CN106939423A - A kind of oil removing clean type is modified antirust agent - Google Patents
A kind of oil removing clean type is modified antirust agent Download PDFInfo
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- CN106939423A CN106939423A CN201710220501.4A CN201710220501A CN106939423A CN 106939423 A CN106939423 A CN 106939423A CN 201710220501 A CN201710220501 A CN 201710220501A CN 106939423 A CN106939423 A CN 106939423A
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/14—Cleaning or pickling metallic material with solutions or molten salts with alkaline solutions
Abstract
Antirust agent is modified the invention discloses a kind of oil removing clean type, its raw material includes sulfoacid calcium, modified degreaser, modified filler, modified antirust agent, the molten ammoniacal copper quaternary of amine, calgon, nano silicon, sodium sulfonate, dodecenylsuccinic acid, zinc naphthenate, petrolatum, BTA, sodium olefin sulfonate, sodium tripolyphosphate, sodium metasilicate, natrium nitrosum, diammonium hydrogen phosphate, triethanolamine, aliphatic acid, trimethylolpropane, dialkyldithiocarbamacompositions sodium, polyisobutene succinimide, methyl benzoate, polytetrafluoroethylene (PTFE), butylene, NPE, AEO, fatty acid methyl ester ethoxylate sulfoacid calcium, DBSA and ethoxylized fatty alcohol polyethenoxy ether sodium sulfate.The modification antirust agent good antirust property of the present invention, and with excellent oil removing clean-up performance.
Description
Technical field
Antirust agent is modified the present invention relates to the technical field of antirust agent, more particularly to a kind of oil removing clean type.
Background technology
Metal processing piece is during production and processing and transport, because oxygen and water act on metal surface generation oxide
With the mixture of hydroxide, therefore easily produce rusty stain, and machinery in operation and storage also easily with the oxygen in air, wet
Gas or the contact of other Korrosionsmediums, these materials can occur electrochemical corrosion in metal surface and get rusty, therefore metal is anti-
Rust is particularly important.Metal is when antirust agent is coated in the prior art, because the spot or oil stain of metal surface
Coating for antirust agent can affect, and directly reduce the efficiency and quality of the coating of antirust agent, it is impossible to meet
Demand in actual production process, therefore need a kind of oil removing clean type modification antirust agent of design badly to meet of the prior art ask
Topic.
The content of the invention
To solve technical problem present in background technology, the present invention proposes that a kind of oil removing clean type is modified antirust agent, prevented
Performance of becoming rusty is good, and with excellent oil removing clean-up performance.
A kind of oil removing clean type proposed by the present invention is modified antirust agent, and its raw material includes by weight：4-8 parts of sulfoacid calcium,
Modified 6-12 parts of degreaser, 4-8 parts of modified filler, modified 5-15 parts of antirust agent, molten ammoniacal copper quaternary 4-8 parts of amine, calgon 1-3
Part, 2-6 parts of nano silicon, 3-9 parts of sodium sulfonate, 4-8 parts of dodecenylsuccinic acid, 4-8 parts of zinc naphthenate, petrolatum 4-8
Part, 2-5 parts of BTA, 1-6 parts of sodium olefin sulfonate, 3-6 parts of sodium tripolyphosphate, 1-4 parts of sodium metasilicate, natrium nitrosum 2-5
Part, 3-6 parts of diammonium hydrogen phosphate, 1-4 parts of triethanolamine, 3-6 parts of aliphatic acid, 2-8 parts of trimethylolpropane, dialkyl dithio ammonia
4-9 parts of base sodium formate, 2-5 parts of polyisobutene succinimide, 1-6 parts of methyl benzoate, 3-9 parts of polytetrafluoroethylene (PTFE), butylene 1-5
Part, 2-5 parts of NPE, 3-9 parts of AEO, fatty acid methyl ester ethoxylate sulfoacid calcium 2-8
Part, 3-6 parts of DBSA, 4-8 parts of ethoxylized fatty alcohol polyethenoxy ether sodium sulfate.
Preferably, modified degreaser is prepared by following technique：Alkali lignin and water are well mixed, 2-3h is stirred,
Then regulation pH then heats to 80-90 DEG C to 10.0-11.0, is incubated 1-2h, is subsequently added into formaldehyde and is well mixed, reacts 10-
20min, then adds urea and is well mixed, continue to react 2-3h, be then cooled to 10-30 DEG C, continue to react 1-3h, then add
Mass fraction is well mixed for 40-60% sodium hydroxide solution, carbon disulfide and sodium chlorate, then heats to 40-60 DEG C, guarantor
Warm 1-3h, is reduced to room temperature and obtains being modified degreaser.
