CN105349226A - Emulsified cutting fluid for aluminium alloy and preparation method thereof - Google Patents
Emulsified cutting fluid for aluminium alloy and preparation method thereof Download PDFInfo
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- CN105349226A CN105349226A CN201510808134.0A CN201510808134A CN105349226A CN 105349226 A CN105349226 A CN 105349226A CN 201510808134 A CN201510808134 A CN 201510808134A CN 105349226 A CN105349226 A CN 105349226A
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Abstract
The invention discloses an emulsified cutting fluid for aluminium alloy. The emulsified cutting fluid is composed of, by weight, 24-40 parts of gum turpentine, 5-13 parts of water, 5-10 parts of fatty acid polyethylene glycol ester, 4-11 parts of lanolin, 7-18 parts of an emulsifier, 4-9 parts of a nonionic surfactant, 4-8 parts of hexadecenyl-Butanedioic acid, 3-9 parts of N-Oleoylsarcosine, 2-6 parts of polyacrylamide, 4-10 parts of nano-cerium oxide, 2-9 parts of an antifoaming agent and 4-13 parts of triethylene glycol diacrylate. The invention also discloses a preparation method of the cutting fluid. The prepared cutting fluid has good anti-rust property and stability. During cutting, cutter abrasion is slight after 2 days of cutting processing, and good cutting performance is also displayed.
Description
Technical field
The invention belongs to metal working fluid field, be particularly related to a kind of aluminium alloy emulsion cutting fluid and preparation method thereof.
Background technology
Cutting fluid is that one is cut at metal, cuts, ground in the course of processing, be used for the industrial type fluid of Cooling and Lubricator cutter and workpiece, cutting force when it can reduce cutting, take away the heat of generation in cutting zone in time to reduce cutting temperature, improve tool life, thus enhance productivity, improve workpiece surface roughness, ensure Workpiece Machining Accuracy.Cutting fluid can simply be divided into according to its composition: oiliness cutting fluid, aqueous cutting fluid and emulsion cutting fluid.It is fast and cut rear workpiece surface easy cleaning that emulsion cutting fluid has cooling efficiency, in use foam is more for traditional emulsion cutting fluid, nontransparent being unfavorable for observes workpiece, also there is the problems such as rust-proof effect difference, workpiece be perishable, affects the quality of whole product.Therefore, need to be provided in working angles and there is the emulsion cutting fluid that good cutting effect has favorable rust preventing effect simultaneously, to improve overall processing quality and the working (machining) efficiency of cutting process.
Summary of the invention
The technical problem solved is: reducing emulsifying agent to the corrosion of workpiece to solve, providing a kind of and having good cutting effect and aluminium alloy emulsion cutting fluid of favorable rust preventing effect and preparation method thereof.
Technical scheme: in order to solve the problem, the invention provides a kind of aluminium alloy emulsion cutting fluid, be made up of following ingredients, counted by parts by weight: gum turpentine 24 ~ 40 parts, 5 ~ 13 parts, water, fatty acid polyglycol ester 5 ~ 10 parts, 4 ~ 11 parts, lanolin, emulsifying agent 7 ~ 18 parts, nonionogenic tenside 4 ~ 9 parts, hexadecylene base succinic acid 4 ~ 8 parts, KORANTIN SH 3 ~ 9 parts, polyacrylamide 2 ~ 6 parts, nano-cerium oxide 4 ~ 10 parts, defoamer 2 ~ 9 parts and triethylene glycol diacrylate 4 ~ 13 parts.
Preferably, described emulsifying agent is alkylphenol polyoxyethylene or benzene sulfonic acid sodium salt.
Preferably, described nonionogenic tenside is alkylphenol polyoxyethylene or polysorbas20.
Preferably, described a kind of aluminium alloy emulsion cutting fluid, be made up of following ingredients, counted by parts by weight: gum turpentine 28 ~ 40 parts, 6 ~ 13 parts, water, fatty acid polyglycol ester 5 ~ 8 parts, 6 ~ 11 parts, lanolin, emulsifying agent 7 ~ 14 parts, nonionogenic tenside 5 ~ 9 parts, hexadecylene base succinic acid 4 ~ 7 parts, KORANTIN SH 5 ~ 9 parts, polyacrylamide 2 ~ 6 parts, nano-cerium oxide 4 ~ 8 parts, defoamer 4 ~ 9 parts and triethylene glycol diacrylate 4 ~ 9 parts.
