CN105861126A - Biodegradable liquid special for micro emulsion type wire cutting and preparation method of biodegradable liquid - Google Patents

Biodegradable liquid special for micro emulsion type wire cutting and preparation method of biodegradable liquid Download PDF

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Publication number
CN105861126A
CN105861126A CN201610241438.8A CN201610241438A CN105861126A CN 105861126 A CN105861126 A CN 105861126A CN 201610241438 A CN201610241438 A CN 201610241438A CN 105861126 A CN105861126 A CN 105861126A
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micro emulsion
acid
biodegradable liquid
oil
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边自海
李胜
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TIANJIN JINLAILI GREASE CO Ltd
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TIANJIN JINLAILI GREASE CO Ltd
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04—Mixtures of base-materials and additives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M173/00—Lubricating compositions containing more than 10% water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/102—Aliphatic fractions
    • C10M2203/1025—Aliphatic fractions used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/04—Ethers; Acetals; Ortho-esters; Ortho-carbonates
    • C10M2207/046—Hydroxy ethers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • C10M2207/127—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids polycarboxylic
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/12—Polysaccharides, e.g. cellulose, biopolymers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/08—Amides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/223—Five-membered rings containing nitrogen and carbon only
    • C10M2215/224—Imidazoles
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/02—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
    • C10M2219/024—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of esters, e.g. fats
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/06—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having phosphorus-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/06—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having phosphorus-to-carbon bonds
    • C10M2223/063—Ammonium or amine salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
    • C10M2227/06—Organic compounds derived from inorganic acids or metal salts
    • C10M2227/061—Esters derived from boron

Abstract

The invention discloses biodegradable liquid special for micro emulsion type wire cutting and a preparation method of the biodegradable liquid. The biodegradable liquid is prepared from a component A, a component B, a component C, a component D, a component E, a component F, a component G, a component H, a component I, a component J and a component K. The biodegradable liquid special for micro emulsion type wire cutting is low in cost and good in processing efficiency and meets the national requirements for energy saving, emission reduction and environment protection.