Preferably, in the preparation technology of modified degreaser, alkali lignin, water, formaldehyde, urea, mass fraction are 40-60%'s
Sodium hydroxide solution, carbon disulfide and sodium chlorate weight ratio are 4-6：1-3：3-6：2-5：4-8：1-4：2-5.
Preferably, modified filler is prepared by following technique：Ferroso-ferric oxide and Silane coupling reagent KH-570 are mixed
Uniformly, 20-40min is stirred in 1500-2500r/min rotating speeds, then heats to 80-90 DEG C, be incubated 1-3h, then add oleic acid
It is well mixed, 20-40min is stirred in 250-350r/min rotating speeds, is then placed in 50-70 DEG C of drying box and dries 20-40min,
Room temperature is cooled to after grinding and obtains modified filler.
Preferably, in the preparation technology of modified filler, the weight ratio of ferroso-ferric oxide, Silane coupling reagent KH-570 and oleic acid
For 1-3：2-5：3-6 is mixed.
Preferably, the raw material of modified antirust agent includes by weight：20-40 parts of emulsifying agent DNS-86, phosphate PAM-
100 3-6 parts, 4-8 parts of deionization, 3-9 parts of butyl acrylate, 2-5 parts of styrene, 1-6 parts of acrylic acid, 3-5 parts of epoxy resin,
2-6 parts of sodium acid carbonate, 1-4 parts of ammonium persulfate, 3-5 parts of BTA, 4-8 parts of hexa, 4-6 parts of ethylene glycol, three
2-5 parts of monoethanolamine.
Preferably, modified antirust agent is prepared by following technique：By emulsifying agent DNS-86, phosphate PAM-100 and go
Ar ion mixing is uniform, and 20-40min is stirred in 450-650r/min rotating speeds, then adds butyl acrylate, styrene, acrylic acid
Well mixed with epoxy resin, magnetic agitation 15-25min obtains material a, and sodium acid carbonate and over cure are then added into material a
Sour ammonium is well mixed, and is warming up to 60-70 DEG C, is incubated 1-3h, is then cooled to 40-50 DEG C, then adds BTA, six Asias
Tetramine, ethylene glycol and triethanolamine are well mixed, stir 20-40min in 1500-2500r/min rotating speeds, are warming up to 70-
80 DEG C, 1-3h is incubated, room temperature is cooled to and obtains being modified antirust agent.
A kind of oil removing clean type proposed by the present invention is modified antirust agent, and its raw material includes sulfoacid calcium, modified degreaser, modification
Filler, modified antirust agent, the molten ammoniacal copper quaternary of amine, calgon, nano silicon, sodium sulfonate, dodecenylsuccinic acid, cycloalkanes
Sour zinc, petrolatum, BTA, sodium olefin sulfonate, sodium tripolyphosphate, sodium metasilicate, natrium nitrosum, diammonium hydrogen phosphate, three
Monoethanolamine, aliphatic acid, trimethylolpropane, dialkyldithiocarbamacompositions sodium, polyisobutene succinimide, benzoic acid first
Ester, polytetrafluoroethylene (PTFE), butylene, NPE, AEO, fatty acid methyl ester ethoxylate sulfonic acid
Calcium, DBSA and ethoxylized fatty alcohol polyethenoxy ether sodium sulfate.Wherein, modified degreaser passes through alkali is wooden
Element and water are well mixed, and then stirring adjusts pH, then heat up, and is incubated, and are subsequently added into formaldehyde and are well mixed, reaction, Ran Houjia
Enter urea to be well mixed, then cool, continue to react, then add sodium hydroxide solution, carbon disulfide and sodium chlorate and be well mixed,
Then heat up, be incubated, be reduced to room temperature and obtain being modified degreaser, in the preparation for the modification antirust agent for applying to the present invention, effectively
Improve the oil removing performance of the modified antirust agent of the present invention.Wherein, modified filler is by by ferroso-ferric oxide and silane coupler KH-
570 are well mixed, and then stirring heats up, and is incubated, and then add oleic acid and are well mixed, and stirring is then placed in drying box and done
It is dry, room temperature is cooled to after grinding and obtains modified filler, using ferroso-ferric oxide as base-material, is changed by Silane coupling reagent KH-570
Property, obtained modified filler applies in the preparation of the modified antirust agent of the present invention, effectively increases the present invention and be modified antirust agent
Rustless property.Wherein, modified antirust agent is stirred by the way that emulsifying agent DNS-86, phosphate PAM-100 and deionization are well mixed
Mix, then add butyl acrylate, styrene, acrylic acid and epoxy resin and be well mixed, magnetic agitation obtains material a, then
Sodium acid carbonate is added into material a and ammonium persulfate is well mixed, is heated up, then insulation cools, and then adds the nitrogen of benzo three
Azoles, hexa, ethylene glycol and triethanolamine are well mixed, stir, and heat up, insulation, are cooled to room temperature and obtain modified anti-
Rust agent, in the preparation for the modification antirust agent for applying to the present invention, effectively increases the rustless property of the modified antirust agent of the present invention.This
The modification antirust agent of invention has excellent oil removing and clean-up performance, and adhesion property is strong, difficult for drop-off.
