely defined constitution
- C10M159/12—Reaction products
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
- C10M2203/106—Naphthenic fractions
- C10M2203/1065—Naphthenic fractions used as base material
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/121—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms
- C10M2207/123—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms polycarboxylic
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- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
- C10M2207/126—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids monocarboxylic
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
- C10M2207/127—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids polycarboxylic
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- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/283—Esters of polyhydroxy compounds
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/286—Esters of polymerised unsaturated acids
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
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- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/108—Polyethers, i.e. containing di- or higher polyoxyalkylene groups etherified
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/08—Amides
- C10M2215/082—Amides containing hydroxyl groups; Alkoxylated derivatives
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/223—Five-membered rings containing nitrogen and carbon only
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
- C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/16—Antiseptic; (micro) biocidal or bactericidal
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- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling
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- Oil, Petroleum & Natural Gas (AREA)
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Abstract
The invention discloses a kind of metalworking fluid with excellent rustless property, its raw material includes by weight: cycloalkanes base oil 20 40 parts, fatty alcohol-polyoxyethylene ether 5 15 parts, modified antirust agent 5 10 parts, EDTA chelating agen 28 parts, corrosion-inhibiting composition 39 parts, triethanolamine 26 parts, petroleum sodium sulfonate 35 parts, methyl benzotriazole 14 parts, polymerization oleic acid synthetic ester lubricant 24 parts, polynary oleic acid synthetic ester lubricant 36 parts, short carbon chain dicarboxylic acids antirust agent 16 parts, Long carbon chain polybasic carboxylic acid antirust agent 25 parts, maleopimaric acid alkylolamides 34 parts, antibacterial 14 parts, defoamer 26 parts, 14 parts of water.The metalworking fluid of the present invention has the rustless property of excellence.
Description
Technical field
The present invention relates to a kind of cutting fluid, particularly relate to a kind of metalworking fluid with excellent rustless property.
Background technology
Metalworking fluid is a kind of important auxiliary material required for process of metal working, and it primarily serves antirust, profit
Effect sliding, that clean and cool down.Cutting fluid is broadly divided into oil base cutting fluid and water base two big kinds the most both at home and abroad, and
There is the oil type trend to water-base cutting fluid transition, the cutting oil that oil base cutting fluid is the most usually said, its greasy property is good, but
Cooling effect is poor, at a high speed and can produce smog under the conditions of heavy cut, and meeting serious environment pollution, and product uses process
In easily catch fire, cause use dangerous.Just because of disadvantage mentioned above, therefore, oil base cutting fluid can not meet advanced metal and added
The use requirement of work technology.And water-base cutting fluid has series of advantages, such as good cooling results, fire line is good, the dirt to environment
Dye problem is easily solved.Therefore, quickly, water-base cutting fluid includes emulsion, synthetic cutting fluid and microemulsion to development in recent years
Cutting fluid (the most semi-synthetic cutting fluid).The liquid form of synthetic cutting fluid approximates with semi-synthetic cutting fluid, and dilution property is transparent
Shape, is easy in the course of processing observe processing situation, and service life is longer 4～6 times than emulsion；Machine tool slide parts can be played good
Good lubricating and antirust effect.
The synthesis of cutting fluid of the prior art is mainly some lubricants, surfactant, antirust agent, coupling agent, has
Machine silicon type defoamer etc. form, and lubricant mainly applies machine oil, Polyethylene Glycol, fatty acid soaps etc., and antirust agent mainly should
With triethanolamine oleate, borate, nitrite, chromate etc..Surfactant is mainly applied NP series, TX series, is gathered
Ether series etc..
The rustless property of cutting fluid of the prior art cannot meet the demand in actual production process, therefore needs exploitation badly
A kind of have the metalworking fluid of excellent rustless property to solve the problems of the prior art.
Summary of the invention
For solving technical problem present in background technology, the present invention proposes a kind of metal with excellent rustless property and cuts
Cut liquid, there is the rustless property of excellence.
