CN104674246A - Universal ultrahigh-pressure spraying and environmental-protection semi-aqueous cleaning agent for aluminum and iron - Google Patents
Universal ultrahigh-pressure spraying and environmental-protection semi-aqueous cleaning agent for aluminum and iron Download PDFInfo
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- CN104674246A CN104674246A CN201510117342.6A CN201510117342A CN104674246A CN 104674246 A CN104674246 A CN 104674246A CN 201510117342 A CN201510117342 A CN 201510117342A CN 104674246 A CN104674246 A CN 104674246A
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- agent
- cleaning
- aqueous cleaning
- acid
- aluminum
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- 229910052782 aluminium Inorganic materials 0.000 title claims abstract description 18
- 239000012459 cleaning agent Substances 0.000 title claims abstract description 17
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 title abstract description 10
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title abstract description 6
- 229910052742 iron Inorganic materials 0.000 title abstract description 5
- 238000005507 spraying Methods 0.000 title abstract 3
- 238000004140 cleaning Methods 0.000 claims abstract description 47
- 229910052751 metal Inorganic materials 0.000 claims abstract description 11
- 239000002184 metal Substances 0.000 claims abstract description 11
- 150000001412 amines Chemical class 0.000 claims abstract description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 8
- 238000005260 corrosion Methods 0.000 claims abstract description 7
- 230000007797 corrosion Effects 0.000 claims abstract description 7
- 239000003112 inhibitor Substances 0.000 claims abstract description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 13
- 239000007921 spray Substances 0.000 claims description 11
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims description 9
- 239000012752 auxiliary agent Substances 0.000 claims description 7
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 6
- -1 amine salt Chemical class 0.000 claims description 6
- 229960001484 edetic acid Drugs 0.000 claims description 6
- FBUKVWPVBMHYJY-UHFFFAOYSA-N nonanoic acid Chemical compound CCCCCCCCC(O)=O FBUKVWPVBMHYJY-UHFFFAOYSA-N 0.000 claims description 6
- 239000000839 emulsion Substances 0.000 claims description 5
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 4
- 239000012964 benzotriazole Substances 0.000 claims description 4
- IJKVHSBPTUYDLN-UHFFFAOYSA-N dihydroxy(oxo)silane Chemical compound O[Si](O)=O IJKVHSBPTUYDLN-UHFFFAOYSA-N 0.000 claims description 4
- 150000003016 phosphoric acids Chemical class 0.000 claims description 4
- 229920001296 polysiloxane Polymers 0.000 claims description 4
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 claims description 4
- 229960004418 trolamine Drugs 0.000 claims description 4
- HXKKHQJGJAFBHI-UHFFFAOYSA-N 1-aminopropan-2-ol Chemical compound CC(O)CN HXKKHQJGJAFBHI-UHFFFAOYSA-N 0.000 claims description 3
- SNTWKPAKVQFCCF-UHFFFAOYSA-N 2,3-dihydro-1h-triazole Chemical compound N1NC=CN1 SNTWKPAKVQFCCF-UHFFFAOYSA-N 0.000 claims description 3
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 3
- XBPCUCUWBYBCDP-UHFFFAOYSA-N Dicyclohexylamine Chemical compound C1CCCCC1NC1CCCCC1 XBPCUCUWBYBCDP-UHFFFAOYSA-N 0.000 claims description 3
- 239000003109 Disodium ethylene diamine tetraacetate Substances 0.000 claims description 3
- 125000000217 alkyl group Chemical group 0.000 claims description 3
- 150000008052 alkyl sulfonates Chemical class 0.000 claims description 3
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 3
- 150000001408 amides Chemical class 0.000 claims description 3
- 125000003354 benzotriazolyl group Chemical group N1N=NC2=C1C=CC=C2* 0.000 claims description 3
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 3
- 239000004327 boric acid Substances 0.000 claims description 3
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 3
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 3
- 235000019301 disodium ethylene diamine tetraacetate Nutrition 0.000 claims description 3
- 150000002019 disulfides Chemical class 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- 239000000194 fatty acid Substances 0.000 claims description 3
- 229930195729 fatty acid Natural products 0.000 claims description 3
- 150000004665 fatty acids Chemical class 0.000 claims description 3
- 150000002632 lipids Chemical class 0.000 claims description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 3
- 239000005077 polysulfide Substances 0.000 claims description 3
- 229920001021 polysulfide Polymers 0.000 claims description 3
- 150000008117 polysulfides Polymers 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- 150000004867 thiadiazoles Chemical class 0.000 claims description 3