Embodiment
The present invention is described in detail with reference to specific embodiment, it should be appreciated that embodiment is served only for illustrating this hair
It is bright, rather than for limiting the invention, any modification made on the basis of the present invention, equivalent etc. are in this hair
In bright protection domain.
In embodiment, the parts by weight of sulfoacid calcium can for 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts,
7.5 parts, 8 parts；The parts by weight of modified degreaser can be 6 parts, 7 parts, 8 parts, 9 parts, 10 parts, 11 parts, 12 parts；The weight of modified filler
It can be 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8 parts to measure part；The parts by weight of modified antirust agent can be with
For 5 parts, 6 parts, 7 parts, 8 parts, 9 parts, 10 parts, 11 parts, 12 parts, 13 parts, 14 parts, 15 parts；The parts by weight of the molten ammoniacal copper quaternary of amine can be 4
Part, 4.5 parts, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8 parts；The parts by weight of calgon can for 1 part, 1.5 parts,
2 parts, 2.5 parts, 3 parts；The parts by weight of nano silicon can be 2 parts, 3 parts, 4 parts, 5 parts, 6 parts；The parts by weight of sodium sulfonate can
Think 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts, 9 parts；The parts by weight of dodecenylsuccinic acid can for 4 parts, 5 parts, 6 parts, 7 parts, 8
Part；The parts by weight of zinc naphthenate can be 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8 parts；Petrolatum
Parts by weight can be 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8 parts；The parts by weight of BTA can
Think 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；The parts by weight of sodium olefin sulfonate can for 1 part, 1.5 parts, 2 parts,
2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts；The parts by weight of sodium tripolyphosphate can for 3 parts, 3.5 parts, 4
Part, 4.5 parts, 5 parts, 5.5 parts, 6 parts；The parts by weight of sodium metasilicate can for 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4
Part；The parts by weight of natrium nitrosum can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；The parts by weight of diammonium hydrogen phosphate
It can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts；The parts by weight of triethanolamine can for 1 part, 1.5 parts, 2 parts,
2.5 parts, 3 parts, 3.5 parts, 4 parts；The parts by weight of aliphatic acid can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts；Three
The parts by weight of hydroxymethyl-propane can be 2 parts, 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts；Dialkyldithiocarbamacompositions sodium
Parts by weight can be 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8 parts, 8.5 parts, 9 parts；Polyisobutene fourth
The parts by weight of imidodicarbonic diamide can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；The parts by weight of methyl benzoate can
Think 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts；The parts by weight of polytetrafluoroethylene (PTFE)
It can be 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts, 9 parts；The parts by weight of butylene can be 1 part, 2 parts, 3 parts, 4 parts, 5 parts；Nonyl
The parts by weight of phenol polyethenoxy ether can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；AEO
Parts by weight can be 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts, 9 parts；The parts by weight of fatty acid methyl ester ethoxylate sulfoacid calcium
It can be 2 parts, 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts；The parts by weight of DBSA can for 3 parts, 3.5 parts, 4 parts,
4.5 parts, 5 parts, 5.5 parts, 6 parts；The parts by weight of ethoxylized fatty alcohol polyethenoxy ether sodium sulfate can for 4 parts, 4.5 parts, 5
Part, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8 parts.