Description

The micro emulsion molded line of a kind of easily biological-degradable cuts special liquid and preparation method thereof
Technical field
The present invention relates to intermetallic composite coating cooling lubricant technical field, be specifically related to the micro-emulsion type of a kind of easily biological-degradable Line cuts special liquid and preparation method thereof.
Background technology
In the prior art, the base oil interpolation one that linear cutter liquid mainly uses and contains alkane or aromatic hydrocarbon Divide the additives such as antirust agent, arc quenching agent, extreme pressure agent.In intermetallic composite coating, easily produce smog, severe contamination working environment, make High with cost.Another linear cutter liquid mainly uses the mineral oil of certain viscosity, adds emulsifying agent, antirust agent, microexplosion Agent, cleaning agent etc., but in Metal Cutting, the steel wire of wire cutting machine uses the cycle short, and processing workpiece greasy dirt and fineness are poor, and And the wire cutting liquid after using easily causes environmental pollution.A kind of low cost, efficiency how can be provided high, readily biodegradable Line cut special liquid become the demand that people are urgent.
Summary of the invention
It is an object of the invention to overcome the deficiencies in the prior art, it is provided that a kind of environmental protection, with low cost, processing workpiece is bright and clean The micro emulsion molded line spending high easily biological-degradable cuts special liquid and preparation method thereof.
For achieving the above object, the technical solution used in the present invention is:
The micro emulsion molded line of a kind of easily biological-degradable cuts special liquid, is made up of the raw material of following weight percentage: component A:15- 35%, component B:8-15%, component C:7-13%, component D:7 13%, component E:6-11%, component F:5-10%, component G:2-5%, Component H:2-5%, component I:1-3%, component J:1-3%, component K:25-40%, wherein:
Component A is one or more in rubber oil, transformer oil, No. 15 white oils, atoleines；
Component B is dodecenylsuccinic acid, N-oleoyl propylhomoserin octadecylamine salt, barium sulfonate, BTA, dinonylnaphthalene sulfonic acid One or more in barium, organic phosphate, borate, sulfoacid calcium, lanolin magnesium soap；
Component C is sorbitan fatty acid ester, polyoxyethylene aliphatic alcohol ether, imidazole type compound, betaine type surface-active One or more in agent, NPE；
Component D is one or more in poly-diethanol 400, polyethylene glycol 1540, glycerine；
Component E be palm oil, animal and plant fat, polyester, binary acid diester, oleate, enuatrol, extreme pressure anti-wear additives T301, One or more in T301/ Monododecylphosphate sylvite, aliphatic amine type oiliness improver, aliphatic acid, SA；
Component F is the one in diphenyl disulfide, sodium tetraborate, sulfuration vegetable and animals oils, chlorinated paraffin, tricresyl phosphate Or it is several；
Component G is one or more in three red oil, BK, borate, phenol, tetrachlorophenol, Sodium Benzoates；
Component H is that butyl must one or more in alcohol, ethylenediamine tetra-acetic acid；
Component I is one or more in polyvinyl alcohol, carboxymethyl cellulose salt, polyacrylate；
Component J is one or both in triethanolamine, diethanol amine；
Component K is one or more in dimethylformamide, EGME, ethylene glycol ethyl ether, dimethicone and water Mixture.
Vulcanizing vegetable and animals oils in described component F is sulfurized castor oil.
The micro emulsion molded line of a kind of easily biological-degradable cuts the preparation method of special liquid, it is characterised in that comprise the following steps:
(1) in a reactor equipped with stirring and heating apparatus, addition component A, component B, component C are warming up to 60～65 DEG C, insulation reaction 30min, add component E, component F, insulation reaction 30min, be cooled to 35 DEG C, filter releasing condensation product and treat With；And
(2) in reactor, it is initially charged the water in component K, starts stirring, add component I, component H so that it is be dissolved into transparent, so Rear addition component D, reaction 30min after, add step (1) gained condensation product, stir 30min, be eventually adding component G, component J and Other auxiliary agents in component K, adjust PH to 8.5～9, get product after filtering and packaging.
Beneficial effects of the present invention: the micro emulsion molded line of a kind of easily biological-degradable of the present invention cuts special liquid and becomes containing mineral oil Dividing few, the biodegradable vegetable oil of energy and synthol composition are many, can form the translucent microemulsion to transparence in water, it is simple to Clear observation to processing parts, and cleaning is good, and chip, iron powder particulate, greasy filth etc. are had good separation and sedimentation Effect, working solution good stability, cutting speed is fast, is not likely to produce bacterium, uses the cycle long, can be biodegradable, and use cost is low Honest and clean.
Accompanying drawing explanation
Fig. 1 is the situation of micro emulsion molded line of the present invention cutting several conventional antirust agent salt fog resistance of special liquid；
Fig. 2 is the relation that micro emulsion molded line of the present invention cuts special liquid growth of microorganism and liquid pH value；