A kind of metalworking fluid with excellent rustless property that the present invention proposes, its raw material includes by weight: cycloalkanes
Base oil 20-40 part, fatty alcohol-polyoxyethylene ether 5-15 part, modified antirust agent 5-10 part, EDTA chelating agen 2-8 part, inhibition group
Compound 3-9 part, triethanolamine 2-6 part, petroleum sodium sulfonate 3-5 part, methyl benzotriazole 1-4 part, polymerization oleic acid synthetic ester lubricant
2-4 part, polynary oleic acid synthetic ester lubricant 3-6 part, short carbon chain dicarboxylic acids antirust agent 1-6 part, Long carbon chain polybasic carboxylic acid are antirust
Agent 2-5 part, maleopimaric acid alkylolamides 3-4 part, antibacterial 1-4 part, defoamer 2-6 part, water 1-4 part.
The preparation method of modified antirust agent, comprises the steps:
S1, by sugarcane fat, soda bath and water mix homogeneously, be heated to 80-90 DEG C, stir 3-5h, be subsequently adding cold water and stir
Mix 1-3h, be cooled to room temperature and obtain material a；
S2, in material a, add calcium chloride solution, stir 3-5h, be heated to 75-85 DEG C of cohesion, cross leaching filtrate, cool down
Material b is obtained to room temperature；
S3, in material b, add cold water, stir 1-3h, be warming up to 85-95 DEG C, remove lower floor waste water, be cooled to room temperature and obtain
To material c；
S4, in material c add gasoline, be heated to 70-80 DEG C, stirring and dissolving, stand 20-40min, the water that venting disengages
Layer, is subsequently adding the water of 40-50 DEG C, washing, stands, branch vibration layer, is cooled to room temperature and obtains material d；
S5, in material d add gasoline cutback, be heated to 75-80 DEG C, cross leaching filtrate obtain Materialien, then in 110-
120 DEG C are reclaimed gasoline, are passed through steam 10-30min, stand 5-15min, are dried, and are cooled to room temperature and obtain modified antirust agent.
Preferably, in the preparation method of modified antirust agent, in S2, the mass fraction of calcium chloride solution is 15-25%.
Preferably, in the preparation method of modified antirust agent, in S5, the temperature being dried is 110-120 DEG C, and the pressure being dried is
650-750mm mercury column, the dry time is 2-3h.
Preferably, corrosion-inhibiting composition is mixed by weight 1-4:3-6 by benzotriazole and mercapto benzothiazole.
Preferably, its raw material includes by weight: cycloalkanes base oil 25-35 part, fatty alcohol-polyoxyethylene ether 8-12 part, change
Property antirust agent 6-9 part, EDTA chelating agen 3-7 part, corrosion-inhibiting composition 4-8 part, triethanolamine 3-5 part, petroleum sodium sulfonate 3.5-4.5
Part, methyl benzotriazole 2-3 part, polymerization oleic acid synthetic ester lubricant 2.5-3.5 part, polynary oleic acid synthetic ester lubricant 4-5 part, short
Carbochain dicarboxylic acids antirust agent 2-5 part, Long carbon chain polybasic carboxylic acid antirust agent 3-4 part, maleopimaric acid alkylolamides 3.2-3.8 part,
Antibacterial 2-3 part, defoamer 3-5 part, water 2-3 part.
Preferably, its raw material includes by weight: cycloalkanes base oil 30 parts, fatty alcohol-polyoxyethylene ether 10 parts, modification are prevented
Rust agent 7.5 parts, EDTA chelating agen 5 parts, corrosion-inhibiting composition 6 parts, triethanolamine 4 parts, petroleum sodium sulfonate 4 parts, methyl benzotriazole 2.5
Part, polymerization oleic acid synthetic ester lubricant 3 parts, polynary oleic acid synthetic ester lubricant 4.5 parts, short carbon chain dicarboxylic acids antirust agent 3.5
Part, Long carbon chain polybasic carboxylic acid antirust agent 3.5 parts, maleopimaric acid alkylolamides 3.5 parts, antibacterial 2.5 parts, defoamer 4 parts, water
2.5 part.