Embodiment 1
A kind of oil removing clean type proposed by the present invention is modified antirust agent, and its raw material includes by weight：6 parts of sulfoacid calcium, change
Property 9 parts of degreaser, 6 parts of modified filler, modified 10 parts of antirust agent, 6 parts of the molten ammoniacal copper quaternary of amine, 2 parts of calgon, nanometer titanium dioxide
4 parts of silicon, 6 parts of sodium sulfonate, 6 parts of dodecenylsuccinic acid, 6 parts of zinc naphthenate, 6 parts of petrolatum, 3.5 parts of BTA, alkenyl
3.5 parts of sodium sulfonate, 4.5 parts of sodium tripolyphosphate, 2.5 parts of sodium metasilicate, 3.5 parts of natrium nitrosum, 4.5 parts of diammonium hydrogen phosphate, three second
2.5 parts of hydramine, 4.5 parts of aliphatic acid, 5 parts of trimethylolpropane, 6.5 parts of dialkyldithiocarbamacompositions sodium, polyisobutene fourth
3.5 parts of imidodicarbonic diamide, 3.5 parts of methyl benzoate, 6 parts of polytetrafluoroethylene (PTFE), 3 parts of butylene, 3.5 parts of NPE, fat
6 parts of fat alcohol APEO, 5 parts of fatty acid methyl ester ethoxylate sulfoacid calcium, 4.5 parts of DBSA, ethoxylation
6 parts of sodium sulfate of polyethenoxy ether of fatty alcohol.
Embodiment 2
A kind of oil removing clean type proposed by the present invention is modified antirust agent, and its raw material includes by weight：4 parts of sulfoacid calcium, change
Property 12 parts of degreaser, 4 parts of modified filler, modified 15 parts of antirust agent, 4 parts of the molten ammoniacal copper quaternary of amine, 3 parts of calgon, nano-silica
2 parts of SiClx, 9 parts of sodium sulfonate, 4 parts of dodecenylsuccinic acid, 8 parts of zinc naphthenate, 4 parts of petrolatum, 5 parts of BTA, alkenyl
1 part of sodium sulfonate, 6 parts of sodium tripolyphosphate, 1 part of sodium metasilicate, 5 parts of natrium nitrosum, 3 parts of diammonium hydrogen phosphate, 4 parts of triethanolamine, fat
3 parts of fat acid, 8 parts of trimethylolpropane, 4 parts of dialkyldithiocarbamacompositions sodium, 5 parts of polyisobutene succinimide, benzene first
Sour 1 part of methyl esters, 9 parts of polytetrafluoroethylene (PTFE), 1 part of butylene, 5 parts of NPE, 3 parts of AEO, fat
Sour 8 parts of FMEE sulfoacid calcium, 3 parts of DBSA, ethoxylized fatty alcohol polyethenoxy ether sodium sulfate 8
Part.
Modified degreaser is prepared by following technique：4 parts of alkali lignins and 3 parts of water are well mixed by weight, stirred
2h is mixed, pH is then adjusted to 11.0, then heats to 80 DEG C, be incubated 2h, 3 parts of formaldehyde is subsequently added into and is well mixed, reaction
20min, then adds 2 parts of ureas and is well mixed, continue to react 3h, be then cooled to 10 DEG C, continue to react 3h, then add 4 parts
Mass fraction is 60% sodium hydroxide solution, 1 part of carbon disulfide and 5 parts of sodium chlorate are well mixed, and then heats to 40 DEG C, guarantor
Warm 3h, is reduced to room temperature and obtains being modified degreaser.
Modified filler is prepared by following technique：By weight by 1 part of ferroso-ferric oxide and 5 parts of silane coupler KH-
570 are well mixed, and 40min is stirred in 1500r/min rotating speeds, then heat to 80 DEG C, are incubated 3h, are then added 3 parts of oleic acid and are mixed
Close uniform, 20min is stirred in 350r/min rotating speeds, be then placed in 70 DEG C of drying boxes and dry 20min, room temperature is cooled to after grinding
Obtain modified filler.