Fig. 3 is that micro emulsion molded line of the present invention cuts extreme pressure agent chemical reaction and the relation of load performance, Qi Zhonghan in special liquid In the oil of sulphur system extreme pressure agent, the mass fraction of sulphur component is 0.5%.
Description of reference numerals:
1, diphenyl disulfide；2, dodecyl disulphide；3, dibenzyldisulfide；4, elemental carbon.
Detailed description of the invention
The micro emulsion molded line of a kind of easily biological-degradable cuts special liquid, is made up of the raw material of following weight percentage: component A: 15-35%, component B:8-15%, component C:7-13%, component D:7 13%, component E:6-11%, component F:5-10%, component G:2- 5%, component H:2-5%, component I:1-3%, component J:1-3%, component K:25-40%, wherein:
Component A is one or more in rubber oil, transformer oil, No. 15 white oils, atoleines；
Component B is dodecenylsuccinic acid, N-oleoyl propylhomoserin octadecylamine salt, barium sulfonate, BTA, dinonylnaphthalene sulfonic acid One or more in barium, organic phosphate, borate, sulfoacid calcium, lanolin magnesium soap；
Component C is sorbitan fatty acid ester, polyoxyethylene aliphatic alcohol ether, imidazole type compound, betaine type surface-active One or more in agent, NPE；
Component D is one or more in poly-diethanol 400, polyethylene glycol 1540, glycerine；
Component E be palm oil, animal and plant fat, polyester, binary acid diester, oleate, enuatrol, extreme pressure anti-wear additives T301, One or more in T301/ Monododecylphosphate sylvite, aliphatic amine type oiliness improver, aliphatic acid, SA；
Component F is the one in diphenyl disulfide, sodium tetraborate, sulfuration vegetable and animals oils, chlorinated paraffin, tricresyl phosphate Or it is several；
Component G is one or more in three red oil, BK, borate, phenol, tetrachlorophenol, Sodium Benzoates；
Component H is that butyl must one or more in alcohol, ethylenediamine tetra-acetic acid；
Component I is one or more in polyvinyl alcohol, carboxymethyl cellulose salt, polyacrylate；
Component J is one or both in triethanolamine, diethanol amine；
Component K is one or more in dimethylformamide, EGME, ethylene glycol ethyl ether, dimethicone and water Mixture.
Vulcanizing vegetable and animals oils in component F is sulfurized castor oil.
In component A, the pour point of atoleine is-10～-5 DEG C, by C12～C14Linear paraffin forms, and density is 760kg/m3, Boiling range is 220～255 DEG C, and this kind of liquid wax is narrow due to its cut, is not easily formed stain.
In component B, organic phosphate includes organic ammonium salt and the imidazoline salt of alkyl phosphoric acid.
Component B mesoboric acid ester is the boron amide type slushing compound that boric acid and diethanol amine react generation at a certain temperature.
Table 1 is the lubricity of organic boric acid ester.
In component B, the structural formula of alkenyl succinic acid is for (wherein R is C10～C14):
Table 2 is the experimental result of each antirust agent.
In component C, betaine type amphoteric surfactant is representational amphion emulsifying agent, the knot of imidazoline type compound Structure formula is following, and (wherein R is C11～C17Alkyl).
In component E, synthetic ester is the product of organic acid and alcohol, has good high-temperature stability, and unit ester is unitary Acid and the product of monohydric alcohol, be widely used in metal working lubricant, and phosphate demonstrates good lubrication property, special It not at high temperature to remain to maintain its stability.Aliphatic amine type oiliness improver such as benzotriazole fatty amine salt has oiliness, antioxygen, prevents The performance such as rotten, wear-resistant, antirust.
Table 3 is the oiliness improver impact on stability of microemulsion.
Table 4 is the biological degradability of several conventional base oil.
Table 5 is sodium tetraborate extreme pressure property in aqueous compounding with organic matter in component F.
In component I, carboxymethyl cellulose salt (CMC-Na) is water-soluble high-molecular compound.
Dimethylformamide in component K, EGME, ethylene glycol ethyl ether in micro emulsion molded line cuts special liquid to reduction Freezing point plays a key effect.
The micro emulsion molded line of a kind of easily biological-degradable cuts the preparation method of special liquid, comprises the following steps:
(1) in a reactor equipped with stirring and heating apparatus, addition component A, component B, component C are warming up to 60～65 DEG C, insulation reaction 30min, add component E, component F, insulation reaction 30min, be cooled to 35 DEG C, filter releasing condensation product and treat With；And
(2) in reactor, it is initially charged the water in component K, starts stirring, add component I, component H so that it is be dissolved into transparent, so Rear addition component D, reaction 30min after, add step (1) gained condensation product, stir 30min, be eventually adding component G, component J and Other auxiliary agents in component K, adjust PH to 8.5～9, get product after filtering and packaging.
Table 6 is the thermal conductivity of several cutting fluid.
Table 7 is the main performance index of embodiment of the present invention gained microemulsified wire cutting liquid.
The above, only in order to technical scheme to be described and unrestricted, those of ordinary skill in the art are to the present invention's Other amendment or equivalent that technical scheme is made, without departing from the spirit and scope of technical solution of the present invention, all should Contain in the middle of scope of the presently claimed invention.