Further, preferably, described a kind of aluminium alloy emulsion cutting fluid, be made up of following ingredients, counted by parts by weight: gum turpentine 32 parts, 9 parts, water, fatty acid polyglycol ester 4 parts, 7 parts, lanolin, emulsifying agent 12 parts, nonionogenic tenside 6 parts, hexadecylene base succinic acid 5 parts, KORANTIN SH 7 parts, polyacrylamide 4 parts, nano-cerium oxide 5 parts, defoamer 6 parts and triethylene glycol diacrylate 5 parts.
The preparation method of a kind of aluminium alloy emulsion cutting fluid described above, comprises the steps:
First, to weigh by weight each raw material; Secondly, water, gum turpentine and lanolin are joined in reaction vessel and is heated to 98 DEG C; Then add KORANTIN SH, polyacrylamide, emulsifying agent, triethylene glycol diacrylate, hexadecylene base succinic acid, nano-cerium oxide and fatty acid polyglycol ester successively, constantly stir; After thing to be mixed is cooled to room temperature again, respectively defoamer and nonionogenic tenside is added, constantly stir and get final product.
The present invention has following beneficial effect: better, in addition, in working angles, after the machining of 2 days, tool wear situation is comparatively light, also demonstrates good cutting ability for the rust-preventing characteristic of cutting fluid prepared by the present invention and stability.
Embodiment
In order to understand the present invention further, below in conjunction with embodiment, invention preferred embodiment is described, but should be appreciated that these describe just for further illustrating the features and advantages of the present invention, instead of limiting to the claimed invention.
Embodiment 1
A preparation method for aluminium alloy emulsion cutting fluid, comprises the steps:
First, to weigh by weight each raw material: gum turpentine 24 parts, 5 parts, water, fatty acid polyglycol ester 5 parts, 4 parts, lanolin, emulsifying agent 7 parts, nonionogenic tenside 4 parts, hexadecylene base succinic acid 4 parts, KORANTIN SH 3 parts, polyacrylamide 2 parts, nano-cerium oxide 4 parts, defoamer 2 parts and triethylene glycol diacrylate 4 parts; Described emulsifying agent is alkylphenol polyoxyethylene or benzene sulfonic acid sodium salt; Described nonionogenic tenside is alkylphenol polyoxyethylene or polysorbas20;
Secondly, water, gum turpentine and lanolin are joined in reaction vessel and is heated to 98 DEG C; Then add KORANTIN SH, polyacrylamide, emulsifying agent, triethylene glycol diacrylate, hexadecylene base succinic acid, nano-cerium oxide and fatty acid polyglycol ester successively, constantly stir; After thing to be mixed is cooled to room temperature again, respectively defoamer and nonionogenic tenside is added, constantly stir and get final product.
Embodiment 2
A preparation method for aluminium alloy emulsion cutting fluid, comprises the steps:
First, to weigh by weight each raw material: gum turpentine 40 parts, 13 parts, water, fatty acid polyglycol ester 10 parts, 11 parts, lanolin, emulsifying agent 18 parts, nonionogenic tenside 9 parts, hexadecylene base succinic acid 8 parts, KORANTIN SH 9 parts, polyacrylamide 6 parts, nano-cerium oxide 10 parts, defoamer 9 parts and triethylene glycol diacrylate 13 parts; Described emulsifying agent is alkylphenol polyoxyethylene or benzene sulfonic acid sodium salt; Described nonionogenic tenside is alkylphenol polyoxyethylene or polysorbas20;
Secondly, water, gum turpentine and lanolin are joined in reaction vessel and is heated to 98 DEG C; Then add KORANTIN SH, polyacrylamide, emulsifying agent, triethylene glycol diacrylate, hexadecylene base succinic acid, nano-cerium oxide and fatty acid polyglycol ester successively, constantly stir; After thing to be mixed is cooled to room temperature again, respectively defoamer and nonionogenic tenside is added, constantly stir and get final product.