Modified antirust agent is prepared by following technique：By weight by 20 parts of emulsifying agent DNS-86,6 parts of phosphate PAM-
100 and 4 parts of deionizations are well mixed, and 20min is stirred in 650r/min rotating speeds, then add 9 parts of butyl acrylates, 2 parts of benzene second
Alkene, 6 parts of acrylic acid and 3 parts of epoxy resin are well mixed, and magnetic agitation 25min obtains material a, then adds 2 into material a
Part sodium acid carbonate and 4 parts of ammonium persulfates are well mixed, and are warming up to 60 DEG C, are incubated 3h, are then cooled to 40 DEG C, then add 5 parts
BTA, 4 parts of hexas, 6 parts of ethylene glycol and 2 parts of triethanolamines are well mixed, in the stirring of 2500r/min rotating speeds
20min, is warming up to 80 DEG C, is incubated 1h, is cooled to room temperature and obtains being modified antirust agent.
Embodiment 3
A kind of oil removing clean type proposed by the present invention is modified antirust agent, and its raw material includes by weight：8 parts of sulfoacid calcium, change
Property 6 parts of degreaser, 8 parts of modified filler, modified 5 parts of antirust agent, 8 parts of the molten ammoniacal copper quaternary of amine, 1 part of calgon, nanometer titanium dioxide
6 parts of silicon, 3 parts of sodium sulfonate, 8 parts of dodecenylsuccinic acid, 4 parts of zinc naphthenate, 8 parts of petrolatum, 2 parts of BTA, alkenyl sulphur
Sour 6 parts of sodium, 3 parts of sodium tripolyphosphate, 4 parts of sodium metasilicate, 2 parts of natrium nitrosum, 6 parts of diammonium hydrogen phosphate, 1 part of triethanolamine, fat
6 parts of acid, 2 parts of trimethylolpropane, 9 parts of dialkyldithiocarbamacompositions sodium, 2 parts of polyisobutene succinimide, benzoic acid
6 parts of methyl esters, 3 parts of polytetrafluoroethylene (PTFE), 5 parts of butylene, 2 parts of NPE, 9 parts of AEO, aliphatic acid
2 parts of FMEE sulfoacid calcium, 6 parts of DBSA, 4 parts of ethoxylized fatty alcohol polyethenoxy ether sodium sulfate.
Modified degreaser is prepared by following technique：6 parts of alkali lignins and 1 part of water are well mixed by weight, stirred
3h is mixed, pH is then adjusted to 10.0, then heats to 90 DEG C, be incubated 1h, 6 parts of formaldehyde is subsequently added into and is well mixed, reaction
10min, then adds 5 parts of ureas and is well mixed, continue to react 2h, be then cooled to 30 DEG C, continue to react 1h, then add 8 parts
Mass fraction is 40% sodium hydroxide solution, 4 parts of carbon disulfide and 2 parts of sodium chlorate are well mixed, and then heats to 60 DEG C, guarantor
Warm 1h, is reduced to room temperature and obtains being modified degreaser.
Modified filler is prepared by following technique：By weight by 3 parts of ferroso-ferric oxides and 2 parts of silane coupler KH-
570 are well mixed, and 20min is stirred in 2500r/min rotating speeds, then heat to 90 DEG C, are incubated 1h, are then added 6 parts of oleic acid and are mixed
Close uniform, 40min is stirred in 250r/min rotating speeds, be then placed in 50 DEG C of drying boxes and dry 40min, room temperature is cooled to after grinding
Obtain modified filler.
Modified antirust agent is prepared by following technique：By weight by 40 parts of emulsifying agent DNS-86,3 parts of phosphate PAM-
100 and 8 parts of deionizations are well mixed, and 40min is stirred in 450r/min rotating speeds, then add 3 parts of butyl acrylates, 5 parts of benzene second
Alkene, 1 part of acrylic acid and 5 parts of epoxy resin are well mixed, and magnetic agitation 15min obtains material a, then adds 6 into material a
Part sodium acid carbonate and 1 part of ammonium persulfate are well mixed, and are warming up to 70 DEG C, are incubated 1h, are then cooled to 50 DEG C, then add 3 parts
BTA, 8 parts of hexas, 4 parts of ethylene glycol and 5 parts of triethanolamines are well mixed, in the stirring of 1500r/min rotating speeds
40min, is warming up to 70 DEG C, is incubated 3h, is cooled to room temperature and obtains being modified antirust agent.