- RYYWUUFWQRZTIU-UHFFFAOYSA-K thiophosphate Chemical compound [O-]P([O-])([O-])=S RYYWUUFWQRZTIU-UHFFFAOYSA-K 0.000 claims description 3
- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 6
- 229910000838 Al alloy Inorganic materials 0.000 abstract description 5
- 238000000034 method Methods 0.000 abstract description 5
- 230000000694 effects Effects 0.000 abstract description 4
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 abstract description 4
- 230000007613 environmental effect Effects 0.000 abstract description 3
- 229910001018 Cast iron Inorganic materials 0.000 abstract description 2
- 229910000831 Steel Inorganic materials 0.000 abstract description 2
- 230000008859 change Effects 0.000 abstract description 2
- 239000007769 metal material Substances 0.000 abstract description 2
- 239000010959 steel Substances 0.000 abstract description 2
- 239000004902 Softening Agent Substances 0.000 abstract 1
- 239000013556 antirust agent Substances 0.000 abstract 1
- 239000008233 hard water Substances 0.000 abstract 1
- 239000004094 surface-active agent Substances 0.000 abstract 1
- 239000002904 solvent Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 3
- 231100000111 LD50 Toxicity 0.000 description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- 239000005864 Sulphur Substances 0.000 description 3
- 239000013543 active substance Substances 0.000 description 3
- 239000004411 aluminium Substances 0.000 description 3
- 239000000460 chlorine Substances 0.000 description 3
- 229910052801 chlorine Inorganic materials 0.000 description 3
- 239000006260 foam Substances 0.000 description 3
- 230000036541 health Effects 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000003960 organic solvent Substances 0.000 description 3
- 239000011574 phosphorus Substances 0.000 description 3
- 229910052698 phosphorus Inorganic materials 0.000 description 3
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 230000035699 permeability Effects 0.000 description 2
- 231100000614 poison Toxicity 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- 230000009471 action Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 239000012847 fine chemical Substances 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 231100001261 hazardous Toxicity 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 229910017053 inorganic salt Inorganic materials 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 230000001473 noxious effect Effects 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 235000019633 pungent taste Nutrition 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 210000001533 respiratory mucosa Anatomy 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
Abstract
The invention discloses a universal ultrahigh-pressure spraying and environmental-protection semi-aqueous cleaning agent for aluminum and iron. The universal ultrahigh-pressure spraying and environmental protection type semi-aqueous cleaning agent is prepared from an antirust agent, organic amine, a metal corrosion inhibitor, a hard water softening agent, a pure water and other auxiliaries. The invention selects the design formula of a high-performance environmental-protection surfactant, the semi-aqueous cleaning agent is suitable for cleaning heavy greasy dirties of metal materials such as steel, cast iron and aluminum alloy (during cleaning the aluminum alloy, aluminum cannot change color and the universality is strong) and has good double effects of cleaning and an rust protection (the cleaning rate is equal to or greater than 98 percent, and the rust protection effect can be maintained equal to or greater than 12 hours). The rust protection process after cleaning can be omitted, the production cost is reduced, and the production efficiency is improved.
Description
Technical field
The present invention relates to a kind of ferro-aluminum clean-out system, be applied in the industries such as all iron aluminium processing the cleaning of metal parts and rust prevention during manufacture.
Background technology
Along with the development of cleaning technique, current industry cleaning link has penetrated into nearly all industrial circle such as machinery, textile printing and dyeing, petrochemical complex, electronic semi-conductor, biology, optics, and market capacity is huge.According to cleanup action principle, industry cleaning link technology roughly can be divided into matting, physical cleaning and differential thing and clean three kinds.Wherein chemical cleaning technique history at most, most species, at present application be also the most extensive.According to the water content of chemical, organic cleaning solvent, aqueous cleaning agent and semi-aqueous cleaning agent three types can be divided into again.