A kind of metalworking fluid with excellent rustless property of the present invention, its raw material includes cycloalkanes base oil, fatty alcohol
Polyoxyethylene ether, modified antirust agent, EDTA chelating agen, corrosion-inhibiting composition, triethanolamine, petroleum sodium sulfonate, methyl benzotriazole, poly-
Conjunction oleic acid synthetic ester lubricant, polynary oleic acid synthetic ester lubricant, short carbon chain dicarboxylic acids antirust agent, Long carbon chain polybasic carboxylic acid are prevented
Rust agent, maleopimaric acid alkylolamides, antibacterial, defoamer and water.Wherein add using cycloalkanes base oil as oil phase base material, auxiliary
Fatty alcohol-polyoxyethylene ether, modified antirust agent, EDTA chelating agen, corrosion-inhibiting composition, triethanolamine, petroleum sodium sulfonate, methylbenzene
Triazole, polymerization oleic acid synthetic ester lubricant, polynary oleic acid synthetic ester lubricant, short carbon chain dicarboxylic acids antirust agent, Long carbon chain are many
Unit's carboxylic acid antirust agent, maleopimaric acid alkylolamides, antibacterial, defoamer and water, as auxiliary agent, give metalworking fluid of the present invention
Excellent rustless property, lubricity, anti-corrosive properties and antibiotic property are more preferably.Wherein modified antirust agent is with sugarcane fat as major ingredient, synthesis of carboxylic acid
Soap antirust agent, gives the rustless property that metalworking fluid of the present invention is excellent, and matches with other adjuvants, the metal cutting obtained
Liquid, lubricity, rust-preventing characteristic and anti-corrosive antibacterial performance effectively improve.The metalworking fluid of the present invention has the rust-preventing characteristic of excellence
Can,
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described in detail, it should be appreciated that embodiment is served only for this is described
Bright rather than be used for limiting the invention, any made on the basis of the present invention amendment, equivalent etc. is all at this
In bright protection domain.
In detailed description of the invention, the weight portion of cycloalkanes base oil can be 20 parts, 21 parts, 22 parts, 23 parts, 24 parts, 25 parts,
26 parts, 27 parts, 28 parts, 29 parts, 30 parts, 31 parts, 32 parts, 33 parts, 34 parts, 35 parts, 36 parts, 37 parts, 38 parts, 39 parts, 40 parts；Fat
The weight portion of fat polyoxyethylenated alcohol can be 5 parts, 6 parts, 7 parts, 8 parts, 9 parts, 10 parts, 11 parts, 12 parts, 13 parts, 14 parts, 15
Part；The weight portion of modified antirust agent can be 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8 parts, 8.5 parts, 9 parts, 9.5 parts,
10 parts；The weight portion of EDTA chelating agen can be 2 parts, 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts；The weight portion of corrosion-inhibiting composition can
Think 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts, 9 parts；The weight portion of triethanolamine can be 2 parts, 3 parts, 4 parts, 5 parts, 6 parts；Stone
The weight portion of oil sodium sulfonate can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；The weight portion of methyl benzotriazole can be 1 part, 1.5
Part, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts；The weight portion of polymerization oleic acid synthetic ester lubricant can be 2 parts, 2.5 parts, 3 parts,
3.5 parts, 4 parts；The weight portion of polynary oleic acid synthetic ester lubricant can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6
Part；The weight portion of short carbon chain dicarboxylic acids antirust agent can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts,
5 parts, 5.5 parts, 6 parts；The weight portion of Long carbon chain polybasic carboxylic acid antirust agent can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5
Part, 5 parts；The weight portion of maleopimaric acid alkylolamides can be 3 parts, 3.1 parts, 3.2 parts, 3.3 parts, 3.4 parts, 3.5 parts, 3.6 parts,
3.7 parts, 3.8 parts, 3.9 parts, 4 parts；The weight portion of antibacterial can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts；
The weight portion of defoamer can be 2 parts, 3 parts, 4 parts, 5 parts, 6 parts；The weight portion of water can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3
Part, 3.5 parts, 4 parts.
Embodiment 1
A kind of metalworking fluid with excellent rustless property that the present invention proposes, its raw material includes by weight: cycloalkanes
Base oil 30 parts, fatty alcohol-polyoxyethylene ether 10 parts, modified antirust agent 7.5 parts, EDTA chelating agen 5 parts, corrosion-inhibiting composition 6 parts,
Triethanolamine 4 parts, petroleum sodium sulfonate 4 parts, methyl benzotriazole 2.5 parts, polymerization oleic acid synthetic ester lubricant 3 parts, polynary oleic acid close
Become ester lubricant 4.5 parts, short carbon chain dicarboxylic acids antirust agent 3.5 parts, Long carbon chain polybasic carboxylic acid antirust agent 3.5 parts, Malaysia Korean pine
Acid alcohol amide 3.5 parts, antibacterial 2.5 parts, defoamer 4 parts, 2.5 parts of water.