Embodiment 4
A kind of oil removing clean type proposed by the present invention is modified antirust agent, and its raw material includes by weight：5 parts of sulfoacid calcium, change
Property 11 parts of degreaser, 5 parts of modified filler, modified 12 parts of antirust agent, 5 parts of the molten ammoniacal copper quaternary of amine, part, nanometer two of calgon 2.5
3 parts of silica, 8 parts of sodium sulfonate, 5 parts of dodecenylsuccinic acid, 7 parts of zinc naphthenate, 5 parts of petrolatum, 4 parts of BTA, alkene
2 parts of base sodium sulfonate, 5 parts of sodium tripolyphosphate, 2 parts of sodium metasilicate, 4 parts of natrium nitrosum, 4 parts of diammonium hydrogen phosphate, 3 parts of triethanolamine,
4 parts of aliphatic acid, 7 parts of trimethylolpropane, 5 parts of dialkyldithiocarbamacompositions sodium, 4 parts of polyisobutene succinimide, benzene
2 parts of methyl formate, 8 parts of polytetrafluoroethylene (PTFE), 2 parts of butylene, 4 parts of NPE, 4 parts of AEO, fat
7 parts of fatty acid methyl esters ethoxylate sulfoacid calcium, 4 parts of DBSA, ethoxylized fatty alcohol polyethenoxy ether sodium sulfate 7
Part.
Modified degreaser is prepared by following technique：4.5 parts of alkali lignins and 2.5 parts of water are mixed equal by weight
It is even, 2.2h is stirred, pH is then adjusted to 10.8, then heats to 82 DEG C, be incubated 1.8h, 4 parts of formaldehyde is subsequently added into and is well mixed,
18min is reacted, 3 parts of ureas is then added and is well mixed, continues to react 2.8h, is then cooled to 15 DEG C, continues to react 2.5h, then
Add 5 parts of mass fractions to be well mixed for 55% sodium hydroxide solution, 2 parts of carbon disulfide and 4 parts of sodium chlorate, then heat to
45 DEG C, 2.5h is incubated, room temperature is reduced to and obtains being modified degreaser.
Modified filler is prepared by following technique：By weight by 1.5 parts of ferroso-ferric oxides and 4 parts of silane couplers
KH-570 is well mixed, and 35min is stirred in 1800r/min rotating speeds, then heats to 82 DEG C, is incubated 2.5h, then adds 4 parts of oil
Acid is well mixed, and 25min is stirred in 320r/min rotating speeds, is then placed in 65 DEG C of drying boxes and dries 25min, is cooled to after grinding
Room temperature obtains modified filler.
Modified antirust agent is prepared by following technique：By weight by 25 parts of emulsifying agent DNS-86,5 parts of phosphate PAM-
100 and 5 parts of deionizations are well mixed, and 25min is stirred in 620r/min rotating speeds, then add 8 parts of butyl acrylates, 3 parts of benzene second
Alkene, 5 parts of acrylic acid and 3.5 parts of epoxy resin are well mixed, and magnetic agitation 22min obtains material a, is then added into material a
3 parts of sodium acid carbonates and 3 parts of ammonium persulfates are well mixed, and are warming up to 62 DEG C, are incubated 2.5h, are then cooled to 42 DEG C, then add
4.5 parts of BTAs, 5 parts of hexas, 5.5 parts of ethylene glycol and 3 parts of triethanolamines are well mixed, in 2200r/min
Rotating speed stirs 25min, is warming up to 78 DEG C, is incubated 1.5h, is cooled to room temperature and obtains being modified antirust agent.
Embodiment 5
A kind of oil removing clean type proposed by the present invention is modified antirust agent, and its raw material includes by weight：7 parts of sulfoacid calcium, change
Property 7 parts of degreaser, 7 parts of modified filler, modified 8 parts of antirust agent, 7 parts of the molten ammoniacal copper quaternary of amine, 1.5 parts of calgon, nano-silica
5 parts of SiClx, 4 parts of sodium sulfonate, 7 parts of dodecenylsuccinic acid, 5 parts of zinc naphthenate, 7 parts of petrolatum, 3 parts of BTA, alkenyl
5 parts of sodium sulfonate, 4 parts of sodium tripolyphosphate, 3 parts of sodium metasilicate, 3 parts of natrium nitrosum, 5 parts of diammonium hydrogen phosphate, 2 parts of triethanolamine, fat
5 parts of fat acid, 3 parts of trimethylolpropane, 8 parts of dialkyldithiocarbamacompositions sodium, 3 parts of polyisobutene succinimide, benzene first
Sour 5 parts of methyl esters, 4 parts of polytetrafluoroethylene (PTFE), 4 parts of butylene, 3 parts of NPE, 8 parts of AEO, fat
Sour 3 parts of FMEE sulfoacid calcium, 5 parts of DBSA, ethoxylized fatty alcohol polyethenoxy ether sodium sulfate 5
Part.