Claims (3)

1. the micro emulsion molded line of an easily biological-degradable cuts special liquid, it is characterised in that by the raw material group of following weight percentage Become: component A:15-35%, component B:8-15%, component C:7-13%, component D:7 13%, component E:6-11%, component F:5-10%, Component G:2-5%, component H:2-5%, component I:1-3%, component J:1-3%, component K:25-40%, wherein:
Component A is one or more in rubber oil, transformer oil, No. 15 white oils, atoleines；
Component B is dodecenylsuccinic acid, N-oleoyl propylhomoserin octadecylamine salt, barium sulfonate, BTA, dinonylnaphthalene sulfonic acid One or more in barium, organic phosphate, borate, sulfoacid calcium, lanolin magnesium soap；
Component C is sorbitan fatty acid ester, polyoxyethylene aliphatic alcohol ether, imidazole type compound, betaine type surface-active One or more in agent, NPE；
Component D is one or more in PEG400, polyethylene glycol 1540, glycerine；
Component E be palm oil, animal and plant fat, polyester, binary acid diester, oleate, enuatrol, extreme pressure anti-wear additives T301, One or more in T301/ Monododecylphosphate sylvite, aliphatic amine type oiliness improver, aliphatic acid, SA；
Component F is the one in diphenyl disulfide, sodium tetraborate, sulfuration vegetable and animals oils, chlorinated paraffin, tricresyl phosphate Or it is several；
Component G is one or more in three red oil, BK, borate, phenol, tetrachlorophenol, Sodium Benzoates；
Component H is that butyl must one or more in alcohol, ethylenediamine tetra-acetic acid；
Component I is one or more in polyvinyl alcohol, carboxymethyl cellulose salt, polyacrylate；
Component J is one or both in triethanolamine, diethanol amine；
Component K is one or more in dimethylformamide, EGME, ethylene glycol ethyl ether, dimethicone and water Mixture.
The micro emulsion molded line of easily biological-degradable the most according to claim 1 cuts special liquid, it is characterised in that described component F Middle sulfuration vegetable and animals oils is sulfurized castor oil.
The micro emulsion molded line of easily biological-degradable the most according to claim 1 cuts the preparation method of special liquid, it is characterised in that Comprise the following steps:
(1) in a reactor equipped with stirring and heating apparatus, addition component A, component B, component C are warming up to 60～65 DEG C, insulation reaction 30min, add component E, component F, insulation reaction 30min, be cooled to 35 DEG C, filter releasing condensation product and treat With；And
(2) in reactor, it is initially charged the water in component K, starts stirring, add component I, component H so that it is be dissolved into transparent, so Rear addition component D, reaction 30min after, add step (1) gained condensation product, stir 30min, be eventually adding component G, component J and Other auxiliary agents in component K, adjust PH to 8.5～9, get product after filtering and packaging.
CN201610241438.8A 2016-04-19 2016-04-19 Biodegradable liquid special for micro emulsion type wire cutting and preparation method of biodegradable liquid Pending CN105861126A (en)

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CN108456590A (en) * 2018-03-12 2018-08-28 苏州福瑞斯德新材料科技有限公司 A kind of environment-friendly type micro-lubricating cutting liquid composition
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CN115521822A (en) * 2022-10-21 2022-12-27 中国石油化工股份有限公司 Linear cutting emulsifier and preparation method thereof

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CN108456590A (en) * 2018-03-12 2018-08-28 苏州福瑞斯德新材料科技有限公司 A kind of environment-friendly type micro-lubricating cutting liquid composition
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