Wherein, corrosion-inhibiting composition is mixed by weight 2.5:4.5 by benzotriazole and mercapto benzothiazole.
Wherein, the preparation method of modified antirust agent, comprise the steps:
S1, by sugarcane fat, soda bath and water mix homogeneously, be heated to 85 DEG C, stir 4h, be subsequently adding cold water stirring 2h,
It is cooled to room temperature and obtains material a；
S2, in material a add mass fraction be the calcium chloride solution of 20%, stir 4h, be heated to 80 DEG C of cohesions, filtration
Take filtrate, be cooled to room temperature and obtain material b；
S3, in material b, add cold water, stir 2h, be warming up to 90 DEG C, remove lower floor waste water, be cooled to room temperature and obtain thing
Material c；
S4, in material c add gasoline, be heated to 75 DEG C, stirring and dissolving, stand 30min, the water layer that venting disengages, so
The water of rear addition 45 DEG C, washing, stand, branch vibration layer, be cooled to room temperature and obtain material d；
S5, in material d add gasoline cutback, be heated to 77.5 DEG C, cross leaching filtrate obtain Materialien, then in 115 DEG C return
Receiving gasoline, be passed through steam 20min, stand 10min, be dried, the temperature being dried is 115 DEG C, and the pressure being dried is 700mm mercury column,
The time being dried is 2.5h, is cooled to room temperature and obtains modified antirust agent.
Embodiment 2
A kind of metalworking fluid with excellent rustless property that the present invention proposes, its raw material includes by weight: cycloalkanes
Base oil 20 parts, fatty alcohol-polyoxyethylene ether 15 parts, modified antirust agent 5 parts, EDTA chelating agen 8 parts, corrosion-inhibiting composition 3 parts, three
Ethanolamine 6 parts, petroleum sodium sulfonate 3 parts, methyl benzotriazole 4 parts, polymerization oleic acid synthetic ester lubricant 2 parts, polynary oleic acid synthetic ester
Lubricant 6 parts, short carbon chain dicarboxylic acids antirust agent 1 part, Long carbon chain polybasic carboxylic acid antirust agent 5 parts, maleopimaric acid alkylolamides 3
Part, antibacterial 4 parts, defoamer 2 parts, 4 parts of water.
Wherein, corrosion-inhibiting composition is mixed by weight 1:6 by benzotriazole and mercapto benzothiazole.
Wherein, the preparation method of modified antirust agent, comprise the steps:
S1, by sugarcane fat, soda bath and water mix homogeneously, be heated to 80 DEG C, stir 5h, be subsequently adding cold water stirring 1h,
It is cooled to room temperature and obtains material a；
S2, in material a add mass fraction be the calcium chloride solution of 25%, stir 3h, be heated to 85 DEG C of cohesions, filtration
Take filtrate, be cooled to room temperature and obtain material b；
S3, in material b, add cold water, stir 1h, be warming up to 95 DEG C, remove lower floor waste water, be cooled to room temperature and obtain thing
Material c；
S4, in material c add gasoline, be heated to 70 DEG C, stirring and dissolving, stand 40min, the water layer that venting disengages, so
The water of rear addition 40 DEG C, washing, stand, branch vibration layer, be cooled to room temperature and obtain material d；
S5, in material d add gasoline cutback, be heated to 80 DEG C, cross leaching filtrate obtain Materialien, then in 110 DEG C of recovery
Gasoline, is passed through steam 30min, stands 5min, is dried, and the temperature being dried is 120 DEG C, and the pressure being dried is 650mm mercury column, is dried
Time be 3h, be cooled to room temperature and obtain modified antirust agent.