The outstanding advantages of organic cleaning solvent is that counterweight greasy dirt cleaning force is strong, and cleaning efficiency is high, good to matrix wetting permeability, but also there is great drawback: one is that flash-point is low, inflammable, has potential safety hazard; Two is that organic solvent is volatile, not only pollutes air, has again fat-soluble (containing poisonous and harmful elements such as phosphorus, chlorine, sulphur in lipid-soluble substance, affecting HUMAN HEALTH).Therefore along with the brute force of pro-environmental society advances, organic cleaning solvent is not more and more had an optimistic view of by market.The aqueous cleaning agent mineral alkali that mainly some alkalescence are stronger or inorganic salt (as sodium hydroxide, sodium carbonate, silicate, phosphoric acid salt etc.), due to the single alkalescence of composition strong (strong to human body skin pungency), cleaning is simple, and cleaning foam is many, range of application is narrow, has applied few at present.At present with fastest developing speed, apply maximum be based on tensio-active agent, add the composite aqueous cleaning agent of multiple auxiliary chemicals.But compared with organic cleaning solvent, aqueous cleaning agent stability will differ from, emulsification penetrating power in some conditions can change, cleaning performance also can be involved, so need when cleaning to ensure that cleaning condition is suitable for, cleaning performance can be improved in addition under the condition heated a little, but cleaning is comparatively complicated, need to carry out many more manipulations, cleaning performance is also slightly poorer than organic solvent.Semi-aqueous cleaning agent, is exactly add water and tensio-active agent and other auxiliary agent in organic solvent, is also referred to as milk sap clean-out system or micro-shape emulsion clean-out system.Compared with solvent cleaner, the cleaning performance of semi-aqueous cleaning agent counterweight greasy dirt, the wetting permeability of matrix can be not a halfpenny the worse, but also expanded the cleansing power in inorganic foulants.Simultaneously adding due to water, improve the flash-point of clean-out system, reduce volatility, enhance security, its range of application is also wider.Due to technique, the reason such as backward in technique, semi-aqueous cleaning agent performance quality commercially available is at present also unsatisfactory, and some problems demand solve.One is the cleaning poor universality (as fine during cleaning iron material matter, but then occurring variable color when cleaning aluminium material, affecting board surface quality) to iron, aluminum alloy material, rust-proof effect bad (also will increase antirust operation together after cleaning, increase production cost); Two is high pressure (100Kgf/cm
2above) produce a large amount of foam during cleaning showers, the operation of impact cleaning; Three is the hazardous and noxious substances generally affecting environmental safety and HUMAN HEALTH in formula containing phosphorus, chlorine, sulphur etc.
Summary of the invention
The object of the present invention is to provide a kind of cleaning performance good, working efficiency is high, the ferro-aluminum general ultra-high voltage spray environment-friendly type semi-aqueous cleaning agent of safety and sanitation.
Technical solution of the present invention is:
The agent of a kind of ferro-aluminum general ultra-high voltage spray environment-friendly type semi-aqueous cleaning, is characterized in that: be grouped into by the one-tenth of following weight percents:
Rust-preventive agent ... 0.1 ~ 10%
Organic amine ... ..5 ~ 20%
Metal corrosion inhibitor ... 0.1 ~ 3%
Ethylene Diaminetetra Acetic Acid ... 0.1 ~ 0.5%
Pure water ... 20 ~ 75%
Other auxiliary agent ... 1 ~ 15%
Above-mentioned each amounts of components sum is 100%.
Rust-preventive agent is one or more in lipid acid, fatty acid metal salt, alkylsulfonate, amine, amine salt, acid amides, ester class, phosphoric acid salt, thiophosphate.
Organic amine is one or more in Monoethanolamine MEA BASF, diethanolamine, trolamine, α-amino isopropyl alcohol, dicyclohexyl amine.
Metal corrosion inhibitor is benzotriazole, methyl benzotriazazole, 1H-1, one or more in 2,4-triazole, thiadiazoles polysulfide, alkyl curing benzoglyoxaline ketone, dialkyl disulfides phosphoric acid zinc salt.
Ethylene Diaminetetra Acetic Acid is one or more in disodium ethylene diamine tetraacetate, tetrasodium ethylenediamine tetraacetate.
Other auxiliary agents are one or more in silicone emulsion, sad, n-nonanoic acid, bay diacid, hexanodioic acid, boric acid, phosphoric acid, metasilicic acid.
The present invention selects high-performance environment protection type tensio-active agent component design, the heavy oil dirt cleaning that product is applicable to the metal materials such as steel, cast iron, aluminium alloy (does not produce aluminium variable color in cleaning aluminum alloy material yet, highly versatile), there is double effects (cleaning rate >=98% of excellent cleaning and rust-preventing characteristic, rust-preventing characteristic >=12 hour), the antirust operation after cleaning can be saved, reduce production cost, enhance productivity.