Modified degreaser is prepared by following technique：5.5 parts of alkali lignins and 1.5 parts of water are mixed equal by weight
It is even, 2.8h is stirred, pH is then adjusted to 10.2, then heats to 88 DEG C, be incubated 1.2h, 5 parts of formaldehyde is subsequently added into and is well mixed,
12min is reacted, 4 parts of ureas is then added and is well mixed, continues to react 2.2h, is then cooled to 25 DEG C, continues to react 1.5h, then
Add 7 parts of mass fractions to be well mixed for 45% sodium hydroxide solution, 3 parts of carbon disulfide and 3 parts of sodium chlorate, then heat to
55 DEG C, 1.5h is incubated, room temperature is reduced to and obtains being modified degreaser.
Modified filler is prepared by following technique：By weight by 2.5 parts of ferroso-ferric oxides and 3 parts of silane couplers
KH-570 is well mixed, and 25min is stirred in 2200r/min rotating speeds, then heats to 88 DEG C, is incubated 1.5h, then adds 5 parts of oil
Acid is well mixed, and 35min is stirred in 280r/min rotating speeds, is then placed in 55 DEG C of drying boxes and dries 35min, is cooled to after grinding
Room temperature obtains modified filler.
Modified antirust agent is prepared by following technique：By weight by 35 parts of emulsifying agent DNS-86,4 parts of phosphate PAM-
100 and 7 parts of deionizations are well mixed, and 35min is stirred in 480r/min rotating speeds, then add 4 parts of butyl acrylates, 4 parts of benzene second
Alkene, 2 parts of acrylic acid and 4.5 parts of epoxy resin are well mixed, and magnetic agitation 18min obtains material a, is then added into material a
5 parts of sodium acid carbonates and 2 parts of ammonium persulfates are well mixed, and are warming up to 68 DEG C, are incubated 1.5h, are then cooled to 48 DEG C, then add
3.5 parts of BTAs, 7 parts of hexas, 4.5 parts of ethylene glycol and 4 parts of triethanolamines are well mixed, in 1800r/min
Rotating speed stirs 35min, is warming up to 72 DEG C, is incubated 2.5h, is cooled to room temperature and obtains being modified antirust agent.
The foregoing is intended to be a preferred embodiment of the present invention, but protection scope of the present invention is not limited thereto,
Any one skilled in the art the invention discloses technical scope in, technique according to the invention scheme and its
Inventive concept is subject to equivalent or change, should all be included within the scope of the present invention.
Claims (7)
1. a kind of oil removing clean type is modified antirust agent, it is characterised in that its raw material includes by weight：4-8 parts of sulfoacid calcium, modification
6-12 parts of degreaser, 4-8 parts of modified filler, modified 5-15 parts of antirust agent, molten ammoniacal copper quaternary 4-8 parts of amine, 1-3 parts of calgon,
2-6 parts of nano silicon, 3-9 parts of sodium sulfonate, 4-8 parts of dodecenylsuccinic acid, 4-8 parts of zinc naphthenate, 4-8 parts of petrolatum,
2-5 parts of BTA, 1-6 parts of sodium olefin sulfonate, 3-6 parts of sodium tripolyphosphate, 1-4 parts of sodium metasilicate, 2-5 parts of natrium nitrosum,
3-6 parts of diammonium hydrogen phosphate, 1-4 parts of triethanolamine, 3-6 parts of aliphatic acid, 2-8 parts of trimethylolpropane, dialkyl dithio amino
4-9 parts of sodium formate, 2-5 parts of polyisobutene succinimide, 1-6 parts of methyl benzoate, 3-9 parts of polytetrafluoroethylene (PTFE), butylene 1-5
Part, 2-5 parts of NPE, 3-9 parts of AEO, fatty acid methyl ester ethoxylate sulfoacid calcium 2-8
Part, 3-6 parts of DBSA, 4-8 parts of ethoxylized fatty alcohol polyethenoxy ether sodium sulfate.