Embodiment 3
A kind of metalworking fluid with excellent rustless property that the present invention proposes, its raw material includes by weight: cycloalkanes
Base oil 40 parts, fatty alcohol-polyoxyethylene ether 5 parts, modified antirust agent 10 parts, EDTA chelating agen 2 parts, corrosion-inhibiting composition 9 parts, three
Ethanolamine 2 parts, petroleum sodium sulfonate 5 parts, methyl benzotriazole 1 part, polymerization oleic acid synthetic ester lubricant 4 parts, polynary oleic acid synthetic ester
Lubricant 3 parts, short carbon chain dicarboxylic acids antirust agent 6 parts, Long carbon chain polybasic carboxylic acid antirust agent 2 parts, maleopimaric acid alkylolamides 4
Part, antibacterial 1 part, defoamer 6 parts, 1 part of water.
Wherein, corrosion-inhibiting composition is mixed by weight 4:3 by benzotriazole and mercapto benzothiazole.
Wherein, the preparation method of modified antirust agent, comprise the steps:
S1, by sugarcane fat, soda bath and water mix homogeneously, be heated to 90 DEG C, stir 3h, be subsequently adding cold water stirring 3h,
It is cooled to room temperature and obtains material a；
S2, in material a add mass fraction be the calcium chloride solution of 15%, stir 5h, be heated to 75 DEG C of cohesions, filtration
Take filtrate, be cooled to room temperature and obtain material b；
S3, in material b, add cold water, stir 3h, be warming up to 85 DEG C, remove lower floor waste water, be cooled to room temperature and obtain thing
Material c；
S4, in material c add gasoline, be heated to 80 DEG C, stirring and dissolving, stand 20min, the water layer that venting disengages, so
The water of rear addition 50 DEG C, washing, stand, branch vibration layer, be cooled to room temperature and obtain material d；
S5, in material d add gasoline cutback, be heated to 75 DEG C, cross leaching filtrate obtain Materialien, then in 120 DEG C of recovery
Gasoline, is passed through steam 10min, stands 15min, is dried, and the temperature being dried is 110 DEG C, and the pressure being dried is 750mm mercury column, dry
The dry time is 2h, is cooled to room temperature and obtains modified antirust agent.
Embodiment 4
A kind of metalworking fluid with excellent rustless property that the present invention proposes, its raw material includes by weight: cycloalkanes
Base oil 25 parts, fatty alcohol-polyoxyethylene ether 12 parts, modified antirust agent 6 parts, EDTA chelating agen 7 parts, corrosion-inhibiting composition 4 parts, three
Ethanolamine 5 parts, petroleum sodium sulfonate 3.5 parts, methyl benzotriazole 3 parts, polymerization oleic acid synthetic ester lubricant 2.5 parts, polynary oleic acid close
Become ester lubricant 5 parts, short carbon chain dicarboxylic acids antirust agent 2 parts, Long carbon chain polybasic carboxylic acid antirust agent 4 parts, maleopimaric acid alcohol acyl
Amine 3.2 parts, antibacterial 3 parts, defoamer 3 parts, 3 parts of water.
Wherein, corrosion-inhibiting composition is mixed by weight 2:5 by benzotriazole and mercapto benzothiazole.
Wherein, the preparation method of modified antirust agent, comprise the steps:
S1, by sugarcane fat, soda bath and water mix homogeneously, be heated to 82 DEG C, stir 4.5h, be subsequently adding cold water stirring
1.5h, is cooled to room temperature and obtains material a；
S2, in material a add mass fraction be the calcium chloride solution of 22%, stir 3.5h, be heated to 82 DEG C of cohesions, mistake
Leaching filtrate, is cooled to room temperature and obtains material b；
S3, in material b, add cold water, stir 1.5h, be warming up to 92 DEG C, remove lower floor waste water, be cooled to room temperature and obtain
Material c；
S4, in material c add gasoline, be heated to 72 DEG C, stirring and dissolving, stand 35min, the water layer that venting disengages, so
The water of rear addition 42 DEG C, washing, stand, branch vibration layer, be cooled to room temperature and obtain material d；
S5, in material d add gasoline cutback, be heated to 79 DEG C, cross leaching filtrate obtain Materialien, then in 112 DEG C of recovery
Gasoline, is passed through steam 25min, stands 8min, is dried, and the temperature being dried is 118 DEG C, and the pressure being dried is 655mm mercury column, is dried
Time be 2.8h, be cooled to room temperature and obtain modified antirust agent.