Add the additive compounds such as high-quality organosilicon, product is at 50 ~ 150kgf/cm
2cleaning showers under pressure (i.e. ultra-high voltage) operating mode, equal non-foam produces, and is suitable for cleaning pressure scope wide.
Formula material all selects biology can high, harmless to the human and environment alternative raw material (not using the toxic substances such as phosphorus, chlorine, sulphur) of degree of falling, product biological Lethal Dose 50 LD50>=5000mg/kg, toxic limit medium dose LC50>=5000mg/m
3, respiratory mucosa stimulates≤1 grade, and safety and sanitation quality is high.
This Project-developing, to the high quality, the greenization level that improve China's semi-aqueous cleaning agent, realizes " developing high-end fine chemical product; improve green manufacturing level " goal task that country proposes; protection of the environment safety and HUMAN HEALTH, development low-carbon (LC), green economy, significant.
Below in conjunction with embodiment, the invention will be further described.
Embodiment
Embodiment 1:
By the component mix and blend of following weight percents, obtain the agent of ferro-aluminum general ultra-high voltage spray environment-friendly type semi-aqueous cleaning:
SA 10%
Trolamine 17%
Benzotriazole 0.5%
Tetrasodium ethylenediamine tetraacetate 0.5%
Pure water 70%
Silicone emulsion 2%.
Embodiment 2:
The agent of a kind of ferro-aluminum general ultra-high voltage spray environment-friendly type semi-aqueous cleaning, is characterized in that: be grouped into by the one-tenth of following weight percents:
Rust-preventive agent ... 0.1 ~ 10%(example 0.1%, 5%, 10%)
Organic amine ... ..5 ~ 20%(example 5%, 10%, 20%)
Metal corrosion inhibitor ... 0.1 ~ 3%(example 0.1%, 1%, 3%)
Ethylene Diaminetetra Acetic Acid ... 0.1 ~ 0.5%(example 0.1%, 0.3%, 0.5%)
Pure water ... 20 ~ 75%(example 20%, 50%, 75%)
Other auxiliary agent ... 1 ~ 15%(example 1%, 5%, 15%)
Above-mentioned each amounts of components sum is 100%.
Rust-preventive agent is one or more in lipid acid, fatty acid metal salt, alkylsulfonate, amine, amine salt, acid amides, ester class, phosphoric acid salt, thiophosphate.
Organic amine is one or more in Monoethanolamine MEA BASF, diethanolamine, trolamine, α-amino isopropyl alcohol, dicyclohexyl amine.
Metal corrosion inhibitor is benzotriazole, methyl benzotriazazole, 1H-1, one or more in 2,4-triazole, thiadiazoles polysulfide, alkyl curing benzoglyoxaline ketone, dialkyl disulfides phosphoric acid zinc salt.
Ethylene Diaminetetra Acetic Acid is one or more in disodium ethylene diamine tetraacetate, tetrasodium ethylenediamine tetraacetate.
Other auxiliary agents are one or more in silicone emulsion, sad, n-nonanoic acid, bay diacid, hexanodioic acid, boric acid, phosphoric acid, metasilicic acid.
Claims (6)
1. a ferro-aluminum general ultra-high voltage spray environment-friendly type semi-aqueous cleaning agent, is characterized in that: be grouped into by the one-tenth of following weight percents:
Rust-preventive agent ... 0.1 ~ 10%
Organic amine ... ..5 ~ 20%
Metal corrosion inhibitor ... 0.1 ~ 3%
Ethylene Diaminetetra Acetic Acid ... 0.1 ~ 0.5%
Pure water ... 20 ~ 75%
Other auxiliary agent ... 1 ~ 15%
Above-mentioned each amounts of components sum is 100%.
2. the agent of ferro-aluminum according to claim 1 general ultra-high voltage spray environment-friendly type semi-aqueous cleaning, is characterized in that: rust-preventive agent is one or more in lipid acid, fatty acid metal salt, alkylsulfonate, amine, amine salt, acid amides, ester class, phosphoric acid salt, thiophosphate.
3. the agent of ferro-aluminum according to claim 1 general ultra-high voltage spray environment-friendly type semi-aqueous cleaning, is characterized in that: organic amine is one or more in Monoethanolamine MEA BASF, diethanolamine, trolamine, α-amino isopropyl alcohol, dicyclohexyl amine.