2. oil removing clean type according to claim 1 is modified antirust agent, it is characterised in that modified degreaser presses following technique
Prepared：Alkali lignin and water are well mixed, 2-3h is stirred, pH is then adjusted to 10.0-11.0, then heats to 80-
90 DEG C, 1-2h is incubated, formaldehyde is subsequently added into and is well mixed, react 10-20min, urea is then added and is well mixed, continues to react 2-
3h, is then cooled to 10-30 DEG C, continues to react 1-3h, and it is 40-60% sodium hydroxide solution, two then to add mass fraction
Nitric sulfid and sodium chlorate are well mixed, then heat to 40-60 DEG C, are incubated 1-3h, are reduced to room temperature and obtain being modified degreaser.
3. oil removing clean type according to claim 1 or 2 is modified antirust agent, it is characterised in that the preparation of modified degreaser
In technique, alkali lignin, water, formaldehyde, urea, mass fraction are 40-60% sodium hydroxide solution, carbon disulfide and sodium chlorate weight
Amount is than being 4-6：1-3：3-6：2-5：4-8：1-4：2-5.
4. the oil removing clean type according to claim any one of 1-3 is modified antirust agent, it is characterised in that modified filler is by such as
It is prepared by lower technique：Ferroso-ferric oxide and Silane coupling reagent KH-570 are well mixed, stirred in 1500-2500r/min rotating speeds
20-40min is mixed, 80-90 DEG C is then heated to, 1-3h is incubated, oleic acid is then added and is well mixed, in 250-350r/min rotating speeds
20-40min is stirred, is then placed in 50-70 DEG C of drying box and dries 20-40min, room temperature is cooled to after grinding and obtains modified fill out
Material.
5. the oil removing clean type according to claim any one of 1-4 is modified antirust agent, it is characterised in that the system of modified filler
In standby technique, the weight ratio of ferroso-ferric oxide, Silane coupling reagent KH-570 and oleic acid is 1-3：2-5：3-6 is mixed.
6. the oil removing clean type according to claim any one of 1-5 is modified antirust agent, it is characterised in that modified antirust agent
Raw material includes by weight：20-40 parts of emulsifying agent DNS-86,3-6 parts of phosphate PAM-100,4-8 parts of deionization, acrylic acid
3-9 parts of butyl ester, 2-5 parts of styrene, 1-6 parts of acrylic acid, 3-5 parts of epoxy resin, 2-6 parts of sodium acid carbonate, 1-4 parts of ammonium persulfate,
3-5 parts of BTA, 4-8 parts of hexa, 4-6 parts of ethylene glycol, 2-5 parts of triethanolamine.
7. the oil removing clean type according to claim any one of 1-6 is modified antirust agent, it is characterised in that modified antirust agent is pressed
It is prepared by following technique：Emulsifying agent DNS-86, phosphate PAM-100 and deionization are well mixed, in 450-650r/min
Rotating speed stirs 20-40min, then adds butyl acrylate, styrene, acrylic acid and epoxy resin and is well mixed, magnetic agitation
15-25min, obtains material a, and sodium acid carbonate is then added into material a and ammonium persulfate is well mixed, 60-70 DEG C is warming up to,
1-3h is incubated, 40-50 DEG C is then cooled to, BTA, hexa, ethylene glycol and triethanolamine is then added mixed
Close uniform, 20-40min is stirred in 1500-2500r/min rotating speeds, be warming up to 70-80 DEG C, be incubated 1-3h, be cooled to room temperature and obtain
Modified antirust agent.
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| CN201710220501.4A CN106939423A (en) | 2017-04-06 | 2017-04-06 | A kind of oil removing clean type is modified antirust agent |
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| CN201710220501.4A CN106939423A (en) | 2017-04-06 | 2017-04-06 | A kind of oil removing clean type is modified antirust agent |
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| CN107354468A (en) * | 2017-07-25 | 2017-11-17 | 马鞍山联邦机电工程有限公司 | A kind of magnetic 4A zeolites fix the compound powdered-metal cleaning agent of degradation bacteria weight dirt and cleaning |
| CN109402650A (en) * | 2017-08-18 | 2019-03-01 | 上海洁安精细化工有限公司 | A kind of antirust spray cleaning agent |
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Application publication date: 20170711 |