Embodiment 5
A kind of metalworking fluid with excellent rustless property that the present invention proposes, its raw material includes by weight: cycloalkanes
Base oil 35 parts, fatty alcohol-polyoxyethylene ether 8 parts, modified antirust agent 9 parts, EDTA chelating agen 3 parts, corrosion-inhibiting composition 8 parts, three second
Hydramine 3 parts, petroleum sodium sulfonate 4.5 parts, methyl benzotriazole 2 parts, polymerization oleic acid synthetic ester lubricant 3.5 parts, the synthesis of polynary oleic acid
Ester lubricant 4 parts, short carbon chain dicarboxylic acids antirust agent 5 parts, Long carbon chain polybasic carboxylic acid antirust agent 3 parts, maleopimaric acid alkylolamides
3.8 parts, antibacterial 2 parts, defoamer 5 parts, 2 parts of water.
Wherein, corrosion-inhibiting composition is mixed by weight 3:4 by benzotriazole and mercapto benzothiazole.
Wherein, the preparation method of modified antirust agent, comprise the steps:
S1, by sugarcane fat, soda bath and water mix homogeneously, be heated to 88 DEG C, stir 3.5h, be subsequently adding cold water stirring
2.5h, is cooled to room temperature and obtains material a；
S2, in material a add mass fraction be the calcium chloride solution of 18%, stir 4.5h, be heated to 78 DEG C of cohesions, mistake
Leaching filtrate, is cooled to room temperature and obtains material b；
S3, in material b, add cold water, stir 2.5h, be warming up to 88 DEG C, remove lower floor waste water, be cooled to room temperature and obtain
Material c；
S4, in material c add gasoline, be heated to 78 DEG C, stirring and dissolving, stand 25min, the water layer that venting disengages, so
The water of rear addition 48 DEG C, washing, stand, branch vibration layer, be cooled to room temperature and obtain material d；
S5, in material d add gasoline cutback, be heated to 76 DEG C, cross leaching filtrate obtain Materialien, then in 118 DEG C of recovery
Gasoline, is passed through steam 15min, stands 12min, is dried, and the temperature being dried is 112 DEG C, and the pressure being dried is 745mm mercury column, dry
The dry time is 2.2h, is cooled to room temperature and obtains modified antirust agent.
The above, the only present invention preferably detailed description of the invention, but protection scope of the present invention is not limited thereto,
Any those familiar with the art in the technical scope that the invention discloses, according to technical scheme and
Inventive concept equivalent or change in addition, all should contain within protection scope of the present invention.
Claims (7)
1. a metalworking fluid with excellent rustless property, it is characterised in that its raw material includes by weight: cycloalkanes basis
Oil 20-40 part, fatty alcohol-polyoxyethylene ether 5-15 part, modified antirust agent 5-10 part, EDTA chelating agen 2-8 part, corrosion-inhibiting composition
3-9 part, triethanolamine 2-6 part, petroleum sodium sulfonate 3-5 part, methyl benzotriazole 1-4 part, polymerization oleic acid synthetic ester lubricant 2-4
Part, polynary oleic acid synthetic ester lubricant 3-6 part, short carbon chain dicarboxylic acids antirust agent 1-6 part, Long carbon chain polybasic carboxylic acid antirust agent 2-
5 parts, maleopimaric acid alkylolamides 3-4 part, antibacterial 1-4 part, defoamer 2-6 part, water 1-4 part.
The metalworking fluid with excellent rustless property the most according to claim 1, it is characterised in that modified antirust agent
Preparation method, comprises the steps:
S1, by sugarcane fat, soda bath and water mix homogeneously, be heated to 80-90 DEG C, stir 3-5h, be subsequently adding cold water stirring 1-
3h, is cooled to room temperature and obtains material a；
S2, in material a, add calcium chloride solution, stir 3-5h, be heated to 75-85 DEG C of cohesion, mistake leaching filtrate, it is cooled to room
Temperature obtains material b；
S3, in material b, add cold water, stir 1-3h, be warming up to 85-95 DEG C, remove lower floor waste water, be cooled to room temperature and obtain thing
Material c；
S4, in material c add gasoline, be heated to 70-80 DEG C, stirring and dissolving, stand 20-40min, the water layer that venting disengages,
It is subsequently adding the water of 40-50 DEG C, washing, stand, branch vibration layer, be cooled to room temperature and obtain material d；
S5, in material d add gasoline cutback, be heated to 75-80 DEG C, cross leaching filtrate obtain Materialien, then in 110-120 DEG C
Reclaim gasoline, be passed through steam 10-30min, stand 5-15min, be dried, be cooled to room temperature and obtain modified antirust agent.