4. ferro-aluminum according to claim 1 general ultra-high voltage spray environment-friendly type semi-aqueous cleaning agent, it is characterized in that: metal corrosion inhibitor is benzotriazole, methyl benzotriazazole, 1H-1, one or more in 2,4-triazole, thiadiazoles polysulfide, alkyl curing benzoglyoxaline ketone, dialkyl disulfides phosphoric acid zinc salt.
5. the agent of ferro-aluminum according to claim 1 general ultra-high voltage spray environment-friendly type semi-aqueous cleaning, is characterized in that: Ethylene Diaminetetra Acetic Acid is one or more in disodium ethylene diamine tetraacetate, tetrasodium ethylenediamine tetraacetate.
6. ferro-aluminum according to claim 1 general ultra-high voltage spray environment-friendly type semi-aqueous cleaning agent, is characterized in that: other auxiliary agents are one or more in silicone emulsion, sad, n-nonanoic acid, bay diacid, hexanodioic acid, boric acid, phosphoric acid, metasilicic acid.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510117342.6A CN104674246A (en) | 2015-03-18 | 2015-03-18 | Universal ultrahigh-pressure spraying and environmental-protection semi-aqueous cleaning agent for aluminum and iron |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510117342.6A CN104674246A (en) | 2015-03-18 | 2015-03-18 | Universal ultrahigh-pressure spraying and environmental-protection semi-aqueous cleaning agent for aluminum and iron |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104674246A true CN104674246A (en) | 2015-06-03 |
Family
ID=53309811
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510117342.6A Pending CN104674246A (en) | 2015-03-18 | 2015-03-18 | Universal ultrahigh-pressure spraying and environmental-protection semi-aqueous cleaning agent for aluminum and iron |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104674246A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108384668A (en) * | 2018-04-25 | 2018-08-10 | 上海尤希路化学工业有限公司 | High magnification dilution, the special-purpose aqueous cleaning agent of 50MPa ultra-high pressure numerical control cleaning centers |
| CN109385638A (en) * | 2018-12-29 | 2019-02-26 | 天津市顺超有限公司 | A kind of alulotion and its preparation and application |
| CN112226774A (en) * | 2020-08-28 | 2021-01-15 | 余姚市永林机械科技有限公司 | Hot galvanizing pretreatment liquid and preparation method and application thereof |
| CN115058716A (en) * | 2022-06-30 | 2022-09-16 | 南京科润新材料技术有限公司 | Neutral water-based metal cleaning solution |
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| CN102002722A (en) * | 2009-08-28 | 2011-04-06 | 比亚迪股份有限公司 | Stainless steel cleaner and stainless steel cleaning method |
| CN103046066A (en) * | 2013-01-08 | 2013-04-17 | 上海尤希路化学工业有限公司 | High-performance and environment-friendly water-based cleaning agent |
| CN104388955A (en) * | 2014-11-13 | 2015-03-04 | 无锡伊佩克科技有限公司 | Water-based cleaning agent for magnesium aluminum alloy and preparation method of water-based cleaning agent |
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1493713A (en) * | 2002-10-28 | 2004-05-05 | 启东尤希路化学工业有限公司 | Wet Levelling liquid |
| CN102002722A (en) * | 2009-08-28 | 2011-04-06 | 比亚迪股份有限公司 | Stainless steel cleaner and stainless steel cleaning method |
| CN103046066A (en) * | 2013-01-08 | 2013-04-17 | 上海尤希路化学工业有限公司 | High-performance and environment-friendly water-based cleaning agent |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108384668A (en) * | 2018-04-25 | 2018-08-10 | 上海尤希路化学工业有限公司 | High magnification dilution, the special-purpose aqueous cleaning agent of 50MPa ultra-high pressure numerical control cleaning centers |
| CN109385638A (en) * | 2018-12-29 | 2019-02-26 | 天津市顺超有限公司 | A kind of alulotion and its preparation and application |
| CN112226774A (en) * | 2020-08-28 | 2021-01-15 | 余姚市永林机械科技有限公司 | Hot galvanizing pretreatment liquid and preparation method and application thereof |
| CN115058716A (en) * | 2022-06-30 | 2022-09-16 | 南京科润新材料技术有限公司 | Neutral water-based metal cleaning solution |
| CN115058716B (en) * | 2022-06-30 | 2023-09-08 | 南京科润新材料技术有限公司 | Neutral water-based metal cleaning solution |
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Application publication date: 20150603 |