Embodiment 3
A preparation method for aluminium alloy emulsion cutting fluid, comprises the steps:
First, to weigh by weight each raw material: gum turpentine 32 parts, 9 parts, water, fatty acid polyglycol ester 7 parts, 8 parts, lanolin, emulsifying agent 12 parts, nonionogenic tenside 6 parts, hexadecylene base succinic acid 6 parts, KORANTIN SH 7 parts, polyacrylamide 4 parts, nano-cerium oxide 7 parts, defoamer 5 parts and triethylene glycol diacrylate 8 parts; Described emulsifying agent is alkylphenol polyoxyethylene or benzene sulfonic acid sodium salt; Described nonionogenic tenside is alkylphenol polyoxyethylene or polysorbas20;
Secondly, water, gum turpentine and lanolin are joined in reaction vessel and is heated to 98 DEG C; Then add KORANTIN SH, polyacrylamide, emulsifying agent, triethylene glycol diacrylate, hexadecylene base succinic acid, nano-cerium oxide and fatty acid polyglycol ester successively, constantly stir; After thing to be mixed is cooled to room temperature again, respectively defoamer and nonionogenic tenside is added, constantly stir and get final product.
Embodiment 4
A preparation method for aluminium alloy emulsion cutting fluid, comprises the steps:
First, to weigh by weight each raw material: gum turpentine 28 parts, 6 parts, water, fatty acid polyglycol ester 8 parts, 6 parts, lanolin, emulsifying agent 14 parts, nonionogenic tenside 5 parts, hexadecylene base succinic acid 7 parts, KORANTIN SH 5 parts, polyacrylamide 4 parts, nano-cerium oxide 8 parts, defoamer 4 parts and triethylene glycol diacrylate 9 parts; Described emulsifying agent is alkylphenol polyoxyethylene or benzene sulfonic acid sodium salt; Described nonionogenic tenside is alkylphenol polyoxyethylene or polysorbas20;
Secondly, water, gum turpentine and lanolin are joined in reaction vessel and is heated to 98 DEG C; Then add KORANTIN SH, polyacrylamide, emulsifying agent, triethylene glycol diacrylate, hexadecylene base succinic acid, nano-cerium oxide and fatty acid polyglycol ester successively, constantly stir; After thing to be mixed is cooled to room temperature again, respectively defoamer and nonionogenic tenside is added, constantly stir and get final product.
Embodiment 5
A preparation method for aluminium alloy emulsion cutting fluid, comprises the steps:
First, to weigh by weight each raw material: gum turpentine 32 parts, 9 parts, water, fatty acid polyglycol ester 4 parts, 7 parts, lanolin, emulsifying agent 12 parts, nonionogenic tenside 6 parts, hexadecylene base succinic acid 5 parts, KORANTIN SH 7 parts, polyacrylamide 4 parts, nano-cerium oxide 5 parts, defoamer 6 parts and triethylene glycol diacrylate 5 parts; Described emulsifying agent is alkylphenol polyoxyethylene or benzene sulfonic acid sodium salt; Described nonionogenic tenside is alkylphenol polyoxyethylene or polysorbas20;
Secondly, water, gum turpentine and lanolin are joined in reaction vessel and is heated to 98 DEG C; Then add KORANTIN SH, polyacrylamide, emulsifying agent, triethylene glycol diacrylate, hexadecylene base succinic acid, nano-cerium oxide and fatty acid polyglycol ester successively, constantly stir; After thing to be mixed is cooled to room temperature again, respectively defoamer and nonionogenic tenside is added, constantly stir and get final product.
Performance test
Now carry out the test of rust-preventing characteristic, stability and cutting ability to the cutting fluid prepared by embodiment 1 to 5, result is as follows:
As seen from the above table, better, in addition, in working angles, after the cutting of 2 days, the wear pattern of cutter is comparatively light, also demonstrates good cutting ability for the rust-preventing characteristic of cutting fluid prepared by the present invention and stability.
Claims (7)
1. an aluminium alloy emulsion cutting fluid, it is characterized in that: be made up of following ingredients, counted by parts by weight: gum turpentine 24 ~ 40 parts, 5 ~ 13 parts, water, fatty acid polyglycol ester 5 ~ 10 parts, 4 ~ 11 parts, lanolin, emulsifying agent 7 ~ 18 parts, nonionogenic tenside 4 ~ 9 parts, hexadecylene base succinic acid 4 ~ 8 parts, KORANTIN SH 3 ~ 9 parts, polyacrylamide 2 ~ 6 parts, nano-cerium oxide 4 ~ 10 parts, defoamer 2 ~ 9 parts and triethylene glycol diacrylate 4 ~ 13 parts.