The metalworking fluid with excellent rustless property the most according to claim 1 and 2, it is characterised in that in S2, chlorination
The mass fraction of calcium solution is 15-25%.
4. according to the metalworking fluid with excellent rustless property described in any one of claim 1-3, it is characterised in that S5
In, the temperature being dried is 110-120 DEG C, and the pressure being dried is 650-750mm mercury column, and the dry time is 2-3h.
5. according to the metalworking fluid with excellent rustless property described in any one of claim 1-4, it is characterised in that inhibition
Compositions is mixed by weight 1-4:3-6 by benzotriazole and mercapto benzothiazole.
6. according to the metalworking fluid with excellent rustless property described in any one of claim 1-5, it is characterised in that it is former
Material includes by weight: cycloalkanes base oil 25-35 part, fatty alcohol-polyoxyethylene ether 8-12 part, modified antirust agent 6-9 part, EDTA
Chelating agen 3-7 part, corrosion-inhibiting composition 4-8 part, triethanolamine 3-5 part, petroleum sodium sulfonate 3.5-4.5 part, methyl benzotriazole 2-3
Part, polymerization oleic acid synthetic ester lubricant 2.5-3.5 part, polynary oleic acid synthetic ester lubricant 4-5 part, short carbon chain dicarboxylic acids antirust
Agent 2-5 part, Long carbon chain polybasic carboxylic acid antirust agent 3-4 part, maleopimaric acid alkylolamides 3.2-3.8 part, antibacterial 2-3 part, froth breaking
Agent 3-5 part, water 2-3 part.
7. according to the metalworking fluid with excellent rustless property described in any one of claim 1-5, it is characterised in that it is former
Material includes by weight: cycloalkanes base oil 30 parts, fatty alcohol-polyoxyethylene ether 10 parts, modified antirust agent 7.5 parts, EDTA chelating agen
5 parts, corrosion-inhibiting composition 6 parts, triethanolamine 4 parts, petroleum sodium sulfonate 4 parts, methyl benzotriazole 2.5 parts, polymerization oleic acid synthetic ester profit
Lubrication prescription 3 parts, polynary oleic acid synthetic ester lubricant 4.5 parts, short carbon chain dicarboxylic acids antirust agent 3.5 parts, Long carbon chain polybasic carboxylic acid are anti-
Rust agent 3.5 parts, maleopimaric acid alkylolamides 3.5 parts, antibacterial 2.5 parts, defoamer 4 parts, 2.5 parts of water.
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| CN106939423A (en) * | 2017-04-06 | 2017-07-11 | 天长市润达金属防锈助剂有限公司 | A kind of oil removing clean type is modified antirust agent |
| CN106967473A (en) * | 2017-04-06 | 2017-07-21 | 天长市润达金属防锈助剂有限公司 | A kind of modified metal cutting fluid with excellent rustless property |
| CN107057808A (en) * | 2017-04-06 | 2017-08-18 | 天长市润达金属防锈助剂有限公司 | A kind of metalworking fluid with excellent lubricity |
| CN107057806A (en) * | 2017-04-21 | 2017-08-18 | 天长市润达金属防锈助剂有限公司 | A kind of medicine equipment prepares and uses anti-rusting antibiotic metalworking fluid |
| CN107099367A (en) * | 2017-06-08 | 2017-08-29 | 广州市联诺化工科技有限公司 | A kind of floorboard with high oil content, environment-friendly water-based semi-synthetic cutting fluid of high anti-friction performance and preparation method thereof |
| CN108913319A (en) * | 2018-07-25 | 2018-11-30 | 歌尔股份有限公司 | semi-synthetic cutting fluid |
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| CN107099367A (en) * | 2017-06-08 | 2017-08-29 | 广州市联诺化工科技有限公司 | A kind of floorboard with high oil content, environment-friendly water-based semi-synthetic cutting fluid of high anti-friction performance and preparation method thereof |
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