2. a kind of aluminium alloy emulsion cutting fluid according to claim 1, is characterized in that: described emulsifying agent is alkylphenol polyoxyethylene or benzene sulfonic acid sodium salt.
3. a kind of aluminium alloy emulsion cutting fluid according to claim 1, is characterized in that: described nonionogenic tenside is alkylphenol polyoxyethylene or polysorbas20.
4. a kind of aluminium alloy emulsion cutting fluid according to claim 1, is characterized in that: described defoamer is silicone emulsion.
5. a kind of aluminium alloy emulsion cutting fluid according to any one of claim 1 ~ 4, it is characterized in that: be made up of following ingredients, counted by parts by weight: gum turpentine 28 ~ 40 parts, 6 ~ 13 parts, water, fatty acid polyglycol ester 5 ~ 8 parts, 6 ~ 11 parts, lanolin, emulsifying agent 7 ~ 14 parts, nonionogenic tenside 5 ~ 9 parts, hexadecylene base succinic acid 4 ~ 7 parts, KORANTIN SH 5 ~ 9 parts, polyacrylamide 2 ~ 6 parts, nano-cerium oxide 4 ~ 8 parts, defoamer 4 ~ 9 parts and triethylene glycol diacrylate 4 ~ 9 parts.
6. a kind of aluminium alloy emulsion cutting fluid according to any one of claim 5, it is characterized in that: be made up of following ingredients, counted by parts by weight: gum turpentine 32 parts, 9 parts, water, fatty acid polyglycol ester 4 parts, 7 parts, lanolin, emulsifying agent 12 parts, nonionogenic tenside 6 parts, hexadecylene base succinic acid 5 parts, KORANTIN SH 7 parts, polyacrylamide 4 parts, nano-cerium oxide 5 parts, defoamer 6 parts and triethylene glycol diacrylate 5 parts.
7. the preparation method of a kind of aluminium alloy emulsion cutting fluid as described in any one of claim 1 ~ 6, is characterized in that: comprise the steps:
First, to weigh by weight each raw material; Secondly, water, gum turpentine and lanolin are joined in reaction vessel and is heated to 98 DEG C; Then add KORANTIN SH, polyacrylamide, emulsifying agent, triethylene glycol diacrylate, hexadecylene base succinic acid, nano-cerium oxide and fatty acid polyglycol ester successively, constantly stir; After thing to be mixed is cooled to room temperature again, respectively defoamer and nonionogenic tenside is added, constantly stir and get final product.
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN109589652A (en) * | 2018-12-19 | 2019-04-09 | 山东科鲁尔化学有限公司 | A kind of defoaming agent and preparation method thereof |
WO2024087293A1 (en) * | 2022-10-27 | 2024-05-02 | 中国机械总院集团海西(福建)分院有限公司 | Multi-working-condition adaptive fully synthetic cutting fluid and preparation method therefor |
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CN104762127A (en) * | 2015-03-18 | 2015-07-08 | 启东尤希路化学工业有限公司 | Nano aqueous completely-synthetic environmental-friendly metal working fluid |
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CN102029551A (en) * | 2010-11-18 | 2011-04-27 | 长沙理工大学 | Lubricating and cooling method for cutting process and device thereof |
CN103045335A (en) * | 2012-12-26 | 2013-04-17 | 奎克化学(中国)有限公司 | Water-based metal cutting fluid suitable for soft water |
CN104073328A (en) * | 2013-03-29 | 2014-10-01 | 上海德润宝特种润滑剂有限公司 | Microemulsion cutting fluid, cutting diluent and preparation and application methods of microemulsion cutting fluid |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109589652A (en) * | 2018-12-19 | 2019-04-09 | 山东科鲁尔化学有限公司 | A kind of defoaming agent and preparation method thereof |
WO2024087293A1 (en) * | 2022-10-27 | 2024-05-02 | 中国机械总院集团海西(福建)分院有限公司 | Multi-working-condition adaptive fully synthetic cutting fluid and preparation method therefor |
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